High Deformation Research Articles

Elastic-Plastic Fully π-Conjugated Polymer with Excellent Energy Dissipation Capacity for Ultra-Deep-Blue Flexible Polymer Light-Emitting Diodes with CIEy = 0.04.

Emerging intrinsically flexible fully π-conjugated polymers (FπCPs) are a promising functional material for flexible optoelectronics, attributed to their potential interchain interpenetration and entanglement. However, the challenge remains in obtaining elastic-plastic FπCPs with intrinsic robust optoelectronic property and excellent long-term and cycling deformation stability simultaneously for applications in deep-blue flexible polymer light-emitting diodes (PLEDs). This study, demonstrates a series of elastic-plastic FπCPs (P1-P4) with an excellent energy dissipation capacity via side-chain internal plasticization for the ultra-deep-blue flexible PLEDs. First, the freestanding P1 film exhibited a maximum fracture strain of 34.6%. More interestingly, the elastic behavior is observed with a low strain (≤10%), and the stretched film with a high deformation (>10%) attributed to plastic processing revealed the robust capacity to realize energy absorption and release. The elastic-plastic P1 film exhibits outstanding ultra-deep-blue emission, with an efficiency of 56.38%. Subsequently, efficient PLEDs are fabricated with an ultra-deep-blue emission of CIE (0.16, 0.04) and a maximum external quantum efficiency of 1.73%. Finally, stable and efficient ultra-deep-blue electroluminescence are obtained from PLEDs based on stretchable films with different strains and cycling deformations, suggesting excellent elastic-plastic behavior and deformation stability for flexible electronics.

Effect of silane treatment on eggshell powder incorporated in poly (L-lactic acid) composite membrane

ABSTRACT The treatment of water containing oil from various industrial and environmental sources is a challenging issue. Polymeric composite membranes with reinforcing fillers have been extensively used to overcome this issue. In this study, poly(L-lactic acid) (PLLA) incorporated with eggshell powder (ESP) composite membranes were prepared to absorb oil in water. ESP has been modified into silane-treated ESP (SESP) by using the silane coupling agent, 3-(methacryloyloxy)propyl trimethoxysilane (MPTS) to enhance the compatibility of the ESP in the membrane. The concentration of MPTS solution used to treat the ESP has been varied at 1%, 3% and 5% denoted as SESP1, SESP3, and SESP5, respectively to observe the chemical and mechanical properties of the composite membrane. Composite membranes reinforced with SESP have high deformation resistance with a modulus value of 2105.45 MPa compared to 1892.77 MPa of PLLA membrane. At 5% MPTS concentration, the membrane’s water contact angle (WCA) increased to 75°. The oil absorption ability of the composite membrane filled with SESP5 increased from ~ 14% to 71%. The use of MPTS to modify the surface of the ESP has improved the compatibility between the reinforcing filler and the polymer matrix as well as with the oil absorption capability.

Failure analysis of stainless steel metal hose used for welding

While using ammonia (NH3) gas at 10 bar/500℃, a stainless steel 304 metal hose used as a bellow expansion joint was fractured. It was observed that the fracture of the metal hose started near the weld between the hose and the flange, and progressed to approximately 1/4 of the circumference of the weld.No metallurgical defects were found in the weld where the crack occurred. However, the folded part of the metal hose is welded to the flange, which can cause cracks. In other words, when the metal hose is forcibly compressed or stretched in order to weld it to the flange, the stress concentration due to cold work, including residual stress cause the metal hose to become brittle or crack. It is determined that when a high strain cyclic load or torsional deformation is applied to a high-hardness metal component, the metal hose will reach fatigue failure in a short period of time.

Extremely sensitive mechanochromic photonic hydrogels with ultrahigh mechanical properties for multicolor displays by naked eyes

Photonic soft materials, especially responsive photonic hydrogels (RPHs) with periodic permittivity on the submicroscale, have been garnering interest as colorimetric indicators and mechanochromic sensors. However, the fabrication of RPHs with both bright discoloration, satisfactory mechanical properties, and excellent mechanochromic sensitivity to meet the practical applications is still a great challenge. Herein, we develop a novel photonic crystal material using a Fe3O4 array embedded poly(N-isopropylacrylamide-co-acrylamide)/ laponite-XLS (PNA-XLS) hydrogel, which is dual-cross-linked by chemical and physical cross-linkers. Due to the interaction of sparse chemical links and apposite physical links between the polymeric networks, the PNA-XLS exhibits a significant energy dissipation and high deformation capacity, with an enhanced tensile strength above 819 kPa and elongation above 1015 %. It almost has a full-color tunable range and shows bright discoloration that can be reversibly actuated by bending, stretching, and small pressures (Pa level), with extremely high sensitivities of pressure (161 nm kPa−1) and tension (1.52 nm %−1). Moreover, its self-adhesion (133 kPa) would make it be an appealing candidate to develop portable sensors or wearable devices without auxiliary adhesive tools. Besides, elastic hydrogels with programmable and multicolor patterns can be designed by the mask-assisted UV photopolymerization of regional pregel solution. Therefore, such hydrogel has a great application potential in colorimetric indicators, mechanochromic sensors, anti-counterfeiting and wearable devices.

Probing the microstructure and deformation mechanism of an FeCoCrNiAl0.5 high entropy alloy during nanoscratching: a combined atomistic and physical model study.

High entropy alloys (HEAs) exhibit superior mechanical properties. However, the nanoscratching properties and deformation behaviour of FeCoCrNiAl0.5 HEAs remain unknown at the nanoscale. Here, we investigate the effect of scratching depth on the microstructural and tribological characteristics of an FeCoCrNiAl0.5 HEA using molecular dynamics simulations combined with a physical model. The scratching force increases significantly as the scratching depth increases. In the lower part of the scratching region, there is a clear atomic movement process, with the load generated in the normal direction causing the atoms to shift downwards. Noticeable shear bands are formed in the subsurface area, and they are both small and narrow compared with the pure Ni. The plastic deformation mechanism of the compressed surface is mainly governed by the formation and expansion of stacking faults during the subsurface evolution process. The evolution process of screw dislocations is similar to that of edge dislocations. In addition, the high strength and deformation resistance of FeCoCrNiAl0.5 HEAs are further evaluated by establishing a microstructure-based physical model. The combined effect of the lattice distortion strengthening and dislocation strengthening promotes the high strength of the FeCoCrNiAl0.5 HEA, which is significantly better than the single strengthening mechanism of pure metals. These results accelerate the understanding of the mechanical properties and deformation mechanisms of HEAs.

Cell size and deformation measurement using constrictions integrated into a microfluidic device

In this study, we developed a microfluidic device to evaluate cell size and deformability. As a specific method, a physical pushing load was applied to the cells using a channel having a constriction with a height of 1 μm. In addition, by orienting the constriction in a vertical direction, it was possible to measure the cell area easily using a microscope under load. The system constructed in this study can evaluate the contact area between the cells and the glass surface before and after applying a load under a microscope. The only input parameter was the syringe flow rate, and it was possible to evaluate multiple cells in a cell suspension simultaneously. Also, since the flow rate is 50 μm min−1 or less, there is no need for a high-speed camera. This time, we evaluated cell types with different characteristics: NIH/3T3 and smooth muscle cells (SMC). To evaluate deformability, we focused on the circularity of the cells during load application. Due to the influence of the flow within the channel, cells with high deformability assumed an almost elliptical shape and flowed through the constriction. Using the device developed in this study, we confirmed that SMCs, which are muscle cells, have large variations in cell size and hardness among individual cells. Finally, we discussed these results and possible future applications.

Effect of Ti micro-addition on the hot tensile behaviour, microstructure and fractography of low-C high-manganese steels

The aim of the work was to determine the effect of Ti micro-addition on the hot tensile behaviour, microstructure and fractography of two low-C high-manganese steels with additions of Si and Al. The hot tensile tests were performed using the Gleeble 3800 thermomechanical simulator. Samples were stretched at a temperature range from 1050 ℃ to 1200 ℃ at a strain rate of 2.5·10 3 s−1. The microstructure of the tested high-manganese steels under conditions of hot deformation was influenced by strain hardening and simultaneous dynamic recrystallization, as well as precipitation processes-depending on the chemical composition of the alloy and plastic deformation parameters. The analysis of the curves registered in the hot tensile tests indicated that a decrease of strain hardening was the result of the dynamic recrystallization. Hot tensile curves of the Ti-micro-alloyed steel were characterized by higher yield stress compared to the Ti-free steel. The Ti micro-addition with a concentration of 0.075 wt.% guaranteeing stable TiN-type nitrides eliminated the possibility of precipitating AlN-type nitrides and complex MnS-AlN type non-metallic inclusions, which are harmful to hot ductility. Fracture modes of the Ti-free steel showed a mixed nature from 1050 ℃ to 1150 °C, i.e. ductile fracture and numerous cavities and voids were identified. As the deformation temperature increased to 1200 °C, the fracture character was brittle with numerous inter-crystalline cracks along austenite grain boundaries. The addition of Ti improved significantly the hot ductility behaviour characterized by higher values of flow stress and reduction in area as well as ductile fracture modes in the entire high deformation temperature range.

Prevalence of Autoantibodies (ACPA) and Rheumatoid Factor among Rheumatoid Arthritis Patients in Sulaymaniyah

Background and objectives: Rheumatoid factor and anticitrullinated protein antibodies are the most characteristic autoantibodies for rheumatoid arthritis. Our aims were to evaluate the prevalence of Rheumatoid factor and anticitrullinated protein antibodies and their association with demographic and clinical characteristics of patients with RA. Methods: This is a cross-sectional study which was conducted at Rheumatology and Rehabilitation Center/Sulaymaniyah from February 2022 to November 2022. The study included patients with rheumatoid arthritis from both sexes. Socio-demographic and clinical data were collected. Enzyme linked immunosorbent assay was used to estimate serum levels of rheumatoid factor and anticitrullinated protein antibodies antibody titer. Results: The prevalence of rheumatoid factor was 72.61%. Each of high disease activity, mean DAS28 scores, rheumatoid nodules and deformities were significantly associated with rheumatoid factor positivity (P= 0.015, P= 0.025, P= 0.007 and P<0.001, respectively). The prevalence of anticitrullinated protein antibodies was 68.87%. High disease activity, rheumatoid nodules and deformities were significantly associated with anticitrullinated protein antibodies (P= 0.014, P<0.001 and P<0.001, respectively). Conclusions: The prevalence of rheumatoid factor and anticitrullinated protein antibodies among patients with rheumatoid arthritis was within the global context. High disease activity and the presence of rheumatoid nodules are positively associated with rheumatoid factor-positivity. Number of tender joints and the presence of rheumatoid nodules were positively associated with anticitrullinated protein antibodies-positivity.

Annealing-induced multi-heterogeneous microstructure strengthening in FeCoCrNiMo0.2 high-entropy alloys

In this study, by conducting cryogenic rolling (CR) followed by short-term annealing (CRA), we achieved the annealing-induced hardening in a single-phase FCC FeCoCrNiMo0.2 high-entropy alloy by introducing multiple heterostructures structures. Through this approach, the yield strength, ultimate tensile strength and tensile fracture elongation of CRA alloy were increased from 1116.8 MPa to 1286.1 MPa, 1363.2 MPa to 1576.3 MPa and 5.4–6.9 %, respectively. Furthermore, a broader steady state of strain softening behavior was found in the CRA alloy, which is attributed to the additional strengthening and hardening effects resulting from high density of deformation nanotwins and phase transformations. Additionally, the research results show that the ultra-high strength and sufficient ductility of CRA alloy are attributed to the synergistic effect of multiple mechanisms, such as strengthening induced by heterogeneous microstructure of σ precipitate/HCP phase/FCC matrix phase, and high work hardening ability caused by the heterogeneity of high density deformation nanotwins, geometrically necessary dislocations (GND), stacking faults (SFs) and Lomer-Cottrell locks (L-C locks) nano-scale defects. This work provides useful insights for alloys that involves multiple heterogeneous microstructures strengthening and provides a promising approach for the design and manufacture of high-strength structural materials.

Hierarchical looping results in extreme extensibility of silk fibre composites produced by Southern house spiders (Kukulcania hibernalis).

Spider silk is a tough and versatile biological material combining high tensile strength and extensibility through nanocomposite structure and its nonlinear elastic behaviour. Notably, spiders rarely use single silk fibres in isolation, but instead process them into more complex composites, such as silk fibre bundles, sheets and anchorages, involving a combination of spinneret, leg and body movements. While the material properties of single silk fibres have been extensively studied, the mechanical properties of silk composites and meta-structures are poorly understood and exhibit a hereto largely untapped potential for the bio-inspired design of novel fabrics with outstanding mechanical properties. In this study, we report on the tensile mechanics of the adhesive capture threads of the Southern house spider (Kukulcania hibernalis), which exhibit extreme extensibility, surpassing that of the viscid capture threads of orb weavers by up to tenfold. By combining high-resolution mechanical testing, microscopy and in silico experiments based on a hierarchical modified version of the Fibre Bundle Model, we demonstrate that extreme extensibility is based on a hierarchical loops-on-loops structure combining linear and coiled elements. The stepwise unravelling of the loops leads to the repeated fracture of the connected linear fibres, delaying terminal failure and enhancing energy absorption. This principle could be used to achieve tailored fabrics and materials that are able to sustain high deformation without failure.

A component method approach for single-sided beam-to-column joints with CHS column and welded double-tee beam

This paper focuses on predicting the flexural stiffness and strength of beam-to-column joints with Circular-Hollow-Section (CHS) columns and externally welded double-tee beams using the Component Method approach. Currently, Eurocode 3 Part 1.8 lacks guidelines for assessing the stiffness of these joints, resulting in their practical modelling using extreme assumptions like pin or full restraint. Nevertheless, the literature demonstrates that these joints can exhibit semi-rigid behaviour due to the relatively high local deformability of the tube in the joint area. Another concern relates to the strength of these joints. In fact, recent studies have shown that Eurocode 3 Part 1.8 formula for predicting the yield resistance of these joints is over-conservative.Within this framework, the purpose of this study is to fill the current knowledge gaps (over-conservative strength prediction and lack of rules for determining the stiffness) by undertaking a thorough investigation involving numerical and analytical activities. Specifically, the research presents a component-based modelling approach for predicting stiffness and strength of CHS to double-tee beam connections.In this regard, the work presented in this paper has involved the selection of experimental tests from literature to validate a Finite Element (FE) model, specifically focusing on X- and T-joints and internal and external beam-to-column joints. The validated numerical models have been then employed to simulate the response under monotonic loading conditions of additional sets comprising forty T-joints and thirty external beam-to-column joints, respectively. The currently available formulations for predicting the resistance of T-joints were applied to the forty cases simulated, evaluating their accuracy. This allowed the individuation of the most accurate literature formula for the strength prediction of T-joints, showing that the recent proposal of Voth and Packer (2012) yields sufficiently accurate results. Instead, analytical formulations for predicting the stiffness of T-joints were properly derived in a closed-form solution and were validated against the results of the parametric study. Finally, drawing upon knowledge regarding the stiffness and strength of T-joints, the flexural response of external beam-to-columns connections was evaluated proposing a component model, whose accuracy was verified against the cases simulated in the parametric analysis.

Biodegradable and Flexible Wood-Gelatin Composites for Soft Actuating Systems.

Compliant materials are indispensable for many emerging soft robotics applications. Hence, concerns regarding sustainability and end-of-life options for these materials are growing, given that they are predominantly petroleum-based and non-recyclable. Despite efforts to explore alternative bio-derived soft materials like gelatin, they frequently fall short in delivering the mechanical performance required for soft actuating systems. To address this issue, we reinforced a compliant and transparent gelatin-glycerol matrix with structure-retained delignified wood, resulting in a flexible and entirely biobased composite (DW-flex). This DW-flex composite exhibits highly anisotropic mechanical behavior, possessing higher strength and stiffness in the fiber direction and high deformability perpendicular to it. Implementing a distinct anisotropy in otherwise isotropic soft materials unlocks new possibilities for more complex movement patterns. To demonstrate the capability and potential of DW-flex, we built and modeled a fin ray-inspired gripper finger, which deforms based on a twist-bending-coupled motion that is tailorable by adjusting the fiber direction. Moreover, we designed a demonstrator for a proof-of-concept suitable for gripping a soft object with a complex shape, i.e., a strawberry. We show that this composite is entirely biodegradable in soil, enabling more sustainable approaches for soft actuators in robotics applications.

Constant-curvature bending response of thin glass: Analytical, numerical and experimental study of “clamp-bending” tests

New generation thin, lightweight and damage-resistant glass, having impressively impact resistance and ability to be bent up to small radii, appears to be the optimal material for extremely deformable structural elements. Its structural use and design require an accurate evaluation of its mechanical properties. However, standard methods to test the glass strength, as the Four-Point Bending and the Coaxial Double Ring test, cannot be used for thin glass, due to its high deformability. Here, an innovative test is proposed, consisting into deforming a thin element into a costant-curvature shape, by prescribing a rotation on two opposite edges of a rectangular plate, while allowing the adjustment of the distance between the supporting hinges. This produces a deformation into an arch of a circle and to a constant stress distribution, allowing to determine the thin glass strength with very simple formulas. An innovative experimental setup, recently proposed for twisting tests on thin glass, has been adapted for constant-curvature bending tests, based on the results of both analytical modelling and numerical analyses. This has been used to perform an experimental campaign, comprising 15 destructive tests on chemically tempered thin glass.

The Swelling–Shrinkage Properties of Intact and Disturbed Clayey and Marly Soils: The Density Effect

Expansive soils commonly encountered beneath foundations often lead to structural issues inducing expensive repairs. With the increase of the frequency of dry summers and irregular rainfall patterns, the clayey and marly soils become more and more sensitive to shrinking and swelling phenomena. So to find solutions and improve the knowledge on such phenomena especially in temperate countries where the saturation state is considered as the usual soil state, the impact of the soil density on shrinkage was studied by varying the compaction mode and introducing a swelling step before shrinkage. As expected, dynamically or statically compacted clayey or marly soils exhibited high shrinkage deformation when the soil had a low density. The swelling before shrinkage impacted the soil structure but ultimately had a low effect on shrinkage deformation. Swelling deformation was also influenced by density; the denser the soil, the more sensitive the compacted soil became to swelling. Furthermore, compaction modes induced differences in swelling or shrinkage amplitude that couldn’t be explained by microstructural observations. Finally, results demonstrated that intact soil behavior after shrinkage could be extrapolated from swelling–shrinkage tests conducted on remolded soil samples, thus decreasing the cost of field investigations.

Preparation of the gradient nanostructured layer in uranium by surface shot peening treatment

The gradient nanostructured layer in uranium prepared by surface shot peening treatment has been systematically characterized. The evolution of the ultrafine grains within the surface layer of uranium was derived. The results show that the gradient microstructures from the surface to the matrix could be divided into four zones including ultrafine grains, high density deformation twins, low density deformation twins, and coarse grain matrix. The deformed microstructures in the four zones were characterized in detail. Twinning and dislocation activities were found to be the main plastic deformation mechanisms for grain refinement in uranium. Four types of twinning and dislocation slip modes were distinguished. The formation of fine equiaxed grains on uranium surface should be attributed to the combined action of the twinning, dislocation activities, and the subgrain rotation driven by mechanical-thermal coupling. The surface microhardness and the natural oxidation corrosion performance were improved in uranium prepared by shot peening treatment.

Site-specific probabilistic seismic hazard analysis in Nuweiba, Gulf of Aqaba, Egypt: Combining area source model and active faults

Gulf of Aqaba in Eastern Egypt is characterized by significant seismic activity and high deformation rate, making it a major source of destructive earthquakes in the region. While previous studies have produced probabilistic seismic hazard analysis (PSHA) maps for the region, they have not adequately accounted for active faults or site response in their calculations. This study introduces a newly developed seismic source model for the Gulf of Aqaba, considering area source, active fault source, and a combination of both models to improve seismic hazard assessment for the region. The study incorporates the previously measured average shear-wave velocity for the upper 30 m (Vs30), fundamental frequency (F0), and amplification factor (A0) at some selected sites in Nuweiba city. Accordingly, site-specific PSHA is carried out for the bedrock condition (Vs30 = 800 m/s, according to the Egyptian Building Code) and for the surface of soft sediments using F0, A0, and Vs30. Uncertainties in slip rate, maximum magnitude, and recurrence model are accounted during PSHA computation. Ground motion parameters such as peak ground acceleration (PGA) and spectral acceleration (SA) for various probabilities of exceedance in 50-year lifetime are calculated for both rock site conditions and soft sediments. The maximum calculated PGA and SA are 0.65 g and 1.25 g, respectively, for a 10% probability of exceedance over 50 years at bedrock conditions.

Investigating the effect of changing the geometric characteristics on the seismic behavior of the yielding shear panels

The use of different types of shear panels as a large group of yielding dampers has been investigated. Acceptable seismic behavior such as stiffness and high deformation capacity, appropriate lateral resistance, ease of construction, and use in the structure are among the most important. Different types of these dampers have been developed, and yield shear panel device (YSPD) dampers are one of them. This research investigates the effects of changes in the geometric dimensions of this type of damper on their seismic behavior. For this purpose, nonlinear finite element models of dampers under cyclic loading were analyzed. The obtained results showed that the simultaneous use of side plates and stiffeners can create suitable conditions for directly controlling the dimensions of the damper. Local buckling in the side plates may concentrate deformations in this part of the damper element, affecting the hysteresis behavior with pinching. In addition, increasing the thickness of the side plate linearly has increased the yield strength and ultimate strength of these dampers. Finally, it was found that the increase in shear plate stiffness can directly increase the energy absorbed by this type of damper, effectively improving the seismic capacity of YSPD dampers.

Reconfigurable 4D printing via mechanically robust covalent adaptable network shape memory polymer.

4D printing enables 3D printed structures to change shape over "time" in response to environmental stimulus. Because of relatively high modulus, shape memory polymers (SMPs) have been widely used for 4D printing. However, most SMPs for 4D printing are thermosets, which only have one permanent shape. Despite the efforts that implement covalent adaptable networks (CANs) into SMPs to achieve shape reconfigurability, weak thermomechanical properties of the current CAN-SMPs exclude them from practical applications. Here, we report reconfigurable 4D printing via mechanically robust CAN-SMPs (MRC-SMPs), which have high deformability at both programming and reconfiguration temperatures (>1400%), high Tg (75°C), and high room temperature modulus (1.06 GPa). The high printability for DLP high-resolution 3D printing allows MRC-SMPs to create highly complex SMP 3D structures that can be reconfigured multiple times under large deformation. The demonstrations show that the reconfigurable 4D printing allows one printed SMP structure to fulfill multiple tasks.

Healthy and diseased tensile mechanics of mouse lung parenchyma

The mechanics of the lung, consisting of high deformation, non-linear, rapid and cyclic loading, remain a critical unknown, hindering advancements in the field despite the pressing urgency of incurable and often fatal pulmonary diseases; such multi-scale ailments impair organ mechanical function by inducing tissue-level alterations. Here, the tensile mechanics of healthy and diseased murine lung parenchyma with induced variable fibrosis and emphysema are compared—exploring multi-rate and directional tissue elasticity and energetics. Remarkably, parenchymal tissue is found to be notably elastic and non-hysteresis prone. Additionally, chronic fibrosis-induced tissues reveal significantly reduced compliance compared to age-matched controls, indicating characteristic stiffening; moreover, maximum stress tends to be greater in exposed than controls. Emphysematous tissues tend to show lower maximum stress than controls, reflective of hallmark tissue destruction and softening. Furthermore, faster loading rate is found to generally yield elevated stiffness and maximum stress, significantly for fibrosis group exposed tissue—this interdependence between loading rate and tissue disease is notable considering the dynamics of breathing. Generally, control tissues are found to be isotropic, as are emphysematous tissues, but fibrosis may lead to increased anisotropy. Additionally, fibrotic and mature-healthy lungs are found to show age effect trends, such as increased strain energy. Along with these findings, this study additionally facilitates future analyses of other diseases by establishing lung biaxial testing protocols for small-scale murine specimens, which can serve as practical and ethical models for exploring human diseases. Overall, this study offers fundamental material characterizations which will enable future formulations of experimentally informed computational models.

Elastic constants of biogenic calcium carbonate

Living organisms form complex mineralized composite architectures that perform a variety of essential functions. These materials are commonly utilized for load-bearing purposes such as structural stability and mechanical strength in combination with high toughness and deformability, which are well demonstrated in various highly mineralized molluscan shell ultrastructures. Here, the mineral components provide the general stiffness to the composites, and the organic interfaces play a key role in providing these biogenic architectures with mechanical superiority. Although numerous studies employed state-of-the-art methods to measure and/or model and/or simulate the mechanical behavior of molluscan shells, our understanding of their performance is limited. This is partially due to the lack of the most fundamental knowledge of their mechanical characteristics, particularly, the anisotropic elastic properties of the mineral components and of the tissues they form. In fact, elastic constants of biogenic calcium carbonate, one of the most common biominerals in nature, is unknown for any organism. In this work, we employ the ultrasonic pulse-echo method to report the elasticity tensor of two common ultrastructural motifs in molluscan shells: the prismatic and the nacreous architectures made of biogenic calcite and aragonite, respectively. The outcome of this research not only provides information necessary for fundamental understanding of biological materials formation and performance, but also yields textbook knowledge on biogenic calcium carbonate required for future structural/crystallographic, theoretical and computational studies.