Hollow Nanospheres Research Articles

Boosting anions storage via union of in-situ N doping and mesoporous hollow hard carbon nanospheres for advanced dual-ion capacitors

High structural strength in-situ N-doped mesoporous hollow hard carbon nanospheres (NMHS) is prepared to overcome the low anions storage capacity (93 mAh g−1) of easy exfoliated graphite for dual-ion capacitors (DICs). The rich mesoporous structure facilitates the anions diffusion, and the hollow cavity provides expansion space in storage and weakens the high diffusion resistance in the nuclear bulge. With the synergistic effect, The NMHS delivers a high reversible capacity of 100 mAh g−1 with a low decay of 8 % over 5000 cycles at 2 A g−1. In-situ Raman reveals the storage mechanism on hard carbon is “adsorption (major)-intercalation (minor)”. DFT calculations decode the effective storage action of graphitic N and pyridinic N. Consequently, the assembled NMHS-DICs exhibit good long-cycle performance and heterotherm stability, providing a high energy/power density of 200 Wh kg−1 and 11858 W kg−1. This work verifies a feasible cathode design strategy with future application potential on DICs.

Unlocking enhanced photocatalytic power: Donor-acceptor synergy in non-metallic g-C3N4 hollow nanospheres

Selecting safe, non-toxic, and non-metallic semiconductor materials that facilitate the degradation of pollutants in water stands out as an optimal approach to combat environmental pollution. Herein, graphitic carbon nitride (g–C3N4)–based hollow nanospheres nonmetallic photocatalyst modified with covalent organic framework materials named TpMA, based on 1, 3, 5-trimethylchloroglucuronide (Tp) and melamine (MA), was successfully synthesized (abbreviated as CNTP). The ordered electron donor-acceptor structure inherent in TpMA contributed to enhancing the transport efficiency of photogenerated carriers in CNTP. The CNTP photocatalysts exhibited excellent performance in degrading rhodamine B and tetracycline in visible light, with optimal degradation rates reached more than 90% in 60 and 80 min, respectively, which were 5.3 and 3.0 times higher than those of pure CNNS. The increased photocatalytic efficiency observed in CNTP composites could be traced back to the covalently connection between the two molecules, forming a π-conjugated system that facilitated the separative efficiency of photogenerated electron-hole pairs and intensified the utilization of visible light. This study provided a new means to design and fabricate highly efficient and environmentally friendly non-metallic photocatalytic materials.

Superior triethylamine-sensing properties based on SnO2 hollow nanospheres synthesized via one-step process

Due to serious harm of triethylamine (TEA) to environmental safety and human health, it is significant to synthesize gas-sensitive materials with high performance for TEA detection. However, it is still a challenge to achieve high-sensitivity detection of TEA at low temperature for a sensor synthesized through an economical and efficient method. In this work, hollow-structured SnO2 (HS-SnO2) nanospheres have been fabricated by a facile, low-cost hydrothermal method in one step, which exhibit superior TEA-sensing properties, including not only ultrahigh response (127.75) for 100 ​ppm TEA, good selectivity, but also fast response and recovery time (17/28 ​s), low detection threshold (1 ​ppm) and robust stability at a relatively low optimum operational temperature of 225 ​°C. The excellent gas-sensitizing performances are ascribed to porous hollow structures with rich oxygen vacancies that provide abundant active sites for raising O2 adsorption and reaction of TEA and oxygen species. This work offers an effective and economical strategy for fabricating high-performance TEA sensors for industrial applications.

Ni Single Atom Decorated Porous Hollow Carbon Nanosphere-Based Electrodes for High Performance Symmetric Solid-State Supercapacitors.

Ni single atom containing hollow carbon nanospheres with nitrogen doping has been synthesized by carbonization of Ni(NO3)2/phloroglucinol-formaldehyde polymer/silica composite. The samples have been characterized by powder X-ray diffraction, nitrogen adsorption/desorption, electron microscopic, Raman and X-ray photoelectron spectroscopic studies. The microstructure and surface area vary with the amount of Ni(NO3)2 employed in the syntheses and the carbonization environment. An optimized amount of nickel and argon as the carbonization gas afford Ni-1.0@N@HCN-Ar which possesses overall superior features. The uniformly dispersed Ni single atoms within the hollow porous carbon framework fully utilize all the electroactive sites thereby improving the supercapacitive performance. The specific capacitance of Ni-1.0@N@HCN-Ar reaches 777 F g-1 at 1 A g-1 with a Coulombic efficiency of 98.4 % and excellent recyclability. The energy and power density of Ni-1.0@N@HCN-Ar are found to be high; at 1 A g-1 its energy density is 155.4 Wh kg-1 with a power density of 600.3 W kg-1. At a high current density of 10 A g-1 the material shows a high energy density of 118.4 Wh kg-1 with excellent power density of 6003.4 W kg-1. A symmetric solid-state supercapacitor assembled with this material, Ni-1.0@N@HCN-Ar//Ni-1.0@N@HCN-Ar using H2SO4/PVA gel electrolyte shows a superior energy density value of 30 Wh kg-1 at a power density of 1200 W kg-1.

Regulating the surface Pt coordination environment in the PtN overlayers on PtCuN hollow nanospheres for efficient oxygen reduction reaction

Engineering the surface Pt coordination environment is a promising strategy for promoting the kinetically sluggish oxygen reduction reaction (ORR) on Pt-based catalysts. In this study, we achieve the compressive strain effect and electronic effect by Cu and N co-doping to synthesize the PtCuN hollow nanospheres with PtN overlayers (PtCuN@PtN HNSs) using a facile solvothermal synthesis. Electrochemical investigations show that the constructed disordered Pt–N coordination structures effectively facilitate the ORR and stabilize Pt atoms in the compressed lattice, whereas an excessive N-doping can lead to the formation of a structurally unstable Pt nitride phase. Theoretical analyses confirm that the oxygen reduction kinetics on the compressed PtN overlayers are regulated by a synergistic effect resulting from N-doping and lattice compression, circumventing the traditional linear scaling relationships (LSR). The optimized PtCuN@PtN HNSs, with the composition of PtCu0.29N1.1, demonstrate an area-specific activity of 1.98 mA cm–2 and a mass-specific activity of 1.81 A mgPt–1.

N-doped hollow carbon nanospheres embedded in N-doped graphene loaded with palladium nanoparticles as an efficient electrocatalyst for formic acid oxidation

N-doped hollow carbon nanospheres embedded in N-doped graphene loaded with palladium nanoparticles as an efficient electrocatalyst for formic acid oxidation

A Novel Electrochemical Sensor Based on Pd Confined Mesoporous Carbon Hollow Nanospheres for the Sensitive Detection of Ascorbic Acid, Dopamine, and Uric Acid.

In this study, we designed a novel electrochemical sensor by modifying a glass carbon electrode (GCE) with Pd confined mesoporous carbon hollow nanospheres (Pd/MCHS) for the simultaneous detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA). The structure and morphological characteristics of the Pd/MCHS nanocomposite and the Pd/MCHS/GCE sensor are comprehensively examined using SEM, TEM, XRD and EDX. The electrochemical properties of the prepared sensor are investigated through CV and DPV, which reveal three resolved oxidation peaks for AA, DA, and UA, thereby verifying the simultaneous detection of the three analytes. Benefiting from its tailorable properties, the Pd/MCHS nanocomposite provides a large surface area, rapid electron transfer ability, good catalytic activity, and high conductivity with good electrochemical behavior for the determination of AA, DA, and UA. Under optimized conditions, the Pd/MCHS/GCE sensor exhibited a linear response in the concentration ranges of 300-9000, 2-50, and 20-500 µM for AA, DA, and UA, respectively. The corresponding limit of detection (LOD) values were determined to be 51.03, 0.14, and 4.96 µM, respectively. Moreover, the Pd/MCHS/GCE sensor demonstrated outstanding selectivity, reproducibility, and stability. The recovery percentages of AA, DA, and UA in real samples, including a vitamin C tablet, DA injection, and human urine, range from 99.8-110.9%, 99.04-100.45%, and 98.80-100.49%, respectively. Overall, the proposed sensor can serve as a useful reference for the construction of a high-performance electrochemical sensing platform.

Tailored Covalent Organic Framework Platform: From Multistimuli, Targeted Dual Drug Delivery by Architecturally Engineering to Enhance Photothermal Tumor Therapy.

Engineering bulk covalent organic frameworks (COFs) to access specific morphological structures holds paramount significance in boosting their functions in cancer treatment; nevertheless, scant effort has been dedicated to exploring this realm. Herein, silica core-shell templates and multifunctional COF-based reticulated hollow nanospheres (HCOFs) are novelly designed as a versatile nanoplatform to investigate the simultaneous effect of dual-drug chemotherapy and photothermal ablation. Taking advantage of the distinct structural properties of the template, the resulting two-dimensional (2D) HCOF, featuring large internal voids and a peripheral interconnected mesoporous shell, presents intriguing benefits over its bulk counterparts for cancer treatment, including a well-defined morphology, an outstanding drug loading capability (99.6%) attributed to its ultrahigh surface area (2087 m2/g), great crystallinity, improved tumor accumulation, and an adjustable drug release profile. After being loaded with hydrophilic doxorubicin with a remarkable loading capacity, the obtained drug-loaded HCOFs were coated with gold nanoparticles (Au NPs) to confer them with three properties, including pore entrance blockage, active-targeting capability, and improved biocompatibility via secondary modification, besides high near infrared (NIR) absorption for efficient photothermal hyperthermia cancer suppression. The resultant structure was functionalized with mono-6-thio-β-cyclodextrin (β-CD) as a second pocket to load docetaxel as the hydrophobic anticancer agent (combination index = 0.33). The dual-drug-loaded HCOF displayed both pH- and near-infrared-responsive on-demand drug release. In vitro and in vivo evaluations unveiled the prominent synergistic performance of coloaded HCOF in cancer elimination upon NIR light irradiation. This work opens up a new avenue for exciting applications of structurally engineered HCOFs as hydrophobic/hydrophilic drug carriers as well as multimodal treatment agents.

Fluorescence Enhancement of CdS:Ag Quantum Dots Co-Assembled with Au Nanoparticles in a Hollow Nanosphere Form.

Colloidal quantum dots (QDs) have exceptional fluorescence properties. Overcoming aggregation-induced quenching and enhancing the fluorescence of colloidal QDs have remained a challenging issue in this field. In this study, composite hollow nanospheres composed of Au nanoparticles (NPs) and CdS:Ag-doped QDs were successfully constructed through controlled microemulsion-based cooperative assembly. This method harnessed the localized surface plasmon resonance (LSPR) effect of Au NPs nearby doped QDs, resulting in enhanced doped QD fluorescence and the observation of the Purcell effect. The composite hollow nanospheres show a fluorescence enhancement compared to that of the pure CdS:Ag QDs. The enhanced fluorescence was demonstrated to come from the synergetic enhancement of the absorption and emission transition of the doped QDs. This approach provides a feasible technological pathway to address the challenge of improving the fluorescence performance of the doped QDs.

Fabrication of Polypyrrole Hollow Nanospheres by Hard-Template Method for Supercapacitor Electrode Material.

Conducting polymers like polypyrrole, polyaniline, and polythiophene with nanostructures offers several advantages, such as high conductivity, a conjugated structure, and a large surface area, making them highly desirable for energy storage applications. However, the direct synthesis of conducting polymers with nanostructures poses a challenge. In this study, we employed a hard template method to fabricate polystyrene@polypyrrole (PS@PPy) core-shell nanoparticles. It is important to note that PS itself is a nonconductive material that hinders electron and ion transport, compromising the desired electrochemical properties. To overcome this limitation, the PS cores were removed using organic solvents to create hollow PPy nanospheres. We investigated six different organic solvents (cyclohexane, toluene, tetrahydrofuran, chloroform, acetone, and N,N-dimethylformamide (DMF)) for etching the PS cores. The resulting hollow PPy nanospheres showed various nanostructures, including intact, hollow, buckling, and collapsed structures, depending on the thickness of the PPy shell and the organic solvent used. PPy nanospheres synthesized with DMF demonstrated superior electrochemical properties compared to those prepared with other solvents, attributed to their highly effective PS removal efficiency, increased specific surface area, and improved charge transport efficiency. The specific capacitances of PPy nanospheres treated with DMF were as high as 350 F/g at 1 A/g. And the corresponding symmetric supercapacitor demonstrated a maximum energy density of 40 Wh/kg at a power density of 490 W/kg. These findings provide new insights into the synthesis method and energy storage mechanisms of PPy nanoparticles.

Preparation of hollow TiO2 nanospheres with highly porous surface for effective nucleating agents in supercritical carbon dioxide foaming of thermoplastic polyurethanes

Preparation of hollow TiO2 nanospheres with highly porous surface for effective nucleating agents in supercritical carbon dioxide foaming of thermoplastic polyurethanes

Bimetallic CuFe Prussian Blue Analogue Nanocubes as a Colorimetric Probe for the Quantification of Glutathione

Label-free bimetallic CuFe Prussian blue analogue nanocubes (CuFe PBA NCs) were directly employed as colorimetric probes for the visual determination of glutathione (GSH). CuFe PBA NCs produce an absorption peak at 400 nm. In the presence of GSH, the CuFe PBA NCs were transformed into larger hollow nanospheres based on the acid-initiated Kirkendall effect, leading to the appearance of a new peak at 520 nm and a solution color change from yellow to red. Thus, the GSH-induced color changes allowed the establishment of a double-signal colorimetric assay for GSH using the ratio of absorbance at 520 and 400 nm (Δ(A520/A400)). Facile determination of GSH from 0.1 to 8 μM with satisfactory specificity was developed, providing a detection limit as low as 0.08 μM. Additionally, GSH concentrations exceeding 3 μM can be directly identified by the naked eye. The colorimetric assay for GSH has also been demonstrated to have application for serum analysis. Compared with conventional single-signal colorimetric determination, the ratiometric probe was demonstrated to provide good selectivity and high sensitivity.

Hollow-structured covalent organic framework decorated with FA-PEG: A biocompatible nanocarrier for targeted and pH-responsive release of doxorubicin

Hollow nanostructures hold great promise for drug delivery applications due to their considerable capabilities for efficient drug encapsulation alongside distinct physicochemical attributes. Herein, an imine-linked hollow nanosphere covalent organic framework (COF) with high surface area and well-structured porosity was developed serving as a versatile drug delivery system (DDS) to achieve targeted and effective delivery of doxorubicin (DOX) as a chemotherapeutic agent. The production of COF hollow nanoparticles included the use of a heterogeneous nucleation and growth method, followed by the subsequent encapsulation of DOX. Following this, the nanoparticles underwent functionalization with folate-poly (ethylene glycol)-amine (FA-PEG) using a bonding defect strategy. An in vitro cytotoxicity assay and flow cytometry study against FR-negative HEK293 and FR-positive MCF7 cells were performed, revealing that FA-PEG-functionalized HCOF exhibited a unique targeting effect on cancer cells, surpassing the impact of DOX@HCOF on FR-positive MCF7 cancer cells. Additionally, the hollow architecture of the COF is engineered to undergo disintegration selectively under conditions of cancer cell pH, facilitating the comprehensive release of DOX. The pH-responsive and tumor-targeted attributes of the DOX@HCOF-PEG-FA open new avenues for incorporating structural engineered HCOFs as a promising drug carrier capable of regulating drug release and augmenting therapeutic efficacy.

Incorporating ZIF-8-derived ZnSe into hollow carbon nanospheres as anodes for lithium-ion batteries

Transition metal selenides (TMSs) show great potential as anode materials for lithium-ion batteries (LIBs), boasting a high theoretical capacity. Nevertheless, their practical utility faces challenges, mainly stemming from significant volume changes that lead to rapid capacity decay during charge and discharge cycles. To overcome this challenge, we present a systematic approach involving the growth of uniformly dispersed ultrafine ZnSe nanoparticles derived from ZIF-8 on the surface of hollow carbon nanospheres (ZnSe@N-HCS/700). When utilized as an anode material for LIBs, the ZnSe@N-HCS/700 electrode demonstrates exceptional electrochemical performance. Specifically, it achieves a capacity of 1299 mAh g−1 after 100 cycles at a current density of 100 mA g−1 and maintains a capacity of 614 mAh g−1 even after 1800 cycles at 2500 mA g−1. The hollow structure of the composite alleviates the volume variation of ZnSe nanoparticles during charge and discharge processes, and provides a large reactive surface area, thereby significantly enhancing lithium storage capacity. In conclusion, our strategy presents an innovative approach to synthesize negative electrode materials with unique structures for LIBs.

Dual single atomic Ni sites constructing Janus hollow graphene for boosting electrochemical sensing of glucose.

Single atom catalysts (SACs) have attracted attention due to their excellent catalysis activity under specific reactions and conditions. However, the low density of SACs greatly limits catalytic performance. The three-dimensional graphene hollow nanospheres (GHSs) with very thin shell structure can be used as excellent carrier materials. Not only can its outer surface be used to anchor metal single atoms, but its inner surface can also provide rich sites. Here, a novel step-by-step assembly strategy is reported to anchor nickel single atoms (Ni SAs) on the inner and outer surfaces of GHSs (Ni SAs/GHSs/Ni SAs), which significantly increases the loading capacity of Ni SAs (4.8 wt%). Compared to conventional materials that only anchor Ni SAs to the outer surface of the carrier (Ni SAs/GHSs), Ni SAs/GHSs/Ni SAs exhibits significantly higher electrocatalytic activity toward glucose oxidation in alkaline media. The sensitivity of Ni SAs/GHSs/Ni SAs/GCE is nearly five times higher than that of Ni SAs/GHSs/GCE. Moreover, the sensor based on Ni SAs/GHSs/Ni SAs can detect glucose in a wide concentrationrange of 0.8µM-1.1244mM with a low detection limit of 0.19µM (S/N = 3). This study not only provides an effective sensing material for glucose detection, but also opens a new avenue to construct high-density metal SACs.

Activating Angiogenesis and Immunoregulation to Propel Bone Regeneration via Deferoxamine-Laden Mg-Mediated Tantalum Oxide Nanoplatform.

Vascularization and inflammation management are essential for successful bone regeneration during the healing process of large bone defects assisted by artificial implants/fillers. Therefore, this study is devoted to the optimization of the osteogenic microenvironment for accelerated bone healing through rapid neovascularization and appropriate inflammation inhibition that were achieved by applying a tantalum oxide (TaO)-based nanoplatform carrying functional substances at the bone defect. Specifically, TaO mesoporous nanospheres were first constructed and then modified by functionalized metal ions (Mg2+) with the following deferoxamine (DFO) loading to obtain the final product simplified as DFO-Mg-TaO. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed that the product was homogeneously dispersed hollow nanospheres with large specific surface areas and mesoporous shells suitable for loading Mg2+ and DFO. The biological assessments indicated that DFO-Mg-TaO could enhance the adhesion, proliferation, and osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs). The DFO released from DFO-Mg-TaO promoted angiogenetic activity by upregulating the expressions of hypoxia-inducible factor-1 (HIF-1α) and vascular endothelial growth factor (VEGF). Notably, DFO-Mg-TaO also displayed anti-inflammatory activity by reducing the expressions of pro-inflammatory factors, benefiting from the release of bioactive Mg2+. In vivo experiments demonstrated that DFO-Mg-TaO integrated with vascular regenerative, anti-inflammatory, and osteogenic activities significantly accelerated the reconstruction of bone defects. Our findings suggest that the optimized DFO-Mg-TaO nanospheres are promising as multifunctional fillers to speed up the bone healing process.

Porous hollow nanospheres nickel phosphide and its high catalytic hydrogenation performance on naomaohu coal soluble portion and model compounds

The catalytic conversion of oxygen-containing aromatic ring in lignite under mild conditions is crucial to obtain clean liquid fuel. Here, hollow nanosphere Ni3P-500–24 catalysts were prepared at a calcination temperature of 500 °C and acid-etching time of 24 h. The porous hollow nanospheres structure could expose more catalytic sites, and the electron-rich nickel exhibited a good catalytic activity. The conversion rate of benzyl phenyl ether (BPE) was 100 % (140 ℃, 1 MPa H2, 2 h), and the main products were methylcyclohexane and cyclohexanol, indicating that the catalyst had good catalytic hydrocracking performance. In addition, the catalyst exhibited certain deoxygenation activity and high product selectivity for other oxygen-containing model compounds. For the catalytic hydrogenation of Naomaohu coal (NMHC) soluble portion, the content of alkanes increased from 19 % to 47 %, while the content of oxygen-containing compounds decreased from 56 % to 21 %, which further demonstrate that the catalyst have good catalytic hydrogenation and deoxygenation performance. Density Functional Theory (DFT) calculations showed that the properties of the Ni3P-500–24 catalyst was similar to noble metal, which could activate H2 to produce two kind of active hydrogen: H radical and diatomic hydrogen. The synergistic pathways for the transfer of active hydrogen during the catalytic hydroconversion (CHC) process were analyzed. Above results could provide theoretical guidance for the conversion of lignite into high-quality clean liquid fuels.

In situ electrodeposited Zn-doped CoNiS as an efficient and stable electrocatalyst for overall water splitting in neutral media

Zinc-doped cobalt nickel sulfides coupled with polypyrrole hollow nanospheres grown on carbon paper (Zn-CoNiS/PHS/CP) were developed by unipolar pulse electrodeposition (UPED) method as efficient and stable electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and overall water splitting in neutral media for the first time. With abundant active sites intrigued by moderate Zn doping, the optimized Zn10-CoNiS delivers improved catalytic performance with small overpotentials of 213 mV and 414 mV to achieve the current densities of 10 mA cm−2 for HER and OER respectively, and outstanding long-term stability. The water electrolyzer device with Zn10-CoNiS as both anode and cathode delivers a current density of 10 mA cm−2 at a cell voltage of 1.896 V in neutral media. The low charge transfer resistance of Zn-CoNiS and confinement effect of 2D Ni9S8/Co9S8 nanosheets on 0D ZnS nanodots endow the bifunctional electrocatalysts with efficient activity and high stability, providing a competitive candidate for green hydrogen production.

The role of Ga and Y on binary Al2O3-Y2O3 and Al2O3-Ga2O3 mixed oxides nanoparticles towards potential Ni water-gas shift catalysts

This work focuses on the study of binary Al2O3-Y2O3-x and Al2O3-Ga2O3-x mixed oxides with varying Y2O3 or Ga2O3 nominal loading (x=25, 50) prepared by hydrothermal synthesis assisted by Triton X-100. The mixed oxides were used to prepare Ni-based (5 wt%) catalysts for the Water Gas Shift Reaction. The Al2O3 sample presented urchin-like hollow nanosphere morphology, which evolved to solid nanospheres with Y2O3 or Ga2O3 in the mixed oxides. The physicochemical characterization indicated good integration of the mixed oxides, especially on the low-content additive oxides. The theoretical results confirmed that Ga goes deeper into the alumina matrix than Y, partially explaining the XPS and HRTEM results in which the Ni dispersion was better in the Ni/AlGa-x samples. The FTIR in-situ measurements of the reaction allowed us to propose that the reaction occurs minimally through the carbonyl mechanism at low temperatures (<300 °C) and the formate mechanism at high temperatures (>300 °C).

Significantly enhanced ion‐migration and sodium‐storage capability derived by strongly coupled dual interfacial engineering in heterogeneous bimetallic sulfides with densified carbon matrix

AbstractThe development of highly efficient sodium‐ion batteries depends critically on the successful exploitation of advanced anode hosts that is capable of overcoming sluggish reaction kinetics while also withstanding severe structural deformation triggered by the large radius of Na+‐insertion. Herein, a hierarchically hybrid material with hetero‐Co3S4/NiS hollow nanosphere packaged into a densified N‐doped carbon matrix (Co3S4/NiS@N‐C) was designed and fabricated utilizing CoNi‐glycerate as the self‐sacrifice template, making the utmost of the synergistic effect of hetero‐Co3S4/NiS with strong electric field and rich reaction active‐sites together with the densified outer‐carbon scaffolds with remarkable electronic conductivity and robust mechanical toughness. As anticipated, as‐fabricated Co3S4/NiS@N‐C anode affords remarkable specific capacity, prolonged cycle lifespan up to 2 400 cycles with an only 0.05% fading each cycle at 20.0 A g−1, and excellent rate feature (354.9 mAh g−1 at 30.0 A g−1), one of the best performances for most existing Co3S4/NiS‐based anodes. Ex situ structural characterizations in tandem with theoretical analysis demonstrate the reversible insertion‐conversion mechanism of initially proceeding with Na+ de‐/intercalation and superior heterogeneous interfacial reaction behavior with strong Na+‐adsorption ability. Further, sodium‐ion full cell and hybrid capacitor based on Co3S4/NiS@N‐C anode exhibit impressive electrochemical characteristics on cycling performance and rate capability, showcasing its outstanding feasibility toward practical use.