High Ecological Risk Research Articles

Comprehensive assessment of ecological risks of Island destinations — A case of Mount Putuo Island, China

Comprehensive assessment of the ecological risks of oceanic island destinations is conducive to determining the characteristics and rules of ecological risks brought by oceanic island tourism development. The purpose of this study is to scientifically examine and study the ecological risks of oceanic island destinations and seek for sustainable development, taking Mount Putuo Island of Zhoushan in China as a case. Based on the landscape ecological risk (ERI) assessment results, pressure-state-response (PSR) ecological risks assessment results of tourism development, and the overlay function of ArcGIS, we carried out a study about comprehensive assessment of ecological risks of oceanic island destinations. The results showed that: (1) From 2010 to 2019, the areas of low-level and medium–low-level ERIs on Mount Putuo Island decreased, whereas the areas of medium-level and medium–high-level ERIs increased year by year, with growth rates of 6.038% and 8.99%, respectively. (2) The results of ecological risks of tourism development showed that the construction of risk tourist attractions, tourism service facilities, tourism accommodations, and commercial facilities is critical to promoting the gradual increase in medium-level and medium–high-level areas. (3) The analysis of comprehensive ecological risks revealed that from 2010 to 2019, the areas of low ecological risks regions decreased significantly, whereas the areas of medium and high ecological risks regions spread from south to north in a concentrated way mainly near the tourist attractions of Mount Putuo Island, with significant hierarchical characteristics and spatial effects. The research results can provide theoretical basis and decision-making reference for the management and monitoring of the ecological security of oceanic island destinations.

Microplastics in sediments from urban and suburban rivers: Influence of sediment properties

Although sediments are considered to be a major sink for microplastics (MP), there is still a relative lack of knowledge on the factors that influence the occurrence and abundance of MP in riverine sediments. The present study investigated the occurrence and distribution of MP in riverine sediments collected at twelve sites representative of different populated and urbanized rivers (To Lich, Nhue and Day Rivers) located in the Red River Delta (RRD, Vietnam, during dry and rainy seasons. MP concentrations ranged from 1600 items kg−1 dw to 94,300 items kg−1dw. Fiber shape dominated and MP were made of polypropylene (PP) and polyethylene (PE) predominantly. An absence of seasonal effect was observed for both fragments and fibers for each rivers. Decreasing MP concentrations trend was evidenced from the To Lich River, to the Nhue River and to the Day River, coupled with a decreasing fiber length and an increasing fragment area in the surface sediment from upstream to downstream. Content of organic matter was correlated to MP concentrations suggesting that, high levels of organic matter could be MP hotspots in urban rivers. Also, high population density as well as in highly residential areas are related to higher MP concentrations in sediments. Finally, a MP high ecological risk (RI: 866 to 4711) was calculated in the RDD.

Freshwater environment risk assessment and derivation of human health ambient water quality criteria for SCCPs in China

Short-chain chlorinated paraffins (SCCPs, CxH2x+2−yCly, where x = 10 to 13 and y = 3 to x) are a complex family of emerging contaminants that have been identified as persistent, bioaccumulative and toxic (PBT) substances. Because of their persistence, high toxicity, bioaccumulation and long-distance mobility, SCCPs were added to the list of controlled POPs in the Stockholm Convention in 2017. China is the largest producer and user of SCCPs all over the world, thus SCCPs have been widely distributed in the freshwater environment. But the ecological risk and human health risk of SCCPs in China were still less evaluated. This study collected and screened the exposure data of SCCPs in freshwater environment in China, and then evaluated the freshwater and sediments ecological risk of SCCPs by risk quotient (RQ) method and the human health risk by margin of exposure (MOE) method. Our results showed that the pollution of SCCPs in the freshwater environment in China was not optimistic. The ecological risks and human health risks had occurred, and even there were high ecological risks occurred in some regions in China. Besides, because of the absence of the concentration threshold of SCCPs to protect human health in freshwater at present, we derived the human health ambient water quality criteria (AWQC) values of SCCPs based on exposure data and bioaccumulation factor (BAF) in China. The human health AWQC values of SCCPs ranged from 14.99 ng L−1 to 154.54 ng L−1 in different regions in China, and the national human health AWQC value was determined as 24.08 ng L−1. This study will provide the scientific references for the management and control of SCCPs in China, especially for the formulation of standard of water environmental quality for SCCPs.

Wastewater treatment plants elevating microplastic abundances, ecological risks, and loads in Japanese rivers: a source-to-sink perspective.

Little were certain about how wastewater treatment plants (WWTPs) affected the Japanese riverine microplastic contamination. This study explored the influences of WWTPs on microplastic pollution, assessed ecological risks, and looked at the sources-to-sinks phenomenon (WWTPs-to-rivers-to-marine) in riverine settings in Japan's Yamaguchi prefecture. Fifty surface water samples from the five selected rivers (Koya, Saba, Shimaji, and Fushino, Nishiki) and 11 effluent samples from WWTPs in the rivers' catchment were examined. Microplastics were analyzed using filtration, wet-peroxidation, density-separation, and attenuated reflectance-Fourier transform infrared spectroscopy techniques. Results suggested that the less populated and rural river (Nishiki) was less contaminated compared to the WWTPs and urban areas affected rivers (Koya, Saba, Shimaji, and Fushino). The WWTPs increased microplastic abundance twofold in the downstream regions compared to upstream stations. Microplastic characterization showed that the smaller microplastics < 500µm, fiber-shaped, transparent, blue, and green color particles were major. Polymer identification demonstrated that the polyethylene, polypropylene, and polyethylene terephthalate were prevalent both for the rivers and WWTP effluents. There was a significant emission of microplastics from WWTPs to rivers (4.671 billion pieces per day; 71.8kg per day) and rivers to Seto Inland Sea (0.13/billion pieces per day/km2; 7.1kg per day). The per capita MP emissions to the rivers via WWTPs ranged from 0.02 to 6.49g per day, which was approximately 2% of per capita single-use plastic wastes in Japan. An assessment of ecological risks showed that the WWTPs posed high ecological risks to rivers, and built up the pollution hotspots to their downstream areas by releasing higher number of microplastics and highly toxic polymers. Overall, the WWTPs influenced the rivers through both abundances and characteristics (shapes-size-color-polymers), increased the complexity of microplastic compositions as well as elevated ecological risks in the rivers. This study contributed to bridging the knowledge gaps about microplastic sources-to-sinks, ecological risks, and pollution management in Japan and beyond.

Can water dating trace the transport history of HCHs in the ocean?

Long-range atmospheric and oceanic transport play a crucial role in the accumulation of persistent organic pollutants (POPs), including hexachlorocyclohexanes (HCHs), in the Arctic Ocean. Herein, transient tracers, specifically chlorofluorocarbon-12 and sulfur hexafluoride, were used to determine the ventilation time of HCHs. Results revealed that dissolved HCHs can penetrate to a depth of ~500 m in the western Arctic Ocean, corresponding to water masses with a mean age of 45 ± 14 years. The average long-range transport time for α-HCH from initial atmospheric release to entering the western Arctic Ocean was estimated to be >30 ± 5 years, indicating continued moderate to high ecological risks from HCHs in the Arctic. This study demonstrates that transient tracers serve as effective water dating tools to elucidate the transport history of stable POPs in the ocean, contributing to a better understanding of their environmental characteristics and fate.

Landscape Dynamics and Ecological Risk Assessment of Cold Temperate Forest Moose Habitat in the Great Khingan Mountains, China.

The change in habitat pattern is one of the key factors affecting the survival of the moose population. The study of the habitat landscape pattern is the key to protecting the Chinese cold-temperate forest moose population and monitoring the global distribution of moose. Through the ecological risk assessment of the moose habitat landscape pattern in a cold-temperate forest, we hope to assess the strength of habitat resistance under stress factors. This study provides a theoretical basis for the protection of the moose population in the cold-temperate forest in China and the establishment of the cold-temperate forest national park. In the study, the MaxEnt model, landscape index calculation and ecological risk assessment model construction were used to analyze the field survey and infrared camera monitoring data from April 2014 to January 2023. The habitat suitability layer of the moose population in the Nanwenghe National Nature Reserve of the Great Khingan Mountains was calculated, and the range of the moose habitat was divided based on the logical threshold of the model. The landscape pattern index of the moose habitat was calculated by Fragstats software and a landscape ecological risk assessment model was established to analyze the landscape pattern and ecological risk dynamic changes of the moose habitat in 2015 and 2020. The results showed that under the premise of global warming, the habitat landscape contagion index decreased by 4.53 and the split index increased by 4.86 from 2015 to 2020. In terms of ecological risk: the area of low ecological risk areas increased by 0.88%; the area of medium ecological risk areas decreased by 1.11%; and the area of high ecological risk areas increased by 0.23%. The fragmentation risk of the landscape pattern of the moose habitat tends to increase, the preferred patch type is dispersed, the degree of aggregation is low, and the risk of patch type transformation increases. The middle and high ecological risk areas are mainly concentrated in the river area and its nearby forests, showing a fine and scattered distribution. Under the interference of global warming and human activities, the fragmentation trend of the moose habitat in the study area is increasing, and the habitat quality is declining, which is likely to cause moose population migration. For this reason, the author believes that the whole cold temperate forest is likely to face the risk of increasing the transformation trend of dominant patch types in the cold-temperate coniferous forest region mainly caused by global warming, resulting in an increase in the risk of habitat fragmentation. While the distribution range of moose is reduced, it has a significant impact on the diversity and ecological integrity of the whole cold-temperate forest ecosystem. This study provides theoretical references for further research on the impact of climate warming on global species distribution and related studies. It is also helpful for humans to strengthen their protection awareness of forest and river areas and formulate reasonable protection and sustainable development planning of cold-temperate forests. Finally, it provides theoretical references for effective monitoring and protection of cold-temperate forests and moose population dynamics.

Persistent thallium enrichment and its high ecological risks developed from historical carbonaceous Hg-Tl mining waste

Thallium (Tl) is a priority pollutant with high biotoxicity and has been of great concern worldwide in recent years. The former Lanmuchang Hg-Tl mining site in southwest China is a hotspot of multiple metal(loid)s pollution that previously caused large-scale chronic Tl poisoning, mainly resulting from carbonaceous Tl-bearing mining waste. However, arable land destroyed by historical mining wastes persists at high ecological risks decades after reclamation, but little is known about the solid phase partitioning and species of Tl during soil formation of underlying mining wastes as potential Tl sources. In this study, a representative reclaimed soil profile (100 cm depth) was selected in the lowlands to explore the geochemical cycling and environmental fate of Tl in mining waste-derived subsoil. The Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) analysis revealed an unexpected enrichment of Mn (2920–7250 mg/kg) and Tl (205–769 mg/kg) in the mining waste-derived subsoil. Results from BCR sequential extraction, X-ray Photoelectron Spectroscopy (XPS), and Electron Probe Microanalyses (EPMA) indicate that high Tl loading Mn oxide particulates (up to 15,712 ppm Tl) dominate the sequestration of Tl in the subsoil via oxidation-complexation and have a high potential for migration to both topsoil and groundwater. In addition, insights from microbial fossils and Fe-metabolizing bacteria closely related to Tl indicated that Fe (hydr)oxide particulates showing high Tl levels (up to 3865 mg/kg) point to biomineralization. Detailed mineralogical investigations revealed that hematite-siderite syngenetic particulates could serve as a promising mineralogical proxy for redox oscillations under periodic flooding and recorded the frequent groundwater level fluctuations experienced in the probed profile. Despite the potential for long-term preservation of high Tl loading Fe/Mn (hydr)oxides under HCO3-rich groundwater conditions in karst areas, the reductive release of Tl will be inevitable during flooding, implying that underlying carbonaceous mining waste will pose persistent and severe hazards to the ecosystem.

Preliminary results on microplastic pollution from agricultural soil in Vietnam: Distribution, characterization, and ecological risk assessment

Microplastics (MPs) have been extensively studied in aquatic systems; however, their presence in general agricultural systems and in particular, soil still needs comprehensive understanding. This study conducted a field survey at 25 sites to investigate the abundance of MPs in agricultural soil. The MPs in these soil samples were separated using sieves and filters by the density separation method with NaCl solution (d = 1.2 g/cm3). The density of MPs in agricultural soils ranged from 1,700 items/kg to 38,800 items/kg, with an average of 11,716 ±10,726 items/kg. The black-colored MPs were found to be dominant, followed by white, purple, red, and blue. The fibers represented most of the MPs' shapes observed in this research (77.9±17.4%). MPs in agricultural soil samples were tiny particles with sizes of &lt;1,000 µm and 1,000-2,000 µm. A significant difference was observed in the concentration of MPs in locations near and far from residential areas and manufacturing facilities. The average concentration of MPs in the soils adjacent to the residential and manufacturing facilities and near the agricultural solid waste collection sites was 21,471±12,729 items/kg and 20,188±4,403 items/kg, much higher than in distant these locations at 4,418±1,573 items/kg. These results suggest that domestic, industrial, and agricultural activities could contribute to MP pollution in agricultural soil. The ecological dangers MPs pose in terrestrial and aquatic environments have drawn much attention from the scientific community. This work represented the first effort to comprehend the ecological risk of MPs on selected samples of Vietnamese agricultural soil. According to the Pollution Load Index (PLI) values, most agricultural soil samples in this study were contaminated with MPs at hazard level IV. The potential ecological risk index (PERI) values of agricultural soil samples from nearby residential, industrial, or agricultural solid waste areas indicated a higher ecological risk.

Phytoremediation strategies for heavy metal-contaminated soil by selecting native plants near mining areas in Inner Mongolia.

Phytoremediation technology, as an eco-friendly and cost-effective approach, is widely used to restore soil contaminated by heavy metal(loid)s. However, the adaptability and absorption capacity of plants to multiple elements are the crucial factors affecting the application of phytoremediation in mining areas. In this study, dominant native plant species and their paired soils were collected near a lead-zinc mine in Inner Mongolia, to assess the ecological risk of heavy metal(loid)s and phytoremediation potential. The results showed that Cd and As were the dominant soil pollutants, with levels of 90.91% and 100%, respectively, exceeding the risk intervention values for soil contamination of agricultural land. The rates of Pb, Cu, and Zn exceeding the risk screening values were 69.70%, 60.61%, and 96.97%, respectively. Extremely high ecological risk of heavy metal(loid)s was observed in this area. The ability of native plants accumulating heavy metals varied among species. The bioconcentration factor (BCF) varied from 0.14 to 2.59 for Cd, 0.02 to 0.45 for As, 0.06 to 0.76 for Pb, 0.05 to 2.69 for Cr, 0.15 to 1.00 for Cu, and 0.22 to 4.10 for Zn. Chinese Cinquefoil Herb (Potentilla chinensis Ser.) showed the potential to accumulate multiple toxic elements based on the biomass, shoot content, translocation factor (TF), BCF, and metal extraction rate (MER), while, other species showed the potential to accumulate single toxic element: goosefoot (Chenopodium album L.), Lespedeza daurica (Laxm.) Schindl. and peashrubs (Caragana korshinskii Kom.), Herba Artemisiae Scopariae (Artemisia capillaris Thunb.), alfalfa (Medicago sativa L.), and Moldavian Dragonhead (Dracocephalum moldavica L.) for Cd, As, Cr, Cu, and Zn, respectively. Furthermore, wild leek (Allium ramosum L.), cogongrass (Imperata cylindrica (L.) Beauv.), fringed sagebrush (Artemisia frigida Willd.), and field bindweed (Convolvulus arvensis L.) were selected for phytostabilization of specific elements, considering the heavy metal contents in the roots and low TF values. This study provides a reference for selecting appropriate species for the remediation of heavy metal-contaminated soils in certain mining areas.

Simulation and Zoning Research on the Ecosystem Service in the Beijing–Tianjin–Hebei Region Based on SSP–RCP Scenarios

Understanding future trends and identifying characteristic differences in regional ecosystem services (ESs), in addition to ecological zoning, is vital for promoting the adjustment of ecological policy and the construction of sustainable ecosystems. Based on shared socioeconomic pathways and representative concentration pathways (SSP–RCP), the spatial distribution pattern of land use in the Beijing–Tianjin–Hebei region (BTH) in 2030 was simulated by using a patch-generating land use simulation model (PLUS) in this study. Water yield, carbon storage, habitat quality, and food product were simulated through the comprehensive evaluation model combining ecosystem services and trade-offs (InVEST). The comprehensive supply capacity of ESs was assessed. The ecological risk level was calculated by comparing the changes in the integrated supply capacity of ESs in 2020 and under each SSP–RCP scenario in 2030, and ecological zoning was established using a two-dimensional discriminant matrix. The results are as follows: (1) The degradation of grassland and cropland accompanied by an increase in construction land and forest to varying degrees will be the common characteristics of the three SSP–RCP scenarios in BTH. (2) Water yield and carbon storage services will exhibit an upward tendency only under SSP1-2.6, while habitat quality and food product services will exhibit a downward trend under three SSP–RCP scenarios. Obvious geographical heterogeneity exists in the comprehensive supply capacity of ESs. (3) Zones with low ecological risks will mainly be distributed in some counties of Zhangjiakou city, while zones with high ecological risks will account for a large proportion of the whole. There will be great ecological risks in the BTH overall. (4) The BTH was split into four types of ecological zones based on supply and risk. These zones comprise the ecological enhancement zone, ecological restoration zone, ecological sensitive zone, and ecological conservation zone. Corresponding control measures were also proposed. The findings of this study can be used to inform the formulation and improvement of environmental conservation policies.

Source and migration patterns of heavy metals and human health risk assessment of heavy metals in soil-corn straw-flue gas system.

The process of rapid urbanization in Northeast China has resulted in severe heavy metal pollution in the environment. In this study, we investigated the characteristics of heavy metal pollution in soil-corn straw and its combustion flue gas system, and the health risks of heavy metal pollution. The results showed that Cu and Zn in soil were more easily absorbed by corn straw roots. Heavy metals in soil, corn straw and flue gas from corn straw burning all pose some health risk to humans, and are more harmful to children than adults. The concentrations of heavy metals in both soil and flue gas from corn straw burning have reached extremely high ecological risk. The main sources of heavy metal elements in soils are, in order, industrial production, agricultural production activities and metallurgical production. This study highlights the key issues of heavy metal contamination in soil-corn straw and its combustion flue gas system, provides an auxiliary guide for the next step in analyzing the transfer mechanisms, and suggests a rational approach to mitigate heavy metal contamination.

Phenolic compounds—Occurrence in water, sediment and sludge, and ecological risk evaluation

AbstractTen phenolic compounds (PC) concentration levels were determined in river water, wastewater, sediments and sludge using solid phase extraction (SPE) microwave assisted extraction (MAE) and ultrasonic extraction (UE), and their ecological risk was evaluated. All the extraction methods showed good sensitivity with limit of detection and limit of quantification values at 0.01–2.00 and 0.02–6.07 µg L−1 for SPE, 0.05–1.20 and 0.17–3.17 µg kg−1 for MAE and 0.09–1.33 and 0.26–3.54 µg kg−1 for UE, correspondingly. Recovery ranges of 75.2–112% (SPE), 80.9–110% (MAE) and 79.3–119% (UE) were obtained. The PC concentrations in wastewater matrix were within the maximum allowable limit except for 2,4‐dichlorophenol at sampling point wdv4. In river water, at Camps Drift the highest concentrations compared to other sampling points was measured, however, all were within the acceptable limits. The risk quotient values exhibited high ecological risk in majority of the sites, with effects range median values indicating toxic effects to the surroundings likely to occur frequently. The probable carcinogenic risk potential was notably found to be high for adults with increment life cancer risk through dermal exposure (ILCRderm) values of 5.34 × 10−2 and 5.92 × 10−2 compared to that for children at 1.26 × 10−2 and 1.39 × 10−2 for both sludge and sediment samples.

Occurrence, sources and environmental risk assessment of organic micropollutants in coastal sediments from the Atacama Region (Chile)

Nowadays, there is still a scientific knowledge gap regarding occurrence and distribution of organic contaminants in remote areas. In this study, we have monitored for the first time the presence of a wide range of persistent and emerging organic pollutants in the Atacama Desert coastal region (Chile), a key area in the Humboldt Current System. Nonylphenols (NPs), polycyclic aromatic hydrocarbons (PAHs), pesticides, UV filters, synthetic fragrances, and organophosphate flame retardants (OPFRs) were determined in sediments along the >500 km length Atacama coastline. NPs, well-known endocrine disruptors, were the predominant pollutants in the area (up to 333.5 ng g−1 dw). We identified inputs of different classes of contaminants from anthropogenic activities such as mining, agriculture, direct effluent discharges, harbors, energy plants, recreational activities, and tourism occurring along the coastline. Environmental risk assessment through calculation of hazard quotients (HQs) showed a high ecological risk level for NPs in the three provinces of Atacama (HQ >1). In the case of PAHs, (pyrene, benz(a)anthracene, chrysene, acenaphthene, naphthalene and benzo(a)pyrene) HQ >1 was showed in Copiapó province. Furthermore, estradiol equivalent concentrations (EEQ) were determined to estimate estrogenicity of the environmental sediment samples. The maximum EEQ value was for NPs in H1 (Carrizal Bajo wetland), province of Huasco, where the highest concentration of NPs was found. The sampling point H1 is a particular location because it is the exit of a wetland and a tourist point used as a beach. The potential risks of anthropogenic chemical substances impacting remote regions such as the one studied here highlight the need of expand monitoring efforts worldwide for a better assessment of the global pollution status.

A Multiphase Coupled Hydrodynamic Model for Fate and Transport Simulation of Polycyclic Aromatic Hydrocarbons in a Semi-Closed Narrow Bay.

With their unique geographical characteristics, semi-closed narrow bays are important places for human survival but vulnerable to pollution. Because pollutants (polycyclic aromatic hydrocarbons, PAHs) migrate and undergo transformation through a dynamic mechanism in bays of this type, environmental authorities have formulated a series of effective measures for pollution prevention and control, but these are difficult to realize. Based on monitoring and historical data, a multiphase-coupled hydrodynamic model combined with a carcinogenic risk-assessment model was able to solve the challenging environmental problem. Results showed that the hydrodynamic condition in the semi-closed narrow bay was very complex. A weaker hydrodynamic force had an adverse influence on the diffusion of pollutants, further amplified in part by the head of the semi-closed narrow bay, resulting in a higher ecological risk. The prediction results indicated that the total amount of PAHs transported from seawater to sediments was about 4.7 × 1013 ng/year, which might cause serious threats to aquaculture or human health.

Accumulation Pattern and Risk Assessment of Potentially Toxic Elements in Permafrost-Affected Agricultural Soils in Northeast China.

The accumulation of potentially toxic elements (PTEs) in agricultural soils is of particular concern in China, while its status, ecological risks, and human health hazards have been little studied in the permafrost areas of Northeast China. In this study, 75 agricultural soil samples (0-20 cm) were collected from the Arctic Village, Mo'he City, in the northernmost part of China. The average concentration (mean ± standard deviation) of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn were 12.11 ± 3.66 mg/kg, 0.11 ± 0.08 mg/kg, 52.50 ± 8.83 mg/kg, 12.08 ± 5.12 mg/kg, 0.05 ± 0.02 mg/kg, 14.90 ± 5.35 mg/kg, 22.38 ± 3.04 mg/kg, and 68.07 ± 22.71 mg/kg, respectively. Correlation analysis, cluster analysis, and principal component analysis indicated that As, Cu, Ni, and Zn likely originated from geogenic processes, Hg and Pb from long-range atmospheric transport, Cd from planting activities, and Cr from Holocene alluvium. The geo-accumulation index and enrichment factor showed that As, Cd, Hg, and Zn are enriched in soils. The Nemerow pollution index showed that 66.67%, 24%, and 1.33% of soil samples were in slight, moderate, and heavy pollution levels, respectively, with Hg being the most important element affecting the comprehensive pollution index. The potential ecological risk index showed that 48.00% and 1.33% of soil samples were in the moderate ecological risk and high potential ecological risk levels, respectively. The non-carcinogenic and carcinogenic human health risk index for adults and children were both less than 1, which was within the acceptable range. This study revealed the accumulation pattern of PTEs in agricultural soils of permafrost regions and provided a scientific basis for research on ecological security and human health.

Soil contamination by trace metals and assessment of the risks associated: the dumping site of Safi city (Northwest Morocco).

The main objective of this work was to determine the soil contamination with trace metals within and around the dumpsite of Safi city (Morocco) and to evaluate the potential environmental risk associated. The results showed that the average soil concentrations of trace metals had the following order: Fe > Zn > Cu > Cr > Cd and exceeded the world and the upper continental background concentrations except for Fe. In addition, the concentrations of Zn, Cu, and Cd remained beyond the limit standards given by the WHO/FAO. Geoaccumulation index, enrichment factor, and pollution load index (PLI) indicated that the dumpsite soil is highly contaminated and deteriorated, presenting evidence of high ecological risk proved by the values of the potential ecological risk index (PERI). Correlation analyses revealed a strong relationship between the organic matter & [Fe, Zn, Cr, Cd], calcium carbonates & [Zn, Cr], and Cr & Cu inside the dumpsite soil. Principal component analysis confirmed the temporal and spatial classification of Zone A as the oldest and Zone C as the youngest and indicated that the regrouped trace metals could have the same behavior and or the same origin. The interpolation of trace metals concentrations and PERI revealed a plausible extension outside the landfill, confirmed by PLI values.

Assessing the landscape ecological risk of road construction: The case of the Phnom Penh-Sihanoukville Expressway in Cambodia

Extensive development of expressway infrastructure alters the layout of terrain resulting and results in major ecological concerns. Therefore, it has become necessary to investigate how to assess the effects of land use changes on the landscape pattern and explore pertinent environmental concerns related to road construction. This study develops a numerical mothed to assess the ecological risk of road construction in terms of landscape pattern by combining the landscape disturbance index and the vulnerability index. The model is used to assess the landscape ecological risk of a particular portion of the Phnom Penh-Sihanoukville Expressway in Cambodia. The empirical study found that the rise in the amount of construction land was transferred from the area of grassland to cultivated land. It is identified through calculating the landscape pattern index that the integrity of the landscape decreases due to the expressway construction; ecological landscape tends to be complicated and fragmented; and the gravity center of the land use landscape pattern transitions in the same direction as the expressway construction. The ecological risk was assessed and it was found that the expressway construction led to a transition to poorer ecological quality along the road as a whole, and that areas of high ecological risk and higher ecological risk were gradually concentrated from the two ends to the central area. The study develops the landscape ecological risk assessment model and extends the landscape ecological risk assessment index to the ecological assessment of expressway construction. It can also effectively guide the ecological risk assessment of major international road projects.

A remote sensing‐based approach for spatiotemporal refined assessment of freshwater wetland ecological risk in coastal zones: A case in Jiangsu's coastal zone

AbstractRapid, long‐term, and robust wetland ecological risk assessment is critical for managing coastal zones. In view of the characteristics of frequent human activities and broken plots in the coastal zone, the traditional assessment method is not fine enough. Satellite earth observation provides an unparalleled source of data for rapidly monitoring and assessing coastal wetland ecological risks through time and across a large spatial range. With the support of multi‐source remote sensing data such as precipitation, temperature, night light, land cover products, etc., a wetland ecological risk assessment method is established in this paper, and the wetland ecological risk is evaluated year by year by a grid. The evaluation results indicate that the ecological risk level of coastal wetlands in Jiangsu Province has shown an upward trend since 2015, with a high ecological risk in the north and a low ecological risk in the south, and the source area mainly appears in the northwest. Meanwhile, the year‐by‐year grid assessment can not only accurately describe the spatial and temporal distribution of wetland ecological risks but also clarify the spatial and temporal characteristics of risk source areas. Additionally, the results obtained by year‐on‐year assessment of consecutive years and clustering and zoning according to the time‐series can better represent the risk status of the time period and exclude the impact of accidental factors on the evaluation results. Although optimization for different types of wetlands can improve the accuracy of assessment, more wetland risk assessment with a longer term and a larger scale, combined with carbon emissions, will provide a basis for global wetland management.

Source apportionment of heavy metal(loid)s in sediments of a typical karst mountain drinking-water reservoir and the associated risk assessment based on chemical speciations.

As important place for water storage and supply, drinking-water reservoirs in karst mountain areas play a key role in ensuring human well-being, and its water quality safety has attracted much attention. Source apportionment and ecological risks of heavy metal(loid)s in sediments of drinking-water reservoir are important for water security, public health, and regional water resources management, especially in karst mountain areas where water resources are scarce. To expound the accumulation, potential ecological risks, and sources of heavy metal(loid)s in a drinking-water reservoir in Northwest Guizhou, China, the surface sediments were collected and analyzed based on the combined use of the geo-accumulation index (Igeo), sequential extraction (BCR), ratios of secondary phase and primary phase (RSP), risk assessment code (RAC), modified potential ecological risk index (MRI), as well as the positive matrix factorization methods. The results indicated that the accumulation of Cd in sediments was obvious, with approximately 61.9% of the samples showing moderate to high accumulation levels, followed by Pb, Cu, Ni, and Zn, whereas the As and Cr were at low levels. A large proportion of BCR-extracted acid extractable and reducible fraction were found in Cd (72.5%) and Pb (40.3%), suggesting high bioavailability. The combined results of RSP, RAC, and MRI showed that Cd was the major pollutant in sediments with high potential ecological risk, while the risk of other elements was low. Source apportionment results of heavy metal(loid)s indicated that Cd (75.76%) and Zn (23.1%) mainly originated from agricultural activities; As (69.82%), Cr (50.05%), Cu (33.47%), and Ni (31.87%) were associated with domestic sources related to residents' lives; Cu (52.36%), Ni (44.57%), Cr (34.33%), As (26.51%), Pb (24.77%), and Zn (23.80%) primarily came from natural geological sources; and Pb (47.56%), Zn (22.46%) and Cr (13.92%) might be introduced by mixed sources of traffic and domestic. The contribution ratios of the four sources were 18.41%, 36.67%, 29.48%, and 15.44%, respectively. Overall, priority control factors for pollution in relation to agricultural sources included Cd, while domestic sources are primarily associated with As. It is crucial to place special emphasis on the impacts of human activities when formulating pollution prevention and control measures. The results of this study can provide valuable reference and insights for water resources management and pollution prevention and control strategies in karst mountainous areas.

Occurrence, source identification and ecological risk assessment of heavy metals in water and sediments of Uchalli lake – Ramsar site, Pakistan

Uchalli Lake is an internationally significant Ramsar site that needs protection for supporting migratory birds. The current study aimed to assess wetland health by examining water and sediments utilizing total and labile heavy metals concentration, pollution indices, ecological risk assessment, water recharge and pollution induction sources through isotope tracer techniques. Al concentration in water was of serious concern as it was 440 times higher than the maximum acceptable concentration of Environmental Quality Standard of the UK for aquatic life in saline waters. Labile concentration predicted very severe enrichment of Cd, Pb, and moderate enrichment of Cu. Modified ecological risk index predicted very high ecological risk in sediments. The δ 18O, δ2H and D-excess values indicate that the lake was mainly recharged by local meteoric water. Enriched values of δ 18O and δ2H suggest a high evaporation of lake water, making lake sediments more enriched with metals. Isotopic and D-excess values of groundwater suggest a quick rainwater recharge to groundwater around the Uchalli Lake. Nitrates isotopes indicate that the rainwater runoff is main source of induction of fertilizers, pesticides and soil bonded metals in the lake system. The lake is recharged by rainwater runoff, from catchment areas, that erode the soil particles and agricultural residual waste dumped in the lake.