In Merapi volcano mitigation, the cooperation within/between the local communities is a key strategy for effective evacuation. In the “sister village” scenario, the meeting area and shelter have been coordinated, but people’s behavior has not been fully considered yet in the vulnerability assessment and government’s contingency plan. The purpose of this study is to assess the people’s behavior, mutual assistance, and social vulnerability index of pedestrian evacuation in four affected regencies. First, we measured the walking speed directly, conducted interviews with stakeholders, and focus group discussions with local communities. We used the multicriteria method and focused on two factors, social and age structure (young, vulnerable, and mutual assistance between them), and risk perception (work, rain, night, alert, and destination). The index reflects the distribution of actual walking speed, mutual assistance, and the government’s plan. The result showed that mutual assistance groups have a higher walking speed than vulnerable people but lower than young people. Mutual assistance coordination is crucial to support vulnerable to effective travel time. The social and age structure of the social vulnerability index has a stronger risk influence than the perception factor in the evacuation process. However, these two factors have a minor impact on social vulnerability to the total population.