High Clay Content Research Articles

Characterizing River Manafwa Floodplain and Adjacent Soils

The objective of this study was to characterise Manafwa River floodplain and adjacent soils. Soil samples were collected from 0 - 20 cm depth in fallowed and cultivated Manafwa floodplain soils for laboratory analysis. Treatments included upland (control), floodplains fallowed for a year, floodplains fallowed for over a year, cultivated floodplains within 5 m and 50 m away from the river banks. Each treatment was replicated three times (3 blocks), and samples collected were analysed for K, Na, available P, total N, exchangeable acidity, pH, organic matter, moisture content, sand, silt, and clay. The soil sampling results were subjected to statistical Analysis of Variance (ANOVA) using Randomised Complete Block Design (RCBD), and the difference between treatment means were dictated using F-, student’s t and F-LSD/pairwise comparison tests. There was statistically no significant (p > 0.05) difference among different floodplains and uplands studied. Upland soils posted 71.67% for the highest pH and 0.09%, 0.87%, 9.74 ppm, 2.23 ppm and 7.264% for the lowest available N, organic matter, Phosphorous, Sodium and Moisture Content, respectively. Cultivated floodplain soil posted highest total P at 29.16 ppm and pH at 6.39% while fallowed floodplains lowest pH at 5.34%, highest available N at 0.32%, highest organic matter at 4.02%, highest K at 21.33%, highest Na at 13.93%, highest exchangeable acidity at 2.32 Cmol/Kg, highest clay content at 14.33%, lowest sand composition at 38.00%, highest silt composition at 54.8% and highest Moisture Content of 32.472%. As depicted by soil fertility analysis results, Manafwa River floodplain and adjacent soils have the capacity to accommodate and boost crop production and productivity. Any nutrients lost to leaching could be gained from subsequent fallowing and sustainable soil fertility management, proper drainage, crop rotation, adding organic manure, and cover cropping, among others

Evaluation of soil water content and bulk electrical conductivity across the U.S. Climate Reference Network using two electromagnetic sensors

AbstractSoil bulk electrical conductivity (BEC) was evaluated alongside soil volumetric water content (VWC) and soil temperature measurements using the HydraProbe (model HydraProbe, Stevens Water Monitoring Systems, Inc.) (hereafter called HP) with accuracy range of BEC ≤ 0.3 S m−1, and the time domain reflectometry (TDR)‐315L Probe (model TDR‐315L, Acclima, Inc.) (hereafter called AP) suitable for BEC up to 0.6 S m−1, at 23 stations of the U.S. Climate Reference Network. Previous evaluations revealed inconsistent performance of both sensors in some clay soils using manufacturer‐recommended calibrations in converting dielectric permittivity measurements to VWC. Here, we found that hourly values of BEC reached 0.6 S m−1 in high clay content soils and exceeded 2 S m−1 in high saline soils, and these high values of BEC were associated with poor performance and failures of both HP and AP sensors. Large values of BEC occurred in predominantly saturated soils where VWC values reached about 0.5 m3 m−3 for saline soils and about 0.7 m3 m−3 for clay soils, while low magnitudes of BEC were associated with low soil water content and seldomly saturated soils. Low hourly BEC values of less than 0.1 S m−1 were observed in wide variety of soil types, where sensor performance was typically excellent. The most influential factor on BEC was high soil water content conditions. Although dielectric permittivity measurements in estimating the soil water content were sensitive to BEC as some high clay content and high salinity soils increased BEC, the impact of large BEC on dielectric permittivity measurements was smaller in the well‐drained top soil layers than in deep soil layers that remained near saturation. Soil temperature had only a small impact on BEC. With high clay content and high salinity, the specific area of clay minerals was also associated with the magnitude of BEC.

Factors controlling long-term carbon sequestration in the paleo-Yellow River delta: Implications for future delta management

River deltas have contributed to the regulation of atmospheric CO2 concentrations throughout Earth's history, but the capacity and controlling factors for deltas to serve as permanent carbon sinks over the long term are unclear. To address this issue, we carried out a high-resolution assessment of carbon burial in a well-dated sediment core (BXZK13) from the paleo-Yellow River delta on the west coast of the Bohai Bay. We found that the sedimentary environments in core BXZK13 since the Late Pleistocene (∼84 k cal yr B.P.) were divided into seven depositional units. The apparent mass accumulation rate (AMAR) of total organic carbon (TOC) and total inorganic carbon (TIC) varied significantly between depositional units. The average rates were highest in delta front deposits (TOC: 135 g m−2 yr−1, TIC: 333 g m−2 yr−1). Notably, the rates of carbon accumulation were dominated by TIC. The differences in the characteristics of TIC in the borehole compare to those of carbonates in Yellow River sediments and the positive correlation between TIC and Fe suggested that authigenic carbonate contributed significantly to long-term carbon burial in the delta. The apparent sedimentation rate (ASR) dominated the variations of the carbon AMAR, and the high clay and Fe content in the sediment enhanced TOC preservation and authigenic carbonate precipitation. Low concentrations of TIC were associated with several cold events, and there was a positive correlation between the chemical index of alteration and TIC. The implication was that climate may have affected the dynamics of inorganic carbon burial by regulating authigenic carbonate precipitation. These results enable a more thorough understanding of the factors that control long-term carbon sequestration, which is critical for both management purposes as well as assessment of the role of deltas in past and future climate change.

Estimating soil organic carbon sequestration potential in the Chinese Mollisols region

AbstractMollisols region of China is a ballast stone of Chinese food security. In this study, 484 soil organic carbon (SOC) data points from the documented soil surface (0–20 cm) samples in the typical Chinese Mollisols region were selected. The regional soil fertility was divided into high, medium, and low levels based on the SOC content from the long‐term positioning fertilization stations in Shenyang, Harbin, and Hailun of Northeast China. Furthermore, the regional SOC balance point (SOCb) model was built driven by the factors of annual mean temperature, annual precipitation, annual effective accumulative temperature, the ratio of precipitation and temperature, soil clay content, and pH. Using geographic information systems (GIS) interpolation method, the regional mean SOCb and SOC sequestration potential (SOCsp) at the SOCb's status were simulated to be 40.10 g kg−1 and 10.71 kg m−2, respectively. Moreover, the SOC content increased (SOCc) and the SOC sequestration capacity increased of medium‐ or low‐fertility soil were evaluated by GIS subtraction. Consequently, the means of SOCc in medium‐ and low‐fertility soils could be 16.88 g kg−1 and 26.79 g kg−1, respectively. Furthermore, the means of SOCsp in medium‐ and low‐fertility soils could be 4.30 kg m−2 and 7.43 kg m−2, respectively. The sensitivity analysis of this model showed that the high SOCb area was distributed in study region with low temperature, dry, high clay content, and low pH. The results provide an actual perspective on estimating regional SOCsp and soil fertility promotion target induced by the different soil fertility levels.

Evaluating the agronomic efficiency of alternative phosphorus sources applied in Brazilian tropical soils

Understanding the efficacy of alternative phosphorus (P) sources in tropical soils is crucial for sustainable farming, addressing resource constraints, mitigating environmental impact, improving crop productivity, and optimizing soil-specific solutions. While the topic holds great importance, current literature falls short in providing thorough, region-specific studies on the effectiveness of alternative P sources in Brazilian tropical soils for maize cultivation. Our aim was to assess the agronomic efficiency of alternative P sources concerning maize crop (Zea mays L.) attributes, including height, shoot dry weight, stem diameter, and nutrient accumulation, across five Brazilian tropical soils. In greenhouse conditions, we carried out a randomized complete block design, investigating two factors (soil type and P sources), evaluating five tropical soils with varying clay contents and three alternative sources of P, as well as a commercial source and a control group. We evaluated maize crop attributes such as height, dry weight biomass, and nutrient accumulation, P availability and agronomic efficiency. Our results showed that, although triple superphosphate (TSP) exhibited greater values than alternative P sources (precipitated phosphorus 1, precipitated phosphorus 2 and reactive phosphate) for maize crop attributes (e.g., height, stem diameter, shoot dry weight and phosphorus, nitrogen, sulfur, calcium and magnesium accumulation). For instance, PP1 source increased nutrient accumulation for phosphorus (P), nitrogen (N), and sulfur (S) by 37.05% and 75.98% (P), 34.39% and 72.07% (N), and 41.94% and 72.69% (S) in comparison to PP2 and RP, respectively. Additionally, PP1 substantially increased P availability in soils with high clay contents 15 days after planting (DAP), showing increases of 61.90%, 99.04%, and 38.09% greater than PP2, RP, and TSP. For Ca and Mg accumulation, the highest values were found in the COxisol2 soil when PP2 was applied, Ca = 44.31% and 69.48%; and Mg = 46.23 and 75.79%, greater than PP1 and RP, respectively. Finally, the highest values for relative agronomic efficiency were observed in COxisol2 when PP1 was applied. The precipitated phosphate sources (PP1 and PP2) exhibited a similar behavior to that of the commercial source (TSP), suggesting their potential use to reduce reliance on TSP fertilization, especially in soils with low clay contents. This study emphasized strategies for soil P management, aimed at assisting farmers in enhancing maize crop productivity while simultaneously addressing the effectiveness of alternative P sources of reduced costs.

Investigating the Mechanical Behaviour of Unbound Granular Material (UGM) for Road Pavement Construction Applications: A Western Victoria Case Study

The behaviour of unbound granular materials (UGMs) used in road construction is crucial in determining the longevity and performance of road pavement. Geotechnical analysis can assist engineers in selecting suitable materials and designing road pavements that meet industry standards. This paper presents the results of laboratory geotechnical tests conducted on unbound granular materials (UGMs) collected from three sites (Roses Gap, Rules East, and Polkemmet Road) in Horsham, Victoria, Australia. UGMs were investigated for their mechanical behaviour and suitability as subgrade materials for road pavements. The study utilised laboratory geotechnical tests, including particle size distribution (PSD), Atterberg limits, compaction (Proctor) test, unconfined compressive strength (UCS), California Bearing Ratio (CBR), and repeated load triaxial (RLT) tests, to evaluate the physical and mechanical properties of the UGM samples. The study indicates that UGM samples collected from different locations displayed variations in their geotechnical properties, such as particle size distribution, water absorption, and CBR strength. Roses Gap samples showed weak cohesion properties, and significant vertical displacements after repeated triaxial tests. However, among the samples in this site, samples with higher clay content (RG21) demonstrated the most promise in triaxial tests. Similarly, the Rules East samples were found to be suitable for low-traffic subgrades due to their satisfactory CBR and RLT testing results, albeit with little cohesion from clay content. Out of three locations, Polkemmet samples were identified as potential subgrade applications, with PR12 being the top recommendation overall. It satisfied PSD, CBR, and RLT test conditions due to acceptable particle size in the largest range, highest CBR strength value, and lowest permanent displacement. The study's findings provide useful information for the design of road pavements using these materials and the characterisation of rural materials around the Horsham region for future use in various other contexts.

Water dispersible clay and micro-structure of soils from coastal plain sands, shale and false-bedded sandstones

Information regarding water-dispersible clays in soils of contrasting textures is needed to evaluate soil qualities that influence susceptibility of soils to slaking in water. Water-dispersible clays (WDCs), plastic limits, and basic properties of soils on Coastal Plain Sands (CPS), Shale (Shale), and False-Bedded Sandstones in southern Nigeria were quantified for use in evaluating management options of some tropical soils. Results revealed that WDCs, micro-aggregate indices, and plastic limits differed significantly amongst the parent materials. At 0–15 cm depth, clay content was 29.7%, 11.2 and 3.8%, for Shale, CPS and False-Bedded sandstones, respectively, indicating significant high clay content in Shale. The highest SOC of 29.8 g kg−1., and very slow saturated hydraulic conductivity (Ksat) of 6.33 cm h−1 were found in Shale. False-Bedded Sandstone had the lowest SOC content of 7.7 g kg−1 and highest Ksat value of 31.10 cm h−1 at 0–15 cm topsoil. Micro-aggregate stability indices measured by aggregated silt+clay (ASC) and clay flocculating index (CFI) were significant in CPS at 0–15 cm, whereas water-dispersible clay (WDC) was significantly higher (p < 0.05) in Shale at 8.32%, compared to very low value of 0.76% in False-Bedded Sandstone. Plastic limit (PL) of 16.5%, was significantly higher (p < 0.05) in Shale, indicating its high sensitivity to mechanical deformation when wet. There was a significant positive correlation between clay content and WDC (r = 0.815, p < 0.01), indicating the positive influence of clay content on WDCs and micro-structural indices, and the tendencies for quick degeneration of the soils.

Pore-scale water–gas distribution and gas permeability of natural gas hydrate reservoirs in the South China Sea

Challenges in water drainage within natural gas hydrate reservoirs in the Shenhu area of the South China Sea, characterized by high clay content and strong hydrophilicity, significantly hinder natural gas recovery. Examining the effects of gas pressure and liquid/gas saturation on gas permeability reveals essential insights for increasing gas production potential. We report gas displacement experiments on clayey-silt sediment samples, alongside X-ray computed tomography imaging, that reveal critical findings: a notable increase in flow rate and permeability as displacement pressure nears compaction pressure, highlighting the role of pressure management in enhancing recovery; water displacement from varying pore sizes under different pressures, highlighting the influence of pore size on fluid dynamics, and structural changes, including microfracture formation and a significant fracture that enlarges total pore space by about 15%, which collectively suggest methods to improve gas flow and recovery. Moreover, our analysis identifies average throat length, fractal dimension, and succolarity as principal controls on gas permeability, indicating the substantial impact of microstructural properties on extraction efficiency. These outcomes offer valuable strategies for optimizing natural gas hydrate reservoir development in the South China Sea, emphasizing the need for meticulous pressure and saturation control and in applying a deep understanding of microstructural dynamics.

High-strength montmorillonite polyurethane nanocomposites with exfoliated montmorillonite: Preparation and characterization

High-strength polyurethane (PU) nanocomposites were synthesized by incorporation of organically modified montmorillonite (OMMT) in different proportions. Cation exchange for MMT was carried out using quaternary ammonium cation of 2,2-bis[4-(4-amino phenoxy)phenyl]propane to induce organophilic nature into the inorganic reinforcement. By in-situ polymerizing polyethylene glycol (PEG, MW 6000) and toluene 2,4 diisocyanate (TDI) at temperatures between 40 and 60 oC, PU/OMMT nanocomposite films were created. Thin nanocomposite films with 2, 4, 8, and 12 % clay content by weight were prepared and analyzed through FTIR, XRD, SEM, tensile testing and TGA. The incorporation of OMMT platelets into the polymer matrix was confirmed through functional group analysis by FTIR spectroscopy. XRD patterns confirmed the organ modification of clay platelets with increased interlayer spacing and homogeneous dispersion within the polymer matrix. SEM depicted fine dispersion with good adherence between both phases. With a higher clay content, the nanocomposites' mechanical strength and thermal stability were enhanced. Thermal decomposition temperature was enhanced from 342 for the neat polymer to 446 °C for 12 wt% of clay content.

Using the kinetic approach for the adsorption of base ions (Ca, Mg, Na, K) by the calm flow method in some soils in the northern of Iraq

Abstract. Four soils were selected from northern Iraq, within the ranks (Mollisols, Inceptisols) from the provinces of Dohuk, Erbil and Sulaymaniyah from different agricultural fields from the root zone (0-0.30 m). Their physicochemical and mineral properties were estimated to study thermally isotropic adsorption by the calm flow method of soil columns using an electrolytic solution. At concentrations of (3) mmol charge.L-1, containing Ca, Mg, K, and Na ions in two repetitions at a constant temperature of approximately 298 ± 2 K. Stabilization filters were collected in which the ions were estimated according to the coefficients. The results indicated that the reactions ranged from medium alkaline to medium acidic. (6.7- (7.8), unaffected by salinity (1.44 - 0.29) dS.m-1 with an ion exchange capacity between (22.43 - (33.9 Cmolc.Kg-1) and is calcareous soil due to its high content of total carbonate minerals (-112) g.kg-1 .In addition to the calcareous origin material, and it has a high clay content (304-534) g.kg-1 with the predominance of smectite, chlorite, Ilite, kaolinite and Ilite clay minerals, the nature of ion exchange using the kinetic entrance of adsorption showed a clear effect of the porous fats and the contact time of the electrolyte solution on the adsorbed quantities depending on the type of soil. Show the mathematical description of the process of arranging the kinetic equations according to their validity as follows: Power &gt; First order &gt; Parabolic &gt; Elovage &gt; Zero order

Fines migration characteristics of illite in clayey silt sediments induced by pore water under the depressurization of natural gas hydrate

Marine gas hydrate is widely distributed in clayey silt sediments, which have high clay content and low permeability. The decomposition of natural gas hydrate will cause the mechanical failure of the reservoir and the decrease of pore water salinity, inducing the migration of clay minerals to clog the pore throat, which has a significant impact on the production efficiency of natural gas hydrate. In this work, the migration behaviour of illite in clayey silt sediments driven by pore water under the depressurization of hydrate was studied through pressure difference, pore throat and content changes. We studied the migration process of silt, excluding the interference of synergistic migration of silt and illite, and then studied the migration of illite under the change of flow rate and salinity. The results show that illite will migrate before silt and that critical flow rate and critical salinity exist. The flow rate mainly affects the torque generated by the forces detaching the illite particles. Illite particle detachment will occur if the flow rate exceeds the critical value and the torque balance is disrupted, and then the pore throat is clogged. There are two effects of salinity decrease on illite migration. Above the critical salinity, the expansion of the pore throat due to decomposition has a significant effect on illite migration. Below the critical salinity, the increase of the diffuse electric double layer thickness and the electrostatic repulsion will lead to an increase of the particle concentration in the pore water, making clogging more likely to occur even at low flow rates. This work suggests that clay migration has a complex impact on the development of clayey silt hydrate, and helps to consider the reasonable combination of saturation and production rate when designing a development plan to reduce the impact of permeability decline due to continuous pore throat clogging on development efficiency.

Freeze-thaw effects on pore space and hydraulic properties of compacted soil and potential consequences with climate change

Freezing and thawing affect the pore-space structure in agricultural soils with implications for soil hydraulic properties and water flow. Previous studies have focused on the upper few centimeters of the tilled topsoil, where most freeze-thaw (FT) cycles occur, even though deeper soil layers are also subject to freezing and thawing in cold climates. Thus, little is known about how freezing and thawing affect untilled soil layers, which often show high bulk densities that restrict vertical water movement. Furthermore, it remains unclear how shifts in FT patterns with climate change may change the pore-space structure and water flow through these soil layers. Here we investigated the effects of freezing and thawing on X-ray imaged pore-space characteristics, water retention and near-saturated hydraulic conductivity (K) in untilled soil directly below plough depth. Intact cores were sampled at two sites in central Sweden under the same long-term reduced tillage management. The two soils, a silt loam and a silty clay loam, were subjected to three FT scenarios in a laboratory environment intended to represent FT patterns that are considered likely under current and future winter conditions for this region. The latter scenario was characterised by more FT cycles and a lower freezing temperature. Freezing and thawing increased K in the near-saturated range in both soils, which we attribute to observed small (<0.01 mm3 mm−3) increases in the volume of pores of diameters close to the X-ray resolution limit. Concomitant increases in pore network connectivity and critical pore diameter, especially in the denser silty clay loam soil, probably contributed to this increase in K. The water retention data suggested that changes in pore-space characteristics below X-ray resolution also occurred in both soils. Furthermore, our results indicate that both soils may show higher drainage rates due to shifts in FT patterns in the future, although longer-term changes in pore-space structure with an increasing number of FT cycles would mostly be limited to soils with relatively high clay contents. These soils are often more compacted below plough depth and, thus, benefits from improvements in soil structure such as improved root growth and plant water supply are also expected to be larger.

Assessment of Phytotoxicity of Potable Water Treatment Plant Sludge-bound Compost Pellets on Seed Germination of Radish (Raphanus sativus L.)

Binding loose compost into pellets needs different binding materials. Maintenance of pellet stability highly depends on the binding materials used. Potable water treatment plant sludge (WTPS) has the potential to be used as a binding material due to the high content of clay, organic matter, and nutrients. However, compost and WTPS may contain heavy metals, toxic compounds, salts, and growth inhibitors. Therefore, the determination of the phytotoxicity of WTPS bound compost pellets is essential before amending them to the soil. The present study aimed to assess the phytotoxicity of different pelleted compost using seed germination bioassay of Raphanus sativus L. Four compost pellets were considered (T1: commercial compost pellet (100% compost), T2: commercial integrated pellet (90% compost+10% inorganic fertilizer), T3: WTPS-bound compost pellet (90% compost+10% WTPS), T4: WTPS-bound integrated pellet (80% compost+10% WTPS+10% inorganic fertilizer)) and pellet aqueous extracts (PAE) were prepared, respectively. Distilled water was used as the control. The dilution sequence of PAE as 50% and 100% were tested for seed germination in Petri dishes in a randomized design with three replicates. pH, EC, and selected heavy metals (Al, Zn, Cu and Cr) were determined in PAE. RSG% (Relative Seed Germination %), RRG% (Relative radicle Growth %), and GI% (Germination Index) were calculated for all the PAE after 72 hours. The PAE had a pH range from 6.8-7.2. The Cr was not detected in all 100% PEA. The highest levels of Al and Zn were detected in 100% PAE of T1. All the treatments in both 50% and 100% PAE showed GI% higher than 80% except the 100% PAE of commercial integrated pellet (T2) and WTPS-bound integrated pellet (T4). The PAE from the T2 and T4 showed low RSG% and RRG% and thereby the GI% is low due to high EC in PAE. The GI% of 100% PAE in T2 and T4 was 32.33% and 67.25%, respectively. The lowest values for RSG% and RRG% were recorded for T2 as 44.44% and 72.75%, respectively. Spearman‘s Rank Correlation coefficients were calculated for EC with RSG%, RRG%, and GI% and all variables showed negative correlations as (-0.44), (-0.97), and (-0.69), respectively. This indicates that high EC reduces radical growth and seed germination. PAE at 100% concentration levels of commercial integrated pellet showed high phytotoxicity, and WTPS-bound integrated pellet showed less phytotoxicity while other treatments did not show any sign of phytotoxicity. All the PAE at 50% concentration level were free from phytotoxicity. Hence, 10% WTPS in w/w basis can be used as a binding agent in pelletizing loose compost. Different WTPS concentrations should be tested in binding process for its optimum utilization. &#x0D; Keywords: Bioassay, Compost, Phytotoxicity, Radish, Water treatment plant sludge

A log-based method for fine-scale evaluation of lithofacies and its applications to the Gulong shale in the Songliao Basin, Northeast China

The Gulong shale demonstrates high clay content and pronounced thin laminations, with limited vertical variability in log curves, complicating lithofacies classification. To comprehend the distribution and compositional features of lithofacies in the Gulong shale for optimal sweet spot selection and reservoir stimulation, this study introduced a lithofacies classification scheme and a log-based lithofacies evaluation method. Specifically, the ΔlgR method was utilized for accurately determining the total organic carbon (TOC) content; a multi-mineral model based on element-to-mineral content conversion coefficients was developed to enhance mineral composition prediction accuracy, and the microresistivity curve variations derived from formation micro-image (FMI) log were used to compute lamination density, offering insights into sedimentary structures. Using this method, integrating TOC content, sedimentary structures, and mineral compositions, the Qingshankou Formation is classified into four lithofacies and 12 sublithofacies, displaying 90.6% accuracy compared to core description outcomes. The classification results reveal that the northern portion of the study area exhibits more prevalent fissile felsic shales, siltstone interlayers, shell limestones, and dolomites. Vertically, the upper section primarily exhibits organic-rich felsic shale and siltstone interlayers, the middle part is characterized by moderate organic quartz-feldspathic shale and siltstone/carbonate interlayers, and the lower section predominantly features organic-rich fissile felsic/clayey felsic shales. Analyzing various sublithofacies in relation to seven petrophysical parameters, oil test production, and fracturing operation conditions indicates that the organic-rich felsic shales in the upper section and the organic-rich/clayey felsic shales in the lower section possess superior physical properties and oil content, contributing to smoother fracturing operation and enhanced production, thus emerging as dominant sublithofacies. Conversely, thin interlayers such as siltstones and limestones, while producing oil, demonstrate higher brittleness and pose great fracturing operation challenges. The methodology and insights in this study will provide a valuable guide for sweet spot identification and horizontal well-based exploitation of the Gulong shale.

Assessment of Impact of Agricultural Land-Use Types on Some Soil Physical and Chemical Properties in Abeokuta, Southwestern Nigeria

Agricultural land-use practices play a pivotal role in shaping the physical and chemical properties of soil, which in turn influence crop productivity, environmental sustainability, and overall ecosystem health. Understanding the impact of different agricultural land-use types on soil properties is crucial for sustainable land management and effective agricultural practices. This study utilized electrical resistivity technique (ERT) and geochemical methods to assess the impact of different land-uses (mineral farms, organic farms, thick plantations, and cattle stations) on soil physicochemical properties. The research aimed to explore the correlation between soil resistivity and fertility, as well as evaluate the influence of specific land-use types on soil characteristics. Four resistivity traverses were conducted, each corresponding to a different land-use type, and soil samples were collected from various depths. Laboratory analysis revealed high clay content in the cattle station, while all land-use types showed high sand content. Available phosphorus was significantly affected by both land-use and soil depth, negatively correlating with electrical conductivity. Exchangeable bases were generally low across all land-use types. The study recommends promoting site-specific, sustainable land management practices within different agricultural land-use systems.

Temperature-Corrected Calibration of GS3 and TEROS-12 Soil Water Content Sensors

The continuous monitoring of soil water content is commonly carried out using low-frequency capacitance sensors that require a site-specific calibration to relate sensor readings to apparent dielectric bulk permittivity (Kb) and soil water content (θ). In fine-textured soils, the conversion of Kb to θ is still challenging due to temperature effects on the bound water fraction associated with clay mineral surfaces, which is disregarded in factory calibrations. Here, a multi-point calibration approach accounts for temperature effects on two soils with medium to high clay content. A calibration strategy was developed using repacked soil samples in which the Kb-θ relationship was determined for temperature (T) steps from 10 to 40 °C. This approach was tested using the GS3 and TEROS-12 sensors (METER Group, Inc. Pullman, WA, USA; formerly Decagon Devices). Kb is influenced by T in both soils with contrasting T-Kb relationships. The measured data were fitted using a linear function θ = aKb + b with temperature-dependent coefficients a and b. The slope, a(T), and intercept, b(T), of the loam soil were different from the ones of the clay soil. The consideration of a temperature correction resulted in low RMSE values, ranging from 0.007 to 0.033 cm3 cm−3, which were lower than the RMSE values obtained from factory calibration (0.046 to 0.11 cm3 cm−3). However, each experiment was replicated only twice using two different sensors. Sensor-to-sensor variability effects were thus ignored in this study and will be systematically investigated in a future study. Finally, the applicability of the proposed calibration method was tested at two experimental sites. The spatial-average θ from a network of GS3 sensors based on the new calibration fairly agreed with the independent area-wide θ from the Cosmic Ray Neutron Sensor (CRNS). This study provided a temperature-corrected calibration to increase the accuracy of commercial sensors, especially under dry conditions, at two experimental sites.

Natural Cement in Portugal: Context in Cement Production and Architectural Use

Natural cement, also known as “Roman cement”, was used across Europe during a historic period, mainly in many building facades, due to its hydraulic properties and aesthetic qualities. In Portugal, the use of natural cement occurred in buildings from the second half of the 19th century to the beginning of the 20th century, a period during which the use of lime binders decreased and before the massive use of Portland cement. Recent conservation and rehabilitation actions resulting from necessary interventions in heritage buildings from this period have played an important role in revealing evidence of the use of natural cement and clarifying the lacunae of information about this material. Due to the inadequate use of reparation materials in previous conservation and rehabilitation interventions, this study summarizes the historical production, study, and use of natural cement in Portugal. Natural cement results from the calcination of clay-rich limestone (marlstone) without any compositional changes after extraction, distinguishing itself from hydraulic lime due to its higher clay content and allowing for the formation of higher quantities of hydraulic reactive phases without free lime. Although this topic has been approached at a European level, mainly focusing on the production and use of natural cement in Central Europe, in Portugal, it is still necessary to produce and disseminate information on this specific subject. Therefore, this study focuses on the evolution of cement production in Portugal and an analysis of the existing knowledge of the binders used in architectural heritage based on the scientific and historical bibliography.

Characterization of Soil Properties Influencing Flash Flood-Related Road Damage in North-Eastern Regions of Bangladesh

Flash floods in the North-Eastern region of Bangladesh pose a severe threat to road infrastructure, causing extensive damage and disruptions. This study focuses on the comprehensive characterization of soil properties that play a pivotal role in exacerbating flash flood-related road damage. The North-Eastern region, characterized by diverse geological formations, including the Surma Basin and the Meghalaya Plateau, experiences recurrent flash floods during the monsoon season. The undulating topography and a network of rivers contribute to the complexity of the hydrogeological system, influencing soil properties and their impact on road infrastructure.&#x0D; Field surveys were conducted to identify flash flood-prone areas, focusing on elevation, slope, and proximity to water bodies. Soil samples were collected at various depths and locations within vulnerable road sections, considering different land uses and topographical features. Laboratory analyses included particle size distribution, moisture content determination, soil classification, and cohesion tests. The results of this study highlight specific road sections vulnerable to flash floods, providing a foundation for targeted soil characterization. Key soil properties influencing road damage include high clay content, poor drainage characteristics, and low cohesion. The results also revealed the correlation between vulnerable road sections and specific combinations of soil properties, allowing for the identification of hotspots prone to flash flood-related damage.&#x0D; Finally, this study contributes to an enhanced understanding of the soil properties influencing flash flood-related road damage in the North-Eastern region. The identified key soil characteristics offer valuable insights for road infrastructure planning and design, emphasizing the need for mitigation measures such as improved drainage systems and the use of appropriate roadbed materials to enhance overall road resilience in flood-prone areas.

A seismic prediction method of reservoir brittleness based on mineral composition and pore structure

The Lucaogou Formation, a typical fine-grained mixed formation in the Jimusaer Sag of the Junggar Basin, exhibits considerable potential for hydrocarbon exploration. Accurate brittle prediction is a crucial factor in determining hydraulic fracturing effectiveness. However, the area features complex lithological characteristics, including carbonate rocks, clastic rocks, volcanic rocks, and gypsum interbeds, along with thin layering and sporadic sweet spots. Traditional prediction methods offer limited resolution and there is an urgent need for a seismic brittle prediction method tailored to this complex geological environment. This paper presents a multi-mineral composition equivalent model for complex lithologies that enables the accurate calculation of Vp and Vs These ratios serve as the foundation for pre-stack elastic parameter predictions, which include Poisson’s ratio and Young’s modulus. By comparing the predicted parameters with well-logging measurements, the prediction accuracy is improved to 82%, with particularly high conformity in intervals characterized by high organic matter and clay content. Additionally, a three-dimensional brittle modeling approach reveals that the brittleness of the reservoir exceeds that of the surrounding rock, showing a gradual improvement in brittleness with increasing burial depth from southeast to northwest. The central area exhibits relatively good brittleness, with a stable, blocky distribution pattern.

Microstructural damage and durability of plateau concrete: Insights into freeze-thaw resistance and improvement strategies

Extreme environmental conditions and inferior building materials in plateau regions present significant challenges to the durability of concrete structures, particularly in resisting freeze-thaw cycles. This study employs an actual mix ratio from a concrete mixing station in the Qinghai-Tibet Plateau for a comparative analysis against conventional mixes in plain terrains. Utilizing a fast-freezing test with controlled variables, the study explores the microstructural evolution of plateau concrete. Results reveal that although the adapted mix ratio meets strength criteria, it falls short in frost resistance compared to standard concrete used in plain regions. Further, the plateau-specific curing conditions were shown to increase both the width and porosity of the interface transition zone (ITZ). High clay content in building materials for plateau construction also impacts the cement paste's microstructure. The study offers engineering recommendations aimed at enhancing the quality and performance of concrete in plateau conditions to address the unique challenges posed by extreme environmental factors.