Recent Record Research Articles

Comment on Souza and Perez Filho (2019) “Late Holocene coastal dynamics, climate pulses and low terraces in the coast of the state of São Paulo, southeast Brazil”

Souza and Perez Filho (2019) inferred two transgressive events in the Late Holocene record of lower Ribeira de Iguape River and Ilha Comprida barrier, Southeastern Brazil, based on luminescence ages and paleoenvironmental interpretation of four columnar sections. In the present paper, we discuss inconsistencies on the methods applied and sample design adopted by those authors, which lead to an incorrect model of coastline evolution for the region over the time period covered by the dates obtained. The dataset presented by Souza and Perez Filho (2019) allows the reinterpretation of the deposits studied as regressive and fits into previous models of regional coastal evolution.

Green Sahara tipping points in transient climate model simulations of the Holocene

The ‘Greening’ and subsequent desertification of the Sahara during the early to mid-Holocene is a dramatic example of natural climate change. We analyse a suite of simulations with a newly palaeo-conditioned configuration of the HadCM3 coupled model that is able to capture an abrupt desertification of North Africa during this time. We find that this model crosses a threshold of moisture availability for vegetation at around 6000 years before present. The resultant rapid reduction in vegetation cover acts to reduce precipitation through moisture recycling and surface albedo feedbacks. Precursor drying events which are not directly forced also indicate that the model is close to a critical moisture level. Similar precursor-like events appear in a Holocene record from the East of the continent, hinting that the natural system may resemble some of the properties of this model simulation. The overall response is not fundamentally altered by the inclusion of solar irradiance variations or volcanic eruptions. The simulated timing of the abrupt transition is mostly controlled by orbital forcing and local positive feedbacks, but it is also modulated to some extent by the state of the atmosphere and ocean. Comparisons with proxy records across North Africa show good agreement with the model simulations, although the simulations remain overly dry in the East. Overall, a threshold response may present a useful model of the real transition, but more high-resolution palaeoclimate records would help to discriminate among the predictions of climate models.

Late glacial–Holocene record of Southern Hemisphere westerly wind dynamics from the Falkland Islands, South Atlantic Ocean

Abstract The Southern Hemisphere westerly wind belt (SHWW) is a major feature of Southern Hemisphere, midlatitude climate that is closely linked with the sequestration and release of CO2 in the Southern Ocean. Past changes in the strength and position of this wind belt are poorly resolved, particularly across the Pleistocene-Holocene transition, a time period associated with fluctuations in atmospheric temperatures and CO2 levels. We used dust geochemistry, particle size measurements, and paleoecological analyses from a peat sequence in the Falkland Islands, South Atlantic Ocean, to describe changes in the SHWW between 16.0 and 6.5 ka (thousands of years before CE 1950). Wind strength was low at ~51°S before and during the Antarctic Cold Reversal (ACR, 14.9–13.0 ka), intensified between 13.1 and 12.1 ka as atmospheric temperatures increased, and then weakened, reaching a minimum between 12.1 and 10.9 ka during the Early Holocene thermal maximum. Northwesterly air masses became more dominant from 12.0 to 10.2 ka, and wind strength remained low until our record was affected by a storm surge or tsunami ca. 7.8 ka. These data indicate a southward shift in the latitude of the SHWW, from north of 51°S prior to and during the ACR, at ~51°S before the onset of the Holocene, and south of 51°S during the early Holocene thermal maximum. This pattern suggests that the latitude of the SHWW was coupled with atmospheric temperatures through the Pleistocene-Holocene transition.

Late Holocene peatland palm swamp (aguajal) development, carbon deposition and environment changes in the Madre de Dios region, southeastern Peru

Tropical peatlands are an important carbon reservoir; however, they are vulnerable to climate change, fire events, and human disturbances, and may become a significant carbon source if degraded. In this paper, we investigated the late Holocene record of vegetation change, peatland evolution, and C accumulation based on analysis of a sediment core through a Mauritia-flexuosa palm dominated swamp (locally called “ aguajal ”) in the Madre de Dios region in southern Peru to better understand tropical peatland dynamics. Sedimentation commenced within shallow water, ponded on an impervious substrate, perhaps within an abandoned river channel or oxbow lake (1380–820 cal yr BP) located adjacent to a steep escarpment with terra firme (upland) rainforest above and lateral to floodplain forests. This was followed by the development of marsh (820–640 cal yr BP). A closed-canopy Mauritia flexuosa -dominated palm swamp was subsequently established (640300calyr BP) which later changed into an open canopy and mixed Mauritia - Hedyosmum palm swamp (300 cal yr BP to present). Two major changes in peat and C accumulation rates were observed: (1) onset of peat and C accumulation at 820 cal yr BP and (2) decrease of peat and C accumulation after 520 cal yr BP. Comparisons of our results with palaeoecological records from aguajales in northern Peru suggest that the dynamics were different in this region. The peat and C accumulation rates in our study core in southern Peru were ca. 4 mm yr −1 and ca. 200 g m −2 yr −1 faster, similar to a few sites in northern Peru. Aguajales in Madre de Dios region in southern Peru are an important carbon sink. Analyzing the dynamics of aguajales which are a kind of typical peatlands in Amazonia and comparing among different sites allows exploration and prediction of regional peatlands' development under the potential future impact of natural changes. • First study of a palm peatland ( aguajal ) development in Madre de Dios region, southern Peru • This study includes late Holocene vegetation dynamics, peat and C accumulation of the aguajal • Controlling factors in the dynamics are fluvial changes and climate • Comparisons with northern Peru suggest different vegetation succession • Peat and C accumulation rates in Madre de Dios were faster, similar to a few sites in northern Peru

Lake level changes and paleo-precipitation estimations based on colluvial stratigraphy of Holocene sediments in West Anatolia (Simav Graben)

Time-controlled quantitative climate data are crucial for reconstructing past environmental contexts of human history. In west Anatolia, the Simav Graben used to be occupied by a lake. However, today it is drained and associated with Holocene sediments that record lake level changes. An initial drill-core at the lake's centre reveals an arid phase before ca. 14 ka (i.e. prior to the Late Glacial warming) followed by a wet phase (marshes and lake) throughout the Holocene. Along the lake's margin, two additional sediment sequences contain a detailed Holocene record of changes in humidity throughout the Simav Graben's watershed. Classification of the shoreline facies from these sequences records drought events marked by colluvium prograding towards the lake. Using 13 radiocarbon dates, sedimentary facies suggest rapid lake contraction phases grossly around 8.0, 3.9, 2.9, 2.4 and 2.0 ka. After the drier periods, recorded by phases of terrestrial progradation, lake level increase is marked by retrogradational lake muds and peats onlapping the colluvium, consistent with increases in total lake volume. Based on modern lake morphology, climate and runoff data, and the elevations recorded by the shoreline facies identified within the marginal Holocene sedimentary sequence, we constructed a paleohydrologic balance model and a precipitation curve. According to the model, annual precipitation may have been fallen below 460 mm during the 8.2 ka event, and 468–478 mm during the 4.2 ka and 3.2 ka events – demonstrating an extreme decrease in precipitation compared to the earlier wet phases. In turn, Holocene Archaeology in West Anatolia outlines (i) a widespread abandonment and/or notable fire events at the end of the Early Bronze Age III (ca. 4.2 ka), and (ii) a high level of social instability at the beginning of the Early Iron Age (ca. 3.2 ka). The correlation between the timing of lake level falls at Simav (water volume depletion caused by drying trends) at 8.0 ka, 3.9 ka and 2.8 ka and cultural fluctuations suggest that drought events may have played a major role in these socio-political changes in western Anatolia. Furthermore, the high lake-level stages (associated with precipitation >500 mm) coincide with the Late Chalcolithic to Early Bronze Age I transition as well as the Hellenistic and Roman periods, both times of economic stability and growth in the region.

Multi-proxy analysis of a Holocene records from a high-altitude tropical peatland in the Serra do Espinhaço Meridional, Brazil

Peatland ecosystems are valuable archives of paleoenvironmental changes, as they preserve organic and inorganic records that enable the reconstruction of the paleoenvironment. A Holocene record of the Araçuaí River peatland in the Serra do Espinhaço Meridional, in the state of Minas Gerais, Brazil, was studied using isotopic composition, environmental geochemistry, and phytolith analysis. As a result, it was possible to determine and quantify the main constituent elements of the peatland and the chronology of paleoenvironmental changes. Five phases of paleoenvironmental changes were inferred: Phase I – 8.9 to 6.6 cal kyr BP - cold local environment (high phytolith index), which was very wet (higher tree cover density and high occurrence of C3 plants) and with watershed instability (higher incidence of erosion and sedimentation); Phase II – 6.6 to 3.9 kyr - very cold local environment, with reduced moisture in relation to the previous phase (decrease of the temperature and mixture of C3 and C4 plants), and increased stability in the watershed, with episodes of erosion at the end of the phase; Phase III – 3.9 to 2.1 cal kyr BP – warmer, drier local environment in relation to the previous phase (increase in the temperature and decrease of tree cover density) and instability in the watershed, with an episode of temperature decrease and moisture increase (respective increase in the climatic phytolith index and in δ15N) in the middle of the phase; Phase IV – 2.1 to 0.25 kyr - colder climate, increased humidity in the local environment in relation to the previous phase (increase in Ic% and D/P and a decrease in the palm cover density phytolith index), and greater stability in the watershed; Phase V – 0.25 kyr to present - increase in temperature, decrease in humidity (decrease in Ic% and expansion of C4 plants), and increased instability in the watershed, possibly influenced by human activity. The results evidence that the Araçuaí River peatland records demonstrate Holocene climate variations, capable of providing information about the paleoenvironment.

Late Holocene increase of winter precipitation in mid-continental North America from a seasonally resolved speleothem record

Abstract Subannual climate reconstructions of the Holocene are rare despite the ability of such records to provide a better understanding of the underlying factors that drive subannual climate variability. We used specialized confocal laser fluorescent microscope imaging and automated secondary ion mass spectrometry microanalysis to resolve a seasonal oxygen isotope (δ18O) record of a late Holocene–aged (2.7–2.1 ka) speleothem from mid-continental North America. We did this by measuring intra-band δ18O variability (Δ18O) within 117 annual bands over a 600 yr span of the late Holocene. We interpret a change in Δ18O values after 2.4 ± 0.1 ka to reflect an increase in the amount of winter precipitation. Our study produced direct measurements of past seasonality, offers new insights into shifting seasonal precipitation patterns that occurred during the late Holocene in central North America, and adds a new tool for understanding the complex precipitation and temperature histories of this region.

Holocene Faulting and Earthquake Recurrence along the Northern Agua Tibia–Earthquake Valley Fault Zone and Implications for Slip Distribution in Southern California

ABSTRACTSlip rates determined along the Elsinore and San Jacinto faults indicate that south of 33.5° N, the slip rate along the Elsinore fault decreases by ∼2.5 mm/yr, whereas the slip rate along the San Jacinto fault increases by nearly 6 mm/yr. A transfer of slip from the Elsinore to the San Jacinto faults is the likely explanation, but a fault with Holocene activity had yet to be identified to support this hypothesis. We report the results of new mapping and paleoseismic work along the Earthquake Valley fault, the eastern strand of the Elsinore fault, in Warner basin. Our paleoseismic investigation at Big Lake documents three stratigraphic horizons at which there is evidence of coeval shattering and displacements. The uppermost interpreted event breaks up to within 20 cm of a historical horizon and suggests a very young surface rupture. We attribute this event (E1) to either the 1890 or 1892 earthquakes. The ages of the two previous earthquakes are constrained to be between 486 C.E. and 1125 C.E., and between 158 B.C.E. and 235 C.E. These data suggest individual interevent recurrence intervals of 1106 ± 340 yr (E1–E2) and 760 ± 406 yr (E2–E3), respectively. The minimum slip rate of 1.95 ± 0.4 mm/yr is estimated for the Earthquake Valley fault from the offset of two main drainages that cut into the sedimentary fill of Warner basin, which contains the Bishop tuff. We propose that with its geomorphological expression, late Holocene earthquake record, and slip rate estimate, the Earthquake Valley fault is the main structure responsible for transferring slip from the northern Elsinore fault to the southern San Jacinto fault. Given the recency of a surface rupture and our recurrence interval calculations, however, a large earthquake along the Earthquake Valley fault in the near future is unlikely, if time dependence is considered.

Geomorphically controlled coral distribution in degraded shallow reefs of the Western Caribbean.

The development of coral reefs results from the interaction between ecological and geological processes in space and time. Their difference in scale, however, makes it difficult to detect the impact of ecological changes on geological reef development. The decline of coral cover over the last 50 years, for example, has dramatically impaired the function of ecological processes on reefs. Yet given the limited-resolution of their Holocene record, it is uncertain how this will impact accretion and structural integrity over longer timescales. In addition, reports of this ecological decline have focused on intrinsic parameters such as coral cover and colony size at the expense of extrinsic ones such as geomorphic and environmental variables. Despite these problems, several attempts have been made to predict the long-term accretion status of reefs based entirely on the contemporary health status of benthic communities. Here we explore how this ecological decline is represented within the reef geomorphic structure, which represents the long-term expression of reef development. Using a detailed geomorphic zonation scheme, we analyze the distribution and biodiversity of reef-building corals in fringing-reef systems of the Mesoamerican Reef tract. We find a depth-related pattern in community structure which shows that the relative species distribution between geomorphic zones is statistically different. Despite these differences, contemporary coral assemblages in all zones are dominated by the same group of pioneer generalist species. These findings imply that first, coral species distribution is still controlled by extrinsic processes that generate the geomorphic zonation; second, that coral biodiversity still reflects species zonation patterns reported by early studies; and third that dominance of pioneer species implies that modern coral assemblages are in a prolonged post-disturbance adjustment stage. In conclusion, any accurate assessment of the future viability of reefs requires a consideration of the geomorphic context or risks miscalculating the impact of ecological changes on long-term reef development.

Development of the marine Holocene environment in a drowned paleovalley with final anthropic influence in the Cartagena Bay (Murcia, SE Spain)

Sedimentological, paleobiological, mineralogical, and geochemical analyses of a sediment core retrieved on the seafront of Cartagena Bay were performed after high-resolution sampling. A wide series of dates obtained through radiocarbon and amino acid racemization proved that the Holocene record on the analyzed core began at ca. 7300 yr cal BP. Reinterpretation of the marine seismic profiles indicated that the beginning of this transgression was channeled along erosive paleochannels excavated on a coastal plain of, at least, MIS5c age. The Holocene paleoenvironmental evolution consisted of a first period marked by marine conditions with strong inputs from a fan delta linked to the reorganized fluvial network that occurred after the sudden rise of the base level, which caused a growing sedimentary prism. Later, the full marine environment was reflected in the development of a Posidonia- Cymodocea meadow hosting a rich biodiversity of marine species (mollusks, foraminifera, ostracoda). Around 3800 yr cal BP, the area underwent a profound change and a silting process started to alter the conditions, turning the area into a paucispecific brackish marsh environment in which mud deposition was dominant. Since Carthaginian times, arrangement works locally affected the record, allowing the arrival of some marine species due to port work (dredging) undertaken to gain depth and showing anthropic influence.

Paleoenvironmental variability and anthropic influence during the last 7300 years in the western Mediterranean based on the pollen record of Cartagena Bay, SE Spain

In this paper, we conduct a palynological analysis of a high-resolution Holocene record from Cartagena Bay, southeast of the Iberian Peninsula, to establish paleoenvironmental variability of coastal areas in the western Mediterranean region at a centennial-scale over the last 7300 years. Statistical analysis of four palynozones allows reconstruction of paleotemperature and paleohumidity conditions. Pinus , steppic, xerophilous, and Mediterranean taxa persisted continuously through the record, and only during periods of increased humidity did deciduous and Mediterranean taxa expand (Zones II, subzone IIIb). Cooler and dry conditions favored the development of Cupressaceae and scrubs between 7300 and 7000 yr cal BP. The mid-Holocene (Northgrippian) mesophytic optimum took place between 6800 and 4000 yr cal BP during which time a Mediterranean climate was present and open forest developed, predominantly consisting of Mediterranean taxa and deciduous trees. The gradual rise in aridity in the Meghalayan (4000–1700 yr cal BP) led to Mediterranean forest being replaced by steppic and xerophilous vegetation, a change related mostly to a decrease in summer insolation, with superimposed centennial-scale variability in humidity. In parallel with forest degradation caused by increasing aridity, the record shows marked evidence of human influence since 4000 yr cal BP, which accelerated the progression of open landscapes from the Chalcolithic onwards, this change being especially marked during the Roman period. Significant denudation of the landscape can be attributed to the use of fire, as well as due to agriculture and grazing, with a major contributor being intense metallurgical and mining activity in the area. The Cartagena Bay record reported herein shows centennial-scale oscillations in humidity and temperature that correlate with well-known climatic events during the late Holocene in the western Mediterranean region, synchronous with variability in solar and atmospheric dynamics. The alternation of persistent North Atlantic Oscillation modes is likely to have played a key role in regulating humid–arid periods. • Pollen content allowed the paleoenvironmental reconstruction during the Holocene. • Centennial-scale oscillations in humidity & temperature correlate with climatic events. • The mid-Holocene mesophytic optimum took place between 6800 and 4000 yr cal BP. • Aridity and xerophytization occurred between 4000 and 1700 yr cal BP. • Human influence accelerated the progression of open landscapes since the Chalcolithic.

Holocene Tephrostratigraphy in the East Sea/Japan Sea: Implications for Eruptive History of Ulleungdo Volcano and Potential for Hemispheric Synchronization of Sedimentary Archives

AbstractActive volcanoes in East Asia pose potential threats to the surrounding areas. The eruptive history of many of the Japanese volcanoes are well understood, but their dispersal pathways are often based on visible tephra. Additionally, other important volcanoes in the region still require a deeper understanding of their eruptive potential. Here, we explore the Holocene cryptotephra record preserved in a marine core 13PT‐P4 in the southwestern East Sea, in order to better reconstruct past eruptive events and their dispersal. Six widespread tephra layers are identified and correlated to their source volcanoes in S Korea (Ulleungdo), China/N Korea (Changbaishan) and Japan (Kikai), with their dispersal ranges updated. Our results rank the 13PT‐P4 sequence the most intensively tephra‐constrained Holocene record in the East Sea, which permits synchronization of this mid‐latitude archive with records in the Arctic and tropical regions. Terrestrially based tephra ages are used to constrain the marine reservoir effect and the age‐depth model of the record. The average reservoir age in the region is estimated to be 1150 ± 3014C yr at ca. 7.3–5.6 cal ka BP and 1565 ± 3014C yr at ca. 1.0 cal ka BP. These observed changes in reservoir age could indicate active upwelling at a regional scale. Additionally, we provide a detailed age estimate and glass geochemistry for a previously poorly understood eruption (U‐1) from the Ulleungdo volcano, thus refining its Holocene eruptive history. The U‐1 eruption is dated to 3354‐3080 cal yr BP (95.4%), and has glass composition that is distinct from other Ulleungdo tephras.

A Late Holocene Record of Variations in the Chemical Weathering Intensity and Pedogenesis in a Lake Catchment from Southern India

A Late Holocene Record of Variations in the Chemical Weathering Intensity and Pedogenesis in a Lake Catchment from Southern India

Lipid biomarkers and metal pollution in the Holocene record of Cartagena Bay (SE Spain): Coupled natural and human induced environmental history in Punic and Roman times

We reconstructed the palaeoenvironmental conditions of Cartagena Bay during the Holocene after a multidisciplinary study to identify natural variations and the anthropic processes of this coastal area. A total of 119 samples were recovered for amino acid racemization dating, 3 for radiocarbon dating (14C), and four sets of 80 samples for sedimentological and palaeontological determination, mineralogical content, biomarker and trace elements quantification. Two natural scenarios were identified from the variations of n-alkane indices and palaeobiological content. The first period (6650–5750 yr cal BP) was marked by the development of euhaline marine conditions with strong inputs from aquatic macrophytes and high biodiversity. After a hiatus, the area underwent a profound change, becoming a paucispecific brackish marsh environment with increasing inputs from land plants, with possible episodes of emersion with a greater presence from terrestrial gastropods (3600–300 cal yr BP). By combining trace element abundance and stanol distributions, our study also provides a novel approach to identify the predominant influence of anthropogenic factors in the last three millennia in the coastal record of Cartagena Bay. Findings confirmed that Pb mining and metallurgy began during the Bronze Age, with considerable inputs of this heavy metal into the atmosphere during Phoenician, Punic and particularly Roman times compared to the Middle Ages. Pollution by Cu and Zn was also observed during Punic and Roman times, and was first documented in the Middle Ages. In addition, faecal stanols, such as coprostanol, derived mainly from humans, and 24-ethylcoprostanol from herbivores were present, thereby indicating for the first time a continuous presence of human populations and significant pollution input since 3600 yr cal BP, this being greater in the late Bronze Age and Phoenician, Punic and Roman times than during Late Antiquity and the Middle Ages, when the city was in decline.

Vegetation and land snail-based reconstruction of the palaeocological changes in the forest steppe eco-region of the Carpathian Basin during last glacial warming

In the present work, well radiocarbon-dated Quaternary malacological and palynological analyses were implemented on 4 cm samples deriving from one of the thickest and best developed last glacial sequences of Central Europe the Madaras brickyard and the borehole of Kolon Lake in the southern part of Hungary. Using a combination of mollusc, anthracological, palynological and climatic proxies evidence preserved within loess, we demonstrate that long-term changes (e.g. the last 39,000 (28,000) years) in paleoclimatic dynamics on the northern edge of the Bácska-Titel loess plateau, on the southern part of the Great Hungarian Plain. These proxy data are reflected in the following ecological changes: a turnover from predominantly cold-tolerant mollusc fauna in a boreal type forest-steppe context under cold conditions during the last glacial then followed by a shift to a predominantly xerotheromphilous land snail fauna in a temperate forest-steppe context under a warm temperate climate in the early Holocene. Certain warm-adapted, Central and SSE European distribution mollusc species such as Caucasotachea vindobonensis and Granaria frumentum, were found to have been associated with temperate forest-steppe in both the Holocene record and the present-day ecosystem.

Impact of climate changes on vegetation and human societies during the Holocene in the South Caucasus (Vanevan, Armenia): A multiproxy approach including pollen, NPPs and brGDGTs

Relationships between steppe vegetation, human practices and climate changes in the past are crucial to disentangle human development in Eurasia. In this frame, our study investigates (1) modern pollen-vegetation relationships and (2) changes in vegetation, human activity and climate in the Holocene record of Vanevan peat (south-eastern shore of Lake Sevan, Armenia), using a multiproxy approach including sediment geochemistry (XRF), pollen, Non-Pollen Palynomorphs (NPPs), and branched Glycerol Dialkyl Glycerol Tetraethers (brGDGTs). Climate reconstructions are provided by (1) water-level changes, (2) brGDGTs, and (3) pollen transfer functions (multi-method approach: Modern Analogue Technique, Weighted Averaging Partial Least Squares regression, Random Forest, and Boosted Regression Trees). Modern pollen assemblages are selected along an altitudinal transect in Armenia. They show a dominance of Chenopodiaceae in semi-desert/steppe regions while meadows steppes, subalpine, and alpine meadows are dominated by Poaceae. Past vegetation is characterized by steppes dominated by Poaceae surrounded during the Mid-Holocene (8200–4200 a cal BP) by scarce open woodlands. Humans have influenced the local vegetation, mainly through their agricultural practices present since 5200 a cal BP with several intensification steps. Our reconstruction indicates a climate shift from a cold and arid Early Holocene toward a warmer and more humid Mid-Late Holocene. An aridification trend marks the last 5000 years causing a drop in water level, which allowed humans to live and cultivate on Lake Sevan shores. Arid events are recorded at 6.2 ka, 5.2 ka, 4.2 ka and 2.8 ka a cal BP, which are commonly related to multi-centennial-scale variations of Westerlies activity (North Atlantic Oscillation). Through our temperature reconstruction, we can assign (1) the 5.2 and 2.8 ka events as being cold and probably related to a strong Siberian High, and (2) the 4.2 ka event as being warm associated with high Arabian subtropical pressures in the South Caucasus and the Near East. Our study suggests a significant impact of these arid events on the Lake Sevan shore populations and they are consistent with cultural phases in the South Caucasus, thus showing the impact of climatic variations on cultural, land use and occupation mode development in this crossroad region between Europe, Africa and Asia.

The nexus among long-term changes in lake primary productivity, deep-water anoxia, and internal phosphorus loading, explored through analysis of a 15,000-year varved sediment record

Increased cultural eutrophication since the 20th century, caused by phosphorus (P) enrichment, has become a major problem worldwide. In deep, stratified lakes, eutrophication-induced hypolimnetic anoxia often stimulates the release of labile P from the sediment into the water column. This positive feedback, termed internal P loading, maintains or even accelerates eutrophication. However, most studies on internal P loading have focused on recent times. Little is known about whether such positive feedbacks caused by labile P release from sediments also played a role under natural conditions with little or no human impact. We investigated a high-resolution 15,000-year sediment record of paleoproduction, anoxia, and five sedimentary P fractions from a small, deep lake, Soppensee, on the Swiss Central Plateau. We estimated long-term qualitative internal P loading by comparing the Holocene record of diatom-inferred epilimnetic total P (DI-TP) concentrations with labile P fraction (Fe P) concentrations in sediments under changing trophic state, redox, and lake mixing regimes. Intensified P cycling from sediments into the water column (enhanced internal P loading) apparently occurred as a positive feedback to natural eutrophication with persistent bottom-water anoxia during the early to mid-Holocene (~9000–6000 cal BP). However, this positive feedback was not inferred for other eutrophic phases. Fe-rich layers formed during seasonal mixing of the lake in the late Holocene (~2000–200 cal BP) and magnetite-type minerals produced by magnetotactic bacteria (MTB) internal P loading during anoxic phases in the mid- to late Holocene (~6000–2000 cal BP) appeared to prevent internal P loading. MTB presence resulted in high concentrations of potentially labile Fe P in sediments. Our study demonstrates the potential contribution of internal P loading during long-term natural eutrophication of deep stratified lakes and has wide implications for lake management and restoration. Our results highlight the importance of the coupled geochemical cycles of P and Fe in the long-term trophic state evolution of stratified, ferruginous, low-sulfate-water lakes, conditions that have been reported to serve as analogs for the Archaean Ocean. • First qualitative estimates of internal P loadings in a deep stratified lake during the Holocene. • Evidence of pre-anthropogenic feedbacks between productivity, anoxia and P cycling. • Microorganisms modulate the Holocene geochemical cycle of P under meromictic conditions. • Postglacial forest and climate changes affect lake productivity, anoxia and P cycling.

Late Holocene sea-surface changes in the North Water polynya reveal freshening of northern Baffin Bay in the 21st century

The accelerating sea-ice, ice sheet and glacial melt associated with climate warming have resulted in important changes in the Arctic region over the past decades. In northern Baffin Bay, the formation of the North Open Water (NOW) polynya, which is intrinsically linked to regional sea-ice conditions and ocean circulation, has become more variable in recent years. To understand how climate-driven changes affect sea-surface conditions in the polynya, we analyzed dinoflagellate cyst assemblages from a sediment core record that covers the past ca. 3800 years, and developed an index based on the locations of modern analogues from a large regional reference dataset. Our results suggest a prolonged open-water season characterized by higher summer sea-surface salinity and temperature between ca. 3800 to 2500 years BP, followed by gradual cooling, freshening and increased sea-ice influence from 2500 to 1500 years BP, and continued sea-surface cooling with a shorter open-water season from 1500 to 156 years BP. The modern warming translates into a rapid turnover in the composition of dinoflagellate cyst assemblages during the last 50 years of our record, unprecedented for at least the past 3800 years studied here. For the uppermost part of our core (ca. 2009 to 2015 CE), the dinoflagellate cyst assemblages suggest increased stratification and sea-surface freshening resulting from increased glacial runoff and Arctic sea-ice export into the NOW region. Arctic climate projections indicate accelerated sea-ice thinning and ice sheet melt in the future, pointing to a shorter polynya season and increased polar inflows leading to fundamental changes within the NOW polynya into future years. • Long-term subdecadal to multidecadal record of summer sea-surface conditions using dinoflagellate cysts in the North Water Polynya. • Development of an index based on the locations of modern assemblage analogues to assess changes to polynya dynamics. • Sea-surface cooling and freshening from ca. 2200 years to 156 years BP. • Late Holocene record shows no comparable analogue to the last ca. 50 years.

A Holocene record of floodplain development in the northernmost portion of the Araguaia Belt, southeastern Amazonia

This work aimed to understand the drivers of landscape evolution and floodplain formation in a Precambrian Shield area of southeastern Amazonia. This area evolved during the Quaternary into a denudational system with strong structural control, which produced valley side slopes between the Araguaia Belt (AB) and the topmost Parnaíba basin and narrow floodplains in the lower Vermelho River. These floodplains developed at approximately 11215–11410 cal yr BP with the deposition of muds on the weathered basement rocks of the Couto Magalhães Formation in the Ab (CMF) long before sea-level stabilization on the Amazon coast. The chondrite- and upper continental crust-normalized patterns, along with Al/Ti and La/Th ratios, clearly indicate that muds were derived from the CMF-AB. The strong positive correlation of most of the trace elements and rare earth elements (REEs) with Al and Ti indicates their control by aluminous clay phases and a similar transport process. Overbank flows of the Vermelho River resulted in the deposition and vertical accretion of sands from the fluvial channel over the floodplain, forming discontinuous marginal levees after 4520–4710 cal yr BP. The accreted sands with the predominance of Si, Zr, and Hf and the depletion of most of the major and trace elements are likely associated with quartz enrichment and a strong sorting of heavy minerals, which is also supported by Al2O3/SiO2 vs Fe2O3/SiO2. The tributaries of the lower Vermelho River were active until 3890–4095 cal yr BP, and subsequently, the channel was abandoned as a result of the filling process. At approximately 3440–3560 cal yr BP, the floodplain was influenced by prolonged and severe droughts that fully exposed the muddy deposits and caused the enrichment of Fe-Mnoxyoxide phases. The affinity of most of the potentially toxic elements with Al signifies that these floodplain deposits are a natural record for geochemical background studies.

Holocene pyrolytic nitrogen compounds by using pyrolysis-GC/MS and its paleoclimatic implication from Jinchuan peatbog, NE China

We present a Holocene record of pyrolytic nitrogen (N) composition from the Jinchuan peat bog within the Longgang Volcanic Field (LVF), NE China. Based on pyrolysis gas chromatography and mass spectrometry (Py-GC/MS) analysis, N-compounds including acetamide, NHetero and NAro have been identified and quantified. Aromatic N-compounds (NAro, benzonitrile and benzamide) are mainly derived from phytoplankton and higher plants, and are resistant to microbial degradation. We propose ‘NHetero/NAro’ as a proxy based on microbial degradation, and has lower values between 10 and 5.8 ka BP, and higher values during the late Holocene. We suggest that temperature is main factor for NHetero/NAro, and sedimentary facies changed from floodplain to peat deposition, variation of effective precipitaion and pH value have limited influence on the performance of the proxy in Jinchuan. Low NHetero/NAro levels, combined with high levels of non-protein derived acetamide, indicate warmer conditions, and vice versa. NHetero/NAro is sensitive to temperature change, and follows a similar pattern to those of previous paleo-temperature time series derived from br-GDGT and long chain alkenones in this region. This Spectral analysis of the NHetero/NAro time series reveals significant periodicities of 103–105, 145 and 482–506 years, suggesting strong influences of solar radiation and monsoon intensity on temperature variations in NE China during the Holocene.