High Potential Ecological Risk Research Articles

Spatial distribution, risk assessment, and source identification of heavy metals in water from the Xiangxi River, Three Gorges Reservoir Region, China.

Heavy metals (HMs) contamination in rivers has attracted wide concern due to its persistence and potential risks to the natural environment and human health. In this study, eight HMs (As, Hg, Cu, Pb, Ca, Zn, Mn, and Ni) were measured by inductively coupled plasma mass spectrometry in 24 water samples to investigate HMs contamination levels in the Xiangxi River of the Yangtze River basin. A geographic information systems kriging interpolation method was used to reveal the spatial distribution of HMs contamination. The results indicate that most HMs occurred at acceptable levels below the Surface Water Quality Standard (GB 3838-2002), with the highest concentration (23.23mgkg-1) of Mn being observed at sampling site X20. The values of the potential ecological risk index (RI) suggest that high potential ecological risks were present at sampling sites X1, X3, X4, X14, X16, X17, and X24, which reached moderate risk level. The highest value of RI (279.56) was observed at site X17. HM spatial distributions show that upstream pollution is more severe than downstream. The hazard index was below 1 for all HMs except for Mn, indicating that HMs in Xiangxi River pose a low risk to human health. HM source identification was accomplished using principal component analysis and Pearson's correlation. Cu, Cd, Ni, and Hg originate primarily from agriculture, while Pb, Zn, and As originate primarily from transportation and mining. This research provides a reference on the risks posed by HMs in Xiangxi River and will support efforts to protect and improve water quality in Xiangxi River.

Contamination of heavy metals in paddy soil in the vicinity of Nui Phao multi-metal mine, North Vietnam

Nui Phao mine in Thai Nguyen Province, Vietnam, is the second-largest tungsten (W) open-pit mine in the world, but the level of environmental impacts is not well known. In order to examine the heavy metal contamination in the ecosystem of this mining area, we analyzed six trace elements (As, Cd, Cr, Cu, Pb and Zn) in the collected soil samples. The analytical results showed that all the soil samples were contaminated by Cd and As. Most of the soil samples were contaminated by As (mean value 50.93 ± 55.44mg/kg) and Cd (mean value 15.22 ± 9.51mg/kg), which figures are up to 16 and 23 times higher, respectively, compared with the Vietnamese soil quality standard for agriculture (QCVN 03-MT:2015/BTNMT) of 15mg/kg for As and 1.5mg/kg for Cd. Contamination factor (CF), enrichment factor (EF), geo-accumulation index (Igeo), principal component analysis (PCA) and hierarchical clustering analysis (HCA) were used to identify the influence of mining activity in the contamination. The CF, EF, pollution index (PI) and Igeo indicated that this area was extremely polluted by Cd, severely to moderately-heavily polluted by As and slightly to moderately polluted by other elements such as Cr, Cu, Pb and Zn. The PCA and HCA results also attribute the source of As, Pb and Zn contamination and enrichment of Cd, Cr and Cu in the study area to Nui Phao mining activities. The PI and contamination degree (Cd) values of soil quality indicate that the study area was contaminated with particular reference to Cd and As and the level of contamination was decreased in the order of Pb > Cr > Cu > Zn. The study area had high potential ecological risk, and the carcinogenic risk value was higher than the acceptable value (1 × 10-6 to 1 × 10-4). This means that the local resident health is strongly affected by Nui Phao mining activities both directly and indirectly via food consumption, when rice plant grown in the paddy field is the dominant crop in the study area.

Ecological and Human Health Risks of Heavy Metals in Shooting Range Soils: A Meta Assessment from China.

Contamination of shooting ranges by heavy metals in particular Pb represents a widespread environmental issue attracting concern worldwide. Contaminant accumulation in shooting range soils can pose potential ecological risks and health risks for shooters and workers. Based on the published data on metal contamination at five shooting ranges in China, potential ecological and human health risks of several metals, and in particular, Pb were assessed for the five surveyed shooting ranges. Data show the mean concentrations of Pb, Cu, Hg, Sb, Ni and Cr in various ranges were all higher than the local soil background values, implying their accumulation was induced by shooting activities. The degree of contamination varied with sites and metals, very high Pb contamination at Range 1, Range 2 and Range 5-1, while moderate Pb contamination at Range 3 and Range 5-2. Comparatively, As, Zn and Co showed no contamination. Among the surveyed metals, Pb, Cu, Hg and Sb in shooting range soils displayed relatively high potential ecological risks. The overall degree of potential ecological risk was very high at Range 1 and Range 2, considerable at Range 4 and Range 5-1, and low at Range 3 and Range 5-2. The mean HI (hazard index) of Pb at Range 2 and the maximum HI values at Range 1 and Range 4 were higher than 1, suggesting a possibility of non-carcinogenic risks of Pb contamination at these sites. However, Pb in other range soils and other metals, across the five ranges, all exhibited no non-carcinogenic risks. The cancer risks of the four carcinogenic contaminants (As, Co, Cr, and Ni) were acceptable or negligible at all ranges. In conclusion, contamination of Pb and other metals such as Cu, Hg and Sb can cause various potential ecological risks at all the surveyed ranges, but only Pb at three ranges shows possible health risks. Contamination of Pb in the surveyed shooting ranges should be managed to reduce its possible environmental and health risks.

Spatiotemporal modeling of soil heavy metals and early warnings from scenarios-based prediction

Prediction of soil heavy metal concentrations based on continuous site specific investigation can provide reference for soil metal contamination prevention and early warning of soil environmental quality. In this study, the spatiotemporal variations of soil heavy metals (Cd, Ni, Zn, Pb and Cu) in Wenling were analyzed with 132 and 169 soil samples gathered in 2011 and 2016. In addition, we adopted a scenario-simulation model to predict future dynamic concentrations of soil heavy metals under optimistic (the pollution inputs are zero under strict environmental policy) and default (the pollution status maintain constant) conditions. Results indicated that the paddy soil was contaminated mainly by Cd and Cu. Spatiotemporal maps revealed distinct patterns in the joint area, where soil Cd, Ni, Zn, Pb and Cu all increased in northwest. Soil heavy metal concentrations as well as the associated ecological risks would decline gradually under optimistic scenario, while sharply increase when no control acts are taken over long term in default condition. The percentages of soil Cd and Cu that exceeding their corresponding risk screening value (RSV) under the default condition would be 1.6 and 1.3 times higher than those under optimistic scenario 10 years later. The probability of high potential ecological risk in default condition would be twice higher than that under optimistic scenario in 2026. Overall, strengthening the control of pollution sources and strict environmental policy are very important for soil heavy metals contamination prevention and control.

Contamination and Potential Ecological Risk Factors of Potentially Toxic Elements Present in the Soil of Shooting Range: Comparison with the Global Soils

This study was carried out to determine potentially toxic element (PTE) contamination and their potential ecological risk factors in shooting range soil. For this purpose soil samples were collected from different locations (left side, right side, shooting point, middle, and stop-butt) from the shooting range of Frontier Corps Training Centre (FCTC) present in Warsak, Peshawar. The soil samples were analyzed for pH, electrical conductivity (EC) and potentially toxic elements including Cd, Cr, Ni, Pb, and Zn. The strong acids digested extracts were analyzed using atomic absorption spectrophotometry to determine the concentrations of selected PTEs. The concentration of Pb was found to be maximum at stop-butt i.e. 2049 mg/kg and exceeded the United States Environmental Protection Agency (US-EPA) critical value of 400 mg/kg, while its concentrations at left, right, shooting point and middle were 14.0 mg/kg, 18.8 mg/kg, 47.4 mg/kg, and 18.2 mg/kg, respectively and exceeded the background level of normal soils which is 10 mg/kg for Pb. This study revealed that the shooting range soil was highly contaminated with Pb, and very high contamination factor and potential ecological risk for Pb was observed at stop-butt, very high contamination factor and potential ecological risk for Cd, while moderate contamination factor for Zn was observed at all locations of the shooting range. In Pakistan, the environmental perspective of shooting range soils is overlooked and there is a need to take steps to avoid such contamination of soils with Pb and other PTEs that can enter into food chains and can also leach to contaminate the aquifer. Replacement of vegetation of shooting range with PTE tolerant species, addition of soil conditioners and uncontaminated soil would reduce the mobility of these contaminants into aerial portions of plants and protect the groundwater contamination.

Spatiotemporal Variation and Pollution Assessment of Pb/Zn from Smelting Activities in China.

Nonferrous smelting is an important source of heavy metals in soil, which causes different degrees of soil pollution, especially in lead–zinc (Pb/Zn) smelting areas. Based on the Pb/Zn environmental release during the Pb/Zn mineral smelting processes in 31 Chinese provinces from the period 2000 to 2015, the study analyzed the spatiotemporal variations in Pb/Zn environmental release at the national level and then evaluated the degree of soil pollution and potential ecological risk based on the heavy metal content in soil from Pb/Zn smelting areas. The results showed that from the period 2000 to 2015, the Pb release had a discrete trend, transferring from the middle east to the west, and the provinces with higher Pb releases were Henan Province, Yunnan Province, and Hunan Province. However, the Zn release showed a tendency towards spatial aggregation, and the release center of this heavy metal presented a shifting trend from south to north; additionally, the release of Zn was highest in Hunan Province. The pollution index analyses indicated that Cd, Pb, Cu, and Zn in Zhuzhou and Huludao all reached extremely polluted levels, while Tongguan was at a safe level. In Gejiu, Mianxian, Fengxian, Zhuzhou, Huludao, and Shaoguan, there were very high potential ecological risks, with Cd having the highest potential ecological risk in most smelting areas, followed by Pb.

Risk assessment of heavy metals in the surface sediment at the drinking water source of the Xiangjiang River in South China

BackgroundThe Xiangjiang River is an important drinking water resource for the Hunan Province of China. It is crucial to ascertain the pollution status, influencing factors, ecological risks, and possible sources of heavy metals in the sediments of the Xiangjiang River. Sediment is both a source and a sink of heavy metals in aquatic ecosystems. In this study, surface sediment was collected from the Zhuzhou Reach of the Xiangjiang River and eight heavy metals were investigated.ResultsIn all sediment samples, all eight heavy metals were detected and their average concentration fell in the order of Zn > Pb > As > Cu > Cr > Ni > Cd > Co. Assessment shows extremely serious Cd pollution and a very high potential ecological risk from Cd. According to correlation analysis and principal component analysis (PCA), As, Cu, Ni, Pb, and Zn originate from industrial wastewater and mineral smelting activities, whereas Co, Cr, and Ni come from natural sources. Redundancy analysis (RDA) reveals that the organic matter content and the particle size of the sediment have a certain influence on the enrichment of heavy metals.ConclusionAmong all eight examined heavy metals in the surveyed area, the content of Zn, Pb, and As is the highest, and that of Cd and Co is the lowest. Despite a low level of absolute content, the Cd in sediment already renders a high ecological risk and thus calls for urgent attention. Anthropogenic activities are the main source of heavy metals in the sediment. The distribution of heavy metals may also be influenced by sediment properties. The results provide guidance for controlling heavy metal pollution and protecting drinking water sources in the Xiangjiang River.

Occurrence and Risk Assessment of Steroidal Hormones and Phenolic Endocrine Disrupting Compounds in Surface Water in Cuautla River, Mexico

In this study, two hormones 17β-estradiol (E2) and 17α-ethynylestradiol (EE2), and three phenolic compounds, bisphenol A (BPA), 4-N-nonylphenol (4-NP) and 4-tert-octylphenol (4-t-OP), were determined in surface water in the Cuautla River at the State of Morelos during the dry-season in Mexico. The endocrine disrupting compounds (EDCs) were extracted from water samples using solid-phase extraction (SPE) with end-capped C18, and then the extracts were chemically derivatized to TMS (trimethylsylane)-compounds and analyzed by gas chromatography coupled to mass spectrometry (GCMS). The most abundant compound was BPA (22.46 ± 30.17 ng L−1), followed by 4-t-OP (11.24 ± 11.76 ng L−1), 4-NP (7.53 ± 14.88 ng L−1), EE2 (2.37 ± 4.36 ng L−1) and E2 (0.97 ± 1.82 ng L−1). The residual amounts of target compounds could either reach stream surface water from direct domestic wastewater discharges, conventional wastewater treatment plant or can be a result from the use of agrochemicals in crop areas. The EDCs in Cuautla River exerted a high pressure on the aquatic ecosystem because their presences in surface water caused medium and high potential ecological risk. Besides, it was found that aquatic organisms were exposed to estrogenic activity.

Heavy metal pollution and potential ecological risk in urban river sediment of Huai’an City, China

Sediment heavy metal pollutant monitoring was carried out at 16 monitoring points of three rivers and one lake in Huai’an city. The contamination degree of heavy metals was evaluated by geoaccumulation index. The potential ecological risk of heavy metals was assessed. The results showed that Hg and Cu geoaccumulation index class exceeded moderately polluted level, especially Hg, and two monitoring points reached highly polluted level. Hg pollution is at a high/extremely high potential ecological risk. Most of the other single-factor heavy metal indexes are at a low ecological risk level. The comprehensive ecological risk index of 6 monitoring points showed a high potential ecological risk. The Hg in urban rivers sediment of Huai’an may come from the deposition of long-term domestic sewage discharge or domestic refuse dump.

Concentration Characteristics, Source Analysis, and Potential Ecological Risk Assessment of Heavy Metals in a Peak-cluster Depression Area, Southeast of Yunnan Province

The pollution characteristics, sources, and ecological risk of heavy metals in farmland soils were studied in a peak-cluster depression area southeast of Yunnan Province. In total, 199 topsoil samples were collected using the grid method and contents of eight heavy metals (As, Cd, Cr, Cu, Pb, Ni, Zn, and Hg) were determined. The geoaccumulation index and potential ecological risk index (RI) were used to evaluate soil pollution levels and potential ecological risks, respectively. The absolute principal component scores-multivariate linear regression (APCS-MLR) model and cluster analysis were used to identify the pollution sources and apportion the heavy metals in the soils. The results show that the mean content of Cd, Hg, Cr, Ni, and Zn was higher than their respective background values, exceeding them by up to 16.00, 7.29, 1.46, 1.45, and 2.39 times, respectively. No evidence of the occurrence of other metals was found. The average RI was 1039.3, which represents a high potential ecological risk, with Cd and Hg being the most crucial elements. The APCS-MLR model revealed that natural sources (PC1), traffic sources (PC2), fossil fuel combustion sources (PC3), and agricultural sources (PC4) were the four main contributors of soil heavy metals. The primary source of Cd, Cr, and Ni was PC1, while PC2 was the main source of Pb and Zn. PC3 and PC4 were the main sources of Cu and Hg with contribution rates of 77.86% and 70.37%, respectively. The main sources of As were PC1 (46.71%) and PC4 (49.46%).

Distribution, ecological risk assessment and source identification of heavy metals in surface sediments of Huixian karst wetland, China

In this study, heavy metals including Cd, Pb, Zn, Mn, Cu, Ni, Cr, As, and Hg, in the surface sediment (0–10 cm) of the Huixian wetland in a karst region were investigated in terms of their spatial distribution, ecological risks, and possible sources. Samples were collected from 13 typical sites throughout the Huixian wetland and were analyzed via inductively coupled plasma–mass spectrometry. The results revealed that the mean concentrations of Cd, Pb, Mn, Cr, As, and Hg were higher than the background and Chinese safe standard values. Based on spatial distribution and ecological risk, the study area was differentiated into three groups of sites with the following order of risk: group 3 > group 2 > group 1. The observed concentrations fluctuated slightly with depth. However, an irregular decreasing trend in the concentration with soil depth was observed among the groups. Multivariate statistical analyses showed that the high accumulation of Cd, Pb, Zn and Cu in the sediments of group 3 sites is due to the natural ancient deposition of minerals rich in heavy metals, while the accumulation of Mn, Cr, As, and Hg is attributed to an anthropogenic origin. Agricultural activities, the use of fertilizers and, pesticides, and local automobile repair stations most probably enriched these heavy metals in the Huixian wetland sediments. Hg and Cd have the highest potential ecological risk, which follows the order Hg > Cd > Pb > As > Ni > Cu > Cr > Mn > Zn. The mean geoaccumulation index (Igeo) values of Pb (0.48) and Hg (1.12) suggested moderate contamination in the study area.

Geo-ecological evaluation of mineral, major and trace elemental composition in waste rocks, soils and sediments of a gold mining area and potential associated risks

An investigation has been undertaken on the distribution of mineral, major and trace elements in mine wastes of a gold mining area from geo-ecological perspective and its association with potential human health risks. Mine waste samples consisting of waste rocks, soils and sediments (including borrow pit, waste dump, stockpile and tailings) were collected in the vicinity of Selinsing gold mine in Malaysia. Major elements in terms of their oxide contents such as SiO2, Al2O3, Fe2O3, K2O and MgO were mainly derived from their mineralogical compositions that were dominated by quartz and muscovite (in waste rocks), kaolinite and illite (in soils) and illite and chlorite-serpentine (in mine tailings). Metallic elements (Al, Fe, Mn, Zn, Sr, Cr, Cd, Ni, Cu, Co, and Pb) were found in the range of acceptable values except for metalloid arsenic. Arsenic was found in the range of 1.84–1915 mg/kg (the highest in the waste rocks of stockpile). Geochemical assessment indicated that some locations were classified as extremely contaminated, highly enriched and having high contamination with respect to arsenic according to geo-accumulation index, enrichment factor and contamination factor. In view of ecological perspective, arsenic contamination was noticeable i.e. some samples were classified as having considerable to high potential ecological risk with respect to arsenic, while contamination with regard to all other metals were classified as having low risk. In terms of health aspect, the hazard index as indicated by the lifetime cancer risk for arsenic was found in tolerable range for regulatory purposes. Other metals possess no significant non-carcinogenic or carcinogenic risks both for adults and children. The arsenic concentrations were comparable with other mining-related sites worldwide, e.g. Spain, China, South Korea, Poland and Mongolia among others. Iron, As and Cd in the tailings and discharges from treatment facilities within the mine have been removed by 82.9–94.7%. Overall, this paper has highlighted the geo-ecological importance and implication of mining exploration to avoid ecological damages so as to sustain mining sector without inflicting the environment.

Soil Lead Concentrations in Dareta Village, Zamfara, Nigeria.

Background. Acute widespread lead poisoning took place in Zamfara State, Nigeria in 2010. Over 735 children were reported dead and thousands sickened by the neurotoxin. The source was traced to artisanal gold mining and processing in the villages. An immediate medical response protocol was developed to provide oral chelation therapy to the vulnerable population. In order not to compromise the efficacy of the chelation therapy, immediate remediation of the affected villages was carried out. An over 95% reduction in soil lead levels was reported immediately after the remediation exercise.Objectives.The aim of the present study was to perform a general audit of soil lead concentrations, conducted between June and July 2013 in Dareta village (one of the most affected villages), to evaluate the soil pollution status of the village three years after the remediation exercise.Methods.Soil samples were collected from residential compounds, cultivated farmlands and other common areas. Lead contents of the samples were determined using atomic absorption spectrophotometer (Shimadzu, model AA-6800, Japan) after wet digestion. Speciation of lead in soil was done following standard analytical methods.Results.Mean soil lead concentrations for residential areas were 1029.42±98.50 mg/kg, 1523.99±201.00 mg/kg, 1404.57±141.00 mg/kg and 6724.68±84.00 mg/kg for residential compounds, market square, old grinding mills and new grinding mills, respectively. The concentrations exceeded both the Dutch target and intervention values and US Environmental Protection Agency limit for soil lead levels in residential areas. Based on the index of geo-accumulation, the ranking of intensity of lead (Pb) pollution of Dareta soils ranged from strongly polluted to extremely polluted, indicating they pose a range of moderate to very high potential ecological risk to the other components of the environment. At the current rate of accumulation, by the year 2025, soil Pb levels of Dareta common areas are expected to exceed the pre-remediation levels associated with several deaths.Conclusions.Findings of this study indicate that the problem of lead poisoning is ongoing in Dareta village. Zamfara State authorities should address the challenge through sustained periodic assessment and cleanup of affected areas. Implementation of safer mining practices should be enforced immediately.Competing Interests.The authors declare no competing financial interests

Ecological risk assessment of metals in small craft harbour sediments in Nova Scotia, Canada

Ecological risk assessment of metals (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) in surface sediments from 31 small craft harbours (SCHs) in Nova Scotia, Canada was conducted using multiple risk assessment approaches. Approaches used were contamination factor, pollution load index, geoaccumulation index, potential ecological risk factor for individual metals, comprehensive potential ecological risk index, mean probable effect level quotient and mean effects range median quotient. Results indicated most SCHs exhibited low ecological risk from sediment metal concentrations, except for two harbours. Metal contamination was highest in Canso Harbour, followed by Clarks Harbour. SCH sediments were only slightly contaminated with low probability of pollution according to mean probable effect level and mean effects range median quotients. However, pollution load and geoaccumulation indexes indicated Cd and Hg had the highest metal contamination across SCH sediments. Cadmium and Hg had the highest potential ecological risk, respectively compared to other metals.

Distribution, risk assessment, and source analysis of heavy metals in sediment of rivers located in the hilly area of southern China

River sediment, the important sink and source of heavy metals, can provide critical information for aquatic ecosystem health. Heavy metal pollution has been a serious problem facing river systems worldwide and can adversely affect human beings via the food chain. However, no comprehensive study has been conducted on heavy metal pollution in sediments of river systems in the hilly area of southern China, which plays a key role in water supply and ecosystem balance. This study is aimed at comprehensively studying the pollution status of heavy metals in river sediments in the hilly area of southern China and apportioning sources. A total of 39 superficial sediment samples were collected from the upstream, midstream, and downstream of 13 rivers (Xiangjiang River, Zishui River, Yuanjiang River, and Lishui River located in Hunan Province; Ganjiang River, Xinjiang River, Fuhe River, Raohe River), and Xiushui River located in Jiangxi Province; Qiantangjiang River and Oujiang River located in Zhejiang Province; Minjiang River and Jiulongjiang River located in Fujian Province) in the hilly area of southern China. The total concentrations of metals of Mn, Zn, Cr, Co, Ni, Cu, As, Cd, Sb, Pb, and V were analyzed using the inductively coupled plasma-mass spectrometry method. The pollution status and potential ecological risk were assessed with the geoaccumulation index (Igeo), sediment quality guidelines (SQGs), and potential ecological risk index (RI). The source apportionment of heavy metals was performed by correlation analysis and principle component analysis (PCA). Results indicated that Mn, Zn, and Pb concentrations were significantly higher than other metals, especially in the upstream of the Jiulong River and midstream and downstream of the Xiangjiang River. Pollution assessment indicated that Cd pollution of sediments was most serious and that more than 50% of sampling sites were significantly polluted, with a very high potential ecological risk. The rivers in Hunan provinces (HN) were identified as the priority controlled rivers because of the high Igeo and RI index values. Correlation and PCA analysis indicated that Mn, Pb, and Zn originated from natural and mineral exploitation activities; As, V, Ni, and Sb originated from industrial wastewater and mineral-smelting activities; Cu and Co originated from agricultural activities; Cr and Ni originated from natural sources. While the most polluted Cd came from a combination of multiple sources described above. Results indicated that Cd was the most common heavy metal pollutant, especially in river sediments of Hunan Province. Anthropogenic activities have become the main source of heavy metals in the river sediments of the hilly area of southern China. Special attention should be paid to Cd, and measures must be taken to prevent from further anthropogenic influence on heavy metal pollution.

Research Progress on Toxic Effects and Water Quality Criteria of Triclosan.

Triclosan (TCS) is an effective broad-spectrum antimicrobial agent that is widely used in personal care products. It has been detected in different environmental media, and poses high potential ecological risk. In this article, we carried out a literature review of recent studies on the toxic effects of TCS from different aspects at the molecular, cell, tissue, organ, and individual level. TCS can exhibit acute toxicity to aquatic organisms, affect the normal expression and physiological function of enzymes and genes, and produce cytotoxicity. Many studies have demonstrated that TCS exerts significant endocrine-disrupting effects on organisms, interfering the normal physiological functions of the reproductive, thyroid, and nervous systems via related signaling pathways. Moreover, we reported current research on the water quality criteria of TCS and discuss possible future research directions.

Pollution Level and Potential Ecological Risk of Heavy Metals in Surface Sediment of A Severe Polluted River in Nanjing

Black and smelly water bodies are generally caused by the enrichment and release of large amount of pollutants such as organic matter and heavy metals in sediments. Surface sediments at 11 sections of a severe polluted urban river in Nanjing were monitored to assess the pollution level and potential ecological risk. Results show that surface sediments were seriously polluted by heavy metals and contents of heavy metals were all higher than respective background values. Cd and Hg were major pollutants with relative high contents, following by Ni, As, and Zn. Comprehensive pollution load index of the river reached 4.1, indicating a “Progressive deteriorate” pollution level, with a contribution degree order of Cd>Hg>Pb>Zn>Cu>Ni>Cr>As. Most sections of the river exhibited high potential ecological risk with a contribution order of Cd>Hg>Pb>Cu>Ni>As>Zn>Cr. Additionally, there are significant positive correlations between Cu and organic matter (r = 0.947, p<0.01), and between Cu and nitrogen and phosphorus (r = 0.866 and 0.860, p<0.01). Cd and Hg contributed most to the high ecological risk of sediment and possibly came from similar anthropogenic sources due to significant correlations. Ecological dredging and disposal methods for the sediments should be seriously considered when comprehensively rehabilitating such a river.

Biota-sediment metal accumulation and human health risk assessment of freshwater bivalve Corbicula fluminea in Dongting Lake, China.

In this study, we analyzed the concentrations of metals in sediments and Corbicula fluminea in China's Dongting Lake to assess the suitability of C. fluminea as an effective biomonitor of metal contamination in sediments and food safety. We analyzed the biota-accumulation capacity by calculating the biota-sediment accumulation factor (BSAF) and assessed the potential human health risk of metals exposure via consumption of C. fluminea using the target hazard quotient (THQ) and total target hazard quotient (TTHQ). The results showed that the average concentrations of As (31.93mgkg-1), Cd (5.54mgkg-1), Cr (105.50mgkg-1), Cu (32.53mgkg-1), and Zn (207.89mgkg-1) in sediments were higher than their respective standard set by the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China. The sediment metals, which were mainly anthropogenic in origin, were at high levels and pose a relatively high ecological risk. Cadium (Cd) showed very high potential ecological risk levels and should be included in the prior pollutants list in the studied area. The mean levels of As (0.81mgkg-1) in C. fluminea were 1.62-times higher than that set by the National Health Commission of the People's Republic of China. BSAF values of the soft tissues of C. fluminea were between 0.05 and 2.14, with higher values for Cu (2.14), Cd (1.77), Zn (1.60), and Ni (1.27). Soft tissues of C. fluminea were able to reflect spatial differences in Sr within sediments around Dongting Lake. The results indicated that C. fluminea could be an potential biomonitor for sediment metals assessment in biomonitoring programs, especially for Cu, Cd, Zn, Ni, and Sr. The mean values for THQ and TTHQ of all the analyzed metals were below 1.0, indicating that the intake of metals via comsumption of C. fluminea does not result in an appreciable risk to human health.

Source identification and risk assessment of heavy metals in road dust of steel industrial city (Anshan), Liaoning, Northeast China

The purpose of the study was to acquire the source and evaluate the risk posed by heavy metals in road dust of steel industrial city (Anshan), Liaoning, Northeast China. Potential ecological risk index (RI), pollution index (PI) and geo-accumulation index (Igeo) were applied to evaluate the heavy metal pollution level, and the carcinogenic risk (RI) and hazard index (HI) were calculated to estimate the human health risk. The geographic information system maps clearly reveal the hot spots of heavy metal spatial distribution. Principle component analysis (PCA) and cluster analysis (CA) classified heavy metals into three groups. The metal Zn and Pb originate from the traffic emission, while Cd, Cr, Fe, Mn, Ni and Sb primarily come from industrial activities. These two pathways were the major source of heavy metals pollution by positive matrix factorization (PMF). The Igeo and PI values of heavy metals were decreased in the following order: Cd > Sb > Zn > Fe > Pb > Cu > Cr > Sn > Mn > Ni. The RI index showed the heavy metals were moderate to very high potential ecological risk. The HI values for children and adults presented a decreasing order of Cr > Pb > Ni > Cu > Cd > Zn. The HI also predicted a possibility of non-carcinogenic risk for children living in urban areas in comparison with adults.

Contamination and Potential Ecological Risk Assessment of Heavy Metals in the Sediments of Yilong Lake, Southwest China

The concentrations of Al, Ti, As, Cd, Cr, Cu, Ni, Pb, Zn, and Hg and chemical speciation of Cd, Cr, Cu, Ni, Pb, and Zn in four short cores sampled from the Yilong Lake, Yunnan Province were analyzed. The vertical and spatial features in the pollution levels and potential ecological risks of heavy metals in the sediments were studied. Except for the wide concentration ranges of Cd, the metals in the sediments showed narrow variations in their concentrations with coefficients of variation less than 0.3. According to the cluster analysis results, all metals could be classified into two groups:metals in group Ⅰ included As, Cd, Hg, and Pb, while metals in group Ⅱ included Al, Ti, Cr, Cu, Ni, and Zn. The metals in each group exhibited similar vertical variations in each core, but their variations were highly different between the cores. The correlation analysis results demonstrated that the variations in metal concentrations in the sediments were greatly regulated by the sediment texture. Therefore, the enrichment factor (EF) method was used for the differentiation of metals from the natural and anthropogenic sources and for the pollution assessment based on the total metal concentrations. The Cd and Pb in the sediments were mainly presented in the reducible speciation with percentages of 48% and 42%, respectively; Cr, Cu, Zn, and Ni were primarily (68%-82%) associated with the residual speciation. Based on the EF and chemical speciation of metals and their enrichment coefficients of the secondary phase, Cd was the typical pollutant with moderate pollution on average, and the other elements were observed in non-to weak pollution levels. Anthropogenic metals were mainly associated with the extractable speciation in the sediment. Combining the ecological risk index, the sediment quality guidelines, as well as the pollution level and chemical speciation of metals, As, Cu, Hg, Ni, Pb, and Zn in the surface sediments of Yilong Lake should have low potential ecological risk. However, Cd may pose a high potential ecological risk.