Properties of rapid heating, quenching, and transformation (RHQT)‐treated powder‐in‐tube (PIT) Nb3Al1−xSnx wires are studied herein. After the RHQ process, the body‐centered cubic (bcc) phase is formed in the Sn‐doped Nb3Al wires. The transformed superconducting A15 phase shows a uniform microstructure and homogenous component distribution feature. With the increase of the Sn doping level, the critical transition temperature (Tc), critical current density (Jc), and irreversibility field (Birr) of the superconducting wires increase first and then reduce, achieving the highest Tc value of 17.6 K and the smallest ΔTc of 0.6 K in the 4% Sn doped Nb3Al wire. The 4% Sn addition helps to improve the layer Jc of the sample to 2.1 × 105 A cm−2 at 8 K and 5 T, which is about 2.5 times that of the pure Nb3Al sample. Furthermore, the Nb3Al1−xSnx (x = 0.04) wire gives the highest Birr value of 17.22, 13.23, and 9.11 T at 8, 10, and 12 K, respectively. The addition of Sn helps to achieve stoichiometric Nb3Al A15 phase and formation of precipitations with the size of 10 nm, which might act as the flux‐pinning center.