Archaeologists interpreted residues inside hollow gold rings found in Roman burials of girls in the Rhineland as a “cement for chasing”. The aim of this study was to analyse this material and to compare it with Mediaeval and modern specimens made from pitch with inorganic filler and organic additives. The cement inside the Roman rings was identified as crystalline sulphur, which has occasionally been reported in the analytical literature as a filler in hollow gold objects from Hellenistic to Merovingian times. As was shown by practical experiments, the consistency of solidified sulphur can easily be adjusted to allow embossing and chasing of filled objects. Therefore, sulphur might act not only as a filler in such items, as was sometimes suggested, but also play a decisive role in the manufacturing of them.