High Adsorption Efficiency Research Articles

High-efficiency adsorption of HF and HCN gases by transition metal X (X=Pd, Mo, Ni) doped WS2 :a first-principles study

Abstract This article studies the adsorption effect of pristine WS2 and Pd, Mo, Ni-doped WS2 on HF and HCN gases based on density functional theory. The energy band structure, density of states (DOS), charge differential density (CDD), adsorption energy, charge transfer, and molecular orbitals of the materials are calculated. The results show that Pd, Mo, Ni-doped WS2 significantly improve the adsorption energy of HF and HCN gases. Moreover, the Mo_WS2/HF system exhibits a charge transfer of 0.48 e, significantly higher than other systems. Mo_WS2 and Ni_WS2 systems exhibit an increase in transferred charges compared to pristine WS2 as adsorbing HCN, which are easy to adsorb HCN. Using recovery time as an indicator, Mo_WS2 is the most suitable for adsorbing HF between 300 K and 400 K, while Ni_WS2 is the most suitable for adsorbing HCN. Analyzed the application of materials in adsorbing harmful gases HF and HCN.

Sustainable Methylene Blue dye removal with activated carbon from Prosopis juliflora stem

This study addresses the environmental challenge posed by the invasive Prosopis juliflora plant by converting its stem into activated carbon for the adsorption of Methylene Blue dye from water. The goal is to create an effective and sustainable wastewater treatment solution. Prosopis juliflora stems were harvested, cleaned, dried, carbonized, and activated with zinc chloride to create Prosopis Juliflora Stem Activated Carbon. This activated carbon was characterized using Brunauer-Emmett-Teller surface area analysis, Fourier transform infrared spectroscopy, and scanning electron microscope imaging. Results revealed a significant surface area of 158.107 m2/g and the presence of functional groups essential for adsorption processes. Batch adsorption experiments were conducted to determine the efficiency of activated carbon in removing Methylene Blue dye at various dosages and contact times. The highest adsorption efficiencies were 73.5% at 80 min, 90.1% at 60 min, and 90.65% at 50 min for dosages of 80, 100, and 120 mg, respectively. These findings show that Prosopis Juliflora Stem Activated Carbon is highly effective at removing Methylene Blue dye, providing a cost-effective and environmentally friendly method of wastewater treatment.

High Methylene Blue Adsorption Efficiency of Cellulose Acetate-Based Electrospun Nanofiber Membranes Modified with Graphene Oxide and Zeolite

High Methylene Blue Adsorption Efficiency of Cellulose Acetate-Based Electrospun Nanofiber Membranes Modified with Graphene Oxide and Zeolite

Copolymeric hydrogels with high capacities of hydration and methylene blue adsorption in water

Copolymers based on monomethyl hydrogen itaconate (βHI) with 2-hydroxyethyl methacrylate (HEMA) and βHI with 2-hydroxypropyl methacrylate (HPMA) were prepared in different monomer molar ratios. The reactivity parameters of copolymerization (r1 and r2) were determined. The values obtained for r1 and r2 indicate that P(βHI-co-HEMA) exhibits a high tendency towards alternate copolymerization. Structural characterization of the copolymeric hydrogels was carried out using Fourier transform infrared (FTIR) and 1H NMR spectroscopies, where the characteristic signals of the constituent functional groups were observed. The typical thermal stability of the polymeric systems was observed by thermogravimetric analysis (TGA). In addition, the swelling capacity in water was evaluated, and a swelling percentage over 655 % and 1249 % presented P(βHI-co-HEMA) and P(βHI-co-HPMA) respectively, in a period of 15 days at pH 10, and presence of 0.05 M NaNO3.Additionally, methylene blue (MB) adsorption capacity was studied in batch mode by varying different experimental parameters. MB adsorption capacity of 122.79 mg g−1 and 112.24 mg g−1 were achieved for P(βHI-co-HEMA) and P(βHI-co-HPMA), respectively. The data obtained were fitted to the Elovich kinetic model and to a Redlich-Peterson isotherm. The thermodynamic parameters indicated that the adsorption phenomenon is spontaneous, endothermic and with a high probability of occurrence. The adsorption efficiency decreases by approximately 60 % in the presence of interfering ions (Na+, K+, Ca2+ and Cl−). The adsorbents are reusable and achieve high MB adsorption efficiency (90 % and 80 % for P(βHI-co-HEMA) and P(βHI-co-HPMA) respectively) in a textile-simulated wastewater. Based on the results obtained, it is concluded that P(βHI-co-HEMA) and P(βHI-co-HPMA) show great potential for use in adsorption of water molecules, for MB retention and purification of simulated effluents from the textile industry.

Carbon-Based Adsorbents for Microplastic Removal from Wastewater.

Plastics are widely used across various industries due to their flexibility, cost-effectiveness, and durability. This extensive use has resulted in significant plastic pollution, with microplastics (MPs) becoming pervasive contaminants in water bodies worldwide, adversely affecting aquatic ecosystems and human health. This review explores the surface characteristics of carbon-based adsorbents, including biochar, activated carbon, carbon nanotubes (CNTs), and graphene, and their influence on MP removal efficiency. Key surface characteristics such as the carbon content, surface area, pore size, and particle size of adsorbents influenced adsorption efficiency. Additionally, hydrophobic interaction, van der Waals forces, π-π interactions and electrostatic interaction were found to be mechanisms by which microplastics are trapped onto adsorbents. Modified biochar and activated carbon demonstrated high adsorption efficiencies, while CNTs and graphene, with their high carbon contents and well-defined mesopores, showed outstanding performance in MP removal. Although a high surface area was generally associated with better adsorption performance, modifications significantly enhanced efficiency regardless of the initial surface area. This review emphasizes the importance of understanding the relationship between surface characteristics and adsorption efficiency to develop optimized adsorbents for MP removal from wastewater. However, challenges such as the lack of standardized testing methods, variability in biochar performance, and the high cost of regenerating carbon adsorbents remain. Future research should focus on developing cost-effective production methods, optimizing biochar production, and exploring advanced modifications to broaden the application of carbon adsorbents. Integrating advanced adsorbents into existing water treatment systems could further enhance MP removal efficiency. Addressing these challenges can improve the effectiveness and scalability of carbon-based adsorbents, significantly contributing to the mitigation of microplastic pollution in wastewater.

FeBTC MOF‐Derived Fe3O4@C Nanocomposite: Controlled Synthesis and Application as Potential Adsorbent for Rhodamine Dye Elimination From Wastewater

ABSTRACTThis study explores the controlled synthesis of a novel Fe3O4@C magnetic nanocomposite derived from FeBTC metal–organic framework (MOF) and its application as an efficient adsorbent for the removal of rhodamine dye from wastewater. The FeBTC MOF was first synthesized and then thermally decomposed in a controlled oxygen atmosphere at 375°C (1 h) to form the Fe3O4@C nanocomposite with a magnetic Fe3O4 core embedded in a porous carbon matrix. A comprehensive characterization of the nanocomposite was performed using x‐ray diffraction (XRD), transmission electron microscopy (TEM), and x‐ray photoelectron spectroscopy (XPS) to confirm the successful formation and to evaluate its structural and morphological properties. The morphological investigation revealed that the particles of Fe3O4 had a spherical shape with diameter of 10–15 nm. The carbon coating appeared as a thin amorphous layer surrounding the Fe3O4 nanoparticles. The adsorption capacity of Fe3O4@C for rhodamine B (RhB) dye was assessed under various conditions, including different pH values, contact times, initial dye concentrations, and temperatures. Complete dye removal was attained in 45 min using 50 mg of the nanocomposite and 50 mL of 5.0 ppm RhB at the optimum pH of 9.1. Under the same experimental conditions, the highest adsorption capacity of 13.0 mg/g was obtained, but using 15.0 mg of the nanocomposite. Fe3O4@C nanocomposite exhibits high adsorption efficiency, with a maximum removal capacity of 100%, which is clearly superior to many conventional adsorbents. This performance can be attributed to the synergistic effects of the magnetic Fe3O4 and the large surface area of the carbon matrix. Kinetic models were employed to understand the adsorption mechanism. The adsorption kinetics followed a pseudo‐second‐order model. The reusability of the adsorbent was tested over multiple cycles and showed a minimal loss of performance (drops to 93.0% after five removal cycles). The study demonstrates that the Fe3O4@C nanocomposite is a promising candidate for the effective removal of organic dyes from wastewater, offering potential benefits for environmental remediation and sustainable water management.

Ultra high sensitive long range surface plasmon resonance sensor for chemical and biochemical sensing

In this work, we proposed a long-range surface plasmon (LRSPR) sensor using a dielectric (Cytop) –Gold (Au)- graphene oxide (GO) layer to enhance the sensor’s detection accuracy (DA), figure of merit (FoM) and imaging sensitivity (Simag). The proposed sensor’s effectiveness for long-range is numerically demonstrated. The GO layer is used to protect the unwanted oxidation of Au and to improve the imaging sensitivity. By comparing its FoM and Simag to that of the traditional surface plasmon sensor (cSPR), the proposed sensor takes advantage of its high adsorption efficiency and high resolution. The Au-GO layer in the cSPR sensor and the cytop-Au-GO layer in the proposed sensor interfaces enhance the electric field intensity and penetration depth (PD). We attain the highest DA, FoM and Simag of 100/°, 1400/RIU, and 4183.9/RIU with 2000 nm of cytop thickness. For chemical and biological applications, the proposed LRSPR sensor design may be advantageous.

Kinetics of Cd adsorption by biochar, activated carbon, and zeolite in some calcareous soils

AbstractDifferent methods have developed to reduce the risks of potentially toxic elements in contaminated soils. Among them, adsorption is one of the most important and effective strategies. In this research, kinetics of Cd adsorption by biochar, activated carbon, and zeolite in some calcareous soils were investigated. A factorial experiment was conducted based on a completely randomized design with three replications. The factors included three types of adsorbents (sunflower's biochar, activated carbon, and zeolite), four levels of Cd (0, 20, 50, and 100 mg/L as Cd (NO3)2), and three soil samples, differing in their cation exchange capacity, soil organic matter, and calcium carbonate equivalent. Batch experiments were carried out to evaluate Cd adsorption isotherms and kinetic models. Furthermore, the effect of adsorbent dosage, contact time, and initial pH on the adsorption efficiency was examined. Optimizing studies revealed that the best pH for Cd adsorption was 5, while the optimal equilibrium time was achieved at 24 h. The results showed that the Freundlich model fitted to the experimental data slightly better than the Langmuir model. Moreover, the pseudo‐second‐order kinetic model better described the kinetic behavior of Cd adsorption for the investigated adsorbents. The maximum Cd removal efficiency (99%) belonged to soil No. 2 with biochar. Lastly, it was concluded that sunflower biochar, a cheap and cost‐effective adsorbent, had high efficiency in Cd adsorption in calcareous soils.

Surfactant-modified zein nanoparticles adsorbents for ultrafast and efficient removal of Cr(VI)

The adsorption and removal of heavy metal ions Cr(VI) is of great significance for human health and ecological environment. Here, an ultrafast and high efficient adsorbent for Cr(VI) was developed based on cetyltrimethylammonium bromide (CTAB)-modified zein nanoparticles (C-ZNPs). In comparison to pristine zein nanoparticles (ZNPs) (11.199 m2 g−1), the surfactant-modified C-ZNPs exhibited larger specific surface area (17.002 m2 g−1). Moreover, C-ZNPs had superior dispersion and more positive charge distribution, which contributed to the improvement for adsorption performance. The results showed that the saturated adsorption of Cr(VI) was reached up to 192.27 mg/g using the C-ZNPs nanosorbent at T = 298 K, pH = 4, t = 10s, and C0 = 125 mg/L. The removal rate was significantly faster than that reported natural polymer-based adsorbents. The experimental values were followed Freundich isothermal model and pseudo-second-order kinetic model, indicating that the adsorption occurred primarily through a multimolecular layer adsorption process, with a strong emphasis on chemisorption. Mechanistic investigations further revealed that the adsorption of Cr(VI) onto C-ZNPs was mediated by various interactions, including electrostatic attraction, complexation, and ion exchange. These findings provide insights into the efficient removal of Cr(VI) by C-ZNPs and suggest potential applications in water treatment and environmental remediation.

Fragrance Carrier Based on Zeolite-A Modified Bentonite as a Controlled Release System in Air Freshener Applications

The quality of air fresheners with low cost production can be improved by using a carrier matrix such as synthetic zeolite to increase the long-lasting properties of fragrance product by encapsulation technique. The zeolite A is considerdas a safe core fragrance carrier matrix to be able to release volatile fragrance from their pores when exposed to atmospheric humidity at room temperature. Zeolite A was synthesized from natural kaolin and was formed into tube pellets with bentonite (20 wt.%) as binder to produce zeolite A-bentonite (ZAB) cylindrical pellets composite and used as a fragrance carrier matrix with a rose essential oil (Rose damascena Mill.) as parfume model. The fresh bentonite can also adsorb the rose essential oil with adsorption capacity of 1.745 g/g bentonite (74.5%). Effects of chemical activation on zeolite-A using acid (HCl) of 0.1 M and base (NaOH) of 0.1 M were studied. The ZAB tube pelletes were found to have high adsorption efficiencies of rose essential oil. ZAB4 has the highest efficiency and was used for regeneration test studies that was carried out over 10 cycles using HCl and NaOH, where the adsorption efficiency was 94.5 and 75.4%, respectively. The activated ZAB4 composite using HCl has a long life time until more than 5 weeks and more than 10 regeneration cycles. This fragrance carrier matrix based on ZAB has significant potential for extended carrier fragrance system.

Efficient microplastics adsorption in aqueous environments via bidirectional ordered graphene oxide/nanocellulose aerogels

Microplastics not only accumulate various harmful substances but also are ingested by marine organisms and humans, causing immeasurable impacts. Therefore, the removal of microplastics has become a crucial proposition for addressing the issue of microplastic pollution. This study investigated a bidirectional ordered graphene oxide (GO)/nanocellulose aerogels (D-DPGG) to remove microplastics from water bodies. The concentration of microplastics before and after adsorption was measured using a fluorescence spectrophotometer. D-DPGG aerogel exhibited excellent adsorption performance for microplastics (241.56 mg/g) and maintained high adsorption efficiency (>80 %) over 20 cycles of adsorption testing. Additionally, the link between GO and dual-directional treatment significantly improved the aerogel microstructure. It had an apparent layered structure in the transverse direction and improves the mechanical properties. D-DPGG aerogel not only served as an effective solution in adsorption but also held promise as a novel material in directional structural design.

Effect of Fe3+ ions doping on adsorption efficiency of Li4Ti5O12 and Li2TiO3 oxides towards Li+ ion

Adsorbents based on Fe3+-doped oxides Li1.33- xFe3xTi1.67–2xO4 (x=0.1–0.9) and Li2–2xFexTi1-xO3 (x=0.05–0.35) were synthesized by solid-phase method. It was found that the Li1.33-xFe3xTi1.67–2xO4 (x=0.1–0.3) and Li2–2xFexTi1-xO3 (x=0.05–0.1) oxides retained cubic (Fd3m) and monoclinic (C2/c) structure and did not contain admixed phases. Li2–2xFexTi1-xO3 (x=0.05–0.1) and Li1.33- xFe3xTi1.67–2xO4 (x=0.1–0.3) samples had unit cell size a of 9.004 and 8.243–8.305 Å and crystallite size of 26.6–25.3 and 37.1–38.0 nm, respectively. There are no new absorption bands, and only a characteristic peak shift of the Ti-O bond was observed on FT-IR spectra of Li1.33- xFe3xTi1.67–2xO4 (x<0.3) and Li2–2xFexTi1-xO3 (x<0.2) samples due to heterovalent substitution of Ti atoms with Fe. The obtained samples had characteristics of a mesoporous texture, and the isotherms were irreversible, belonging to pseudo-type II and had H3-type hysteresis loops. The specific surface area and mesopore volume of the obtained samples increased slightly with raising the amount of introduced dopant from 5 to 11 m2/g and from 8 to 15 m2/g for Li1.33-xFe3xTi1.67–2xO4 and Li2–2xFexTi1-xO3, respectively. The SEM data showed the prevalence of homogeneous monolithic spherical particles with a size of ∼250 nm. The degree of conversion to the H-form reached 98 and 73–91 % for Li1.33-xFe3xTi1.67–2xO4 and Li2–2xFexTi1- xO3. The adsorption capacity of Fe3+ ion-doped oxides Li1.33- xFe3xTi1.67–2xO4 and Li2–2xFexTi1- xO3 at V/m=250 cm3/g, C(Li+)=1.0 g/L, pH=12.0 reached 59.9 and 50.3 mg/g, respectively. The high structure stability and adsorption efficiency in 5 cycles of acid regeneration for Fe3+ ion-doped oxides were observed. The obtained Li-Ti oxides doped with Fe3+ ions are of interest for further investigation as selective adsorbents of Li+ ions.

Removal of Methylene Blue from Aqueous Solution through Adsorption and Heterogeneous Fenton Reaction using Iron Oxides Produced by Different Methods

Direct discharge of industrial wastewater containing dyes into water bodies has contributed to the scarcity of drinking water. As environmental legislation becomes stricter, it is increasingly important to develop efficient methods for wastewater treatment. Traditional methods are commonly costly and have limited efficiency. This study aimed to prepare iron oxides via different synthetic routes and evaluate the effect of synthesis method on the efficiency of these materials as adsorbents and heterogeneous Fenton catalysts for the removal of methylene blue from aqueous solution. Iron oxides were synthesized by non-hydrolytic sol–gel (NHSG) and co-precipitation (CP) methods, followed by hydrothermal treatment for different times. CP oxides demonstrated high efficiency in dye adsorption, particularly the sample subjected to hydrothermal treatment for 6 h (CP-R6). This sample achieved 94.04% removal in 120 min. NHSG materials, by contrast, were less effective. The CP series of materials showed superior catalytic performance in heterogeneous Fenton experiments, with CP-R6 reaching 98.79% decolorization in 240 min. X-ray diffraction analysis indicated that iron oxides were composed of crystalline hematite and maghemite. Scanning electron microscopy revealed that CP materials were more porous and homogeneous than NHSG materials. The results demonstrated the efficiency of the developed iron oxides in removing methylene blue via adsorption and heterogeneous Fenton degradation and clarified how synthesis method influences adsorptive and catalytic properties.

Microstructural tuning and high-efficiency adsorption performance of carbonaceous porous adsorbents from coal gasification fine slag for methylene blue removal

Environmental protection and resource recycling are pressing global concerns, making the development of cost-effective and efficient adsorbents for treating toxic dye wastewater a priority. This study presents a novel, low-cost, and highly efficient carbon-based adsorbent material (CSM), synthesized from waste coal gasification fine slag (CGFS) using a two-step acid-base method, for the removal of methylene blue (MB) from dye-contaminated wastewater. Our research significantly advances the field by demonstrating the effective removal of MB under various conditions, including initial dye concentration, contact time, temperature, pH, and adsorbent dosage. Kinetic analysis indicated that the pseudo-second-order model best describes the experimental data, suggesting that the adsorption process is primarily governed by chemisorption. The Langmuir isotherm model revealed a maximum adsorption capacity of 735.29 mg/g at 318 K. Thermodynamic analysis confirmed the spontaneity and endothermic nature of the adsorption process, accompanied by an increase in entropy. Additionally, CSM exhibited excellent reusability, maintaining a MB removal efficiency of 77.83 % after five cycles, along with notable selectivity and interference resistance. Characterization techniques indicated that the adsorption mechanism involves a synergistic effect between physical and chemical adsorption, with physical adsorption attributed to the hierarchical porous structure of CSM and chemical adsorption reliant on surface functional groups and intermolecular interactions. In summary, CSM represents a groundbreaking advancement in materials for dye-contaminated wastewater treatment, showcasing its potential as an ideal solution in this critical area due to its high adsorption capacity, excellent selectivity, and good recyclability.

Preparation of artificial humic acid from corn straw and its high-efficiency adsorption on norfloxacin

In this study, the biomass artificial humic acid (AHA) with efficient adsorption performance for norfloxacin (NOR) was prepared by ultrasonic-assisted acid-alkaline combined hydrothermal method with corn straw as raw material. Characterization analysis showed that AHA was a typical amorphous structure, and the oxygen content of AHA prepared by ultrasonic-assisted hydrothermal method was obviously improved compared with that without ultrasonic-assisted method. The saturated adsorption capacity of AHA was 551.53 mg/g, which was higher than that of other reported materials, such high-efficiency adsorption is due to the abundant oxygen-containing groups (–OH, –C=O, etc.) in AHA, which were functional groups that can be π-π stacked, hydrogen bonded and electrostatically bonded with NOR. It had good selective adsorption for NOR, with less interference from acidity of environmental water, coexisting inorganic ions and common antibiotics. When it was applied to adsorb NOR with concentration of 10.0 mg/L in simulated water prepared by environmental water, the highest removal rate was 91%, which indicated that AHA could not only remove all the NOR in the polluted water with complex components at the highest concentration of 630 μg/L, but also its adsorption capacity far exceeded the pollution amount. The research had important practical significance in realizing the recycling of agricultural wastes and the removal of environmental pollution.

Effects of electrode/electrolyte materials on heavy-metal removal in industrial wastewater with flow capacitive deionization method

The expansion of industrial facilities poses a significant environmental risk due to the generation of extensive wastewater containing complex components that effluent human health. Flow-electrode Capacitive Deionization (FCDI) technology has emerged as a promising solution for wastewater treatment due to its unlimited adsorption capacity and continuous long-term operations compared to conventional systems. This study investigates the efficiency of the FCDI system in purifying industrial wastewater by extracting complex heavy metal ions, intending to achieve complete recycling and zero discharge. Different electrolyte/electrode materials were investigated to achieve high removal efficiency, including electrolytes such as sodium chloride (NaCl) and sodium sulfate (Na2SO4), and electrodes such as active carbon (AC) and C65 carbon black (C65 CB) used in lithium-ion batteries. We found that the innovative combination of Na2SO4 electrolyte with 0.1 g of C65 CB exhibited an exceptional salt removal efficiency of 90 %, surpassing NaCl electrolyte which showed 68 % efficiency. Additionally, we observed higher adsorption with C65 CB slurry compared to AC when using Na2SO4 electrolyte. To deepen our insights, Molecular Dynamics (MD) simulations were conducted to explore heavy metal ions interactions with electrode/electrolyte and membrane materials under an electric field. The results indicated that Ni2+ ions had the highest passage rate of 80 % across the membrane, followed by Cr2+, Cu2+, and Zn2+. Furthermore, superior adsorption of Ni2+ ions onto the C65 CB electrode was noted, contributing to enhanced charge transfer and overall conductivity. Furthermore, we evaluated the economic and environmental implications associated with implementing the FCDI system in practical. This study presents a novel approach by using C65 carbon black (CB) with Na2SO4 as the electrolyte, indicating high adsorption efficiency at low carbon loading electrode. This combination offers a cost-effective and sustainable solution for improving complex heavy metal ion removal in FCDI systems. Overall, our study’s findings significantly contribute to offering crucial insights into optimizing FCDI technology for efficient heavy metal ions removal in industrial wastewater treatment using lithium-ion battery anode/cathode electrode material.

Phosphate adsorption from phosphorus-polluted wastewater by peanut hull-derived biochar functionalized with eggshell-based calcium chloride: preparation, adsorption performance and mechanism

Phosphorus (P) recovery from wastewater, which contain large amounts of P by biochar can not only purify sewage, but promotes the reuse of P resources. The traditional enhancement of biochar's adsorption capacity through metal ion modification, such as with Ca2+, has shown promising results but is often hindered by high preparation costs. In this innovative work, we present a novel approach to prepare Ca-laden biochar (label as Ca-PSB) using egg-shells as a sustainable and low-cost calcium source. The biochar was prepared by peanut shell through anaerobic pyrolysis for 2 h at 400 °C under N2 atmosphere. Three kinds of Ca-PSB were prepared according to the content of modifier (CaCl2). The physiochemical properties of the Ca-PSBs were more conducive to adsorption of P. The economic cost of preparing was evaluated. The pore parameters were changed after the Ca modification. Especially, specific surface area of Ca-PSBs were increased by 4.82 %−12.05 % than raw biochar. The P adsorption capacity of Ca-PSB was 111.34 %−114.34 % higher than that of raw biochar. Ca-laden biochar showed excellent P adsorption, due to the Ca and CaOx on the Ca-PSB surface reacted with PO43- through hydrogen bonds or through stable inorganic precipitation. This work provides an inexpensive strategy for preparing biochar with high efficiency for phosphorus adsorption.

Cost-Effective Synthesis of MXene Cadmium Sulfide (CdS) for Heavy Metal Removal.

Background Environmental contamination resulting from the release of untreated industrial wastewater has emerged as a critical worldwide issue. These effluents frequently have high levels of heavy metals and antibiotics, which are bad for aquatic ecosystems and human health. Oftentimes, conventional wastewater treatment techniques fall short of effectively eliminating these pollutants. Innovative materials that may efficiently absorb or break down contaminants from contaminated water sources are, therefore, desperately needed. Hydrothermally produced MXene cadmium sulfide (CdS) composites have shown great promise as an adsorbent material because of their special qualities, which include high surface area, chemical stability, and customizable surface functions that improve their adsorption capacity for heavy metals and antibiotics alike. Aim The aim of this study is to produce MXene-CdS nanoparticles in a cost-effective method for the simultaneous removal of heavy metals from aqueous contaminants for water pollution control. Methods and materials MXenes were synthesized by selectively etching Ti3AlC2 MAX-phase ceramics using aqueous HF. CdS nanoparticles were synthesized separately and integrated with MXenes via a hydrothermal process. The resulting MXene CdS nanocomposites were characterized using scanning electron microscopy (SEM) for morphology, energy dispersion spectrum (EDS) for elemental composition, X-ray diffraction(XRD) study for phase identification, and removal of heavy metals viaMXene CdS. Results Consistent distribution of CdS nanoparticles on the MXene surface and the creation of MXene CdS nanomembranes with a well-defined shape were observed by SEM analysis. Ti, C, Cd, and S elements, indiciaries of a successful composite formation, were confirmed to be present by EDS. The crystalline structure of both the MXene and CdS phases was confirmed by the distinctive peaks seen in the XRD patterns. MXene-CdS composites facilitate the effective removal of chromium ions from contaminated water. The excellent hydrophilicity of the produced nanomembrane allowed for effective interaction with watery contaminants. Conclusion This study showcases the successful synthesis and characterization of MXene-CdS nanocomposites for environmental remediation, particularly in removing toxic metals like chromium from industrial effluents. SEM analysis confirmed the uniform distribution of CdS nanoparticles on the MXene surface, while elemental composition validated their integration. XRD analysis confirmed the crystalline structures of both components. The nanocomposite exhibited excellent hydrophilicity, enhancing the efficient adsorption of heavy metals. Its large surface area and chemical stability contribute to high adsorption efficiency, making it ideal for wastewater treatment. The scalable synthesis process supports practical applications. This research highlights MXene-CdS nanocomposites as a cost-effective, sustainable solution for water pollution control.

Cation-Doped Nanocarbons for Enhanced Perfluoroalkyl Substance Removal: Exotic Bottom-Up Solution Plasma Synthesis and Characterization.

Perfluorinated alkyl substances (PFAS), such as perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), are pervasive organic contaminants that are widespread in aquatic environments, posing significant health risks to humans and wildlife. Due to their persistent nature, urgent removal is necessary. Conventional adsorbents are inefficient at removing PFOS and PFOA, highlighting the need for alternative materials. Herein, we present a synthetic method for quaternary ammonium cation-doped carbon nanoparticles (QACNs) using a solution plasma process for the efficient removal of PFOS and PFOA. QACN is formed simultaneously through a one-step discharge of nonequilibrium plasma at the interface of benzene and pyridinium chloride. The resulting material exhibited a high surface electrical charge and enhanced hydrophilicity as well as an amorphous structure of a nonporous nature, involving nanoparticles with an undefined shape. The obtained adsorbent demonstrated high adsorption efficiency and stability, adsorbing 998.45 and 889.37 mg g-1 of PFOS and PFOA, respectively, exceeding the efficiencies of conventional carbon-based adsorbents (80.89-313.15 mg g-1). The adsorption performance was dependent on the adsorbent dosage, pH of the solution, and the coexisting ionic species. Adsorption studies, including adsorption kinetics, isotherms, and thermodynamics, revealed that PFOS and PFOA were chemisorbed to the QACN surface, forming multilayers endothermically and spontaneously. Experimental and computational analyses revealed that adsorption primarily occurs via electronic interactions between the PFAS active sites and the quaternary ammonium group in the carbon framework. The slightly lower adsorption potential of the PFOS and PFOA fluorocarbon chains on the adsorbent was elucidated. Furthermore, the dispersibility of the adsorbent in solution significantly affected the adsorption performance. These findings highlight the potential of the novel synthetic method proposed in this study, offering a pathway for the development of highly effective carbon adsorbents for environmental remediation.

The solid-solution HxPO4@Fe3O4 synthesized by irradiation enhances the adsorption capacity of tungsten(VI) and anti-interference of coexisting oxoanion in waste water: Surface oxolation interaction

Tungsten (W), mainly existing as hexavalent oxidation state in nature, has been considered as an increasingly prominent waterborne pollutant, but it is also a critical metal. Therefore, it is important to develop a material to adsorb W(VI) from the waste water containing W(VI) to realize the high-efficiency enrichment and recovery of W(VI). Inspired by self-assembly of phosphate and W(VI) ions in the acidic solutions to form phosphotungstic polyoxoanions (e.g., Keggin-type PW12O403−), in this work, we have loaded the phosphate ion to surface of the magnetic Fe3O4 nanoparticles (Fe3O4 NPs) by β particle irradiation to synthesize a composite adsorbent, HxPO4@Fe3O4 solid-solution (SS). This novel adsorbent is very efficient for W(VI) adsorption and recovery. The results of a batch of adsorption experiments indicate that HxPO4@Fe3O4 SS has a high adsorption efficiency for W(VI) in aqueous environments and strong anti-interference of coexist ions especially PO43−. Under room temperature conditions (∼25 °C), the maximum adsorption capacity reaches 88.44 mg g−1. This method not only ensures a substantial increase in W(VI) adsorption but also provides a facile means for adsorbent recovery, while minimizing additional environmental burdens. Based on the characterization results from Fourier transform infrared, Zeta potential, and X-ray photoelectron spectroscopies, we speculated that the possible mechanism of the adsorption process is that formed W(VI) polyoxoanions in acidic solutions are initially attracted by electrostatic attraction to the positively charged HxPO4@Fe3O4 surface, and then oxolation reaction occurs between W-OH of polyoxoanions and phosphate hydroxyl (P-OH) on the HxPO4@Fe3O4 surface to form P-O-W bridging oxygen group. This adsorption mechanism is also reflected in the adsorption kinetics, following a pseudo-second-order kinetic model, and adsorption thermodynamics, exhibiting a large enthalpy change (−76.3 kJ/mol) and a significant entropy reduction (−174.5 J/(mol K)).