High Wettability Research Articles

Physical and biological study of Yttrium oxide/titanium oxide/carbon nanotube/polystyrene films for wound healing purpose

Different contributions of dopants based on Yttrium oxide (Y2O3)/titanium(IV) oxide (TiO2)/carbon nanotube (CNT)/have been incorporated into the polymeric matrix of Polystyrene (PS). These films were fabricated in films due to their feasibility and low cost. The contact angle revealed that the dopants supported the hydrophilicity of the films that Y2O3/TiO2/CNT/PS represents the second highest wettability with (56.15 ± 6.35°) films, while Y2O3/PS film displays rough surface with the highest wettability with (32.5 ± 0.9°). we examined the impact of Y2O3/TiO2/CNT/PS composite on the viability of a human lung cell-line to better understand its biological behavior. Specifically, we measured cell viability as a means to assess the effect of the composite. The results revealed that at a concentration of 5000 μg/ml, the cell viability was measured to be 31.8 %. However, at a lower concentration of 2.4 μg/ml, the cell viability increased significantly to 117.9 %. These findings highlight a concentration-dependent relationship between the composite and the viability of the human lung cell-line. The observed cell viability exceeding 100 % indicates that the Y2O3/TiO2/CNT/PS composite scaffold had a positive effect on cell proliferation and generation. This suggests that the modified PS scaffold is conducive to cellular growth and can be considered safe for human use. The results imply that the composite scaffold promotes a favorable cellular environment, potentially supporting tissue regeneration and indicating its potential suitability for biomedical applications. The surface morphology shows that the topography of the films was changed clearly with the dopants of Yttrium oxide, titanium(IV) oxide and CNT components. The TiO2 granules implanted in the PS composition cause an increase in pore size to an average of 2.2 μm. Pore diameters ranging from 100 to 500 μm may enhance cell proliferation, while lower sizes lead to more stable implantable discs.

Investigations on MoS2 plasma by infra-red pulsed laser irradiation in high vacuum

MoS2 targets were irradiated by infra-red (IR) pulsed laser in a high vacuum to determine hot plasma parameters, atomic, molecular and ion emission, and angular and charge state distributions. In this way, pulsed laser deposition (PLD) of thin films on graphene oxide substrates was also realized. An Nd:YAG laser, operating at the 1064 nm wavelength with a 5 ns pulse duration and up to a 1 J pulse energy, in a single pulse or at a 10 Hz repetition rate, was employed. Ablation yield was measured as a function of the laser fluence. Plasma was characterized using different analysis techniques, such as time-of-flight measurements, quadrupole mass spectrometry and fast CCD visible imaging. The so-produced films were characterized by composition, thickness, roughness, wetting ability, and morphology. When compared to the MoS2 targets, they show a slight decrease of S with respect to Mo, due to higher ablation yield, low fusion temperature and high sublimation in vacuum. The pulsed IR laser deposited MoS x (with 1 < x < 2) films are uniform, with a thickness of about 130 nm, a roughness of about 50 nm and a higher wettability than the MoS2 targets. Some potential applications of the pulsed IR laser-deposited MoS x films are also presented and discussed.

Singlet oxygen species induced by colloidal crystalline carbon nitride induced for efficient H2O2 synthesis with in situ antibacterial effect

Solar-driven hydrogen (H2) and hydrogen peroxide (H2O2) generation over visible-light responsive carbon nitride (CN) photocatalysts for in situ efficient sterilization is a promising and eco-friendly strategy. Herein, a colloidal potassium-ion (K+) intercalated crystalline CN nanosheets (KCCN) photocatalyst was constructed for boosting synergetic H2O2 synthesis with isopropanol (IPA) oxidation and in situ antibacterial effect. The surface hydroxyl (−OH) and cyano (−CN) groups induced by molten salt (KCl)-assisted thermal treatments contributed to the colloidal nature of CN, facilitating for high wettability of KCCN in aqueous solution to gain active hydrogen (H+) from water sustainably. Meaningfully, the enhanced high-energy singlet oxygen species (1O2) produced by KCNN-2 were verified by electron paramagnetic resonance (EPR) and 9,10-anthracenediyl-bis(methylene)-dimalonic acid (ABDA)-fluorescent probe, significantly contributing to H2O2 production and antibacterial effect. Consequently, the optimal KCCN-2 exhibited a much enhanced H2 generation of 4.11 mmol g−1 h−1, and H2O2 production activity of 1.82 mmol L−1 h−1 with acetone yield rate of 47.3 mmol g−1 h−1 under visible-light (λ > 420 nm) irradiation in 10 vol% IPA solution. The in-situ generated H2O2 can be activated to produce reactive oxygen species (ROS), especially 1O2, to effectively kill the Escherichia coli, reaching an improved an antibacterial rate of 89.7% under stimulated sunlight irradiation in 1 h. This work could offer a new insight into the photoinduced ROS for aqueous H2O2 photosynthesis and antibacterial application.

Study the Structure and Properties of TiO&lt;sub&gt;2&lt;/sub&gt;/HAp Coating onto Ti-6Al-4V Alloy Using Electrophoretic Deposition

In the present study, (TiO2/HAP) and TiO2 coatings were fabricated with electrophoreticdeposition on substrate for titanium alloy. This study aims to increase improve this alloyantibacterial properties by coating the surface with a bio ceramic (TiO2 and TiO2/HAP)nano-powders. Coating on Ti-6Al-4V with an electrophoretic deposition(EPD) technique,ideal conditions of 20V and a deposition time of (4 min). The surface properties of coatedsubstrates, such as, micro-hardness, surface roughness and wettability antibacterial test wereevaluated and compared to that of the uncoated substrate. The results showed that theelectrophoretic deposition is a favorable technique to make a bio coating on Ti-6Al-4Vsubstrate with excellent properties and structure for applications biomedical.The average micro-hardness of the TiO2/HAP coated sample is 1024 HV compared withthat of uncoated substrates is 80 HV. The average thickness of TiO2/HAP coating isdetermined to be (18µm) on the substrate surface at factor deposition time (4 min). The resultsof previous research indicate that the high wettability and surface roughness at the micronscale were for the synergistic effect of reduction on cell adhesion and growth.

Electrochemical characteristics of flexible open-cell supercapacitors employing different electrolyte types: KOH and ionic liquid

A carbonate hydroxide compound with substantial wettability was deposited on a porous Ni foam substrate, employing the Ni-based chemical precursor by a facile hydrothermal method. The resulting Ni2(CO3)(OH)2 electrode exhibits a nanowire structure characterized by a significant surface area. These electrodes represent highly promising materials for faradaic capacitors. They demonstrate high wettability on the electrode surface, facilitating charge and discharge processes on the electrode surface through redox reactions. A flexible hybrid open-cell supercapacitor, designed to operate at 1.5 V, was constructed with the Ni2(CO3)(OH)2 electrode as the positive terminal and graphene as the negative terminal, employing two distinct electrolytes (KOH and ionic liquid named MPPyFSI with 1-Methyl-1-propylpyrrolidinium Bis(fluorosulfonyl)imide structure). The open-cell devices, fabricated with 6 M KOH and MPPyFSI electrolyte, exhibit high energy densities of 39.6 and 24.8 Wh kg−1 and power densities of 1752.1 and 2908.5 W kg−1 at current densities of 2 A g−1, respectively. Furthermore, the energy storage devices utilizing aqueous KOH and MPPyFSI demonstrate excellent stability, maintaining 73.4 and 87.1% of their specific capacity after 5,000 charge/discharge cycles. The mechanical properties of the flexible open-cell device were characterized, and the electrochemical values corresponding to the banding angle of the device were measured.

Exploring triazene derivative's antimicrobial activity and its incorporation onto 3D-printed coatings

Antimicrobial resistance has emerged as a significant health concern demanding the urgent development of new active molecules. Furthermore, within healthcare settings, medical devices can be the cause of microorganisms’ proliferation leading to infection. Thus, nowadays the need for novel antimicrobial biomaterials is mandatory. In this work different 1,3-diaryltriazenes were synthesized for incorporation as antimicrobials onto 3D-printed hydrogel coatings for polydimethylsiloxane (PDMS) substrates used in the production of different medical devices. Symmetric and asymmetric aryltriazenes were synthesized and characterized by spectroscopic methods. Antimicrobial activity was screened and the most active triazene was selected to be incorporated into the 3D-printed coatings that were further characterized by contact angle measurements, FTIR-ATR, SEM, drug release, antimicrobial activity, and cytocompatibility.The 1,3-bis (4-nitro-2-(trifluoromethyl)phenyl) triazene showed activity against Staphylococcus aureus with a minimum inhibitory concentration of 1 μg/mL and revealed no cytotoxicity towards HaCat cells. 3D-printed hydrogel coatings (comprising chitosan/starch and sodium alginate) loaded triazene were successfully produced for PDMS substrates. Triazene coatings presented high wettability and smoothness and revealed antimicrobial and antibiofilm activity (i.e., 96 % reduction) towards S. aureus. Additionally, the produced coatings showed no cytotoxicity under the tested conditions. This study marks the initial proof that incorporating triazenes into 3D-printed hydrogel-based coatings can diminish biofilm formation on widely used biomaterials, such as PDMS surfaces. Herein achieved outcomes have allowed us to confirm and propose a novel type of hybrid construct as an antimicrobial hydrogel coating.

PH- and Photoresponsive Liquid Plasticine.

Liquid marbles (LMs) can be prepared by adsorption of hydrophobic particles at the air-liquid interface of a water droplet. LMs have been studied for their application as microreaction vessels. However, their opaqueness poses challenges for internal observation. Liquid plasticines (LPs), akin to LMs, can be prepared by the adsorption of hydrophobic particles with a diameter of 50 nm or less, at the air-liquid interface of a water droplet. Unlike LMs, LPs are transparent, allowing for internal observation, thus presenting promising applications as reactors and culture vessels on a microliter scale. In this study, the surface of silica particles, approximately 20 nm in diameter, was rendered hydrophobic to prepare hydrophobic silica particles (SD0). A small amount of poly(2-(diisopropylamino)ethyl methacrylate) (PDPA) was then grafted onto the surface of SD0, yielding SD1. SD0 particles exhibited consistent hydrophobicity irrespective of the environmental pH atmosphere. Under acidic conditions, SD1 became hydrophilic due to the protonation of pendant tertiary amines in the grafted PDPA chains. However, SD1 alone was unsuitable for LP preparation due to its high surface wettability regardless of atmospheric pH, attributable to the presence of PDPA-grafted chains. Therefore, to prepare pH-responsive LP, SD1 and SD0 were mixed (SD1/SD0 = 3/7). Upon exposure to HCl gas, these LPs ruptured, with the leaked water from the LPs being absorbed by adjacent paper. Moreover, clear LPs, prepared using an aqueous solution containing a water-soluble photoacid generator (PAG), disintegrated upon exposure to light as PAG generated acid, leading to LP breakdown. In summary, pH-responsive LPs, capable of disintegration under acidic conditions and upon light irradiation, were successfully prepared in this study.

A novel poly (lactic-acid) and poly (butylene adipate-co-terephthalate) blend membrane modified with hesperidin for oily water emulsions separation

The oily wastewater produced by a variety of industrial operations presents a serious threat to both humans and the environment. Separation efficiency, good mechanical stability, high flux, and recyclability are critical parameters for a suitable oil-water separation membrane. In this study, a novel blend membrane of (poly (lactic acid)/poly (butylene adipate-co-terephthalate)) with hesperidin-NPs was synthesized by using the phase inversion technique to effectively separate oily-water emulsions. Herein, hesperidin (HSP) was harnessed for the first time as a green agent to optimize its content in the polymeric matrix. (FTIR) Fourier transform infrared spectroscopy, (FESEM) Field emission scanning electron microscopy, (CA) contact angle, mechanical tester, pore size and porosity were utilized to comprehensively characterize the manufactured (PLA/PBAT/HSP) membranes. The current work presents the proposed interaction mechanism between the contents of PLA/PBAT/HSP and the interaction mechanism of PLA/PBAT/HSP membrane with H2O molecules. The synthesized (PLA/PBAT/HSP) membrane manifested high wettability and has a 49° water contact angle and oleophobicity under a water contact angle of 146±2° for diesel oil. The PLA/PBAT membrane exhibited a homogeneous and symmetric spongy-like structure from top to bottom across its entire cross-section with very tiny active layer observed at the top surface of the membrane in FESEM images. Meanwhile, incorporating of 0.0125 wt% HSP into the casting solution has resulted in a significant change in the structural morphology. Furthermore, upon adding the HSP to the polymeric matrix, distinct changes in the structure were formed, which resulted in enhancing the mechanical features (tensile strength) of the membranes. Modified membrane with 0.025 wt% HSP displayed an optimal flux for pure water (220.5 L/m2.h1) and the modified membranes maintained a high rejection (more than 99%) against oil-water emulsions. Outcomes demonstrated that the improved permeation and separation characteristics of the (PLA/PBAT/HSP) membranes could present a potential option to treat applications that use oily wastewater.

Interface bonding characteristics and thermal damage behavior of brazed diamond with Nb-added Ni[sbnd]Cr filler alloys

NiCr alloy is one of the important filler for brazed diamond tools because of its high hardness, high wear resistance and good wettability to diamond. However, the high brazing temperature and catalytic action of Ni element contained in alloy tend to cause the thermal damage of diamond and interface failure of brazed samples. In this work, the noval NiCr filler alloys added with different contents of Nb are prepared, and the microstructures, mechanical and wear resistance properties of brazed layers used these alloys are investigated. On this basis, the interfacial bonding characteristics and thermal damage behaviors of diamond brazed with Nb-added NiCr filler alloys are further studied. The results show that the addition of Nb element improves the hardness and wear resistance of NiCr filler layer, and the filler alloys exhibit good wettability and climbing effect to diamond. The refined Cr3C2 and Cr7C3 carbides are formed on the surface of diamond, which effectively enhances the interface bonding strength between filler alloy and diamond. Meanwhile, the addition of Nb element consumes some Ni and generates NbNi compound, which weakens, to some extent, the graphitization catalysis and chemical erosion of Ni to diamond. When the addition amounts of Nb are 1–1.2 wt%, the brazed diamond samples present excellent interfacial bonding strength and mechanical properties.

Precisely adjusting the interface adhesion of carbon fiber/epoxy composites by regulating the micro-configuration of graphene oxide nanosheets on the fiber surface

Different micro-configurations of graphene oxide (GO) nanosheets on the carbon fiber (CF) surface, including the distribution and size, endow CF-GO enhanced microstructure and physiochemical characteristics of the CF/epoxy (CF/EP) composites. In order to investigate the relationship between the GO micro-configuration and the interfacial adhesion of the CF/EP, here, polyether imide (PEI)-GO heterogeneous reinforcement was grafted onto the CF surface (CF-PEI-GO) by precisely modulating the mass ratio of CFs to GO. The micro-configuration and properties of the CF-PEI-GO hybrids, together with the thickness and modulus variation of the interface layer are investigated, in order to make certain on the enhancement mechanisms of both interfacial and mechanical performances. Optimal performances of the CF-PEI-GO/EP composites are achieved with a CF/GO mass ratio of 40:1. The uniformly “upright” distribution of moderate-size GO on the CF surface induces a synergistic effect of improved mechanical interlocking, chemical bonding, high wettability, and effective interface adhesion, which are stemmed from higher surface roughness, more active functional groups, higher surface energy, and wider interface thickness with gradient descent modulus. This work presents a valid, practical strategy to precisely control the interfacial adhesion of the CF/EP composites by adjusting the micro-configuration of 2D materials on the fiber surface.

Energy-efficient bubble aeration guided by bubble dynamics model: From bubble formation at submerged orifice to oxygen utilization during uprising

Bubble aeration is a significant consumer of energy in wastewater treatment processes. Optimizing oxygen transfer, from an energy usage perspective, is crucial in the development of clean production techniques and for the stimulation of the circular economy. Although large efforts have been made in enhancing this process, particularly in ameliorating bubble diffusers, a main problem lies in energy wastage due to over-pursuing ultra-fine bubble generation. In this study, a dynamic model, that integrated both bubble expansion and detachment at submerged orifices, and consequential oxygen utilization during the uprising, was developed in order to better facilitate energy savings during the control of bubble generation. We demonstrate through calibrated models that bubble formation is governed by many factors including gas flow rate, orifice radius, surface tension, liquid viscosity, and surface wettability. Small bubbles are more prone to form when subjected to conditions of high wettability, small orifice size and low flow rate, since the bubbles are easily detached by the increasing upward forces in these scenarios. The oxygen transfer during the rising process was calculated as a function of bubble size, gas type and water depth. Bubbles with a radius smaller than a threshold value can shrink and collapse while below the water surface and thus provide 100% oxygen utilization. The threshold values of bubble radius are determined to be 150 μm and 250 μm at 5 m and 15 m initial water depth, respectively. The parameter set for bubble generation in order to obtain the desired bubble size may then be inversely determined by our bubble formation model, and it's considered as optimal aeration strategy to realize precise aeration. With these results, our study highlights the viability of the approach employing the proposed model in order to direct energy-efficient bubble generation.

Deferoxamine-Loaded Chitosan-Based Hydrogel on Bone Implants Showing Enhanced Bond Strength and Pro-Angiogenic Effects.

Angiogenesis is vital for bone fracture healing and plays a significant role in the fate of orthopedic implants. The growth and maintenance of new blood vessels at the fracture site of patients is essential, which promotes the clinical outcome of plasma sprayed Ti (PST) coated orthopedic implants. In order to endow the PST coating with pro-angiogenic effects, deferoxamine-loaded chitosan-based hydrogel was fabricated on the coating surface. Polydopamine-modified chitosan (CS/PDA) hydrogel exhibited enhanced bonding strength to PST coatings as evidenced by scratch test. The deferoxamine-loaded CS/PDA (CS/PDA-DFO) exhibited a sustained drug-release property, and the cumulative concentration of released DFO reached 20.21 μg/mL on day 7. PST-CS/PDA with higher wettability and active group quantity enhanced the viability and adhesion characteristics of human umbilical vein endothelial cells (HUVECs) and upregulated the secretion level of nitric oxide and vascular endothelial growth factor. Moreover, the introduction of DFO in PST-CS/PDA further enhanced the pro-angiogenic effects. Above all, this study offers a novel approach for developing hydrogel coating on orthopedic implants showing enhanced bonding strength and pro-angiogenic effects.

Antibacterial and wound healing performance of a novel electrospun nanofibers based on polymethyl-methacrylate/gelatin impregnated with different content of propolis

Wound management and care mainly relies on the production of new and effective wound dressing materials. Chronic wounds require protection against pathogens and bacterial infection. Therefore, it is very important to design wound dressings with antibacterial and restorative capabilities. In this research, polymethyl-methacrylate (PMMA) and gelatin (Gel) nanofibers (NFs) were produced in different ratios by electrospinning method. Propolis (Pro) as a wound healing drug was added to the optimal PMMA70/Gel30 parent scaffold at different concentrations (10, 30 and 50 %w/v). Physical and chemical characterization, porosity, degradation, water vapor transmission rate (WVTR), swelling, mechanical properties and contact angle of the mats were analyzed. The NFs presented a homogeneous and defect-free morphology. The PMMA70/Gel30 mats showed the lowest average diameter (362.1 ± 132.3 nm) among the scaffolds. In addition, the highest wettability (∼70°) and WVTR (∼250 g/m2 × 24h) are related to PMMA70/Gel30. The addition of Pro extract (up to 50%) increased the mean diameter of NF (571.1 ± 171.8 nm). None of the scaffolds showed toxicity in the environment. The optimal PMMA/Gel/Pro50% NF showed more adhesion and higher cell viability than other samples. The antioxidant activity of PMMA/Gel/Pro50% is more about 10 times compared to PMMA70/Gel30. Pro extract showed significant antibacterial activity in the scaffolds, so that the release of Pro (∼70% in 24hrs) in the PMMA/Gel/Pro50% caused the inhibition of S. aureus (9 mm) and E. coli (11 mm) bacteria in Mueller's culture medium. All these findings confirm that the produced NF mats, especially those loaded with Pro, have a high potential to be used as an effective wound dressing.

Wetting Kinetics of Lithium-Sodium Orthoborate on Nickel and Stainless Steel under CO2-Lean and Saturated Conditions.

Contact angle measurements were conducted on lithium-sodium orthoborate, an alkali-metal borate-based high-temperature carbon capture sorbent, in contact with nickel and stainless steel under air, N2, and CO2 atmospheres at 600 °C in order to assess the compatibility of this innovative sorbent with packed-bed reactors, typically used in the commercial carbon capture industry. On nickel, the results reveal the melt to be wetting (contact angle θ ≤ 90°), albeit with a contact angle reaching an apparent equilibrium over the experimental time considered. It was found that θ was lower under N2 than under CO2, which was explained as a consequence of the oxide-ion activity difference between the CO2-lean and saturated melts. On stainless steel, however, the melt rapidly spreads, tending toward complete wetting of the metal sheet (θ = 0°) in all atmospheres. For the two metals investigated, the results indicate high to very high wettability, hence the adequacy of using lithium-sodium orthoborate in conventional gas-liquid contactors, further backing this sorbent as a potential alternative to existing sorbents for CO2 capture.

Influence of chemistry and surface roughness of various thermal barrier coatings on the wettability of molten sand

High temperature wettability experiments were carried out to investigate how chemistry and surface roughness affect wetting characteristics of molten sand several promising thermal/environmental barrier coatings. Contact angle experiments were performed on varying as-sprayed and polished yttria-stabilized zirconia (YSZ), rare-earth oxide-YSZ (REO-YSZ), and rare-earth silicate coatings subjected to molten synthetic sand at 1260 °C. The results showed that the spreading rate of molten sand was higher on silicate-based environmental barrier coatings (~60°/min) than on Zr-based thermal barrier coatings (~25°/min). Increased surface roughness had opposite effects on the wettability depending on the reactivity of the coatings. Wettability decreased on coatings such as YSZ (which did not react with sand) but increased for REO-YSZ coatings (which formed reaction products with sand). It was found that while the REO-YSZ coatings were able to promote formation of the apatite that performed as a sealing layer to reduce further infiltration, molten sand wetting increased. YSZ was found to have greater wetting resistance in the roughened state while the REO-YSZ coatings had greater wetting resistance in the polished state. Surface energy, microstructure, and molten sand penetration also play a key role in the wetting kinetics and are discussed. This work reveals the dependency of chemistry and surface roughness on influencing the “sandphobicity” (analogous to hydrophobicity) of a material and provides insights for optimizing these variables to realize more “sandphobic” coatings.

Droplet migration induced by non-uniform wetting microgroove structure promotes condensation water collection

Microgroove structure, as an efficient condensation structure, has good application prospects in many fields. However, the interconnection of surface droplets caused by the inability to remove droplets from the ridge of the microgroove in a timely manner affects the efficiency of droplet condensation on the surface of the microgroove. In this paper, we report the promotion of droplet migration by designing non-uniform wetting surfaces with hydrophilic microgrooves and hydrophobic waxy layer ridges. The results indicate that the generation of a liquid film at the bottom of the microgroove is critical to facilitate the adsorption of ridge liquid to the bottom of the microgroove. In addition, the difference in high wettability between the ridges and the bottom contributes to bottom liquid film generation, and ridge adhesion affects the state of the surface after the ridge droplets are detached. This work is of great significance as it provides a reference for the structural design of high-efficiency fog collection systems.

Insight into the Improvement Strategies of Aqueous Electrolyte for Aqueous Rechargeable Batteries

AbstractAqueous rechargeable batteries (ARBs) have attracted wide attention due to their rich resources, environmental friendliness, and safety. The high ionic conductivity, safety and interfacial wettability of the aqueous electrolyte are essential for energy storage devices. However, the narrow electrochemical stability window (ESW) of the aqueous electrolyte and the side reactions of the electrode/electrolyte lead to the low energy density of the ARBs. In the past studies, the above problems were generally solved by improving the ion transport characteristics of the electrolyte and the electrode/electrolyte interface. Herein, we discuss the background, limitations, and key concepts for performance improvement of aqueous electrolytes, aiming to provide a comprehensive perspective and inspiration for further research on aqueous electrolytes and promote their development and application in the field of energy storage.

Effect of laser micromachining crater-array–multi-grooves on the bonding strength and failure mode of aluminum alloy adhesive joints

The strength of aluminium (Al) alloy adhesive joints is essential for aerospace, ship and automotive applications. This study proposes the two-step laser processing of crater-array–multi-groove (CAMG) to maximize the shear strength of adhesive joints for 7075-T6 aluminum alloys. Firstly, the effects of CAMG feature parameters (groove pattern, groove spacing L, and groove depth Gp) on the surface roughness (Sa), shear strength (τ), and microscale failure mode were studied. The failure mode and anchoring structure reveal the influence mechanism of CAMG feature parameters on τ. Then, the parameters are optimized to obtain the best combination that maximizes τ. Finally, the advantages of CAMG were demonstrated by comparing it with a reference specimen and analyzing the surface morphology, wettability, chemical properties, and anchorage structure. The results show that for CAMG the surface had high cleanliness, wettability, and chemical modifications. The multi-scale anchoring structure formed by the grooves, craters, and micropores on the surfaces with the adhesive was sufficiently strong to allow cohesive failure (CF) to occur throughout the bonding region, maximizing τ. When the groove pattern is parallel-groove, L ≤ 100 μm, and the number of scans is N = 2–5, CAMG maximizes τ (∼29.34 MPa). To increase efficiency and save energy, the optimal combination of parameters for laser processing CAMG is parallel-groove, L = 100 μm, and N = 2. Compared with laser processing multi-grooves, CAMG improved the processing efficiency by 3.5 % and reduced the laser energy by 35.2 %. The proposed method shows great advantages in improvement of bonding strength.

Vinyl Polymers as Key Materials in Contact Lens Design: A Review of Progress and Future Directions

AbstractVinyl polymers, crucial in contemporary contact lens design, present unique attributes with promising implications for vision correction. This comprehensive review navigates the trajectory and future trajectories of vinyl polymer‐based contact lenses. The introduction underscores the vital role of contact lenses in vision correction and positions vinyl polymers as ideal materials due to their exceptional properties. Delving into material specifics—high oxygen permeability, optical clarity, surface wettability, and mechanical strength—the analysis emphasizes their influence on corneal health, comfort, and durability. The versatility of manufacturing techniques, encompassing spin casting, molding processes, polymerization, and surface modification, underscores their feasibility in crafting high‐quality lenses. Examining clinical applications, encompassing daily disposables, extended wear, silicone hydrogel, and specialty lenses, alongside biocompatibility assessments and user feedback, provides a nuanced understanding of vinyl polymer‐based lens effectiveness. The article candidly addresses challenges—dehydration, deposits, mechanical stability, and durability—alongside regulatory considerations. Future prospects involve novel formulations, smart materials, bioinspired designs, and noninvasive technologies to amplify comfort and performance. In conclusion, this review distills progress, acknowledges challenges, and charts a sanguine course for vinyl polymer materials in advancing contact lens design, envisioning a future marked by enhanced vision correction technologies.

A Super Hydrophilic Material for Self-Cleaning by Cold Plasma of Zinc Selenite Nanostructure

This research is devoted to the fabrication of zinc selenide nanostructures using the pulsed laser deposition (PLD) technique in a vacuum under a pressure of [Formula: see text] mbar. The structure and structural properties were studied, as it was observed that it had polycrystalline structures and showed peaks for zinc and selenium and peaks belonging to the compound zinc selenide. As for the morphological characteristics of the nanostructures, the structures showed the nature of the surface and the roughness to identify its surface properties. Photocatalysis was carried out using several techniques (visible light, ultraviolet radiation and cold plasma), where a plasma jet system produced under normal atmospheric pressure was used in the treatment, with an exposure time of 4[Formula: see text]min and an argon gas flow rate of 3[Formula: see text]l/min. The hydrophilic properties were studied to apply these compositions in the self-cleaning process and photocatalytic activity. The results show that the ZnSe nanostructures have high wettability under UV light which has been shown to have excellent catalysis in the UV region, making its application as a self-cleaning material an attractive option.