The structure of the planetary boundary layer above a valley of the Swiss Plateau is investigated. The very high night-time loss rates of O 3 observed are mainly attributable to dry deposition at the surface. Although it can be inferred that smog-chemistry plays an important role, homogeneous chemistry accounts on average for only about 20% of the observed O 3 destruction rates. It is concluded that the dry deposition of O 3 at night is much more effective in the hilly terrain around the field site than over horizontally homogeneous terrain. This increase in efficiency is linked with a local wind system. The O 3 destruction due to dry deposition occurs mainly in layers of nocturnal downslope wind where O 3-rich air is brought to the ground during the whole night. Hence the air reaching the bottom of the valley has a very low O 3 content and the upward airflow associated with this local wind system leads to continuous O 3 depletion within the lower part of the boundary layer. It follows that the increased effectiveness of the dry deposition in hilly terrain results in a self-cleaning mechanism of the atmosphere which is not necessarily restricted to O 3.
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