Hollow Spheres Research Articles

High activity nitrogen-doped hollow carbon/silicon hollow spheres as encapsulated Pd–Fe nanoreactors for acetylene dialkoxycarbonylation

Hollow spheres were successfully prepared and encapsulated with palladium-iron alloy as catalysts with high selectivity and remarkable durability.

FeNi decorated nitrogen-doped hollow carbon spheres as ultra-stable bifunctional oxygen electrocatalyst for rechargeable zinc-air battery with 2.7% decay after 300 hours cycling.

Research on non-noble metal bifunctional electrocatalysts with high efficiency and long-lasting stability is crucial for many energy storage devices such as zinc-air batteries. In this report, nitrogen-doped porous hollow carbon spheres with a size of about 300 nm were fabricated using a modified Stöber method and decorated with an FeNi alloy through a pyrolytic reduction process, resulting in a promising bifunctional electrocatalyst for both the oxygen evolution reaction and oxygen reduction reaction. The as-prepared FeNi@NHCS electrocatalyst exhibits excellent bifunctional activity in KOH electrolyte, attributed to its mesoporous structure, large specific surface area, and the strong coupling between the FeNi nanoalloy and nitrogen-doped carbon carriers. The electrocatalyst demonstrates excellent ORR performance with E1/2 = 0.828 V and OER activity with Ej=10 mA = 1.51 V. A zinc-air battery using FeNi@NHCS as the air electrode achieves an open-circuit voltage of 1.432 V and a maximum power density of 181.8 mW cm-2. After 300 h of galvanostatic charge-discharge cycles, the charge-discharge voltage gap (ΔU) of the battery had only decayed by 2.7%, demonstrating superior cycling stability.

Triple-shelled Ni@MnO/C hollow sphere with enhanced performance for rechargeable Zinc-ion capacitor

Electrochemical activation techniques and multi-shell structured materials are effective strategies to enhance the electrochemical performance of rechargeable aqueous Zinc-ion capacitors (ZICs). In this study, we successfully synthesized spherical Ni3Mn-MOF via...

NIR and magnetism dual-response multi-core magnetic vortex nanoflowers for boosting magneto-photothermal cancer therapy.

Due to the relatively low efficiency of magnetic hyperthermia and photothermal conversion, it is rather challenging for magneto-photothermal nanoagents to be used as an effective treatment during tumor hyperthermal therapy. The advancement of magnetic nanoparticles exhibiting a vortex-domain structure holds great promise as a viable strategy to enhance the application performance of conventional magnetic nanoparticles while retaining their inherent biocompatibility. Here, we report the development of Mn0.5Zn0.5Fe2O4 nanoflowers with ellipsoidal magnetic cores, and show them as effective nanoagents for magneto-photothermal synergistic therapy. Comparative studies were conducted on the heating performance of anisometric Mn0.5Zn0.5Fe2O4 (MZF) nanoparticles, including nanocubes (MZF-C), hollow spheres (MZF-HS), nanoflowers consisting of ellipsoidal magnetic cores (MZF-NFE), and nanoflowers consisting of needle-like magnetic cores (MZF-NFN). MZF-NFE exhibits an intrinsic loss parameter (ILP) of up to 15.3 N h m2 kg-1, which is better than that of commercial equivalents. Micromagnetic simulations reveal the magnetization configurations and reversal characteristics of the various MZF shapes. Additionally, all nanostructures displayed a considerable photothermal conversion efficiency rate of more than 18%. Our results demonstrated that by combining the dual exposure of MHT and PTT for hyperthermia treatments induced by MZF-NFE, BT549, MCF-7, and 4T1 cell viability can be significantly decreased by ∼95.7% in vitro.

From silicon to silica: a green chemistry approach for hollow sphere nanoparticle formation.

Herein we report on an environmentally friendly and scalable production route for hollow silica spheres (HSSs). The process is based on close to 100% conversion of non-crystalline solid Si nanoparticles (D̄ = 40 ± 9 nm) in mild alkaline solutions (pH ≤ 9.0) at ambient temperature. The Si nanoparticles are prepared using the centrifugal chemical vapor deposition (cCVD) method. Combining transmission electron microscopy (TEM) imaging and nanoparticle size analysis with hydrogen evolution data, elemental mapping, and nitrogen adsorption for surface area measurement, we show for the first time experimental data that document a Kirkendall type Si-to-HSS formation process. Our understanding is that the Si nanoparticles exposed to air form a SiO2 film, which is stable in the mild alkaline environment. Silicon from the Si nanoparticles is transported through the thin SiO2 film and is reacting with H2O/OH- species on the particle surface or in the already thickened SiO2 shell to form silicic acid that in turn rapidly gets converted to a sol-gel to continue the growing of the silica shell. We foresee that this green chemistry approach can be utilized for HSS preparation for use in batteries, insulation materials and drug delivery.

Preparation of nickel foam modified by multiwalled hollow spheres of NiCo2O4 as a promising non-enzymatic glucose sensor.

Nickel foam modified by hollow sphere NiCo2O4 particles was successfully prepared via a hydrothermal method using nanosphere SiO2 particles as the hard template for the hollow structure. Characterisation using SEM-EDX and TEM confirmed the structure as multiwalled hollow spheres with an average size of 270 nm, while characterisation using SEM, XRD, and XPS confirmed that the NiCo2O4 particles were attached on the surface of the nickel foam. BET analysis showed that the surface area of the synthesized NiCo2O4@Ni foam was nearly three times higher compared to that of the unmodified Ni foam. Investigation of the NiCo2O4-modified nickel foam as an electrode for the detection of glucose in sodium hydroxide solution showed high linearity of the anodic currents (R2 = 0.99) in the concentration range of 0-2.5 μM with sensitivity of 0.060 mA μM-1 and an estimated limit of detection of 0.060 μM. Excellent stability of the current response was also obtained with a relative standard deviation of 1.51% (n = 10). Furthermore, the developed sensor demonstrates strong applicability for glucose detection in real samples of human blood plasma, making it highly suitable for practical use. The results indicate that the material is promising for the further development of nickel-based sensors.

Steam reforming of methane by titanium oxide photocatalysts with hollow spheres

TiO2 photocatalysts with a hollow sphere structure were synthesized and loaded with spatially separated co-catalysts to improve SRM efficiency.

Numerical analysis of the binder angle effect on convective heat transfer and pressure drop in drilled-hollow sphere architected foams

Due to their capability of generating customized microstructures, additive manufactured cellular materials are promising to being employed in heat transfer devices. To this aim, among printable cellular materials Drilled-Hollow Spheres Architected (DHSA) foams are investigated. However, at the present status, limited data on pressure drop and heat transfer in DHSAs are available. Starting from hollow spheres, a metal DHSA foam is generated with CAD software in this study. Forced air convective heat transfer in the foam is investigated numerically, under the assumptions of air incompressible laminar flow and uniform wall heat flux from the solid to the fluid phase. Mass, momentum and energy equations in the fluid region are written and solved numerically, for various values of the foam binder angle and the velocity of the inlet air. The convective heat transfer coefficients, the pressure drop and the friction factor are predicted. The effects of the binder angle and the air inlet velocity on heat transfer and pressure drop are highlighted.

Large-scale synthesis of N-doped carbon spherical shells as high-performance cathode materials for Li–X (X = O2, S, Se) batteries

A cost-effective, reproducible, and scalable method to produce meso- and macro-porous hollow carbon spheres for high performance Li–X (X = O2, S, Se) batteries.

Platinum-group-metal quaternary alloys with lattice defects for enhanced oxygen electrocatalysis.

We propose a facile coreduction method to synthesize a platinum-group-metal quaternary alloy anchored on nitrogen-doped hollow carbon spheres (PtPdRuIr/HCS) by using [MClx]y--1-butyl-3-methylimidazole (M = Pt, Pd, Ru, and Ir) ionic liquid. Owing to the steric hindrance of the imidazolium cations, Pt-group metal atoms of different sizes can be deposited at approximately the same pace for the growth of an alloy with lattice defects. The lattice-distorted PtPdRuIr/HCS exhibits enhanced activity toward oxygen electroreduction when benchmarked against Pt counterparts.

Zeolitic imidazolite framework derived bifunctional N,P-codoped hollow carbon sphere electrocatalysts decorated with Co2P/Fe for rechargeable Zn–air batteries

Co2P nanoparticles and Fe–Nx species were anchored on N,P codoped hollow carbonized spheres by structural and active site engineering. This work provides a facile strategy for the construction of bifunctional electrocatalysts for Zn–air batteries.

Boosting sodium-ion batteries performance by N-doped carbon spheres featuring porous and hollow structures.

Carbon materials are considered among the most promosing candidates for sodium ion batteries because of their competitive performance. Nevertheless, they suffer from low initial coulombic efficiencies (ICEs) and limited electrochemical performance. Herein, nitrogen-doped hollow carbon spheres (NHCSs) with a distinct porous structure are developed by a template-assisted carbonization of dopamine, followed by a template removal procedure. This advanced structural design, coupled with the surface chemistry of carbonized polydopamine, leads to an impressive ICE of 89.18% and a reversible capacity stabilized at ∼700 mA h g-1 at 50 mA g-1 after 100 cycles. Compared to commercial hard carbon anodes, NHCSs demonstrate superior rate performance, delivering a capacity of ∼200 mA g h-1 at 5 A g-1 with minimal capacity fading of ∼0.057 mA h g-1 per cycle over 1000 cycles. These findings highlight the potential of NHCSs as a high-performance anode material for sodium-ion batteries, offering both high efficiency and excellent cycling stability.

Análise dinâmica de uma laje aliviada biaxial submetida a ações humanas

Abstract The bi-axial hollow slab is the result of applying a technology that removes concrete from the least useful region and replaces it with hollow plastic spheres. This technique leads to material economy and self-weight saving, without considerable inertial loss, enabling larger and more flexible spans. Consequently, these spans are vulnerable to unwanted vibrations and dynamic acceleration caused by external actions, such as movements produced by human activity. This way, understanding the dynamic behavior of this technology and confronting it with normative limits on the project phase is essential for a good performance in the serviceability limit state, bringing comfort to the user. This paper studies the dynamic behavior of a bi-axial hollow slab submitted to human actions, such as jumping, dancing, clapping, moving the body, and moving and clapping at the same time. For that, this work made a numerical model of the structure and applied dynamic actions to it. The numerical results show that, for most of the actions, normative limits are satisfied, but the slab presents excessive accelerations in the case of jumping and dancing.

High electromagnetic wave absorption and flame retardancy performance from NF@HCS/NF-filled epoxy-based electronic packaging material

A nano-microscale nickel ferrite-assembled hollow carbon sphere (NF@HCS/NF) filled epoxy-based composite possessing high EMW absorption performance, flame retardancy, and electrical insulation was applied in advanced electronic packaging fields.

Synergistic regulation of Li deposition on F-doped hollow carbon spheres toward dendrite-free lithium metal anodes.

The notorious issues of lithium (Li) dendrite growth and volume change hinder the practical applications of Li metal anodes. LiF as a key component of the solid electrolyte interface (SEI) governs Li+ transport and deposition, yet the formation of LiF consumes the anions (PF6-/TFSI-) in the electrolyte, preventing the stable cycling of Li anodes. Herein, fluorine (F)-doped hollow carbon (FHC) was synthesized and used to construct a composite current collector with FHC as an F-rich buffer layer for modifying the Cu foil. The F content provided by FHC not only mitigates the anion (PF6-/TFSI-) consumption but also enhances the stability of SEI. The hollow structure of FHC with abundant internal space can accommodate deposited Li to relieve the volume change during cycling. Besides, the significantly improved specific surface area of the electrode effectively reduces the local current density to achieve a homogeneous Li deposition. Due to the above cooperation, the symmetrical cell of Cu@FHC-Li||Cu@FHC-Li maintains stable cycling for more than 1800 h with a hysteresis voltage of 19 mV. In addition, full cell coupling with LiFePO4 cathode delivers excellent long-term cycling and rate performance. This work provides an effective route for developing stable Li metal anodes.

3D structure-functional design of a biomass-derived photocatalyst for antimicrobial efficacy and chemical degradation under ambient conditions.

Surface sterilization and hazardous chemical degradation under ambient conditions can provide significant benefits for public and environmental health. Materials with sterilization and chemical degradation capacity under sunlight can efficiently reduce infectious disease incidence rates and toxic chemical exposure. Utilizing renewable energy for sustainable sterilization and degradation is more desirable as it reduces the potential secondary contamination. Herein, we report functional structure design using lignin, a renewable carbon heterogeneous polymer, to synthesize a highly efficient and stable photocatalyst that degrades environmentally hazardous organic compounds rapidly. Through a hydrolysis reaction between Ti-OH and the hydroxyl groups of lignin, Ti-O-C and Ti-O-Ti bonds were established and a lignin based photocatalyst with a hollow sphere structure (Clignin@H-TiO2) was formed. The presence of a homozygous carbon modified TiO2 structure contributes to the enhanced photodegradation activity with solar light. The close hetero-interfacial contact between carbonized lignin and TiO2 further improves the photocatalytic efficiency by facilitating effective charge carrier separation. After synthesis optimization, the resulting Clignin@H-TiO2 photocatalyst exhibits excellent performance in the degradation of atenolol under solar light irradiation with 100% degradation within five minutes. Additionally, it efficiently removes approximately 50% of PFOA and kills about 90% of bacteria within three hours. The uniform distribution of lignin within the crosslinking structures ensures a durable carbon modified TiO2 framework, which remains stable after 10 cycles of usage. The robustness of the lignin-based photocatalyst enables incorporating the catalyst into diversified material formats and various usages. Coating of the photocatalyst onto device surfaces shows bacterial killing efficacy under sunlight. The photocatalysts based on lignin valorization present a green chemistry approach for environmental remediation and surface sterilization, which has long-term environmental protection benefits, with broad applications in toxin treatment and health protection against pathogen infection.

Synthesis of hollow sphere structured TiO2 loaded with Ag2O and its photocatalytic activity

Owing to its high stability and catalytic activity, TiO2 has been widely used as a photocatalyst where its photocatalytic performance can be significantly improved by microstructure regulation and semiconductor loading.

Zinc-doped C4N3/BiOBr S-scheme heterostructured hollow spheres for efficient photocatalytic degradation of tetracycline.

Photocatalytic degradation of organic pollutants in water is of great significance to the sustainable development of the environment, but encounters limited efficiency when a single compound is used. Thus, there have been enormous efforts to find novel photocatalytic heterostructured composites with high performance. In this work, a novel S-scheme heterostructure is constructed with BiOBr and Zn2+ doped C4N3 (Zn-C4N3) by a solvothermal method for efficient photodegradation of tetracycline (TC), a residual antibiotic difficult to be removed from the aquatic environment. Thanks to Zn2+-doping induced improvement in chemical affinity between Zn-C4N3 and BiOBr, well-formed Zn-C4N3/BiOBr heterostructured hollow spheres are formed. This structure can efficiently suppress fast recombination of photogenerated electron-hole pairs to enhance the photocatalytic activity of BiOBr dramatically. At a room temperature of 25 °C and neutral pH 7, the catalyst can degrade a significant portion of TC pollutants within 30 min under visible light. Also, the Zn-C4N3/BiOBr heterostructure displays good stability after recycling experiments. Free radical capture experiments and ESR tests show that ˙O2- is the main active substance for photocatalytic degradation of TC. This study provides new insights for constructing heterostructures with an intimate interface between the two phases for photocatalytic applications.

A New Heat Transfer Model for Multi-Gradient Drilling with Hollow Sphere Injection

A New Heat Transfer Model for Multi-Gradient Drilling with Hollow Sphere Injection

Co9S8 core-shell hollow spheres for enhanced oxygen evolution and methanol oxidation reactions by sulfur vacancy engineering.

Cobalt sulfides, especially Co9S8, have been widely studied as a potential earth-abundant electrocatalyst for many electrochemical reactions, such as oxygen evolution reaction (OER) and methanol oxidation reaction (MOR). However, the electrocatalytic performance of Co9S8 is not satisfactory because of its comparatively sluggish charge transport and reaction kinetics. Defect engineering and constructing hollow nanostructures are effective methods to improve their electrocatalytic performance, therefore, exploring an efficient route to obtain Co9S8 catalysts, simultaneously possessing sulfur vacancies and hollow nanostructure, is necessary. In this study, Co9S8-x core-shell hollow spheres with sulfur vacancies were prepared via a two-step solvothermal strategy, followed by thermal treatment under an H2/Ar atmosphere. The content of sulfur vacancies can be regulated by varying the temperature during the thermal treatment. The obtained Co9S8-x core-shell hollow spheres exhibited interesting sulfur vacancy defect-dependent activity, one of which showed outstanding electrocatalysis performance for OER with an overpotential (η) of 294 m V (at 10 mA cm-2) and MOR catalysis efficiency (164.9 mA cm-2 at 1.8 V vs. RHE) in an alkaline medium. This study provides a promising and feasible pathway for developing efficient trifunctional electrocatalysts for renewable energy technologies.