High Utilization Ratio Research Articles

The effects of longitudinal joint assembly imperfections on the internal forces in segmental linings

AbstractDuring the assembly of concrete segments into a tunnel lining, small geometric imperfections are unavoidable. In the longitudinal joints, they lead to contact deficiencies, which affect the eccentricities of the forces transferred through them. This influences the development of internal forces along the lining's circumference. However, it is often not realistically considered in structural calculations. In this paper, the effects of longitudinal joints assembly imperfections on the lining's internal forces were investigated by employing finite element models for various lining configurations. The results show that assembly imperfections have an unfavorable effect on the internal forces in most cases. Depending on the loading situation, this can lead to more required reinforcement and higher utilization ratios in the segments field and joints compared to perfectly assembled linings. Stiffer and less deformable configurations are at higher risk of experiencing more severe effects. In systems at risk, an individual assessment is recommendable. Therefore, a simplified method is introduced that requires a significantly reduced modeling effort and calculation time and lower software capabilities.

A review of near‐net shape forming by hot isostatic pressure technology

AbstractNear‐net shaping hot isostatic pressing (NNS‐HIP) forming process has the advantage of high material utilization ratio and good uniformity of billet microstructure. It is widely used to produce critical parts for harsh service environments in special fields such as aerospace and energy and chemical industry. This paper introduces the process characteristics and production flow of hot isostatic near‐net forming, the representative materials of hot isostatic near‐net forming, the development and application at home and abroad, and the micro‐ and macromodels of numerical simulation powder densification by HIP near‐net forming. Finally, the challenges and development trends of this technology are prospected, and corresponding countermeasures are put forward.

A hierarchical host microstructure enables regulated inner Li deposition for stable Li metal electrodes

Dendritic lithium (Li) deposition is a critical issue hindering the development of next-generation high-energy-density Li metal batteries (LMBs). Confining Li deposition within a three-dimensional host is a general strategy to suppress the volume expansion of the Li electrode. However, precise control of continuous Li growth in the pore space of the host is rarely investigated, which is a crucial issue to enable a high utilization ratio of the hosted Li for practical LMBs. Herein, a novel hierarchical host structure possessing a multifunctional secondary porous structure to regulate the continuous Li growth with high uniformity and reversibility is proposed. The secondary porous structure consisting of carbon nanotubes, nickel and Li2O-enriched solid electrolyte interphase is in-situ generated via lithiation reaction of a modified nickel foam scaffold, exhibiting high lithiophilicity, fast Li+ transportation and charge transfer. The LMB utilizing Li metal electrodes hosted by this rational structure achieved a stable cycling over 300 cycles with a practical LiFePO4 positive electrode (~2.5 mAh cm-2) at 0.5C/0.5C in the voltage window of 2.5-4.4 V. This work provides a novel approach to designing the host microstructure for constructing more stable Li metal electrode in practical LMBs.

Pyrene-Based Metal-Organic Frameworks with Coordination-Enhanced Electrochemiluminescence for Fabricating a Biosensing Platform.

Enhancing the electrochemiluminescence (ECL) properties of polycyclic aromatic hydrocarbons (PAHs) is a significant topic in the ECL field. Herein, we elaborately chose PAH derivative luminophore 1,3,6,8-tetrakis(p-benzoic acid)pyrene (H4TBAPy) as the organic ligand to synthesize a new Ru-complex-free ECL-active metal-organic framework Dy-TBAPy. Interestingly, Dy-TBAPy exhibited a more brilliant ECL emission and higher ECL efficiency than H4TBAPy aggregates. On the one hand, TBAPy luminophores were assembled into rigid MOF skeleton via coordination bonds, which not only enlarged the distance between pyrene cores to eliminate the aggregation-caused quenching (ACQ) effect but also obstructed the intramolecular motions of TBAPy to diminish the nonradiative relaxation, thus realizing a remarkable coordination-enhanced ECL. On the other hand, the ultrahigh porosity of Dy-TBAPy was beneficial to the diffusion of electrons, ions, and coreactant (S2O82-) in the skeleton, which efficiently boosted the excitation of interior TBAPy luminophores and led to a high utilization ratio of TBAPy, further improving ECL properties. More intriguingly, the ECL intensity of the Dy-TBAPy/S2O82- system was about 4.1, 87.0-fold higher than those of classic Ru(bpy)32+/TPrA and Ru(bpy)32+/S2O82- systems. Considering the aforementioned fabulous ECL performance, Dy-TBAPy was used as an ECL probe to construct a supersensitive ECL biosensor for microRNA-21 detection, which showed an ultralow detection limit of 7.55 aM. Overall, our study manifests that coordinatively assembling PAHs into MOFs is a simple and practicable way to improve ECL properties, which solves the ACQ issue of PAHs and proposes new ideas for developing highly efficient Ru-complex-free ECL materials, therefore providing promising opportunities to fabricate high-sensitivity ECL biosensors.

Optimized design of cubic grid coil system with high space utilization ratio for weak biomagnetic signal measurement

The uniform field coils with large uniform region are important for improving the resolution in bio-magnetic signal measurements. The traditional coil design methods suffer from small space utilization ratio which limits the mobility and accuracy of bio-magnetic signal measurements. In this paper, a novel cubic grid coil (CGC) design method is presented, with significantly improved space utilization ratio and simple structure. The iterative fastest current drop method (IFCD) is proposed to simplify coil structure, thus ensuring the controllability of the cubic grid coil system. The superiority of CGCs has been demonstrated by finite element simulations and a series of experiments. The space utilization ratio of CGCs reaches 22.4% while maintaining 2% inhomogeneity, improved by about 6 times compared with traditional coils. Furthermore, the CGC-based system for directly eliminating the geomagnetic field achieves a low residual magnetic field noise of 29.7 pT/Hz/1/2 at 1 Hz. The CGCs can provide new ideas for high-resolution, lightweight mobile measurements of weak bio-magnetic signals in the human body.

Meshing principle and numerical study of classic conic worm drive

To explore the meshing mechanism of classic conic worm drive and provide a theoretical basis for creating other types of worm drive, a complete meshing theory on the proposed worm pair and its meshing performance are investigated. A new mathematical model containing a full set of geometric parameters on this drive is established using differential geometry. The formulae for calculating the reference point coordinates in different coordinate systems are attained, and then the blank size of the conical worm wheel is given. To build tooth surface boundaries, the meshing theory based on reference point is applied, which ensures the location of this point on the tooth surface. By solving multivariate nonlinear equation system in MATLAB environment, these conjugate regions and instantaneous contact lines are plotted within the axial section of the conic worm pair, at the same time, these values of sliding angle and induced principal curvature at meshing points are calculated. Finally, a numerical study is performed and the results verify that the conic worm pair has a relatively high tooth surface utilization ratio and favorable conditions for contact stress and lubrication, which is consistent with the practical application.

Facile Lithium Densification Kinetics by Hyperporous/Hybrid Conductor for High-Energy-Density Lithium Metal Batteries.

Lithium metal anode (LMA) emerges as a promising candidate for lithium (Li)-based battery chemistries with high-energy-density. However, inhomogeneous charge distribution from the unbalanced ion/electron transport causes dendritic Li deposition, leading to "dead Li" and parasitic reactions, particularly at high Li utilization ratios (low negative/positive ratios in full cells). Herein, an innovative LMA structural model deploying a hyperporous/hybrid conductive architecture is proposed on single-walled carbon nanotube film (HCA/C), fabricated through a nonsolvent induced phase separation process. This design integrates ionic polymers with conductive carbon, offering a substantial improvement over traditional metal current collectors by reducing the weight of LMA and enabling high-energy-density batteries. The HCA/C promotes uniform lithium deposition even under rapid charging (up to 5mA cm-2) owing to its efficient mixed ion/electron conduction pathways. Thus, the HCA/C demonstrates stable cycling for 200 cycles with a low negative/positive ratio of 1.0 when paired with a LiNi0.8Co0.1Mn0.1O2 cathode (areal capacity of 5.0mAhcm-2). Furthermore, a stacked pouch-type full cell using HCA/C realizes a high energy density of 344Whkg-1 cell/951WhL-1 cell based on the total mass of the cell, exceeding previously reported pouch-type full cells. This work paves the way for LMA development in high-energy-density Li metal batteries.

Zinc‐Coordinated Imidazole‐Based Ionic Liquid as Liquid Salt for All‐Temperature Aqueous Zinc‐Ion Batteries

AbstractOwing to the intrinsically high safety, low cost, natural abundance, and high energy density of Zn metal, aqueous Zn ion batteries (AZIBs) have become a promising candidate for large‐scale energy conversion and storage. However, the practical application of AZIBs is hampered by the severe Zn dendrites growth and the poor low‐temperature performance due to the elevated freezing point of aqueous electrolyte. Herein, the study proposes a new kind of room‐temperature liquid Zn salt, which is called Zn coordinated ionic liquid (i.e., (EMIM)5Zn(OTF)7), for all‐temperature AZIBs. The aqueous electrolyte containing 0.261 mol kg−1 (EMIM)5Zn(OTF)7 in Ethylene Glycol (EG) / H2O (6:4) exhibits ultralow freezing point below −100 °C. The liquid Zn salt and EG molecules not only modulate the solvation structure of Zn2+ ion, reducing the coordinated H2O in the first solvation sheath, but also suppresses the parasitic side reaction. As a proof of concept, Zn || Zn symmetric cells and Zn || PANI full cells with the designed electrolyte achieve improved cycling stability and can operate under wide temperature (from −40 to 60 °C). Even with high Zn utilization ratio of 40%, long cycle life over 70 times with capacity retention of 80% is achieved.

Comparative Analysis of Consequent-Pole PM Vernier Machines With Different Rotor Types

Taking advantage of flux modulation effects, consequent-pole PM vernier (CPMV) machines have been widely investigated recently, featuring high torque density and PM utilization ratio. However, the low-order harmonics of modulated flux fields additionally cause high iron saturation, which results in relatively low average torque under overload conditions, especially for the CPMV machines with an interior CPM (ICPM) rotor. Therefore, this paper proposes two hybrid CPM (HCPM) rotors of PMV machines to improve the overload performance by adding SPMs into the conventional ICPM rotor. First, the topologies of the proposed HCPM rotors are presented, named HCPM1 and HCPM2 rotors, respectively. Then the HCPM rotors and a conventional ICPM rotor with the V-shaped PM arrangement are designed and optimized to find out the optimal design parameters. Moreover, the electromagnetic performances including back-EMF, torque performance, efficiency, flux-weakening capability, and end effect are comprehensively investigated and compared. It indicates that the two proposed HCPM rotors both can generate equivalently high average torque, efficiency, and flux-weakening capability, compared to the conventional ICPM rotor. Furthermore, the proposed HCPM2 rotor can produce ≥22.9% higher torque at overload conditions. In addition, due to the bipolar PM arrangement, the unipolar flux leakage of the HCPM2 rotor is significantly reduced and lower than 0.05T. Finally, the prototype of a 12-stator-slot/ 20-rotor-pole CPMV machine with the HCPM2 rotor is manufactured to validate the finite element (FE) results.

The single metal atom (Ni, Pd, Pt) anchored on defective hexagonal boron nitride for oxidative desulfurization.

Single-atom catalysts (SACs) have attracted great attention for various chemical reactions because of their strong activity, high metal utilization ratio, and low cost. Here, by using the density functional theory (DFT) method, the stability of a single VIII-group metal atom (M = Ni, Pd, Pt) anchored on the defective hexagonal boron nitride (h-BN) sheet and its possible application in oxidative desulfurization (ODS) are investigated. Calculations show that the stability of the single M atom embedded in the h-BN surface with B and N vacancies is strikingly enhanced compared to that on the perfect h-BN surface. The catalytic activities of the defective h-BN-supported single metal atom are further studied by the activation of molecular oxygen and subsequent oxidation of dibenzothiophene (DBT). O2 is activated to the super-oxo state with large interaction energies on three M/VN surfaces. However, among the three M/VB surfaces, only Pt/VB performs efficient activation of O2. The oxidation of DBT proceeds in two steps; the rate-determining step is the initial step, in which activated O2 oxidizes DBT to produce sulfoxide. By comparing the energy barrier in the first reaction step, both Ni/VN and Pt/VB are revealed as promising candidates for the ODS reaction.

Low Loading and High Utilization Ratio of Iridium Catalyst Coated Smoltek Carbon Nanofibers Used as Anode Material for PEM Water Electrolyzers

Proton exchange membrane water electrolyzers (PEMWE) are a core technology for the future green hydrogen production market. The installed power for PEMWE is estimated to be 40 GW by 2030 [1]. The oxygen evolution reaction (OER) catalyst on the anode side is dominated by Iridium (Ir)-based materials, one of the rarest noble metals in the crust of Earth. It is critical to lower the loading of Ir-based catalyst to ≈ 0.1 mg Ir/cm2 without compromising the overall performance to enable the mass manufacturing targets. It is a big challenge due to the poor electrical contact between the resulting catalyst layers and the anode substrate [2-3]. To reach this goal, Smoltek invented an advanced porous transport electrode (PTE) concept using its proprietary carbon nanofiber (CNF) technology [4] and unique Ir coating technology. An anode porous transport layer (PTL) is first modified by vertically aligned CNFs to increase surface area, followed by coating a corrosion-resistant and conductive layer (e.g. Platinum) and a subsequent OER catalyst layer (Fig. 1a). Cathodic electrodeposition in a three-electrode static cell was performed for Ir-based catalyst deposition. We demonstrate that with this method, the morphology and deposition process of Ir are controllable at very low loading amounts (≥ 0.1 mg Ir/cm2). An Ir coating layer can be formed on the highly structured CNF-based surface. The electrodeposited Ir has strong adhesion with the CNF PTEs, resulting in a high electrical conductivity [5].This unique Ir-electrodeposited CNF PTEs structure maximizes the anode surface area and paves a new way to increase the utilization ratio of catalyst surface at a low loading amount, which makes it a competitive anode material in today’s PEMWE market. References Stiber et al. Adv. Energy Mater., 2021, 11, 2100630.Möckl et al. J. Electrochem. Soc., 2022, 169, 064505.Bernt et al. Chem. Ing. Tech., 2020, 92, 31-39.https://www.smoltek.com/applications/electrolyzers/Krivina et al. Adv.Mater., 2022, 34, 2203033. Figure 1

Sphere-Confined Reversible Zn Deposition for Stable Alkaline Aqueous Batteries.

The practical applications of alkaline zinc-based batteries are challenged by poor rechargeability with an insufficient zinc utilization ratio. Herein, a sphere-confined reversible zinc deposition behavior from a free-standing Zn anode is reported, which is composed of bi-continuous ZnO-protected interconnected and hollowed Zn microspheres by theKirkendall effect. The cross-linked Zn network with in situ formed outer ZnO shell and inner hollow space not only inhibits side reactions but also ensures long-range conductivity and accommodates shape change, which induces preferential reversible zinc dissolution-deposition process in the inner space and maintains structural integrity even under high zinc utilization ratio. As a result, the Zn electrode can be stably cycled for 390h at a high current density of 20mA cm-2 (60% depth of discharge), outperforming previously reported alkaline Zn anodes. A stable zinc-nickel oxide hydroxide battery with a high cumulative capacity of 8532 mAh cm-2 at 60% depth of discharge is also demonstrated.

Improving Torque Analysis and Design Using the Air-Gap Field Modulation Principle for Permanent-Magnet Hub Machines

The Double Permanent Magnet Vernier (DPMV) machine is well known for its high torque density and magnet utilization ratio. This paper aims to investigate the torque generation mechanism and its improved design in DPMV machines for hub propulsion based on the field modulation principle. Firstly, the topology of the proposed DPMV machine is introduced, and a commercial PM machine is used as a benchmark. Secondly, the rotor PM, stator PM, and armature magnetic fields are derived and analyzed considering the modulation effect, respectively. Meanwhile, the contribution of each harmonic to average torque is pointed out. It can be concluded that the 7th-, 12th-, 19th- and 24th-order flux density harmonics are the main source of average torque. Thanks to the multi-working harmonic characteristics, the average torque of DPMV machines has significantly increased by 31.8% compared to the counterpart commercial PM machine, while also reducing the PM weight by 75%. Thirdly, the auxiliary barrier structure and dual three-phase winding configuration are proposed from the perspective of optimizing the phase and amplitude of working harmonics, respectively. The improvements in average torque are 9.9% and 5.4%, correspondingly.

A sulfur cathode design strategy for polysulfide restrictions and kinetic enhancements in Li-S batteries through oxidative chemical vapor deposition

Lithium-sulfur (Li-S) batteries offer a promising solution for achieving high-density and low-cost energy storage devices. However, the practical utilization of Li-S batteries is hindered by the main bottleneck of polysulfides transport from the cathode to the electrolyte and anode, which leads to the detrimental degradation of the electrolyte and non-uniform microstructure evolution on the anode, ultimately resulting in rapid capacity fading. To overcome this limitation, we propose a groundbreaking mitigation strategy that leverages the oxidative chemical vapor deposition (oCVD) technique to limit the shuttling of polysulfides in the cathode. This gas-phase approach is unique in that highly conducting and conformal polymer coating entirely eliminates the use of traditional binders in the cathode while enhancing the kinetic conditions of the sulfur conversion and inhibiting the shuttling of polysulfides during battery operation. Complementary experimental and theoretical investigations identify that polysulfides are physically and chemically confined in the cathode region. The sulfur cathode manufactured using this approach demonstrates high active material loading (90 wt%), a high sulfur utilization ratio of 84.4% (∼1413 mAh g−1 at 0.1 C), and capacity retention of 85% after 300 cycles (∼810 mAh g−1) at 0.5 C. The pouch cell also showcases a high specific energy of up to 202 Wh kg−1 with a low electrolyte/sulfur ratio of 4.55, proving the immense potential for practical applications.

Ion Tunnel Matrix Initiated Oriented Attachment for Highly Utilized Zn Anodes.

Metallic zinc is an ideal anode for aqueous energy storage, however, Zn anodes suffer from nonhomogeneous deposition, low reversibility and dendrite formation; these lead to an over-provision of zinc metal in full cells. Herein, we report oriented-attachment-regulated Zn stacking initiated through a trapping-then-planting process with a high zinc utilization rate (ZUR). Due to the isometric topology features of cubic-type Prussian blue analogue (PBA), the initial Zn plating occurs at specific sites with equal spacing of ∼5 Å in the direction perpendicular to the substrate; the trace amount of zinc ions trapped in tunnel matrix provides nuclei for the oriented attachment of Zn (002) deposits. As results, the PBA-decorated substrate delivers high reversibility of dendrite-free zinc plating/stripping for more than 6600 cycles (1320h) and achieves an average Coulombic efficiency (CE) of 99.5% at 5mA cm-2 with 100% ZUR. Moreover, the anode-limited full cell with a low negative-positive electrode ratio (N/P) of 1.2 can be operated stably for 360 cycles, displaying an energy density of 214Wh kg-1 ; this greatly exceeds commercial aqueous batteries. This work provides a proof-of-concept design of metal anodes with high utilization ratio and a practical method for developing high energy density batteries. This article is protected by copyright. All rights reserved.

The novel π–d conjugated TM2B3N3S6 (TM = Mo, Ti and W) monolayers as highly active single-atom catalysts for electrocatalytic synthesis of ammonia

Recently, single-atom catalysts (SACs) are receiving significant attention in electrocatalysis fields due to their excellent specific activities and extremely high atomic utilization ratio. Effective loading of metal atoms and high stability of SACs increase the number of exposed active sites, thus significantly improving their catalytic efficiency. Herein, we proposed a series (29 in total) of two-dimensional (2D) conjugated structures of TM2B3N3S6 (TM means those 3d to 5d transition metals) and studied the performance as single-atom catalysts for nitrogen reduction reaction (NRR) using density functional theory (DFT). Results show that TM2B3N3S6 (TM = Mo, Ti and W) monolayers have superior performance for ammonia synthesis with low limiting potentials of −0.38, −0.53 and −0.68 V, respectively. Among them, the Mo2B3N3S6 monolayer shows the best catalytic performance of NRR. Meanwhile, the π conjugated B3N3S6 rings undergo coordinated electron transfer with the d orbitals of TM to exhibit good chargeability, and these TM2B3N3S6 monolayers activate isolated N2 according to the “acceptance–donation” mechanism. We have also verified the good stability (i.e., Ef < 0, and Udiss > 0) and high selectivity (Ud = –0.03, 0.01 and 0.10 V, respectively) of the above four types of monolayers for NRR over hydrogen evolution reaction (HER). The NRR activities have been clarified by multiple-level descriptors (ΔG*N2H, ICOHP, and Ɛd) in the terms of basic characteristics, electronic property, and energy. Moreover, the aqueous solution can promote the NRR process, leading to the reduction of ΔGPDS from 0.38 eV to 0.27 eV for the Mo2B3N3S6 monolayer. However, the TM2B3N3S6 (TM = Mo, Ti and W) also showed excellent stability in aqueous phase. This study proves that the π-d conjugated monolayers of TM2B3N3S6 (TM = Mo, Ti and W) as electrocatalysts show great potentials for the nitrogen reduction.

Determining Factors of Capital Structure and its Effect on the Value of Public Companies in Indonesia

The purpose of this study is to analyze the determinants of capital structure and how its affect firm value. The sample selected from public companies listed on the IDX which four (4) industries were selected by using stratified and purposive random sampling that have been selected 74 companies with 222 observations from 2017 to 2019. Estimation technique of panel data in this study by using the FEM approach. The results of hypothesis testing reveal that in the first model, three (3) variables that have a significant positive effect on the company's capital structure, namely AUR, LSIZE and ROA. Furthermore, in the second model, the company's capital structure has a negative effect on firm value. This study also reveals that companies tend to use debt as the first alternative when internal sources of funds are insufficient. Investors are advised to be careful in investing their funds in companies that have a very high debt utilization ratio, because in addition to burdening the company's cash flow, the company will also have the potential to lead to bankruptcy if the use of the debt is not managed properly.

Differential Analysis of Three Copper-Based Nanomaterials with Different Morphologies to Suppress Alternaria alternata and Safety Evaluation.

The overuse of copper-based fertilizers and pesticides over the last few decades has resulted in detrimental risks to our environment. Nano-enabled agrichemicals with a high effective utilization ratio have shown great potential for maintaining or minimizing environmental issues in agriculture. Copper-based nanomaterials (Cu-based NMs) serve as a promising alternative to fungicides. Three types of Cu-based NMs with different morphologies were analyzed for their different antifungal effects on Alternaria alternata in this current study. Compared to commercial copper hydroxide water power (Cu(OH)2 WP), all tested Cu-based NMs, including cuprous oxide nanoparticles (Cu2O NPs), copper nanorods (Cu NRs) and copper nanowires (Cu NWs), especially Cu2O NPs and Cu NWs, showed higher antifungal activity against Alternaria alternata. Its EC50 were 104.24 and 89.40 mg L-1, respectively, achieving comparable activity using a dose approximately 1.6 and 1.9-fold lower. Cu-based NMs could introduce the downregulation of melanin production and soluble protein content. In contrast to trends in antifungal activity, Cu2O NPs showed the strongest power in regulating melanin production and protein content and similarly exhibited the highest acute toxicity to adult zebrafish compared to other Cu-based NMs. These results demonstrate that Cu-based NMs could offer great potential in plant disease management strategies.

Atomically dispersed Au anchored on CeO2 to enhancing the antioxidant activity

The modification of Au nanoparticles can improve the antioxidant activity of CeO2, however, nano Au/CeO2 has also met some problems such as low atomic utilization, the limit of reaction conditions, and high cost. Au single atom catalysts can well solve the above-mentioned problems, but there are some contradictory results about the activity of single atom Au1/CeO2 and nano Au/CeO2. Here, we synthesized rod-like Au single atom Au/CeO2 (0.4% Au1/CeO2) and nano Au/CeO2 (1% Au/CeO2, 2% Au/CeO2 and 4% Au/CeO2), and their antioxidant activity from strong to weak is 0.4% Au1/CeO2, 1% Au/CeO2, 2% Au/CeO2 and 4% Au/CeO2, respectively. The higher antioxidant activity of 0.4% Au1/CeO2 is mainly due to the high Au atomic utilization ratio and the stronger charge transfer between Au single atoms and CeO2, resulting in the higher content of Ce3+. Due to the coexistence of Au single atoms and Au NPs in 2% Au/CeO2, the antioxidant activity 2% Au/CeO2 is higher than that of 4% Au/CeO2. And the enhancement effect of Au single atoms was not affected by the concentration of ·OH and material concentration. These results can promote the understanding of the antioxidant activity of 0.4% Au1/CeO2 and promote its application.

Synergistic effect of Li2S@Li3PS4 nanosheets and MXene for high performance lithium-sulfur batteries

Lithium sulfide (Li2S) is a promising cathode material for Lithium-sulfur (Li–S) batteries, but poor conductivity and electrochemical reactivity seriously hinders its applications. Herein, Ti3C2 nanosheet (TNS) supported core-shell nano-Li2S@Li3PS4 composite (NLi2S@LPS) is comprehensively designed to tackle these challenges. It displays fast Li+/e− transport kinetics, low energy barrier and high catalytic activity for the electrochemical redox reactions, which are derived from the synergistic effect of nano-sized Li2S, Li3PS4 coating and catalytic MXene (Ti3C2) components. The NLi2S@LPS/TNS composite electrode exhibits high utilization ratio of the active materials with low polarization and robust rate capability for charge/discharge, resulting in improved cycling stability for Li–S batteries. The Li–S batteries with NLi2S@LPS/TNS electrode have a capacity retention rate of 77% after 300 cycles of charge and discharge at 0.5C rate, corresponding to an average decay rate of 0.08% per cycle.