High Temperature Sensitivity Research Articles

Halometallate Ionic Liquid Dynamically Regulates Zwitterionic Hydrogels by Synergistic Multiple‐Bond Networks

AbstractImproving the compatibility between high concentration metallic ions and zwitterions to controllable construction of coordination bonds is critical and extremely challenging. Here, a facile and effective strategy to fabricate multifunctional hydrogels by randomly copolymerizing halometallate ionic liquids (ILs) and zwitterions through electron beam irradiation is reported. Introducing metal ions into ILs can balance charges and establish moderate and stable cross‐linked networks with zwitterions. The synergistic effect of coordination bonds and multiple interactions with varying strengths endows hydrogel with outstanding stretchability, compressive strength, rapid response, advanced self‐healing ability, and excellent frost resistance. The multifunctional sensor assembled from hydrogels can timely, accurately, and stably monitor human movement, write anti‐counterfeiting and remotely transmit Morse code signals. Multiple hydrogel sensors are also assembled into a flexible sensor array to track the tactile trajectory and detect spatial distribution of force. Moreover, the obtained hydrogel displays high temperature sensitivity with resistance temperature coefficient of −3.85% °C−1 at 25–40 °C, which can detect tiny temperature changes (0.1 °C). Interestingly, the processed hydrogel can effectively modulate the transmissivity through salt triggering to achieve patterning. Considering the structural designability of halometallate ILs, this work provides new insights for the development of multifunctional hydrogels.

A novel Bi3+,Eu3+ co-doped Ca3Zr2SiGa2O12 phosphors for high-sensitive temperature measurement

High-sensitive optical thermometers have garnered significant attention due to rapid technological advances. Here, novel Bi3+,Eu3+ co-doped Ca3Zr2SiGa2O12 (CZSG) phosphors with high temperature sensitivity were synthesized. Extensive researches of structure, photoluminescence and mechanism of energy transfer from Bi3+ to Eu3+ in CZSG:Bi3+,Eu3+ were carried out. Under excitation of 291 nm light, a broadband at 310–400 nm from Bi3+ ions as well as peaks at 580–710 nm from Eu3+ ions are both observed in CZSG:Bi3+,Eu3+. Fluorescence intensity (FI) of Bi3+ and fluorescence intensity ratio (FIR) of Bi3+ and Eu3+ were used to design dual-mode optical thermometer. The maximal relative sensitivities (SR) are 2.98 %K−1 @ 573 K (FI) and 1.88 %K−1 @ 303 K (FIR), respectively. Noticeably, when two modes are combined, the minimal SR of CZSG:Bi3+,Eu3+ is higher than 1.04 %K−1 over the whole temperature range (303–573 K). Above results indicate the potential application of CZSG:Bi3+,Eu3+ sample in optical thermometers.

High-sensitivity ocean temperature sensor usinga reflective optical microfiber coupler andmachine learning methods.

This paper proposes a novel seawater temperature sensor, to the best of our knowledge, that utilizes an optical microfiber coupler combined with a reflective silver mirror (OMCM). The sensor's sensitivity and durability are enhanced by encapsulating it in polydimethylsiloxane (PDMS). Additionally, a specially designed metal casing prevents the OMCM from responding to pressure, thus avoiding the challenge of multi-parameter demodulation and increasing its adaptability to harsh environments. The paper analyzes the advantages of the new sensor structure and evaluates its performance in terms of temperature sensitivity and compressive strength through experiments. Finally, the paper employs machine learning demodulation methods. Compared with traditional demodulation methods, the particle swarm optimization support vector regression (PSO-SVR) algorithm demonstrates a substantial reduction in the demodulation error. Specifically, the mean absolute percentage error (MAPE) relative to the full scale drops from 2.16% to 0.157%. This paper provides an effective solution for high-precision monitoring of the ocean environmental temperature.

Highly Sensitive Solid Ratiometric Luminescent Thermometer Based on N,C-Chelating Four-Coordinate Organoboron Compounds.

Realizing ratiometric thermometers using single-component organic solid-state luminophores is attractive but challenging. Here, we synthesized a series of N,C-chelated tetra-coordinated organoboron compounds and characterized their structures. Among them, sample BN2Br can be used as a luminescent thermometer and exhibits a high temperature sensitivity (3.67% K-1), a wide response range of 120-280 K, and good reversibility, which is mainly due to the temperature-dependent intermolecular stacking effect in the solid state. The proposed ratiometric thermometry protocol may provide new insights for developing photonic thermometers.

Comparative investigation of the effect of rare earth elements (Y, Sm and La) in NiO-based NTC thermistors with high temperature sensitivity

Negative temperature coefficient (NTC) thermistors with high temperature sensitivity have significance to the high-accuracy applications for temperature measurement and control. While, a NTC thermistor with high temperature sensitivity is typically accompanied by high room temperature resistivity (ρ25), and vice versa. To develop NTC thermistors with high temperature sensitivity and low ρ25, NiO-based ceramics modified with rare earth (RE) elements (Y, Sm and La) were prepared using the traditional solid-phase reaction method. The microstructure, morphology and electrical properties of these ceramics were thoroughly investigated. All ceramics doped with different concentrations of RE ions exhibited the main phase of rock-salt NiO structure and demonstrated typical NTC characteristics. Depending on the RE ion content, the prepared ceramics presented adjustable properties, low ρ25 and NTC material constant B higher than 5200 K can be received. The differences in conduction behavior and temperature sensitive characteristics affected by the RE ions were comparatively investigated, considering both grain effect and grain boundary effect.

Dual-Channel High-Sensitivity Temperature and Magnetic Field Sensor Based on Mach–Zehnder Interference and Surface Plasmon Resonance

Dual-Channel High-Sensitivity Temperature and Magnetic Field Sensor Based on Mach–Zehnder Interference and Surface Plasmon Resonance

Plasmon-enhanced NIR-II photoluminescence of rare-earth oxide nanoprobes for high-sensitivity optical temperature sensing.

With ongoing advancements in photothermal therapy, achieving efficient tumor cell eradication while minimizing damage to healthy tissues necessitates a highly effective and non-invasive real-time temperature monitoring technique for human tissues. Herein, we report a near-infrared (NIR)-II optical temperature sensing nanoprobe featuring rare-earth-doped gadolinium oxide nanocrystals (RENCs) attached to the dumbbell mesoporous silica-coated gold nanorods (AuNRs). The composite nanoprobe presents an intense absorption in the NIR region, and NIR-II photoluminescence (PL) increases by 97.2 to 102-fold compared to pure RENCs upon 980 nm irradiation. The localized electric field generated through surface plasmon resonance effects of AuNRs demonstrated a dumbbell-shaped distribution that aligns with the structure of nanoprobes, maximizing the PL enhancement of RENCs. Moreover, the NIR-II emissions are changed with the rising temperature, with an exceptional relative sensitivity of 7.25% K-1 at 338 K based on PL lifetime, indicating the nanoprobe is highly potential for optical temperature sensing.

Flexible Thermoelectric BiSbTe/Carbon Paper/BiSbTe Sandwiches for Bimode Temperature‐Pressure Sensors

AbstractBimode temperature‐pressure sensors hold significant promise in personal health monitoring, wearables and robotic signal detection. Traditional bimode sensors typically combine two independent sensors, leading to fabrication complexity. This study develops a bimode temperature‐pressure sensor by using a facile electrodeposition method to create sandwiched BiSbTe/Carbon Paper/BiSbTe thin films and stacking them to a vertical structure. It demonstrates high sensitivity for temperature sensing, capable of detecting temperature difference as low as 1 K, and a rapid response time of 0.92 s due to a vertical structure. Utilizing its thermoelectric mechanism, the sensor achieves self‐powered sensing for finger touch and respiration states. Furthermore, its island‐like contact surface ensures high sensitivity with an extremely fast response time of 0.17 s, by rapidly changing contact resistance under pressure, allowing it to detect various human behaviors, including body movements and micro‐expressions. Beyond its sensing capabilities, the film excels in flexibility, electromagnetic interference shielding, and stability, presenting significant potential for integration into self‐powered electronic skin systems for health monitoring, wearables, artificial intelligence, and other electronic skin applications.

Upconversion luminescence and thermosensitive properties of NaGd(PO3)4:Yb3+/Er3+

High-sensitivity optical temperature measurement has attracted extensive attention in both fundamental studies and practical applications. In this study, a series of upconversion (UC) luminescence phosphors composed of NaGd(PO3)4 (NGP) doped with 20 at% Yb3+ and various concentrations of Er3+ (0.5 at% as the optimal concentration) was synthesized by high-temperature solid-state method. And their crystal structure and the distribution of lanthanide dopants were analyzed using X-ray diffraction with Rietveld refinement verifies. Under 980 nm laser excitation, the obtained phosphors show the characteristic Er3+ upconversion green and red emission bands through two-photon processes. The fluorescence intensity ratio (FIR) based on the thermal coupled states demonstrates the thermal sensing ability in a wide temperature range of 200–573 K. The thermal sensitivity is relatively high with the maximum absolute thermal sensitivity Sa of 0.53 % K−1 (523 K) and the maximum relative thermal sensitivity Sr of 2.60 % K−1. The phosphor NGP:Yb/Er also exhibits high repeatability as the thermal sensors reach 97 %. These findings postulate the potential of NGP:Yb/Er as a promising candidate in optical thermal sensing applications.

Ultra-Thin Highly Sensitive Electronic Skin for Temperature Monitoring.

Electronic skin capable of reliable monitoring of human skin temperature is crucial for the advancement of non-invasive clinical biomonitoring, disease diagnosis, and health surveillance. Ultra-thin temperature sensors, with excellent mechanical flexibility and robustness, can conformably adhere to uneven skin surfaces, making them ideal candidates. However, achieving high sensitivity often demands sacrificing flexibility, rendering the development of temperature sensors combining both qualities a challenging task. In this study, we utilized a low-cost drop-casting technique to print ultra-thin and lightweight (thickness: approximately 3 µm, weight: 0.61 mg) temperature sensors based on a combination of vanadium dioxide and PEDOT:PSS at room temperature and atmospheric conditions. These sensors exhibit high sensitivity (temperature coefficient of resistance: -5.11%/°C), rapid response and recovery times (0.36 s), and high-temperature accuracy (0.031 °C). Furthermore, they showcased remarkable durability in extreme bending conditions (bending radius = 400 µm), along with stable electrical performance over approximately 2400 bending cycles. This work offers a low-cost, simple, and scalable method for manufacturing ultra-thin and lightweight electronic skins for temperature monitoring, which seamlessly integrate exceptional temperature-measuring capabilities with optimal flexibility.

High-sensitivity fiber temperature sensor based on composite film structure and lossy mode resonance

In this work, we proposed and demonstrated a high-sensitivity optical fiber temperature sensor based on lossy mode resonance (LMR). The sensor is composed of a D-shaped fiber and a thin composite film. The composite film consists of tin dioxide (SnO2) and polydimethylsiloxane (PDMS). PDMS is inserted as an intermediate layer between D-shaped fiber and SnO2 layer, realizing the separation of TM and TE polarization to reduce polarization crosstalk, while also serving as a temperature sensitive layer. The polarization state of the excited LMR can be freely controlled by adjusting the thickness of the composite film. The proposed sensor exhibits a high temperature sensitivity of −1.1883 nm/°C with a measurement range of 10–90 °C. Meanwhile, a fast response time of ∼ 109 ms was observed due to the ultra-thin PDMS interlayer.

Infrared non-uniformity correction method based on binocular detection system without blindsight

The output image of an infrared detector often suffers from non-uniformity due to the inhomogeneity of the device material and limitations in the manufacturing process, which can reduce the detector's capability to detect and identify targets. It is therefore necessary to adequately correct the non-uniformity to fully utilize the high temperature sensitivity of the detector. Calibration-based non-uniformity correction technology is one of the earliest and most effective methods of correcting non-uniformity. Typically, a relatively uniform shutter is used to mask the field of view for calibration correction. However, this process interrupts the observation due to the need for masking, severely limiting its use in real-world projects. In order to maintain the performance superiority of the calibration-based method and eliminate the defect of target loss caused by masking, this paper takes the occlusion calibration as the theoretical basis, which consists of dual detectors to form a binocular detection system, and uses one of the occluded calibration auxiliary detector to assist the other occlusion-free primary detector, and takes advantage of the fact that the radiation is the same when observing the same target at the same time to make the correct response based on the steepest gradient descent learning algorithm, which removes the non-uniformity while achieving detail fidelity, no ghosting and continuous output.

Stronger Impact of Extreme Heat Event on Vegetation Temperature Sensitivity under Future Scenarios with High-Emission Intensity

Vegetation temperature sensitivity is a key indicator to understand the response of vegetation to temperature changes and predict potential shifts in ecosystem functions. However, under the context of global warming, the impact of future extreme heat events on vegetation temperature sensitivity remains poorly understood. Such research is crucial for predicting the dynamic changes in terrestrial ecosystem structure and function. To address this issue, we utilized historical (1850–2014) and future (2015–2100) simulation data derived from CMIP6 models to explore the spatiotemporal dynamics of vegetation temperature sensitivity under different carbon emission scenarios. Moreover, we employed correlation analysis to assess the impact of extreme heat events on vegetation temperature sensitivity. The results indicate that vegetation temperature sensitivity exhibited a declining trend in the historical period but yielded an increasing trend under the SSP245 and SSP585 scenarios. The increasing trend under the SSP245 scenario was less pronounced than that under the SSP585 scenario. By contrast, vegetation temperature sensitivity exhibited an upward trend until 2080 and it began to decline after 2080 under the SSP126 scenario. For all the three future scenarios, the regions with high vegetation temperature sensitivity were predominantly located in high latitudes of the Northern Hemisphere, the Tibetan Plateau, and tropical forests. In addition, the impact of extreme heat events on vegetation temperature sensitivity was intensified with increasing carbon emission intensity, particularly in the boreal forests and Siberian permafrost. These findings provide important insights and offer a theoretical basis and guidance to identify climatically sensitive areas under global climate change.

PEDOT:PSS-Based Wearable Flexible Temperature Sensor and Integrated Sensing Matrix for Human Body Monitoring.

Flexible temperature sensors have been widely used in electronic skins and health monitoring. Body temperature as one of the key physiological signals is crucial for detecting human body's abnormalities, which necessitates high sensitivity, quick responsiveness, and stable monitoring. In this paper, we reported a resistive temperature sensor designed as an ultrathin laminated structure with a serpentine pattern and a bioinspired adhesive layer, which was fabricated with a composite of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)/single-wall carbon nanotubes/reduced graphene oxide (PEDOT:PSS/SWCNTs/rGO) and polydimethylsiloxane (PDMS). The temperature sensor exhibited a high temperature sensitivity of 0.63% °C-1, coupled with outstanding linearity of 0.98 within 25-45 °C. Furthermore, it showed fast response and recovery speeds of 4.8 and 5.8 s, respectively, between 25 and 36 °C. It also demonstrated exceptional stability when subjected to stress and bending disturbances with the maximum bending interference deviation of 0.03%. Additionally, it displayed good cyclic stability over a broad temperature range from 25 to 85 °C, and the standard deviation at 25 °C is 0.14%. A series of experiments including blowing detection, respiratory monitoring with or without a mask, and during rest or sleep were conducted to show the potential of the flexible temperature sensors in human body monitoring. Furthermore, a 4 × 4 flexible temperature sensor matrix was integrated to detect and map objects such as wrenches and blood vessels through human hand skin. The results were consistent with those of infrared measurements. The flexible temperature sensor is capable of real-time temperature monitoring and has the potential in tracking human respiration, assessing sleep quality, and mapping the temperature of various objects.

Ratiometric optical temperature sensing properties based on up-conversion luminescence of novel NaLaTi2O6:Yb3+,Er3+/Ho3+ phosphors

To satisfy the increasing necessity of contactless optical thermometry, utilizing both thermally coupled (TCLs) or non-thermally-coupled (NTCLs) energy levels of rare earth ions in novel phosphors has significant potential for devising the optical thermometers with high temperature sensitivity. Herein, a sequence of novel Yb3+,Er3+/Ho3+ doped NaLaTi2O6 (NLTO) phosphors were sintered using a high-temperature solid-state reaction approach. Structure, phase component and luminescence performance were identified in detail. Upon 980 nm near-infrared (NIR) excitation, the obtained materials presented typical Er3+/Ho3+ characteristic emission wavelengths in visible region, which include two green emission bands around 522 and 543 nm, as well as a weaker red band around 661 nm for Er3+ doped NLTO, a green emission band around 545 nm and a red band around 657 nm for Ho3+ doped NLTO. Besides, a unusual emission band around 757 nm of Ho3+ in visible edge region was also clearly found. The temperature sensing properties of representative NLTO:Yb3+,Er3+/Ho3+ samples were assessed based on the fluorescence intensity ratio (FIR) technique of TCLs or NTCLs energy levels. The maximal absolute sensitivity (Sa) and relative sensitivity (Sr) were determined to be 0.0374 K-1 (293 K) and 0.970% K-1 (293 K) by taking the FIR of NTCLs 2H11/2→4I15/2 and 4F9/2→4I15/2 transitions in NLTO:Yb3+,Er3+. Simultaneously, the maximal Sa and Sr were 0.0306 K-1 (573 K) and 0.776% K-1 (373 K) using the FIR of NTCLs 5F5→5I8 and 5F4,5S2→5I7 transitions in NLTO:Yb3+,Ho3+. Consequently, the temperature sensitivities above can be compared to reported results, which indicate that as-prepared materials have a promising application in optical temperature sensors field.

Water-based metamaterial absorber for temperature modulation

In this study, a transmissive all-dielectric metamaterial absorber comprising a photosensitive resin and water layers was proposed. The water layers comprised coin rings, crosses, and fan shapes. The as-obtained absorber achieved >90% absorption of electromagnetic waves within the frequency range of 18.4–41.7 GHz, and the absorption bandwidth covered the Ka-band. Because of the symmetric structure of the designed metamaterial, it was not influenced by polarization. The inherent dispersive properties of water result in a dielectric constant that varies significantly with temperature. This led to fluctuations in the absorption efficiency of the designed metamaterial to different degrees with changes in temperature. The analysis of electric and magnetic fields distributions revealed that the primary absorption physical mechanism of the designed metamaterial originated from magnetic resonances in the water layers. The proposed transmissive metamaterial absorber has potential applications in high-sensitivity thermal and temperature sensors.

Self‐Powered and 3D Printable Soft Sensor for Human Health Monitoring, Object Recognition, and Contactless Hand Gesture Recognition

AbstractA new galvanic cell design of a self‐powered and 3D‐printable soft sensor showing health monitoring, object recognition, and contactless hand gesture recognition, is reported. The soft sensor consists of a 3D‐printed poly(acrylic acid) (PAA) hydrogel electrolyte layer, a soft anode layer, and a soft cathode layer. The anode layer is a 3D‐printed and Cu2+ cross‐linked poly(N,N‐dimethylacrylamide‐co‐3‐alanine‐2‐hydroxypropylmethacrylate) (PDA) hydrogel dispersed with Cu metal particles (PDA/Cu2+/Cu hydrogel), while the cathode layer is a bottom thin layer of the PAA hydrogel containing MnO2 (PAA/MnO2). Using graphite films as the soft electrodes, the soft sensor is finally assembled. The soft sensor has high force and temperature sensitivities. It gives different electric current responses under stretching, bending, pressing, and impact loading. The soft sensor is demonstrated to be useful in detecting human motion and physiological activities, e.g., breath. Based on the force and contactless temperature sensitivities, the soft sensor is used to recognize human hand gestures and plastic balls with different diameters. This 3D printable soft sensor with self‐powering, contactless motion capturing, and multi‐pimulus sensing capabilities illustrates a new pathway to make soft sensory devices for healthcare and human‐machine interaction applications.

InP/ZnS Quantum Dots for High-Sensitivity Temperature Sensors.

In this work, we report the synthesis of high-quality, nontoxic InP/ZnS core-shell quantum dots (QDs). The temperature-dependent optical properties such as photoluminescence (PL), absorption, and PL decay with time have been investigated. Based on the temperature dependence of optical properties of QDs, three different configurations of temperature sensors using PMMA as the QD host material were fabricated. The temperature sensor configurations are planar thin-film (InP/ZnS QD)/PMMA deposited on a Si wafer (sensor 1), (InP/ZnS QD)/PMMA-filled borosilicate fibers (sensor 2), and InP/ZnS QD-doped electrospun PMMA nanofibers deposited on a Si wafer (sensor 3). After fabrication, the performance of the temperature sensors have been thoroughly investigated through photoluminescence reversibility tests in consecutive heating-cooling cycles, and the sensitivity of the sensors has been calculated. The three sensors have shown different critical reversible temperatures above which they go through irreversible structural damage and lose their reversibility. The highest critical reversible temperature of 95 °C and the highest sensitivity of 2.1% °C-1 have been achieved, which are comparable to Cd- and dye-based temperature sensors reported to date. The sensors were found to be highly stable, which demonstrated negligible degradation even after 30 days of exposure to ambient conditions. The InP/ZnS QD-based optical temperature sensors can be considered to be a potential replacement for toxic heavy-metal QD-based optical temperature sensors.

High sensitivity metamaterial thin film: bio and thermal sensors based on Fano resonances and nematic liquid crystals

ABSTRACT In this research, a new sensor was designed that exhibits high biological and thermal sensitivities. It is suitable for use as a biosensor, a thermal sensor, or both simultaneously. This nanostructure sensor is based on two non-identical copper rings, which are dependent on two dielectric environments, and has been optimised to enhance sensitivity. To control and increase the sensitivity of the designed metamaterial, the E7 liquid crystal was used, which has a temperature-dependent refractive index. The optimised data indicate that the highest sensitivity for the structural parameters; R, dr and d are 70, 43 and 30 nm, respectively. This nanostructure demonstrates a refractive index sensitivity of 500 nm/RIU and a very high temperature sensitivity of 11 nm/K in the wavelength range of 500–1000 nanometres and a temperature range of 290–330 Kelvin. The second peak has the highest sensitivity to the refractive index and the third peak has the highest sensitivity to temperature. The high temperature sensitivity reported is at a 90-degree orientation angle of the liquid crystal director. Therefore, the simulation and optimisation of this ultra-thin film indicates that it can be suitable for use as a high-quality bio-thermal sensor with a high figure of merit.

An optical fiber high sensitivity temperature sensor with MZI and FPI parallel connection

Accurate detection of temperature is of great significance in the field of medical research. The focal point of this article centers around an optical fiber sensor that integrates Fabry Perot interferometer (FPI) filled with polydimethylsiloxane (PDMS) and Mach Zehnder interferometer (MZI), leveraging the principle of the vernier effect. By introducing the vernier effect principle, the sensitivity is 31.09 nm/°C in the detection range of 36 ∼ 40°C, and the maximum temperature measurement error is about 0.55 %. In addition, good linear response and longtime stability make it suitable for application in various scenarios where accurate temperature measurement is required.