Honeycomb Hole Research Articles

Microwave drying coupled with convective air and steam for efficient dehydration of extruded zeolite honeycomb monolith

Zeolite honeycomb monoliths (ZHMs) as key adsorbents or catalysts are widely applied in industries, for which, however, the popularization is limited by its low production efficiency due to the long and careful drying process of the fragile ZHMs green body. Here we address this challenge by developing a microwave drying strategy coupled with convective air and steam. The individual microwave, microwave-air, and microwave-air-steam drying characteristics on the honeycomb and slab monoliths of 13X zeolite were systematically studied, and the drying quality-microwave power/air temperature/humidity relationship was correlated. The results showed that microwave achieves rapid dehydration of ZHMs, eliminating 29.94 % relative mass of water within only 660 s. However, the uncontrollable microwave adsorbing inhomogeneity and thermal accumulation over the hydrophilic ZHM resulted in overburning, cracking and deformation issues. Introducing convective air at room temperature eliminates overburning and cracking phenomena, and after coupled with 110 g/m3 steam, the irregular deformation of ZHMs was further mitigated (shrinkage rate reduced from 2.10 % to 1.11 %) with even increased drying efficiency by 4.47 %. The advantageous mechanism of microwave-air-steam coupling drying was revealed as the combined effect of the heat and mass transfer through the honeycomb hole enhanced by convective air and the heating and dehydration homogeneity improved by uniform microwave absorbing on surface-condensable steam. The efficacy of the optimized drying strategy was demonstrated by significantly shortened time for scale-up production of 1 m3 ZHMs from nearly 1 month to 2 days. This work affords new insights for improving production efficiency of high-quality ZHMs and presents microwave-air-steam drying process as a platform to advancing structured material preparation.

Investigation of the radiated emission of honeycomb structured aluminum foam/cellular heatsinks at 1–10 GHz

Metal foams or cellular structures like honeycombs, can also be evaluated according to mechanical, acoustic, thermal, and chemical resistance parameters in terms of functionality. However, it is vital to investigate the performance of these cellular structures' radiated emission (RE), which can be used as PCB heatsinks. In this study, the radiated emission (RE) performance of honeycomb-structured aluminum foam (or cellular) heatsinks (AFH), which can be considered as unidirectional regular foam, is examined in the frequency range of 1–10 GHz as a novelty. Also, the effect of four primary variables (the geometry of AFH, honeycomb hole direction, honeycomb cell size, and honeycomb cell wall thickness) on the RE performance of AFH is investigated. Unlike classical honeycomb production methods, the investment flask mold casting (loss wax) method is preferred due to the complex offset strip geometry of designed honeycombs. The original design offset hexagonal honeycomb structures were successfully produced using this investment casting method with additive manufacturing technologies from molten metal. While all simulations are carried out using CST Studio Suite, the RE performance of the proposed AFHs is measured in a standard 3 m fully anechoic chamber using a reference horn antenna and vector network analyzer (VNA). When the results are examined, the measured and simulated results agree with each other quietly. Regarding RE, structures with a CPI value of 14 are better at low frequencies, while structures with a CPI value of 3.5 are better at high frequencies. Secondly, the honeycomb cell thickness value does not significantly affect EMI performance. Lastly, although there is no significant difference in EMI in the low-frequency region, it is better to use a directional structure with vertical holes in the high-frequency region. As a result, in the design of AFH, the RE performances of the heatsinks and their thermal performance should be considered.

Evidence for electron-hole crystals in a Mott insulator.

The coexistence of correlated electron and hole crystals enables the realization of quantum excitonic states, capable of hosting counterflow superfluidity and topological orders with long-range quantum entanglement. Here we report evidence for imbalanced electron-hole crystals in a doped Mott insulator, namely, α-RuCl3, through gate-tunable non-invasive van der Waals doping from graphene. Real-space imaging via scanning tunnelling microscopy reveals two distinct charge orderings at the lower and upper Hubbard band energies, whose origin is attributed to the correlation-driven honeycomb hole crystal composed of hole-rich Ru sites and rotational-symmetry-breaking paired electron crystal composed of electron-rich Ru-Ru bonds, respectively. Moreover, a gate-induced transition of electron-hole crystals is directly visualized, further corroborating their nature as correlation-driven charge crystals. The realization and atom-resolved visualization of imbalanced electron-hole crystals in a doped Mott insulator opens new doors in the search for correlated bosonic states within strongly correlated materials.

Study on Bending Performance of Tightly Spliced Truss-Reinforced Plate-Honeycomb Flat Beam

The tightly spliced truss-reinforced plate-honeycomb flat beam is a novel type of composite beam, with the advantages of high rigidity, high bearing capacity, and ease of construction. In this study, on the basis of the performance in bending tests, the numerical analysis method is used to study the influence of the honeycomb hole–height ratio, and section height on the bearing capacity of the honeycomb composite flat beam. On this basis, the simplified method to calculate the ultimate bending capacity of the new honeycomb composite flat beam was proposed. The research results show the failure modes of the specimens are mainly divided into two states, including the deflection exceeding the limit and the concrete flange plate separating from the steel beam. The tightly spliced truss-reinforced plate-honeycomb flat beams have good ductility, of which the average value reaches 8.2. The simplified method proposed in this article for calculating this type of honeycomb composite beam has an error of less than 10% in terms of bending bearing capacity, which has advantages over the double T-shaped steel method. The calculation method and design suggestions proposed in this study provide a basis for the research and application of this type of composite flat beam.

Natural convection characteristics of honeycomb fin with different hole cells for battery phase-change material cooling systems

As a nature production the lightweight honeycomb is used as a fin to increase the contact area with the PCM and improve its overall thermal conductivity. In this paper the effects of different honeycomb core shapes, sizes, and arrangements on melting under natural convection were investigated to determine the optimal honeycomb cell parameters. In this study, transient simulations based on VOF and enthalpy-porosity methods are developed, and the results show that compared with heat conduction, the melting time under natural convection conditions can be reduced. By analyzing different shapes, it is discovered that the melting effects of triangles, trapezoids, rectangles, and rhombuses are better than that of hexagons, the triangular melting time is reduced by 23.1%. The orthogonal experiments show that the ranking order of the effects on melting time and natural convection is Ra > Shape > LHR. Furthermore, the optimal honeycomb hole core parameters are obtained from the analysis of a single factor. Compared with the hexagonal honeycomb fin, a battery's PCM with an optimal triangular honeycomb fin under natural convection exhibits a 23.3% increase in terms of temperature decrease.

Self-assembly of superstructures at all scales

Summary Controllable assembly of molecular and nanoscale building blocks into uniform superstructures up to bulk dimensions remains a key challenge in the next phase of nanotechnology development. Here, we report the self-assembly of superstructures at all scales by taking advantage of the partial miscibility of water and 1-butanol to generate transient aqueous emulsion droplets that can encapsulate the target materials and introduce them into template holes. Further diffusion of water into 1-butanol depletes the emulsion droplets, assembling the building blocks into one well-defined superstructure in each hole. Superstructuring of various types and shapes of nanoparticles, biomolecules, and inorganic compounds could be achieved without the need for surfactants and chemical modifications. The versatility, scalability, low-cost, and accurate positioning are crucial advantages for the future development of advanced precision manufacturing.

Self-Assembled GO Honeycomb Microarray for Selective Cancer Cell Capture and Single Cell Analysis of Proteolytic Expression.

Proteolytic enzymes expressed by circulating tumor cells are proved to facilitate their invasion into multiple organs via cleaving natural ECM networks, leading to consequent metastasis colonization and malignant lethality. Recent evidence suggests the rare metastasis initiating cells with higher proteolytic levels among circulating tumor cells (CTCs) may strongly increase the risk of metastasis. Beyond selective CTC capture, the heterogeneity in proteases expression provides a promising indicator for metastasis happening. To this end, the graphene oxide (GO) honeycomb microarray with single CTC matched sizes is fabricated via the self-assembly breath figure approach, which serves as an integrated protocol for selective CTC capture and single-cell analysis of protease activity. Contributing to synergistic effects of structure and chemistry, CTCs can be efficiently isolated and individually trapped in each honeycomb hole. Meanwhile, the crosstalk among CTCs can be erased by blocking direct cell-to-cell contact, which offers promising potentials in the single-cell analysis of protease expression. Integrating specific capture and in situ analysis of single CTCs on GO micropatterned surface is of significant importance in various biological and clinical applications such as cancer diagnostics and cancer therapeutic evaluation.

Unsymmetrical Alveolate PMMA/MWCNT Film as a Piezoresistive E-Skin with Four-Dimensional Resolution and Application for Detecting Motion Direction and Airflow Rate.

Flexible and piezoresistive electronic skins (E-skins) with high spatial resolution are highly desired in artificial intelligence and human-machine interactions. In this study, a simple method is developed to pattern a piezoresistive layer using lithography, which can realize real-time tactile sensing and spatial resolution. The piezoresistive layer with a honeycomb hole array based on polymethyl methacrylate (PMMA)/multiwalled carbon nanotubes (MWCNTs) was fabricated using a reverse mold with a ZnO nanorod array. The device exhibits an ultrahigh sensitivity of 88 kPa-1 in the low-pressure regime (<10 kPa) and a fast response time of 110 ms owing to the conductive honeycomb structure. The E-skin-based PMMA/MWCNT honeycomb array film can be applied to monitor bending and vibration by changing the contact area of the hole walls. A 4 × 4 piezoresistive matrix was fabricated by lithography for a 16-pixel tactile-sensing E-skin, which realizes a four-dimensional resolution including the space and time resolutions of pressure points. In addition, by using the unsymmetrical structure of an alveolate PMMA/MWCNT film, the detection of direction and velocity for the movement and gas flow were realized. The obtained piezoresistive and unsymmetrical tactile sensor realized a four-dimensional resolution, including a three-dimensional space and a fourth dimension of timeline, which enables future applications of human-machine interactions.

Effects of a porous honeycomb structure on critical heat flux in downward-facing saturated pool boiling

In this study, the effect of a porous honeycomb structure on downward-facing pool boiling was investigated. The effects of hole diameter and the hole–area ratio of a porous honeycomb plate were investigated to determine which honeycomb structure had an optimal effect on critical heat flux (CHF). Through images acquired by a high-speed camera, it was observed that bubbles generated on the honeycomb surface were large and difficult to coalesce. Compared with a bare surface, a heated surface with a porous honeycomb structure has a higher CHF. Within the experimental range, CHF is dependent on the hole–area ratio, not the diameter of the honeycomb hole. There exists a turning point for CHF enhancement with hole–area ratio, demonstrated by both experimental data and a model, considering water supply and bubble removal ability. Maximum CHF can be obtained with a hole–area ratio of 0.4 and a CHF enhancement ratio of approximately 2.3-fold. Capillary theory for downward-facing can explain the experimental results obtained. The results are essential for determining the optimal performance of the porous honeycomb structure.

Experimental characterisation of the bound acoustic surface modes supported by honeycomb and hexagonal hole arrays

The Dirac point and associated linear dispersion exhibited in the band structure of bound (non-radiative) acoustic surface modes supported on a honeycomb array of holes is explored. An aluminium plate with a honeycomb lattice of periodic sub-wavelength perforations is characterised by local pressure field measurements above the sample surface to obtain the full band-structure of bound modes. The local pressure fields of the bound modes at the K and M symmetry points are imaged, and the losses at frequencies near the Dirac frequency are shown to increase monotonically as the mode travels through the K point at the Dirac frequency on the honeycomb lattice. Results are contrasted with those from a simple hexagonal array of similar holes, and both experimentally obtained dispersion relations are shown to agree well with the predictions of a numerical model.

Counterpropagating topological interface states in graphene patchwork structures with regular arrays of nanoholes

Triangular and honeycomb lattices are dual to each other -- if we puncture holes into a featureless plane in a regular triangular alignment, the remaining body looks like a honeycomb lattice, and vice versa, if the holes are in a regular honeycomb alignment, the remaining body has a feature of triangular lattice. In this work, we reveal that the electronic states in graphene sheets with nano-sized holes in triangular and honeycomb alignments are also dual to each other in a topological sense. Namely, a regular hole array perforated in graphene can open a band gap in the energy-momentum dispersion of relativistic electrons in the pristine graphene, and the insulating states induced by triangular and honeycomb hole arrays are distinct in topology. In a graphene patchwork with regions of these two hole arrays put side by side counterpropagating topological currents emerge at the domain wall. This observation indicates that the cerebrated atomically thin sheet is where topological physics and nanotechnology meet.

Short-Term Deposition of PM2.5 Particles on Contact Lens Surfaces: Effect on Oxygen Permeability and Refractive Index

ABSTRACTPurposes: To identify the deposition of fine (≤2.5 μm diameter) particulate matter (PM) particles (PM2.5) on contact lens surfaces and to investigate the effects of such deposition on the oxygen permeability (OP) and refractive index (RI) of contact lenses.Methods: A total of 36 contact lenses, including rigid gas permeable (RGP) lens and soft contact lens (SCL), were investigated. RGP lens (n=12) and SCL (n=12) (experimental group) were incubated in a PM2.5 solution for 24 h, after which PM2.5-treated RGP lens (n=6) and SCL (n=6) were further washed for 1 h in phosphate-buffered saline (PBS). All lenses were examined by field emission scanning electron microscopy. OP and RI of all lenses were measured.Results: Average-sized PM2.5 particles deposited on RGP contact lens and SCL surfaces after immersion in the PM2.5 solution were 3.192 ± 1.637 and 2.158 ± 1.187/100 μm2, respectively. On RGP lens surfaces, we observed both large (≥2.5 µm diameter) and small (PM2.5) particles. PM2.5 particles were deposited in diffuse patterns, primarily along the honeycomb structural border of SCL, while no PM2.5 particles were found in the honeycomb hole of SCL surfaces. Washing in PBS removed the larger PM particles from RGP lens surfaces, but left copious amounts of PM2.5 particles. In contrast, nearly all PM particles were removed from SCL surfaces after PBS washing. OP values of RGP lens and SCL appeared to be unchanged by PM2.5 deposition. RI values increased in both RGP lens and SCL groups after PM2.5 deposition. However, these increases were not statistically significant, suggesting that PM2.5 deposition itself does not cause fluctuations in contact lens RI.Conclusions: Deposition of PM2.5 particles on contact lens surfaces varies according to lens material. PM2.5 particles deposited on SCL, but only large particles on RGP surfaces were able to be removed by washing in PBS and did not appear to alter OP and RI of either lens type.

Improved metal assisted chemical etching method for uniform, vertical and deep silicon structure

This paper presents a preliminary result about ultra-deep etched microstructures on 〈1 0 0〉 silicon wafer based on metal assisted chemical etching (MaCE). Honeycomb hole arrays with 50 µm width were successfully etched, as deep as 280 µm. The porous defects on the patterned surface and the lateral etching on the sidewall were effectively suppressed by optimizing the etchant solution. The results in this paper indicate that 〈1 0 0〉 silicon can be etched vertically with smooth sidewalls by an etchant solution containing ethanol, instead of the conventional aqueous-based solution. This improved method of MaCE has potential application in large-scale Si etching as a supplementary method to the expensive and complicated dry etching method.

Development of Scallop Cut Type Damper Seal for Centrifugal Compressors

This paper deals with a new type of damper seal developed for a high-pressure centrifugal compressor. Honeycomb seals and hole pattern seals are popularly used as damper seals and provide superior rotordynamic damping characteristics. Honeycomb seals are expensive because the manufacturing process is complex. Hole pattern seals are easier to manufacture, but they are still expensive. Use of a scallop pattern is one way to reduce manufacturing cost and time. A new seal that has a scallop pattern and small teeth on the stator surface is proposed. This pattern is cut on the stator surface using a disk type tool. To estimate the rotordynamic coefficients of this new seal, a bulk flow model code that is based on a two-control-volume model developed by Matsuda for labyrinth seals was newly developed. This model uses the Hirs model for the viscous shear stresses. The friction factor coefficients for the rotor surface, the stator surface, and the surface between the two-control-volumes were determined by computational fluid dynamics (CFD) steady analysis. The rotordynamic coefficients can also be obtained by using CFD perturbation analysis. The high accuracy of the bulk flow model was demonstrated by comparing its results with CFD perturbation analysis results. In the perturbation analysis, the whirling motion was treated as a steady-state problem by using a rotating frame of reference. For the damper seal, the rotor surface and its neighboring region were treated with a rotating frame of reference and the neighboring region of the stator was treated with a stationary frame of reference. The damping property of the new seal was evaluated by conducting rotor stability tests using a high-pressure compressor with an electromagnetic exciter. The new seal equipped with swirl brakes was used for the balance piston of the compressor. Stability was evaluated by exciting the rotor during operation and identifying the eigenvalues of the rotor. The experimental results showed that the new seal increases damping. Comparison of the damping effect with calculations based on the bulk flow analysis showed good agreement.

Non-tumor mast cells cultured in vitro on a honeycomb-like structured film proliferate with multinucleated formation

Mast cells are released from bone marrow into the circulatory system as immature precursors and differentiate upon their arrival at diverse organs and tissues. Because mast cell functions can be altered in these tissues, we propose that mast cells are sensitive to their surrounding microenvironment. To examine the morphological responses of mast cells, we cultured a proliferative mouse non-tumor cell line of mast cells (NCL-2 cells) on a honeycomb-like structured polystyrene film (HCF) representing a microenvironmental scaffold. In this study, the NCL-2 cells cultured on the HCF proliferated without apoptosis. Furthermore, NCL-2 cells cultured on 3- and 5-μm HCFs exhibited multinuclear formation. These observations of different NCL-2 cell morphologies and proliferation rates on HCF scaffolds with different hole sizes suggest that mast cells undertake specific proliferative shapes depending on the surrounding microenviroment. Moreover, HCFs may lead to the regulation of mast cell differentiation. From the Clinical EditorThis team reports on the development of a honeycomb-like structured film to study mast cell differentiation of non-cancerous origin, demonstrating that different microenvironments provided by different honeycomb hole sizes determine the morphology of the differentiated cells.

ANALYSIS OF THE STRUCTURAL PERFORMANCE AND STRETCHING PROCESS OF THE HONEYCOMB PAPER CORE

Honeycomb paper core stretching is an important process in paper core manufacture because the performance and the quality of paperboard are greatly enhanced when the honeycomb hole is stretched to a regular hexagon structure. In view of the above, first the finite element method is used to compare the mechanical performances of honeycomb paperboards of different aperture ratios, and the aperture ratio, which has an important influence on the performance of the honeycomb paper, is explained. Next, a paper core stretching simulation is carried out by means of the dynamic software; thus the variation trend of the stretching force, the stretching speed, and the lateral shrinkage needed in paper core manufacture of different specifications can be obtained. This research can provide useful instruction in the actual manufacture of honeycomb paper core.

Polymer‐Relief Microstructures by Inkjet Etching

Polymer microstructures are prepared by inkjet etching. By varying the distance between the printed solvent droplets, rectangular and honeycomb hole arrays like those shown in the figure are formed. These holes can act as reservoirs for other inkjet-printed materials, such as quantum dots. The technique holds promise for rapid- prototyping applications and microarray fabrication.

Temperature dependence of vortex configuration by honeycomb hole arrays in a superconducting Nb film

A honeycomb array of submicrometer holes in a Nb superconducting thin film has been fabricated to investigate the flux pinning effect. It is found that the minima positions reveal two regimes characterized by the matching fields and the fractional ones. It is believed that the complex behavior may come from more than one vortex being captured per pinning site. Furthermore, the temperature dependence of the saturation number of vortices per pinning site together with vortex-vortex interaction gives the complex vortex configurations.

A laboratory scale moulding technique to fabricate high precision 2D columnar and honeycomb structures

Two-dimensional columnar structures as well as honeycomb hole structures for electromagnetic bandgap (EBG) applications in the microwave range are generated by vacuum moulding of a specially designed wax feedstock of high alumina loadings into a polyethylene wax mould. Its counterpart, honeycomb hole structures, are produced by usage of silicone rubber moulds. The structured ceramic parts with an aspect ratio of about 4 show an Archimedes-type density of about 97.0%. Damages on the sample's structures that could occur during demoulding/debinding were minimized by the adjustment of the mould material to the feedstock system, the implementation of a suitable moulding technique and an optimisation of the thermal wax burnout process. The processing technique describes a route to obtain ceramic structures of high precision with a minimum of technical requirements.

Mesoscopic patterning of cell adhesive substrates as novel biofunctional interfaces

In this report, cell adhesion to honeycomb-patterned films is described with respect to the dimensions of the honeycomb structure. The honeycomb-patterned films can be fabricated by casting a dilute solution of amphiphilic polymers on solid substrates. The honeycomb structure is not homogeneous in all dimensions. Analysis of distribution of the honeycomb hole sizes demonstrates a gradual decrease in honeycomb hole diameter along the radius of the cast area. The largest holes were located near geometric center of the cast area. The diameter of the largest honeycomb holes in the cast area could be controlled by varying the cast volume of the polymer solution. Cell cultures on the honeycomb films demonstrated that cell adhesion could be inhibited at the outer region of the cast area. The extent of the inhibition of cell adhesion was influenced by the chemical properties of the polymers constituting the honeycomb films.