High Temperature Sensitivity Research Articles

Ultra-Thin Highly Sensitive Electronic Skin for Temperature Monitoring

Electronic skin capable of reliable monitoring of human skin temperature is crucial for the advancement of non-invasive clinical biomonitoring, disease diagnosis, and health surveillance. Ultra-thin temperature sensors, with excellent mechanical flexibility and robustness, can conformably adhere to uneven skin surfaces, making them ideal candidates. However, achieving high sensitivity often demands sacrificing flexibility, rendering the development of temperature sensors combining both qualities a challenging task. In this study, we utilized a low-cost drop-casting technique to print ultra-thin and lightweight (thickness: approximately 3 µm, weight: 0.61 mg) temperature sensors based on a combination of vanadium dioxide and PEDOT:PSS at room temperature and atmospheric conditions. These sensors exhibit high sensitivity (temperature coefficient of resistance: −5.11%/°C), rapid response and recovery times (0.36 s), and high-temperature accuracy (0.031 °C). Furthermore, they showcased remarkable durability in extreme bending conditions (bending radius = 400 µm), along with stable electrical performance over approximately 2400 bending cycles. This work offers a low-cost, simple, and scalable method for manufacturing ultra-thin and lightweight electronic skins for temperature monitoring, which seamlessly integrate exceptional temperature-measuring capabilities with optimal flexibility.

High-sensitivity fiber temperature sensor based on composite film structure and lossy mode resonance

In this work, we proposed and demonstrated a high-sensitivity optical fiber temperature sensor based on lossy mode resonance (LMR). The sensor is composed of a D-shaped fiber and a thin composite film. The composite film consists of tin dioxide (SnO2) and polydimethylsiloxane (PDMS). PDMS is inserted as an intermediate layer between D-shaped fiber and SnO2 layer, realizing the separation of TM and TE polarization to reduce polarization crosstalk, while also serving as a temperature sensitive layer. The polarization state of the excited LMR can be freely controlled by adjusting the thickness of the composite film. The proposed sensor exhibits a high temperature sensitivity of −1.1883 nm/°C with a measurement range of 10–90 °C. Meanwhile, a fast response time of ∼ 109 ms was observed due to the ultra-thin PDMS interlayer.

Plasmon-enhanced NIR-II photoluminescence of rare-earth oxide nanoprobes for high-sensitivity optical temperature sensing

Plasmon-enhanced NIR-II photoluminescence of rare-earth oxide nanoprobes for high-sensitivity optical temperature sensing

Stronger Impact of Extreme Heat Event on Vegetation Temperature Sensitivity under Future Scenarios with High-Emission Intensity

Vegetation temperature sensitivity is a key indicator to understand the response of vegetation to temperature changes and predict potential shifts in ecosystem functions. However, under the context of global warming, the impact of future extreme heat events on vegetation temperature sensitivity remains poorly understood. Such research is crucial for predicting the dynamic changes in terrestrial ecosystem structure and function. To address this issue, we utilized historical (1850–2014) and future (2015–2100) simulation data derived from CMIP6 models to explore the spatiotemporal dynamics of vegetation temperature sensitivity under different carbon emission scenarios. Moreover, we employed correlation analysis to assess the impact of extreme heat events on vegetation temperature sensitivity. The results indicate that vegetation temperature sensitivity exhibited a declining trend in the historical period but yielded an increasing trend under the SSP245 and SSP585 scenarios. The increasing trend under the SSP245 scenario was less pronounced than that under the SSP585 scenario. By contrast, vegetation temperature sensitivity exhibited an upward trend until 2080 and it began to decline after 2080 under the SSP126 scenario. For all the three future scenarios, the regions with high vegetation temperature sensitivity were predominantly located in high latitudes of the Northern Hemisphere, the Tibetan Plateau, and tropical forests. In addition, the impact of extreme heat events on vegetation temperature sensitivity was intensified with increasing carbon emission intensity, particularly in the boreal forests and Siberian permafrost. These findings provide important insights and offer a theoretical basis and guidance to identify climatically sensitive areas under global climate change.

PEDOT:PSS-Based Wearable Flexible Temperature Sensor and Integrated Sensing Matrix for Human Body Monitoring.

Flexible temperature sensors have been widely used in electronic skins and health monitoring. Body temperature as one of the key physiological signals is crucial for detecting human body's abnormalities, which necessitates high sensitivity, quick responsiveness, and stable monitoring. In this paper, we reported a resistive temperature sensor designed as an ultrathin laminated structure with a serpentine pattern and a bioinspired adhesive layer, which was fabricated with a composite of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)/single-wall carbon nanotubes/reduced graphene oxide (PEDOT:PSS/SWCNTs/rGO) and polydimethylsiloxane (PDMS). The temperature sensor exhibited a high temperature sensitivity of 0.63% °C-1, coupled with outstanding linearity of 0.98 within 25-45 °C. Furthermore, it showed fast response and recovery speeds of 4.8 and 5.8 s, respectively, between 25 and 36 °C. It also demonstrated exceptional stability when subjected to stress and bending disturbances with the maximum bending interference deviation of 0.03%. Additionally, it displayed good cyclic stability over a broad temperature range from 25 to 85 °C, and the standard deviation at 25 °C is 0.14%. A series of experiments including blowing detection, respiratory monitoring with or without a mask, and during rest or sleep were conducted to show the potential of the flexible temperature sensors in human body monitoring. Furthermore, a 4 × 4 flexible temperature sensor matrix was integrated to detect and map objects such as wrenches and blood vessels through human hand skin. The results were consistent with those of infrared measurements. The flexible temperature sensor is capable of real-time temperature monitoring and has the potential in tracking human respiration, assessing sleep quality, and mapping the temperature of various objects.

Infrared non-uniformity correction method based on binocular detection system without blindsight

The output image of an infrared detector often suffers from non-uniformity due to the inhomogeneity of the device material and limitations in the manufacturing process, which can reduce the detector's capability to detect and identify targets. It is therefore necessary to adequately correct the non-uniformity to fully utilize the high temperature sensitivity of the detector. Calibration-based non-uniformity correction technology is one of the earliest and most effective methods of correcting non-uniformity. Typically, a relatively uniform shutter is used to mask the field of view for calibration correction. However, this process interrupts the observation due to the need for masking, severely limiting its use in real-world projects. In order to maintain the performance superiority of the calibration-based method and eliminate the defect of target loss caused by masking, this paper takes the occlusion calibration as the theoretical basis, which consists of dual detectors to form a binocular detection system, and uses one of the occluded calibration auxiliary detector to assist the other occlusion-free primary detector, and takes advantage of the fact that the radiation is the same when observing the same target at the same time to make the correct response based on the steepest gradient descent learning algorithm, which removes the non-uniformity while achieving detail fidelity, no ghosting and continuous output.

Ratiometric optical temperature sensing properties based on up-conversion luminescence of novel NaLaTi2O6:Yb3+,Er3+/Ho3+ phosphors

To satisfy the increasing necessity of contactless optical thermometry, utilizing both thermally coupled (TCLs) or non-thermally-coupled (NTCLs) energy levels of rare earth ions in novel phosphors has significant potential for devising the optical thermometers with high temperature sensitivity. Herein, a sequence of novel Yb3+,Er3+/Ho3+ doped NaLaTi2O6 (NLTO) phosphors were sintered using a high-temperature solid-state reaction approach. Structure, phase component and luminescence performance were identified in detail. Upon 980 nm near-infrared (NIR) excitation, the obtained materials presented typical Er3+/Ho3+ characteristic emission wavelengths in visible region, which include two green emission bands around 522 and 543 nm, as well as a weaker red band around 661 nm for Er3+ doped NLTO, a green emission band around 545 nm and a red band around 657 nm for Ho3+ doped NLTO. Besides, a unusual emission band around 757 nm of Ho3+ in visible edge region was also clearly found. The temperature sensing properties of representative NLTO:Yb3+,Er3+/Ho3+ samples were assessed based on the fluorescence intensity ratio (FIR) technique of TCLs or NTCLs energy levels. The maximal absolute sensitivity (Sa) and relative sensitivity (Sr) were determined to be 0.0374 K-1 (293 K) and 0.970% K-1 (293 K) by taking the FIR of NTCLs 2H11/2→4I15/2 and 4F9/2→4I15/2 transitions in NLTO:Yb3+,Er3+. Simultaneously, the maximal Sa and Sr were 0.0306 K-1 (573 K) and 0.776% K-1 (373 K) using the FIR of NTCLs 5F5→5I8 and 5F4,5S2→5I7 transitions in NLTO:Yb3+,Ho3+. Consequently, the temperature sensitivities above can be compared to reported results, which indicate that as-prepared materials have a promising application in optical temperature sensors field.

Water-based metamaterial absorber for temperature modulation

In this study, a transmissive all-dielectric metamaterial absorber comprising a photosensitive resin and water layers was proposed. The water layers comprised coin rings, crosses, and fan shapes. The as-obtained absorber achieved >90% absorption of electromagnetic waves within the frequency range of 18.4–41.7 GHz, and the absorption bandwidth covered the Ka-band. Because of the symmetric structure of the designed metamaterial, it was not influenced by polarization. The inherent dispersive properties of water result in a dielectric constant that varies significantly with temperature. This led to fluctuations in the absorption efficiency of the designed metamaterial to different degrees with changes in temperature. The analysis of electric and magnetic fields distributions revealed that the primary absorption physical mechanism of the designed metamaterial originated from magnetic resonances in the water layers. The proposed transmissive metamaterial absorber has potential applications in high-sensitivity thermal and temperature sensors.

Self‐Powered and 3D Printable Soft Sensor for Human Health Monitoring, Object Recognition, and Contactless Hand Gesture Recognition

AbstractA new galvanic cell design of a self‐powered and 3D‐printable soft sensor showing health monitoring, object recognition, and contactless hand gesture recognition, is reported. The soft sensor consists of a 3D‐printed poly(acrylic acid) (PAA) hydrogel electrolyte layer, a soft anode layer, and a soft cathode layer. The anode layer is a 3D‐printed and Cu2+ cross‐linked poly(N,N‐dimethylacrylamide‐co‐3‐alanine‐2‐hydroxypropylmethacrylate) (PDA) hydrogel dispersed with Cu metal particles (PDA/Cu2+/Cu hydrogel), while the cathode layer is a bottom thin layer of the PAA hydrogel containing MnO2 (PAA/MnO2). Using graphite films as the soft electrodes, the soft sensor is finally assembled. The soft sensor has high force and temperature sensitivities. It gives different electric current responses under stretching, bending, pressing, and impact loading. The soft sensor is demonstrated to be useful in detecting human motion and physiological activities, e.g., breath. Based on the force and contactless temperature sensitivities, the soft sensor is used to recognize human hand gestures and plastic balls with different diameters. This 3D printable soft sensor with self‐powering, contactless motion capturing, and multi‐pimulus sensing capabilities illustrates a new pathway to make soft sensory devices for healthcare and human‐machine interaction applications.

InP/ZnS Quantum Dots for High-Sensitivity Temperature Sensors.

In this work, we report the synthesis of high-quality, nontoxic InP/ZnS core-shell quantum dots (QDs). The temperature-dependent optical properties such as photoluminescence (PL), absorption, and PL decay with time have been investigated. Based on the temperature dependence of optical properties of QDs, three different configurations of temperature sensors using PMMA as the QD host material were fabricated. The temperature sensor configurations are planar thin-film (InP/ZnS QD)/PMMA deposited on a Si wafer (sensor 1), (InP/ZnS QD)/PMMA-filled borosilicate fibers (sensor 2), and InP/ZnS QD-doped electrospun PMMA nanofibers deposited on a Si wafer (sensor 3). After fabrication, the performance of the temperature sensors have been thoroughly investigated through photoluminescence reversibility tests in consecutive heating-cooling cycles, and the sensitivity of the sensors has been calculated. The three sensors have shown different critical reversible temperatures above which they go through irreversible structural damage and lose their reversibility. The highest critical reversible temperature of 95 °C and the highest sensitivity of 2.1% °C-1 have been achieved, which are comparable to Cd- and dye-based temperature sensors reported to date. The sensors were found to be highly stable, which demonstrated negligible degradation even after 30 days of exposure to ambient conditions. The InP/ZnS QD-based optical temperature sensors can be considered to be a potential replacement for toxic heavy-metal QD-based optical temperature sensors.

High sensitivity metamaterial thin film: bio and thermal sensors based on Fano resonances and nematic liquid crystals

ABSTRACT In this research, a new sensor was designed that exhibits high biological and thermal sensitivities. It is suitable for use as a biosensor, a thermal sensor, or both simultaneously. This nanostructure sensor is based on two non-identical copper rings, which are dependent on two dielectric environments, and has been optimised to enhance sensitivity. To control and increase the sensitivity of the designed metamaterial, the E7 liquid crystal was used, which has a temperature-dependent refractive index. The optimised data indicate that the highest sensitivity for the structural parameters; R, dr and d are 70, 43 and 30 nm, respectively. This nanostructure demonstrates a refractive index sensitivity of 500 nm/RIU and a very high temperature sensitivity of 11 nm/K in the wavelength range of 500–1000 nanometres and a temperature range of 290–330 Kelvin. The second peak has the highest sensitivity to the refractive index and the third peak has the highest sensitivity to temperature. The high temperature sensitivity reported is at a 90-degree orientation angle of the liquid crystal director. Therefore, the simulation and optimisation of this ultra-thin film indicates that it can be suitable for use as a high-quality bio-thermal sensor with a high figure of merit.

An optical fiber high sensitivity temperature sensor with MZI and FPI parallel connection

Accurate detection of temperature is of great significance in the field of medical research. The focal point of this article centers around an optical fiber sensor that integrates Fabry Perot interferometer (FPI) filled with polydimethylsiloxane (PDMS) and Mach Zehnder interferometer (MZI), leveraging the principle of the vernier effect. By introducing the vernier effect principle, the sensitivity is 31.09 nm/°C in the detection range of 36 ∼ 40°C, and the maximum temperature measurement error is about 0.55 %. In addition, good linear response and longtime stability make it suitable for application in various scenarios where accurate temperature measurement is required.

High sensitivity gas pressure and temperature optical sensors based on tapered no-core fiber coated with polydimethylsiloxane (PDMS)

This article introduces a novel high-sensitivity pressure and temperature sensor utilizing a tapered no-core fiber (NCF) structure created by splicing the NCF with a single-mode fiber (SMF) to form a “SMF-NCF-SMF” structure, tapering the NCF, and applying a polydimethylsiloxane (PDMS) film on the tapered NCF surface. The experimental results show that the device with a diameter of 10 μm has a pressure sensitivity of 86.63 nm/MPa within one to two atmospheres. Furthermore, the temperature sensitivity is −1.97 nm/°C from 30 °C to 60 °C. The sensor exhibits excellent stability and repeatability, and the PDMS film enhances the mechanical strength of the device, indicating promising potential for high-sensitivity pressure and temperature applications.

Hydroxyl-driven construction of dual-emitting CsPbBr3/EuWO4(OH) composite for radiometric thermometer and information encryption applications

Self-assembled inorganic metal halide perovskite composites with high emitting efficiency, tunable multimode emission and stimuli-responsive luminescence demonstrated great potential in diversified luminescence applications. Here, a novel CsPbBr3/EuWO4(OH) composite was successfully prepared through the surface adsorption of Pb2+ ions on hydroxylated EuWO4(OH) microsheets and subsequent nucleation of CsPbBr3 peroviskite quantum dots (PQDs) by the anti-solvent crystallization in CsBr containing N,N-dimethylformamide (DMF) solution. Due to the distinct fluorescent thermochromic switching properties of temperature-insensitive Eu3+ and sensitive CsPbBr3 PQDs emitting centers, the resultant CsPbBr3/EuWO4(OH) composite exhibits excellent ratiometric temperature sensing performance. The CsPbBr3/EuWO4(OH) thermometer based on the fluorescence intensity ratio (FIR) technique originating from emissions of Eu3+ to CsPbBr3 PQDs was then explored with a high temperature sensitivity (Sr) of 5.8 % ℃−1 at 54 ℃. In addition, a high-security-level information encryption scheme was proposed by utilizing the excitation-wavelength-dependent switchable fluorescence of CsPbBr3/EuWO4(OH) composite. This study provides a simple and feasible strategy for assembling dual-emission CsPbBr3/EuWO4(OH) composite, showing potential applications in optical ratiometric thermometry and information encryption fields.

Test-Retest Reliability of the STRAQ-1: A Registered Report

This Registered Report provides the first test of measurement invariance across time points and estimates of test-retest reliability for the Social Thermoregulation, Risk Avoidance Questionnaire (STRAQ-1, Vergara et al., 2019). The scale was developed and validated to understand the physiological drives underlying interpersonal bonding, measured by four constructs: the desire to socially regulate one’s temperature, the desire to solitary regulate one’s temperature, the sensitivity to higher temperatures, and the desire to avoid risk. Previous studies with large samples across 12 countries showed that the STRAQ-1 has a stable factorial structure, satisfying internal consistencies for the temperature subscales, and expected correlations in its nomological network. However, to date, this instrument has no estimates of test-retest reliability. Throughout four academic years (from 2018 to 2022), N = 183 French student participants took the STRAQ-1 at least two times. Out of the four STRAQ-1 subscales, only two were longitudinally invariant across two-time points. Thus, half of the STRAQ-1 constructs and latent scores were dissimilar and incomparable across time. We then conducted test-retest reliability using Intra Class Correlation coefficient (ICC) for the Social Thermoregulation, Solitary Thermoregulation, High-Temperature Sensitivity, and Risk Avoidance subscales. ICCs estimates were respectively for agreement and consistency: .70, .70 overall moderate to good, .62, .62 overall moderate, .67, .67 overall moderate, and .53, .53 overall poor to moderate, respectively. Our study suggests that test-retest reliability was insufficient for psychological diagnosis, and that future studies should address the problem of low generalizability of the constructs.

Development of a high-sensitivity and fast-response fiber temperature sensor utilizing Ti3C2TX MXene/PDMS composites and Vernier effect

Precisely measuring temperature holds great significance for human daily life and industrial production. A high-sensitivity and fast-response optical fiber temperature sensor based on the vernier effect is proposed. A Fabry-Perot interferometer (FPI) filled with Ti3C2TX MXene and polydimethylsiloxane (PDMS) composites is employed as a sensing probe for the first time, and a cascaded Mach-Zender interferometer (MZI) as a reference unit due to its insensitivity to temperature. The temperature sensitivity of the FPI filled with Ti3C2TX MXene/PDMS composites is 1.63 nm/°C owing to the excellent thermal expansion characteristics of PDMS, and the response time is shortened from 3.021 s to 719 ms compared to that of the FPI filled with pure PDMS attributed to the high thermal conductivity of MXene. The cascading of FPI and MZI with similar free spectral ranges generates the vernier effect. The sensitivity is magnified by 19.44 times, reaching up to 31.62 nm/°C in the range of 36.5 - 37.2 °C, and the response time is 721 ms. Furthermore, experimental results demonstrate the sensor’s good stability, implying its potential applications of the sensor in medical diagnosis, environmental monitoring and biosensing.

Design of an on-chip integrated multi-channel comb filter based on the Bragg grating structure.

We designed a multi-channel comb filter generation scheme with nearly consistent channel numbers and free spectral range (FSR) in standard 220-nm-thick silicon-on-insulator (SOI) technology. This scheme relies on the formation of optical microcavities using Bragg grating structures, which serve as reflectors. By precisely designing the optical path length of the microcavity, we can generate optical filters with a specific number of channels. Using this scheme, we developed and tested three devices to implement two-channel, three-channel, and four-channel comb filters, with FSRs of approximately 5.5 nm, 4 nm, and 3.3 nm, respectively. As an application, this three-channel filter can be used to implement a temperature sensor with a high temperature sensitivity of about 53 pm/K. The proposed multi-channel comb filter provides a novel, to the best of our knowledge, scheme to utilize Bragg gratings, offering a new perspective for future densely integrated silicon photonics.

Design and Characterization of SAW-Based Wireless and Passive Temperature Sensing System

Abstract The Surface Acoustic Wave (SAW) temperature sensor has received significant attention due to its wirelessly-powered, battery-free, and chipless capabilities. This paper proposes a wireless sensing system comprising a one-port SAW resonator, antennas, and transceiver circuit. The SAW resonator utilized in this system was based on Aluminum Nitride (AlN) thin film, which exhibits high SAW velocity and excellent piezoelectric properties. To completely investigate the performance of the SAW resonator, simulation and experiments were conducted. Upon connecting the SAW sensor to the temperature sensing system via the antenna, the reflection peak of the SAW resonator was clearly observed in the spectrum of the return signal. Additionally, during the temperature tests, the response frequency displayed almost linear behavior as the temperature increased from 30°C to 150°C. The fitted temperature coefficient of frequency (TCF) was 30.68ppm/°C, indicating that the wireless temperature sensing system has high temperature sensitivity.

Phase signal analysis for high-sensitive temperature fiber-optic external Fabry-Perot-cavity sensor

We experimentally demonstrate a highly temperature-sensitive external Fabry-Perot cavity. The interferometric structure is composed of an air-microcavity; its fabrication uses a microcapillary and UV polymer. A temperature sensitivity close to 5.7 nm/ºC is achieved with suitable linearity (0.9896) and minimal hysteresis; a phase analysis technique is proposed and applied to overcome the trade-off between sensitivity and range of operation. This technique provides a competitive sensitivity (0.84 rad/ºC), good linearity (0.9934), and a range of operation from 25 °C to 41 °C.

Toward Accurate Photoluminescence Nanothermometry Using Rare-Earth Doped Nanoparticles for Biomedical Applications.

ConspectusPhotoluminescence nanothermometry can detect the local temperature at the submicrometer scale with minimal contact with the object under investigation. Owing to its high spatial resolution, this technique shows great potential in biomedicine in both fundamental studies as well as preclinical research. Photoluminescence nanothermometry exploits the temperature-dependent optical properties of various nanoscale optical probes including organic fluorophores, quantum dots, and carbon nanostructures. At the vanguard of these diverse optical probes, rare-earth doped nanoparticles (RENPs) have demonstrated remarkable capabilities in photoluminescence nanothermometry. They distinguish themselves from other luminescent nanoprobes owning to their unparalleled and versatile optical properties that include narrow emission bandwidths, high photostability, tunable lifetimes from microseconds to milliseconds, multicolor emissions spanning the ultraviolet, visible, and near-infrared (NIR) regions, and the ability to undergo upconversion, all with excitation of a single, biologically friendly NIR wavelength. Recent advancements in the design of novel RENPs have led to new fundamental breakthroughs in photoluminescence nanothermometry. Moreover, driven by their excellent biocompatibility, both in vitro and in vivo, their implementation in biomedical applications has also gained significant traction. However, these nanoprobes face limitations caused by the complex biological environments, including absorption and scattering of various biomolecules as well as interference from different tissues, which limit the spatial resolution and detection sensitivity in RENP temperature sensing.Among existing approaches in RENP photoluminescence nanothermometry, the most prevalent implemented mechanisms either leverage the changes in the relative intensity ratio of two emission bands or exploit the lifetimes of various excited states. Photoluminescence intensity ratio (PLIR) nanothermometry has been the mainstream method owing to the readily available spectrometers for photoluminescence acquisition. Despite offering high temperature sensitivity and spatial resolution, this technique is restricted by tedious calibration and undesirable fluctuation in photoluminescence intensity ascribed to factors such as probe concentration, excitation power density, and biochemical surroundings. Lifetime-based nanothermometry uses the lifetime of a specific transition as the contrast mechanism to infer the temperature. This modality is less susceptible to various experimental factors and is compatible with a broader range of photoluminescence nanoprobes. However, due to relatively expensive and complex instrumentation, long data acquisition, and sophisticated data analysis, lifetime-based nanothermometry is still breaking ground with recently emerging techniques lightening its path.In this Account, we provide an overview of RENP nanothermometry and their applications in biomedicine. The architectures and luminescence mechanisms of RENPs are examined, followed by the principles of PLIR and lifetime-based nanothermometry. The in-depth description of each approach starts with its basic principle of accurate temperature sensing, followed by a critical discussion of the representative techniques, applications as well as their strengths and limitations. Special emphasis is given to the emerging modality of lifetime-based nanothermometry in light of the important new developments in the field. Finally, a summary and an outlook are provided to conclude this Account.