Thermal Mass Research Articles

Exploring multifaceted properties of Polypyrrole-Cobalt ferrite nanocomposites: A comprehensive study

The remarkable properties of Polypyrrole (PY) hold immense potential for revolutionizing electronic device technologies. From flexible electronics to high-performance sensors, PY and its nanocomposites offer a plethora of opportunities to engineer advanced electronic components with enhanced functionalities. The properties of Polypyrrole (PY), Cobalt ferrite (CF) and their nanocomposites (PY1, PY2, PY3, PY4) have been explored with increasing amount of Cobalt ferrite. Their synthesis and nano size are confirmed by X-ray diffraction and Fourier transform infrared spectroscopy. SEM confirmed the Walnut morphology of PY and it is maintained in nanocomposites but size of particles has been increased. Consequently, optical band gap (Eg) and thermal stability of samples observed from UV-Visible Spectroscopy and Thermogravimetric analysis get affected. A. C. Conductivity shows the dispersive nature and a significant increase can be seen from PY1 to PY4 i.e. ac conductivity increases with cobalt ferrite composition into the nanocomposites. Dielectric losses were explained using polarization effect and conductivity values of materials. Diamagnetic nature of PY changes into ferromagnetic in the nanocomposites. Electrodes of each sample were prepared using slurry method and their electrochemical analyses were done in 2 M KOH solution. By enhancing thermal stability, electrical conductivity, and capacitance while simultaneously reducing the optical band gap, the integration of Cobalt ferrite into the PY matrix unlocks new avenues for electronic device design. These advancements pave the way for the development of more efficient and sustainable electronic devices.

Micro-sample Nd isotopic measurement on reference rock powders via the thermal ionization mass spectrometer Nd+ mode

The Sm–Nd isotopic system has been broadly utilized for dating and tracing in earth and planetary sciences. However, low Nd+ ionization efficiency permanently hinders precise and accurate measurements on small amounts of Nd samples. So far, isotopic measurement of micro-amount Nd sample via thermal ionization mass spectrometry (TIMS) Nd+ mode was mostly performed on Nd reference solutions, but less on natural rock or mineral samples. In the present study, analytical procedures to measure isotopic composition via the TIMS Nd+ mode were designed for natural rock powders by using 1–5 ng pure Nd. The analytical technique was refined through low-blank sample digestion, small-column chemistry for Nd extraction from matrix elements, loading Nd using purified H3PO4 solution, and careful heating of filaments before data acquisition. Measurements on small Nd amounts (1 ng–5 ng) of either the JNdi-1 reference solution or four reference rock powders yielded satisfactory results of 143Nd/144Nd value with respect to precision and accuracy. The analytical results agree well with the recommendation values of the reference materials within analytical errors and the internal precision is better than ±0.005 % (2RSE). When using 1 ng or 2 ng Nd amounts, 144Nd ion flow can remain stable in a signal intensity of >100 mV, and without the assistance of an additional ionization enhancer. Therefore, the analytical procedure, featured by low procedural blank (about 10–22 pg), high Nd+ ionization efficiency, and easy operation, has broad prospects for the application of Nd isotope in single-grain minerals or micro-samples.

Diminishing benefits of thermal mass in Iranian climate: Present and future scenarios

Thermal mass, a pivotal element in a building's performance, functions as an indoor thermal buffer. While literature underscores its advantages, the enduring impact of thermal mass amid climate change remains uncertain. This study methodically assesses thermal mass effects in 21 Iranian cities across contemporary and future climates, juxtaposing heavyweight and lightweight constructions. The EPSAP algorithm, a generative building design method, created a dataset of two-story single-family houses. Cooling and heating demands were evaluated in EnergyPlus, accounting for current and future system design efficiencies. Future climates were simulated using EC-Earth3 model estimations for the SSP5-8.5 scenario in 2050 and 2080 timeframes. The findings reveal that the energy efficiency advantage of heavyweight over lightweight buildings will diminish by up to 0.60 kW·h·m−2 in 2050 (40 % less than the present-day climate difference between constructions) and 0.93 kW·h·m−2 in 2080 (63 %) for cities in central and southern regions. The performance differences between constructions will sometimes be null, making thermal mass negligible. Conversely, only three cities in Northern Iran exhibit an opposing trend for mid to very-high thermal transmittances. Regarding building geometry, heavyweight construction correlates strongly with indexes related to building compactness, while lightweight construction aligns more with glazing-related indexes. However, as climates warm or we move towards warmer regions, discernible differences between lightweight and heavyweight constructions vanish for both shape- and glazing-related indexes. In conclusion, although the use of thermal mass will be less effective, building design professionals will have greater latitude for innovative construction and design solutions.

Electromagnetic–thermal–mass transport triple hybrid model for energy-efficient hydrogen release from metal particles by induction heating

Hydrogen storage in metals is anticipated to be a highly promising technical approach for managing hydrogen in diverse energy applications, emphasizing the need to establish efficient operating conditions. In this study, we developed a numerical model that can simultaneously calculate hydrogen and heat transport combined with electromagnetic induction heating of metal particles. Using the developed numerical simulator, we investigated the behavior of the hydrogen release process from the hydrogen-absorbing metal and proposed important indicators for the operation. The fractions of the electromagnetic energy absorbed by the metal particle used for the hydrogen release, sensible heat, interfacial heat conduction, and thermal radiation were systematically evaluated. Considering the trade-off between temperature rise and the hydrogen concentration gradient, an optimal diameter of metal particles existed for the maximum hydrogen release rate. Similarly, the trade-off between temperature rise and energy consumption revealed an optimal electromagnetic power density for the heat utilization fraction for hydrogen release. Our electromagnetic–thermal–mass transport triple hybrid model constitutes a useful numerical simulator for the design of energy-efficient hydrogen storage systems.

The mechanism by which thermal coupling leads to an asymptotic maldistribution stability boundary for flow boiling in parallel channels

Phase change heat transfer processes are attractive for the efficient thermal management of advanced semiconductor devices, with flow boiling in parallel microchannel heat sinks being one promising solution. However, there are several implementation challenges associated with two-phase flow in parallel microchannels, particularly flow maldistribution, which can adversely affect performance and reliability. Two-phase flow models can be useful in predicting and understanding the instability mechanisms that leads to maldistribution, such that parametric performance trends and safe regions of operation can be identified. Channel-to-channel thermal coupling has been shown to alleviate maldistribution, but it is not yet understood why this effect is limited to some critical lateral thermal conductance above which there is no further benefit. In the current work, a two-phase flow model with a lumped thermal capacitance representation of the heat sink wall is developed to identify the mechanism for this asymptotic maldistribution stability boundary for thermally coupled microchannels. The lumped model allows the nature of stability boundary to be explained via a scaling analysis of the eigenvalues. In such systems, it is identified that a single eigenvalue determines the occurrence of flow maldistribution. Scaling analysis shows that, for small values of thermal conductance, this eigenvalue becomes a quadratic function of thermal coupling, which enhances the stability of microchannels and moves the stability boundary. However, for large values of thermal conductance, the eigenvalue is dependent only on the fluid properties, leading to a limit at which thermal coupling can no further improve stability or affect the stability boundary. The lumped model developed in this work enables mechanistic understanding of the role of channel-to-channel thermal coupling on mitigating flow maldistribution and therefore may offer important guidance on the design of flow boiling systems and heat sinks.

Fundamental heat and entropy transfer mechanisms of convection underlying the first and second laws for an unsteady multiport system and their applications in parallel flow heat exchangers

Although thermal convection is ubiquitous in nature and technology, it has long been argued whether convection can be considered as an independent mode of heat transfer. Here, we show that pure convection mode is generally recognized from the classical first and second laws via mass flow by rooting the unsteady mass conservation relation through an equivalent multiport system. The fundamental distinction is made between convection driven by the thermal and entropy potential differences and mass flow accompanied by zero potential difference. The constitutive relations of the convective heat and entropy fluxes and their thermodynamic relationship are developed in terms of their potential differences with the exponential distribution of temperature difference in a compressible flow. In the absence of work transfer, the first and second laws are simply expressed by the standard Maxwell’s electromagnetic type equations via the total heat and entropy flux vectors. The pure convection theory is applied to a parallel-flow heat exchanger and the linear temperature difference distribution is obtained for both streams via the first-law definitions of the convective and overall heat transfer coefficients in an internal flow. The entropy generation rate inside a heat exchanger is recalculated and indicated to be driven by the difference between the reciprocal of outlet temperatures of two streams, from which the entropy generation number between outlets is developed to eliminate the entropy generation paradox. The present linear temperature difference profiles agree well with the experimental data, and the outlet entropy generation number is also justified by comparing with the previous nondimensionalizing entropy generation numbers.

Influence of building orientation and thermal mass configuration on the prediction of Natural Ventilation Potential (NVP) of various climates of India.

Natural ventilation potential (NVP) of a climate is a theoretical basis, and it gains importance due to the promising need for building energy conservation while conceding required thermal comfort conditions. A modified NVP analytical model is proposed by considering parameters involved in the earlier models (Yang et al., Build Environ 40:738-746, 2005; Luo et al., Build Environ 42:2289-2298, 2007). The effect of the dynamic thermal behavior of the wall/roof and building orientation on the indoor air temperature has been evaluated. The analytical model is applied to 11 major cities of India that belong to composite, hot-dry, temperate, and warm-humid climates. Five different envelope configurations are analyzed to envisage the NVP of concern climate (ED-I to ED-V). The results show that the effect of dynamic thermal response factors on the NVP is significant, and optimization of thermal response factors in addition to the U-value is mandatory. The impact of wind frequency on the selection of building orientation is substantial since it influences the total heat gained by the building envelope. Moreover, it is perceived that the optimum building orientation is independent of the climate and weather conditions. ED-II and ED-III are energy-efficient envelopes for composite, temperate, warm-humid, and hot-dry climates. The results revealed that the Mumbai climate has the highest NVP of 66% while the building is oriented in an E-W direction, and the lowest is observed for Jodhpur, i.e., 44% of the year when the building is in the NE-SW direction. The model helps the building architectural designers envisage the true NVP and assess the suitability of the building for natural ventilation.

Theoretical simulation of steady flowing manifold in hybrid pneumatic power system

Improving the energy efficiency of existing power systems is part of energy conservation and carbon reduction efforts. Internal combustion engines (ICEs) are currently the most commonly used power source in transportation, and they can be combined with gas power sources to form hybrid power systems for enhanced energy efficiency and potential commercialization. This study introduces hybrid pneumatic systems that integrate energy from ICEs and exhaust gas through a manifold to reuse waste heat. However, the turbulence caused by compressed air in the manifold can prevent the smooth transfer and mixing of thermal energy, leading to reduced power at the final outlet. We use ANSYS Fluent software to conduct heat flow streamline analysis of the three-dimensional flow field in the manifold structure, with key parameters including throttle valve opening, manifold geometry, pressure, and temperature. Through this analysis, we explore the flow situation and heat transfer phenomenon inside the pipe, observe the flow field changes in the pipe, and adjust the diameter of the compressed air end channel for effective thermal energy. A backflow with velocity magnitude up to 72 m/s in high pressure case can be solved by compressing pipe and temperature increases from 349.9 K to 682.5 K with more efficient heat transfer and gas mixing. Thermal power, enthalpy, and mass flow rate of the hybrid power system are also investigated, enabling the ICE to operate at its optimal point. The waste heat from the ICE can also be recycled and converted into effective mechanical energy through flow work.

Energy and structural optimization of mid-rise light-frame timber buildings for different climates and seismic zones in Chile

Location determines not only the climatic condition but also the structural loads that the structure must withstand. Given the broad variety of climatic and seismic requirements of Chile, the design of lightweight timber buildings considering both energy and seismic design parameters and boundary conditions becomes a difficult task. The main objective of this research is to analyze and quantify the effect of climates, seismic loads, lateral anchorage, and story number on the optimal energy design solutions, including the seismic behavior in a light-frame timber building. Furthermore, the optimal design was parametrically analyzed considering five Chilean cities that consider different climates, seismic zone, number of stories, and lateral anchorage systems to prevent rocking (overturning) due to lateral seismic forces. The optimal wall insulation thickness, stud spacing, and thermal mass exhibited significant variations depending on the buildings' number of stories, lateral anchorage system, climate, and seismic zone. Therefore, the results of this investigation reinforce the necessity of integrating energy and seismic designs for light-frame timber buildings. The optimal designs obtained in this investigation showed considerable variations depending on the combination of climatic and seismic loads as well as the number of stories and anchoring systems. The article's main contributions are the evidence of the structural and energy design interconnection of light-frame timber buildings and how design variables, such as stud spacing, floor concrete thickness layer, and wall insulation thickness, are related and change according to the different climates, seismic loads, lateral anchorage, and story number.

Abstract PO3-26-04: Discovery of novel inhibitors of the epigenetic regulatory KAT6A histone acetyl transferase and their anti-tumor activity in breast cancer cells

Abstract KAT6A is a histone acetyltransferase (HAT) which directs chromatin structural rearrangement and subsequent changes in gene transcription through acetylation of histones, primarily specific lysine residues on histone H3. KAT6A is modified in cancer, including genomic amplification, overexpression, mutation, as well as genetic rearrangement resulting in the production of fusion proteins. Dysregulation of this MYST family member and its acetyl transferase activity is known to drive gene expression and tumorigenic progression in cancers. An inhibitor of KAT6A and related MYST family member KAT6B has entered phase 1 clinical trials with durable partial responses seen in a variety of tumor types, including estrogen-receptor positive (ER+) breast cancer previously treated with a CDK4/6 inhibitor (Sommerhalder, ASCO2023). Evidence of dose dependent pharmacodynamics (H3K23Ac inhibition) was observed in peripheral blood mononuclear cells and paired tumor biopsies. Isosterix has developed 2 distinct series of KAT6A selective inhibitors which engage in the active site of KAT6A in the acetyl CoA substrate binding pocket and inhibit histone acetylation activity. The kinetics of target enzyme binding and inhibition will be discussed for both series of inhibitors. These compounds have been characterized for potency and cellular activity in a variety of assays. Both series of compounds inhibit KAT6A-mediated histone acetylation with single digit nM potency in a biochemical assay as well as significant potency in the breast cancer tumor cell line ZR-75-1, inhibiting H3K23 acetylation. Using a thermal shift assay (CETSA) and mass spectrometry-based protein quantitation, direct target engagement of KAT6A within cells has been shown. These compounds reduce cell viability of a number of breast cancer cell lines with 10 days of compound administration confirming the dependence of these tumor cell lines on KAT6A acetyl transferase activity for proliferation and cell cycle progression. Compounds are orally bioavailable with excellent pharmacokinetic (PK) properties in mice including half-lives >5 hours with oral administration. Finally, Isosterix inhibitors demonstrated anti-tumor efficacy with oral administration in a ZR-75-1 mouse xenograft tumor model. Inhibitors against this novel epigenetic target demonstrate the potential for efficacy in ER+ breast cancer as well as other tumor indications through suppression of KAT6A-directed transcriptional induction and chromatin remodeling. Table. Compound Kat6A Biochemical IC50 (µM) ZR-75-1 H3K23 Acetylation EC50 (µM) Mouse PK (p.o.) Mouse PK (i.v.) Inhibitor class %F T½ (h) Cl (mL/min/kg) SL-IST-001 0.007 0.01 100 5.2 0.47 Series 1 SL-IST-002 0.007 0.005 100 6 0.48 Series 2 Citation Format: Leslie Holsinger, Roopa RaI, Rahul R. Nagawade, Benoy Pal, Samir Pawar, Pankaj Singh, Krishna Putta, Mahaboobi Jaleel, Tove Bostrom, Jakob Karen, Qianyang Huang, Alison Hannah. Discovery of novel inhibitors of the epigenetic regulatory KAT6A histone acetyl transferase and their anti-tumor activity in breast cancer cells [abstract]. In: Proceedings of the 2023 San Antonio Breast Cancer Symposium; 2023 Dec 5-9; San Antonio, TX. Philadelphia (PA): AACR; Cancer Res 2024;84(9 Suppl):Abstract nr PO3-26-04.

Evaluation of the Demand Flexibility Potential Through Joint Optimization of Building Thermal Response and Indoor Air Quality in Commercial Buildings

Abstract Large commercial buildings may display demand flexibility, which reduces electric energy expenses for the building owner and carbon emissions from grid operations, provides distributed energy resources, and increases the penetration of renewable energy sources. Demand-controlled ventilation (DCV) and building thermal mass control can individually and jointly provide such flexibility. The performance and financial payback of these technology options can be dramatically improved if based on hourly electric prices and carbon emissions rates. In this study, a modeled but actual large office building, simulated using New York City hourly electric prices, hourly CO2e emissions rates, and weather data for the summer 2019 cooling season is based on these dynamic driving parameters. A joint optimization of a building’s thermal mass and indoor CO2 content is presented. Superior energy savings and carbon emissions reductions are found for the joint optimization scenario when compared to both the baseline operation and individual optimization of building thermal mass and indoor CO2 content. These findings motivate the development of a real-time joint control system that utilizes closed-loop model predictive control (MPC) to optimally harness both sources of demand flexibility, a system that would require the future development of forecasting algorithms for external and control-oriented system models.

Oscillating thermal switch using electrostatic forces

Thermal control devices such as thermal switches, thermal diodes, thermal regulators and thermal capacitors can control the intensity and direction of heat flow, which has proven useful in various thermal management applications. Their operation is analogous to that of their electrical counterparts, where temperature differences correspond to voltage differences and heat flow corresponds to electric current. Here we design and fabricate a thermal switch that controls the heat flow from the heat source by changing the thermal conductance when switching ON and OFF. The thermal switch uses electrostatic forces for actuation and makes thermal contact between the heat source and the heat sink when in the ON state, and breaks contact when in the OFF state. The thermal switch is constructed using the commercially available materials. The heat sink and heat source are made of silicon, and the active part of the heat switch is a flexible gadolinium sheet with a thickness of 161 µm. The proof-of-concept device was evaluated for a magnetocaloric application; however, the proposed thermal switch can be used in any thermal circuit for fast thermal regulation and advanced thermal control.

The ALMA Survey of 70 μm Dark High-mass Clumps in Early Stages (ASHES). XI. Statistical Study of Early Fragmentation

Fragmentation during the early stages of high-mass star formation is crucial for understanding the formation of high-mass clusters. We investigated fragmentation within 39 high-mass star-forming clumps as part of the Atacama Large Millimeter/submillimeter Array Survey of 70 μm Dark High-mass Clumps in Early Stages (ASHES) survey. Considering projection effects, we have estimated core separations for 839 cores identified from the continuum emission and found mean values between 0.08 and 0.32 pc within each clump. We find compatibility of the observed core separations and masses with the thermal Jeans length and mass, respectively. We also present subclump structures revealed by the 7 m array continuum emission. Comparison of the Jeans parameters using clump and subclump densities with the separation and masses of gravitationally bound cores suggests that they can be explained by clump fragmentation, implying the simultaneous formation of subclumps and cores within rather than a step-by-step hierarchical fragmentation. The number of cores in each clump positively correlates with the clump surface density and the number expected from the thermal Jeans fragmentation. We also find that the higher the fraction of protostellar cores, the larger the dynamic range of the core mass, implying that the cores are growing in mass as the clump evolves. The ASHES sample exhibits various fragmentation patterns: aligned, scattered, clustered, and subclustered. Using the Q -parameter, which can help distinguish between centrally condensed and subclustered spatial core distributions, we finally find that in the early evolutionary stages of high-mass star formation, cores tend to follow a subclustered distribution.

Development of a capillary temperature control system for capillary electrophoresis instruments designed for spaceflight applications.

Capillary temperature control during capillary electrophoresis (CE) separations is key for achieving accurate and reproducible results with a broad array of potential methods. However, the difficulty of enabling typical fluid temperature control loops on portable instruments has meant that active capillary temperature control of in situ CE systems has frequently been overlooked. This work describes construction and test of a solid-state device for capillary temperature control that is suitable for inclusion with in situ instruments, including those designed for space missions. Two test articles were built, a thermal mass model (TMM) and a functional model (FM). The TMM demonstrated that temperature gradients could be limited using the proposed control scheme, and that our thermal modeling of the system can be relied on for future adaptations of physical geometries of the system. The FM demonstrated CE analytical performance while under active temperature control and that the device was compatible with the harsh thermal-vacuum environments that might be encountered during space flight.

Constraining hot dark matter sub-species with weak lensing and the cosmic microwave background radiation

Although it is well known that the bulk of dark matter (DM) has to be cold, the existence of an additional sub-dominant, hot species remains a valid possibility. In this paper we investigate the potential of the cosmic shear power spectrum to constrain such a mixed (hot plus cold) DM scenario with two additional free parameters, the hot-to-total DM fraction ($f_ hdm $) and the thermal mass of the hot component ($m_ hdm $). Running a Bayesian inference analysis for both the Kilo-Degree Survey cosmic shear data ( as well as the cosmic microwave background (CMB) temperature and polarisation data from Planck we derive new constraints for the mixed DM scenario. We find a 95 per cent confidence limit of $f_ hdm <0.08$ for a very hot species of $m_ hdm eV. This constraint is weakened to hdm <0.25$ for $m_ hdm eV. Scenarios with masses above hdm eV remain unconstrained by the data. Next to providing limits, we investigate the potential of mixed DM to address the clustering (or $S_8$) tension between lensing and the CMB. We find a reduction of the 2D ($ - S_8$) tension from 2.9sigma to 1.6sigma when going from a pure cold DM to a mixed DM scenario. When computing the 1D Gaussian tension on $S_8$ the improvement is milder, from 2.4sigma to 2.0sigma

Quasiparticle cosmology

We consider thermodynamics of the Universe within a quasiparticle approach where the collective dynamics of a system is governed by the thermal mass of the constituents. The spacetime dependence of this thermal mass leads to a negative contribution to the pressure and a positive contribution to the energy density, similar to the effect due to dark energy. We propose a mechanism based on thermodynamic arguments to quantify this contribution from the thermal vacuum of the system. For a sufficiently large spacetime variation of the thermal mass, the effective pressure can become negative and could mimic a dark energy equation of state. We validate our framework using results from renormalizable interacting scalar field theory and demonstrate an application on QCD axion. Published by the American Physical Society 2024

Engineering lightweight Poly(lactic acid) graphene nanoribbon nanocomposites for sustainable and stretchable electronics: Achieving exceptional electrical conductivity and electromagnetic interference shielding with enhanced thermal conductivity

The challenge of creating flexible and sustainable electronics with properties such as lightweight, electrical and thermal conductivity, and electromagnetic interference (EMI) shielding is addressed in this study. Carbon nanotubes and graphene are commonly used in flexible electronic devices, but gaps exist in their conductivity and flexibility. A novel and scalable fabrication method is introduced, involving the creation of bio-based nanocomposites by integrating flexible and high aspect-ratio graphene nanoribbons (GNRs) into a poly (lactic acid) (PLA) matrix. The nanocomposites were drawn above the glass transition temperature (Tg) of PLA, resulting in the formation of extended shish structures, as observed in scanning electron microscope (SEM) images. These structures significantly enhanced thermal and electrical conductivities, as well as EMI shielding features. The combination of flexible GNR nanofillers with uniaxial stretching led to a substantial increase in Young's modulus, tensile strength, and toughness by approximately 550 %, 440 %, and 600 %, respectively, most likely due to the increased network connection despite the higher flexibility of GNRs. Moreover, in-plane thermal conductivity registered a notable enhancement of approximately 110 %. The EMI shielding reached 26 dB, with an absorption contribution to EMI shielding of around 45 %. Additional improvement was achieved through foaming of the stretched samples, resulting in multilayer structures with alternative extended shish and foam structures. Furthermore, a significant augmentation of approximately 33 dB in total EMI shielding of the foamed samples, accompanied by an 85 % increase in SEA was documented. These promising findings underscore potential applications across diverse domains, including thermal interface materials, electronic packaging, capacitors, and energy storage devices, with a specific emphasis on the realm of sustainable and stretchable electronics.

Enhance thermal response behavior of energetic composite by doping fluorinated graphene

Fluorinated graphene (FGO) is a two-dimensional layered compound with thermal conductivity and hydrophobicity. Different percentage of FGO (1.00 wt.%, 3.00 wt.%, 5.00 wt.%) was added to the composite energetic system boron/potassium nitrate (B/KNO3). Through elemental analysis (EA), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS), the results show that with the increase of fluorination degree, the stretching vibration peak of C-F bond was more obvious, and the contents of fluorocarbon functional groups, especially C-F2 rise. The results of synchronous thermal analysis and mass spectrometry (DSC-TG-MS) showed that the initial decomposition temperature of fluorinated graphene was around 400 ℃, the enthalpy value was about 7279 J g−1, and a large number of fluorine-containing gas products arising therefrom. The effect of fluorinated graphene on the thermal decomposition performance of energetic system was analyzed by DSC-MS. The results show that fluorinated graphene delayed initial exothermic peak temperature of B/KNO3 system, and promoted subsequent exothermic reaction. The service performances of B/KNO3 composites were compared with or without FGO. While adding fluorinated graphene, the moisture resistance and thermal conductivity of the B/KNO3 composites was improved, flame sensitivity was reduced, thermal safety was improved, gaseous products and combustion heat were increased, flame duration was prolonged, and the ignition delay period was shortened. It is implied that the present of FGO made the composite energetic materials safer under lower heat and more reliable under high heat. FGO plays a role of intelligent regulation and smart responds to different thermal stimuli.

Formation of secondary organic aerosols from Cl-initiated oxidation of anisole: Rapid release of ultrafine particles and organic chlorides

Recent studies have highlighted the increased occurrence of reactive chlorine, drawing significant attention to the process of chlorinated chemical oxidation of oxygenated aromatics emitted from biomass burning (BB) in the formation of secondary organic aerosols (SOA). This study selected an oxygenated aromatic, anisole, as a representative of BB, and investigated the products and mechanisms of its reaction with Cl•, as well as exploring the implications of precursor-to-oxidant ratio ([anisole/Cl2]0), NOx levels, and seed particles on SOA generation. The gas-phase composition, SOA composition, and particle information were determined using a single-photon ionization time-of-flight mass spectrometry (SPIMS), a thermal desorption unit gas chromatography mass spectrometry (TDU-GC/MS), and a scanning mobility particle sizer (SMPS), respectively. Experimental results indicate that within minutes of turning on the ultraviolet (UV) lights, a large quantity of ultrafine particles (UFPs) (diameter <100 nm) is immediately formed. The SOA yield is significantly dependent on [anisole/Cl2]0, decreasing from 66.2% to 20.0% as the [anisole/Cl2]0 increases. Upon oxidation by Cl•, anisole promptly released organic chlorides, including 2-chlorophenol and 2,4,6-trichlorophenol. The addition of NOx decreased the SOA yield, enhanced the role of OH• in the reaction process, and led to the formation of organic nitrogen products, such as C6H5NO3 and C7H7NO4. Furthermore, Cl• primarily initiates reactions through H-abstraction and Cl-substitution, resulting in the oxidation products largely retaining the benzene ring. This provides a potential explanation for the high SOA yield induced by Cl• in this study. Overall, our work suggests that the release of UFPs and organic chlorides can be found in the Cl-initiated oxidation of anisole, which contributes to high SOA yields. Against the backdrop of increasing wildfire frequency due to global warming, it is necessary to consider the contributions and sources of UFPs and organic chlorides caused by the reaction of wildfire emissions with Cl atoms.

Hydrogen Storage Capacity of Cobalt Cluster Ions.

The adsorption of H2 on gas-phase Con± (n = 5-12) clusters at 300 K and the desorption of H2 from ConHm± upon heating were studied experimentally by combining thermal desorption spectrometry and mass spectrometry to elucidate the hydrogen storage property of the Co clusters. Hydrogen atoms adsorbed well on Con+ (n = 5, 10-12) and Con- (n = 5-12) at 300 K to form ConHm±. The atomic ratios, m/n, for ConHm- (0.9-1.4) were higher than those for ConHm+ (0.2-1.1). According to density functional theory (DFT) calculations, the first few H2 molecules had a tendency to dissociatively adsorb onto the Co clusters. Further, the bonding nature of the H atoms was ionic, similar to the H atoms in the metallic hydrides. In contrast, H2, adsorbed molecularly, was explained in terms of σ complex formation. H2 molecules were desorbed from the clusters upon heating. The temperature dependences showed that ConHm- released H2 at a higher temperature (700-800 K) than ConHm+ (600-700 K), suggesting that Con- should have a higher affinity to hydrogen than Con+. The desorption temperatures were lower than those of VnHm+, which was consistent with the fact that the adsorption energies of H2 were lower for the Co clusters than those for the V clusters. The low adsorption energies were ascribed to their large highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) gaps in the Co clusters.