High-temperature Superconducting Materials Research Articles

Calculation of AC loss using 2D homogenization method for HTS synchronous condenser rotor and validation

Compared with low-temperature superconductors, second-generation high-temperature superconducting materials offer higher current densities and temperature margins, which provide a boost to the development of superconducting condenser towards large capacity and light weight. In this paper, a 3D-to-2D dimensionality reduction and simplification method is proposed to address the problem of massive computation of 3D finite element model during the optimization of superconducting condenser rotor performance parameters. This method splits the pole based on the geometric characteristics of the rotor pole, establishes a 2D simplified model of each part of the pole after splitting, and uses the simplified model to calculate the key physical quantities such as the magnetic field, AC loss, temperature change, etc., during the excitation process of the superconducting condenser rotor. This method effectively reduces the computational complexity of the model and improves the efficiency of the calculation and iterative optimization of the magnet pole parameters. In order to verify the correctness of the electromagnetic calculation results of the simplified model, the rotor magnet model was assembled to carry out experiments in liquid nitrogen bath, and the experimental results were in good agreement with the calculation results.

A new perspective on ductile high-Tc superconductors under ambient pressure: few-hydrogen metal-bonded hydrides

Superconducting materials have garnered widespread attention due to their zero-resistance characteristic and complete diamagnetism. After more than 100 years of exploration, various high-temperature superconducting materials including cuprates, nickelates, iron-based compounds, and ultra-high pressure multi-hydrides have been discovered. However, the practical application of these materials is severely hindered by their poor ductility and/or the need for high-pressure conditions to maintain structural stability. To address these challenges, we first provide a new thought to build high-temperature superconducting materials based on few-hydrogen metal-bonded hydrides under ambient pressure. We then review the related research efforts in this article. Moreover, based on the bonding type of atoms, we classify the existing important superconducting materials and propose the new concepts of pseudo-metal and quasi-metal superconductivity, which are expected to be helpful for the design of new high-temperature superconducting materials in the future.

Characterisation of Large-Sized REBaCuO Bulks for Application in Flux Modulation Machines.

High temperature superconductors (HTSs) are enablers of extensive electrification for aircraft propulsion. Indeed, if used in electrical machines, HTS materials can drastically improve their performance in terms of the power-to-weight ratio. Among the different topologies of superconducting electrical machines, a flux modulation machine based on HTS bulks is of interest for its compactness and light weight. Such a machine is proposed in the FROST (Flux-barrier Rotating Superconducting Topology) project led by Airbus to develop new technologies as part of their decarbonization goals driven by international policies. The rotor of the machine will house large ring-segment-shaped HTS bulks in order to increase the output power. However, the properties of those bulks are scarcely known and have barely been investigated in the literature. In this context, the present work aims to fill out partially this scarcity within the framework of FROST. Thus, a thorough characterisation of the performances and homogeneity of 11 large REBaCuO bulks was carried out. Ten of the bulks are to be utilized in the machine prototype, originally keeping the eleventh bulk as a spare. A first set of characterisation was conducted on the eleven bulks. For this set, the trapped field mapping and the critical current were estimated. Then, a series of in-depth characterisations on the eleventh bulk followed. It included critical current measurement, X-ray diffraction, and scanning electron microscopy on different millimetre-size samples cut out from the bulk at various locations. The X-ray diffraction and scanning electron microscopy showed weakly oxygenated regions inside the bulk explaining the local drop or loss in superconducting properties. The objective was to determine the causes of the inhomogeneities found in the trapped field measured on all the bulks, sacrificing one of them, here the spare one. To help obtain a clearer picture, a numerical model was then elaborated to reproduce the field map of the eleventh bulk using the experimental data obtained from the characterisation of its various small samples. It is concluded that further characterisations, including the statistics on various bulks, are still needed to understand the underlying reasons for inhomogeneity in the trapped field. Nonetheless, all the bulks presented enough current density to be usable in the construction of the proposed machine.

Prediction of potential high-temperature superconductivity in ternary Y–Hf–H compounds under high pressure

Compressed ternary alloy superhydrides are currently considered to be the most promising competitors for high-temperature superconducting materials. Here, the stable stoichiometries in the Y–Hf–H ternary system under pressure are comprehensively explored in theory and four fresh phases are predicted: Pmna-YHfH6 and P4/mmm-YHfH7 at 200 GPa, P4/mmm-YHfH8 at 300 GPa and P-6m2-YHfH18 at 400 GPa. The four Y–Hf–H ternary phases are thermodynamically and dynamically stable at corresponding pressure. In addition, structural features, bonding characteristics, electronic properties, and superconductivity of the four ternary Y–Hf–H phases are systematically calculated and discussed. As the hydrogen content and the density of states of H atoms at the Fermi level increase, the superconducting transition temperatures (Tc) of Y–Hf–H system are significantly enhanced. The P-6m2-YHfH18 with high hydrogen content exhibits a high calculated Tc value of 130 K at 400 GPa.

Synthesis and characterization of BaIrO3-doped YBCO superconducting thin films via TFA-MOD technique

High-temperature superconducting materials (HTS) are characterized by remarkably high critical current density (Jc) values when exposed to low temperatures and magnetic fields. In the realm of such investigations, various crystalline imperfections, including finely dispersed non-superconducting phases, dislocations, vacancies, grain boundaries, twin boundaries, antiphase boundaries, and insulating regions within grain boundaries, have been recognized as potential sources of pinning centers. However, it is essential to acknowledge that Jc values experience a rapid decline as the temperature rises in the presence of a magnetic field. The primary contributing factors to this decline are attributed to the intrinsic crystalline anisotropy of HTS materials and the thermal fluctuations that prevail at elevated temperatures. Nevertheless, a noteworthy factor in the diminishment of Jc values is the scarcity of efficacious pinning centers. In response to these challenges, a pioneering technology has emerged, revolving around nanostructure engineering for the deliberate creation of artificial pinning centers within HTS materials. In alignment with this approach, the present study endeavors to augment the critical current density and enhance the flux pinning properties of YBa2Cu3O6.56 (YBCO) superconducting films. This augmentation is achieved through the integration of BaIrO3 (BIO) perovskite nanodots, nanorods, or nanoparticles as strategically positioned pinning centers. The films are deposited on a SrTiO3 (STO) substrate employing the Trifluoroacetate Metal–Organic Deposition (TFA-MOD) technique. This research initiative seeks to contribute to the advancement of knowledge regarding the controlled manipulation of artificial pinning centers in HTS materials, particularly focusing on YBCO thin films, with the ultimate goal of enhancing their performance under the influence of elevated magnetic fields.

Gamma radiation effects on high-temperature superconducting ReBCO tape

High-temperature superconducting (HTS) magnets are crucial components in future fusion reactors, subjected to prolonged irradiation and complex mechanical conditions. While the irradiation sensitivity of HTS materials has been extensively studied, limited research has explored the effects of force conditions during irradiation. This study investigated the influence of irradiation on ReBCO tapes. An irradiation experiment was conducted utilizing a Co60 source irradiation device. Superconductor properties were evaluated through the induction method, while microstructure analysis was performed using x-ray diffraction measurements. The results indicate that the critical current initially increases and subsequently decreases, while the critical temperature remains relatively stable. Furthermore, the bending degree during irradiation affects the critical current density, with a decrease in radius corresponding to a first increase and then subsequent decrease in critical current density. The force applied during irradiation exhibits a impact on the superconducting properties, underscoring the importance of considering force conditions in future investigations.

Experimental study on the an-isotropic critical current of REBCO tape.

Superconducting magnets are widely used in nuclear fusion reactors, high-energy particle accelerators, steady-state high magnetic fields, etc. Higher magnetic fields and higher operating temperatures are two application trends. High temperature superconducting (HTS) materials are the only choice for high temperature and high field magnets in the future. The first- and second-generation HTS materials have a typical tape structure; their critical performance is magnetic field angle and temperature dependent. A new test facility is developed for an experimental study on the an-isotropic critical current. The field angle can be changed from 0° to 360° with a resolution of 1°. The rotation deviation angle is measured to be 0.2° when the upper part rotates 90°. The temperature can be changed from 4.2 to 80K. The temperature errors are ±50, ±80, and ±135 mK for 4.2-20, 20-40, and 40-80K, respectively. The angle dependence of critical current (Ic) of the tested rare-earth barium copper oxide tape within 0°-30° is strong. From 30° to 90°, the sample Ic almost does not change with the magnetic field angle. The implementation of the project will not only promote the structural optimization of HTS tapes but also promote the miniaturization and economical application of HTS magnets.

Radiation protection methods for suborbital aircrafts

This paper presents the outcomes of a study conducted by SALTO team in the framework of the Student Aerospace Challenge, focusing on designing structures to optimize passenger protection against radiation in a suborbital vehicle. The study delves into space radiation characteristics and their potential impact on human health during suborbital flights. Through comprehensive research and the utilization of CARI-7A software, the team evaluated radiation exposure and explored both passive and active shielding solutions. The passive shielding solution involved the design of a multifunctional sandwich panel and a shielding layout for windows, minimizing weight penalties on the vehicle’s structure. Additionally, an active shielding concept utilizing high-temperature superconductor material and solenoid layouts was investigated. The study underscores the benefits and challenges associated with both passive and active shielding methods, emphasizing the importance of further exploration to enhance suborbital flight safety and pave the way for future human space exploration endeavors.

Prediction of ambient pressure superconductivity in cubic ternary hydrides with MH6 octahedra

Exploring high-temperature superconducting (high-Tc) material at ambient pressure holds immense significance for physics, chemistry, and materials science. In this study, we perform a high-throughput screening of strong electron-phonon interactions in X2MH6 compounds (X = Li, Na, Mg, Al, K, Ca, Ga, Rb, Sr, and In; M are 3d, 4d, and 5d transition metals). These compounds have a cubic structure featuring an MH6 octahedron motif. Our screening calculations suggest that 26 compounds exhibit dynamic stability and strong electron-phonon coupling. Among them, Mg2RhH6, Mg2IrH6, Al2MnH6, and Li2CuH6 show promising energetic stability and Tc of more than 50 K at ambient pressure. This study underscores promising high-Tc compounds at ambient pressure with distinctive MH6 motifs.

Cryogen-free 400-MHz nuclear magnetic resonance spectrometer as a versatile tool for pharmaceutical process analytical technology.

The discovery of new ceramic materials containing Ba-La-Cu oxides in 1986 that exhibited superconducting properties at high temperatures in the range of 35 K or higher, recognized with the Nobel Prize in Physics in 1987, opened a new world of opportunities for nuclear magnetic resonance (NMRs) and magnetic resonance imaging (MRIs) to move away from liquid cryogens. This discovery expands the application of high temperature superconducting (HTS) materials to fields beyond the chemical and medical industries, including electrical power grids, energy, and aerospace. The prototype 400-MHz cryofree HTS NMR spectrometer installed at Amgen's chemistry laboratory has been vital for a variety of applications such as structure analysis, reaction monitoring, and CASE-3D studies with RDCs. The spectrometer has been integrated with Amgen's chemistry and analytical workflows, providing pipeline project support in tandem with other Kinetic Analysis Platform technologies. The 400-MHz cryofree HTS NMR spectrometer, as the name implies, does not require liquid cryogens refills and has smaller footprint that facilitates installation into a chemistry laboratory fume hood, sharing the hood with a process chemistry reactor. Our evaluation of its performance for structural analysis with CASE-3D protocol and for reaction monitoring of Amgen's pipeline chemistry was successful. We envision that the HTS magnets would become part of the standard NMR and MRI spectrometers in the future. We believe that while the technology is being developed, there is room for all magnet options, including HTS, low temperature superconducting (LTS) magnets, and low field benchtop NMRs with permanent magnets, where utilization will be dependent on application type and costs.

Impact of Superconductor Technologies on Network Design and Energy Cost- a Case Study in Libya

Several studies and investigations haveattempted to introduce a new design for the conventionaldistribution networks. This proposed design aims to offer a reduction in substation installation cost and in power losses by eliminating some voltage levels in networks. Sine, this is difficult to achieve with conventional distribution networks, when the conventional cables and transformers are used, where the impedance of conventional equipment is high. Due to High-Temperature Superconductor (HTS) materials provide extremely low impedance to AC when cooled to the boiling point of liquid nitrogen (77K), the interest in using HTS materials to produce power cables and transformers is increased. The present paper investigates the practical impacts of installing HTS cables and transformers and seeks to introduce a future network design which leads to the best implementation for superconducting networks, thus, a drop in the substation installation cost and energy losses cost by eliminating some voltage levels in the traditional networks.

Effect of doping on evolution of He<sup>+ </sup>ion irradiation defects and superconductivity in EuBa<sub>2</sub>Cu<sub>3</sub>O<sub>7–δ</sub> superconducting strips

Rare-earth barium copper oxide (REBCO) as a representative of the second-generation high-temperature superconducting materials possesses superior physical advantages such as high critical magnetic field, elevated critical temperature, and superior current density, which has been applied to many domains. Although the introduction of non-superconducting nanoscale particle dopants, as a critical method, can enhance the magnetic flux pinning capability of REBCO strips, the effect of the doping on the performance change and microstructure evolution of the strips under irradiation is ignored. In this work, undoped and 3.5% BaHfO<sub>3</sub> (BHO) doped EuBa<sub>2</sub>Cu<sub>3</sub>O<sub>7–δ</sub> strips are investigated in the room-temperature irradiation experiments (1.4 MeV He<sup>+</sup> ions) with three distinct doses of 5×10<sup>14</sup>, 5×10<sup>15</sup>, and 5×10<sup>16</sup> ions/cm<sup>2</sup>, respectively. Electrical performance tests reveal that the undoped strips exhibit a slight increase in <i>J</i><sub>c</sub> after the low-dose irradiation. However, with dose increasing, <i>J</i><sub>c</sub> decreases by over 60%. In contrast, doped strips experience a significantly smaller decline in <i>J</i><sub>c</sub>, ranging only between 30% and 40% at high-dose irradiation. Raman spectroscopy and transmission electron microscopy characterizations confirm that the defects induced by He<sup>+</sup> ion irradiation lead to amorphization and structural disorder within the superconducting layers, which is the primary reason for the decline in the superconducting properties of the strips. The results show that the introduction of localized strain through BHO nanophase in the superconducting layer changes the migration and aggregation behavior of irradiation-induced defects, repairing the damaged superconductor structure. Furthermore, the field dependence and temperature dependence of <i>J</i><sub>c</sub> of doped strips are irradiation-resistant due to BHO nanocrystals as strong pinning centers. Additionally, unlike the superconducting properties of the REBCO strips that can be repaired through oxygen annealing after neutron or heavy ion irradiation, the electrical properties of the two types of strips irradiated with high doses of He<sup>+</sup> ions in this work are further deteriorated after being annealed. It is worth noting that compared with the undoped strip, the localized strain generated by BHO in the doped strip inhibits the size growth of helium defects in the three-dimensional direction at high temperatures, which changes the magnetic flux pinning characteristics and delays the disorder and amorphization of the superconducting layer structure caused by the severe growth of helium bubbles. This study provides a reference for the application of REBCO superconducting strips in the irradiation environment.

Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor

Electrochemical sensing is an excellent analytical means with multiple applications. Most of the electrochemical developments are based on the novel electrochemically active substrates. A lot of them have been adopted from other fields of material science. Every new class of functional materials has impacted on the development of electroanalytical chemistry. In this view, lanthanide cuprates, a well recognized high temperature superconducting materials were considered for adrenaline sensing. Obtained from corresponding oxides, a highly crystalline La2CuO4 found to be a suitable substrate for analytical method development. It inherited sponge-like morphology common for the most of the previously reported lanthanum cuprates with narrow pore size distribution at 400–700 nm. Excellent charge mobility and low resistivity provided a carbon paste electrode with improved linearity range and low limit of detection. Repeatability and stability of the developed sensor were at satisfactory level. Sensor functionality was verified on the real samples with excellent recovery rates. With this work we suggest further development of electroanalytical methods with application of lanthanide cuprates.

Surface inducing high-temperature superconductivity in layered metal carborides Li2BC3 and LiBC by metallizing σ electrons.

Metallizing σ electrons provides a promising route to design high-temperature superconducting materials, such as MgB2 and high-pressure hydrides. Here, we focus on two MgB2-like layered carborides Li2BC3 and LiBC; their bulk does not have superconductivity because the B-C σ states are far away from the Fermi level (EF), however, based on first-principles calculations, we found that when their bulk systems are cleaved into surfaces with B-C termination, high Tc of ∼80 K could be observed in the exposed B-C layer on the surfaces. Detailed analysis reveals that surface symmetry reduction, due to lattice periodic breaking, not only introduces hole self-doping into surface B-C layers and shifts the σ-bonding states towards the EF - associated with emergent large electronic occupation, but also makes in-plane stretching modes on the surface layer experience significant softness. The enhanced σ states and softened phonon modes work to produce strong coupling, thus yielding high-Tc surface superconductivity, which distinctly differs from the superconducting features of the MgB2 film, which generates phonon stiffness accompanied by suppressed superconductivity. Our findings undoubtedly provide a novel platform to realize high-Tc surface superconductivity, and also clearly elucidate the microscopic mechanism of surface-enhanced superconductivity in favor of creating more high-Tc surface superconductors among MgB2-like layered materials.

A systematic study on the phase diagram and superconductivity of ternary clathrate Ca-Sc-H at high pressures.

This work explores potential high-temperature superconductor materials in hydrogen-rich systems. Here, the crystal structure stabilities of ternary Ca-Sc-H systems under high-pressure (P = 100-250 GPa) and their superconductivities are investigated using the particle swarm optimization methodology combined with first-principles calculations. For the predicted candidate structures of Ca-Sc-H systems, the pressure-dependent phase diagram and thermodynamic convex hull were investigated across a wide range of compositions; the electronic properties of all the predicted phases were analyzed in detail to study the bonding behavior of these stable phases. We identified the crystal structures of four thermodynamically stable compounds: R3̄m-CaScH6, Immm-CaSc2H9,C2/m-Ca2ScH10, and R3̄m-CaScH12. Among them, R3̄m-CaScH12 was predicted to have the highest Tc value (i.e., 173 K) at 200 GPa. The discovery of this previously unreported pressure-induced decomposition of Ca-Sc-H systems will pave the way for investigations on the nature of hydrogen-metal interactions.

Overall design of a 5 MW/10 MJ hybrid high-temperature superconducting energy storage magnets cooled by liquid hydrogen

The integration of superconducting magnetic energy storage (SMES) into the power grid can achieve the goal of storing energy, improving energy quality, improving energy utilization, and enhancing system stability. The early SMES used low-temperature superconducting magnets cooled by liquid helium immersion, and the complex low-temperature cooling system greatly limited the promotion and application of such devices. SMES based on high temperature superconductivity (HTS) materials can operate in the temperature range of 15–30 K, which simplifies the cooling system and reduces the cooling loss, and greatly improves the operating efficiency and stability of the cooling system. In this paper, the overall design of a 5 MW/10 MJ SMES based on state of the art HTS materials is achieved. The structural parameters of YBCO and MgB2 cables are introduced and the structural parameters of energy storage magnet are analyzed. And the cooling scheme for SMES is provided.

Fault current limiter based on high temperature superconductors

High Temperature Superconductors (HTS) made the Superconducting Fault Current Limiter (SFCL) a reality in power electric grids. Resistive SFCL, which is the subject of this article, is based on a unique property of superconductors to quench from a non-dissipative to a high dissipative state above a given current. SFCL is an attractive response to the poorly solved problem of fault currents in power electric grids and makes it possible to enhance the security and quality of electricity, something that matters more than ever. Liquid nitrogen cryogenics – which is possible thanks to HTS- makes the cryogenics user friendly. In-field SFCL operations confirm this. Second generation (2 G) HTS materials or Coated Conductors suit well to SFCL. Due to its high interest, SFCL has been the subject of a great deal of research and development. In terms of Technology Readiness Level (TRL) it reaches 8 with several in grid test experiences.Here a short history of SFCL is presented with a highlight about Curl 10, Ampacity and SuperOx devices. The two major locations in the grid are reported: grid coupling and feeder protection. The quench phenomena is described in a bit more detail before the basic design (length and cross section) is presented. The design is primarily thermal, considering two extreme operations: fault with very high prospective current (clear short-circuit) and fault with prospective current close to the minimum runaway current along the length. This operation is called the hot spot one. It is due to the intrinsic variation of the critical current along the length and to the low Normal Zone Propagation Velocity (NZPV). The cost of the superconducting conductor is given, showing no bottleneck for an economic development. All the more it is still possible to lower the cost with some developments. This article ends with two real advances presently underway: Current Flow Diverter (CFD) and Sapphire substrate superconducting 2 G tape. CFD aims to increase the NZPV, to still further secure the operation and to reduce the conductor cross section. The use of sapphire substrates allows to reduce significantly the length of the design.

Unraveling quench dynamics and real-time continuous detection in HTS tapes through distributed fiber optic sensing

High-temperature superconducting (HTS) tapes, coils, and magnets often experiences intricate quench instabilities and failures during high current-carrying operations, posing challenges to their practical applications. This study addresses the need for a measurement approach capable of monitoring multi-field signals in superconducting structures within cryogenic and extreme electromagnetic environments. We explore the application of distributed fiber optic sensing (DFOS) technology, specifically employing the optical frequency domain reflectometry scheme, which offers distinct advantages over traditional point-type electrical testing methods, particularly for superconducting materials and magnets. In this experimental study, we continuously track the quench evolution process in superconducting tapes using both bonded and stress-free fibers for real-time monitoring. A comprehensive analysis of the acquired temperature and thermoelastic strain profiles provides essential insights into the dynamic behavior of quench events. The findings demonstrate the effectiveness of DFOS in identifying and characterizing the onset and propagation of quenches. By arranging bonded and stress-free fibers in parallel on the HTS tape’s surface, we successfully decouple the effects of strain-temperature cross-sensitivity, enabling the extraction of temperature and train profiles. The bonded fiber optic sensor demonstrates rapid sensitivity to the thermally quenched events. Temporal derivatives of voltage and thermal strain exhibit characteristic plateaus and slope changes during quenches, respectively. The voltage rate displays two plateaus corresponding to superconducting-to-normal transitions, while strain rates exhibit potential as criteria for identifying quench events in HTS materials. Moreover, DFOS outperforms traditional terminal average voltage measurement, capturing quench evolution tails from the initial point of quench until the complete transition of the segment into the normal state. This experiment provides a solid foundation for further exploration of the underlying quench mechanism.

Engineering REBCO high temperature superconductor materials for applications

This article is a lookback at the road traveled in the last 36 years to realize the abundant potential of high temperature superconductors (HTS) that had evoked worldwide excitement on their discovery. Numerous advances have been made in the materials science and manufacturing of HTS to overcome the many obstacles in implementing them in applications.

The research on the influence mechanism of internal deformation for the performance of Bi-2212

Cable-in-conduit conductor (CICC), one of the most promising conductors for manufacturing magnets in magnetic confinement fusion devices, has attracted lots of attention. In the production of CICC, porosity control is necessary for its stability. The porosity control is usually realized by the diameter-reducing process, which would also lead to indentation damages to the elements of CICC-superconducting wires. In this article, systematic research of indentation damages was carried out on the next generation of high-temperature superconducting materials–Bi-2212 wires. The results indicate that the current carrying capacity of the indentation-damaged wire would first keep steady and then show exponential decline with the increase of indentation depth. The wires subjected to pre-overpressure (pre-OP) treatment exhibit slightly improved resistance against indentation damage at shallow indentation depths. However, their critical current (I c) deteriorates more rapidly at greater indentation depths when compared to wires that have not undergone the per-OP process. The following structural characterization analyzed the reasons for the property changes with the help of scanning electron microscopy, energy dispersive x-ray spectroscopy, computed tomography, and hardness tester. Misalignment between the Bi-2212 grains and shaped filaments was found in the indentation-damaged wires, with which the degradation in I c of the wires and the differences in properties of the two kinds of wires were further discussed.