High-temperature Superconducting Films Research Articles

Passive bandpass filters for modern microwave communication systems

Background. Bandpass filters are an integral part of any radio engineering systems and modern communication systems. Research and development of new passive components is due to growing need for such elements for modernization and creation of new modern communication systems.
 Aim. A brief overview of passive bandpass filters. Their classification according to the type of implementation is given.
 Methods. Results of experimental research and design of different passive bandpass filters are considered.
 Results. Lumped elements filters, microstrip filters, filters on high-temperature superconductor films, filter on dielectric resonators, surface acoustic wave filters, bulk acoustic wave filters are considered. At a qualitative level, the main advantages and disadvantages are considered from point of view of electrical parameters and size indicators. Examples of topological and constructive implementation are given.
 Conclusion. The passive bandpass filters considered in the paper make it possible to implement frequency selection devices at operating frequencies up to 6 GHz and higher, taking into account modern system trends and requirements for devices of this type.

In-field electro-magnetic-force characteristics of high-temperature superconducting films containing cracks

Superconducting materials have so far been applied in the fields of superconducting motors, flux pumps and nuclear magnetic resonance, but they are prone to mechanical damage due to their material properties. In this paper, the influences of different crack types (including position, angle, size, quantity and spacing) on the characteristics of current-carrying and excited superconducting thin films are analyzed by numerical simulations, as well as their electromagnetic and mechanical characteristics. Several novel and important conclusions are found. In both states, the boundary crack presents the largest current density concentration, while the central crack produces the largest stress concentration. With the increase of crack spacing, the current density on the multi-crack film decreases and eventually tends to be stable. In the current-carrying state, compared with 3 mm cracked film, the current density of 1 mm cracked film is reduced by up to 62.5 %. The von Mises stress of high-temperature superconducting film with 0.1 mm single-spacing cracks is 22.5 % higher than that for 0.3 mm double-spacing cracks, which indicates that close spacing and a high number of crack types are most detrimental to the mechanical properties of high-temperature superconducting films. In the excited state, when the crack angle θ is 90°, the current density streamlines cannot be segmented effectively, which results in the current distribution trend closer to the defect-free film. A large amount of induced current flows into the low-flux region at the 3 mm crack, leading to an increased risk of film quench. The films with 1 mm single-spacing and double-spacing cracks form a low-flux region between the cracks, which makes the magnetic field more difficult to penetrate.

Temperature dependent behavior of a kA-class superconducting flux pump with a continuous cylindrical stator

A high temperature superconducting (HTS) dynamo is a type of device known as a “flux pump” that can inject DC into a closed superconducting circuit. Here, we report experimental results from a variable-temperature dynamo-type HTS flux pump operated within a cryo-cooled chamber. This device employs a “continuous stator” topology, whereby an HTS “coated conductor” is wrapped to form a cylinder around a mechanical rotor such that applied flux from the rotor magnet must always penetrate the stator. This leads to a high current device that can inject >1 kA into a series-connected HTS coil at 53 K. The open-circuit DC output voltage (Voc) from this HTS dynamo has been studied at stator temperatures between 35 and 95 K and attained a maxima at a temperature ∼5 K lower than the stator Tc. At lower temperatures, Voc decreases and falls to zero below ∼40 K. This non-intuitive effect is found to be due to flux-screening by critical currents flowing with the HTS stator, which increase with decreasing temperature. These shielding currents prevent flux from penetrating the HTS stator and, hence, reduce the magnitude of locally induced emf (and thus DC output) within the HTS film. A key implication of these results is that all magnetically driven HTS flux pumps should be operated at temperatures well above their flux-screening point, and this consideration must be taken into account for future designs of multi-kA class HTS flux pumps.

Optimization of high-temperature superconducting multilayer films using artificial intelligence

We have studied the possibility of utilizing artificial intelligence (AI) models to optimize high-temperature superconducting (HTS) multilayer structures for applications working in a specific field and temperature range. For this, we propose a new vortex dynamics simulation method that enables unprecedented efficiency in the sampling of training data required by the AI models. The performance of several different types of AI models has been studied, including kernel ridge regression (KRR), gradient-boosted decision tree (GBDT) and neural network. From these, the GBDT based model was observed to be clearly the best fitted for the associated problem. We have demonstrated the use of GBDT for finding optimal multilayer structure at 10 K temperature under 1 T field. The GBDT model predicts that simple doped-undoped bilayer structures, where the vast majority of the film is undoped superconductor, provide the best performance under the given environment. The obtained results coincide well with our previous studies providing further validation for the use of AI in the associated problem. We generally consider the AI models as highly efficient tools for the broad-scale optimization of HTS multilayer structures and suggest them to be used as the foremost method to further push the limits of HTS films for specific applications.

A High-Temperature Superconducting Wideband Bandpass Filter at the L Band for Radio Astronomy

In order to ensure the normal operation of radio astronomy observations, an extremely sensitive receiver system needs to be equipped in front of the large radio telescope. An 8-pole wideband high-temperature superconducting (HTS) filter using a Coplanar Spiral Resonator Structure with a passband of 1160∼1670 MHz is developed to suppress strong radio interference. The filter is fabricated on a 36 mm × 14 mm YBCO HTS film, which is deposited on a 0.5 mm thick MgO substrate. The minimum insertion loss measured in the liquid nitrogen temperature region is 0.03 dB, and the first parasitic passband appears at 2600 MHz. The measured results are in good agreement with the simulations. The filter can be used in radio telescope receivers for the observation of neutral hydrogen and pulsars, as well as in high-sensitivity satellite navigation instruments.

A process for the preparation of high-quality and uniform large-scale Bi2212 superconducting films via the sol-gel method

Bi2212 high-temperature superconducting films (HTSFs) have garnered significant interest as a potential material for the development of high-Tc microwave and terahertz (THz) devices due to their intrinsic Josephson effect. This work presents the utilization of the polyvinyl pyrrolidone (PVP) -assisted sol-gel dip coating (PSGDC) method for the large-scale production of Bi2212 HTSFs. Initially, Bi2212 HTSFs were prepared on a small-scale single crystal (001)-oriented SrTiO3 substrates, and comprehensive characterization of their phase purity, crystal structure, surface morphology, microstructure, stress state, and transport properties was conducted as a foundation for further analysis. By optimizing the crystallization conditions and PVP content, the Bi2212 HTSF achieved improved performance, including a higher onset superconducting transition temperature (Tc, onset) of 94 K, zero-resistance temperature (Tc, zero) of 86 K, and a critical current density (Jc) of 6.8 × 104 A/cm2 under a zero magnetic field at 2 K. Subsequently, the optimized process was applied to successfully prepare a large-scale Bi2212 HTSF with a diameter of 50 mm, exhibiting uniform phase composition, surface morphology, and superconducting properties, expanding the potential applications of Bi2212 HTSFs.

Comment on "Anisotropic Scattering Caused by Apical Oxygen Vacancies in Thin Films of Overdoped High-Temperature Cuprate Superconductors".

Comment on "Anisotropic Scattering Caused by Apical Oxygen Vacancies in Thin Films of Overdoped High-Temperature Cuprate Superconductors".

Optimization of La2−xSrxCuO4 Single Crystal Film Growth via Molecular Beam Epitaxy

Atomic layer-by-layer molecular beam epitaxy (ALL-MBE) combined with ozone is one of the best methods to fabricate single-crystal thin films of complex oxides. Cuprate such as La2−xSrxCuO4 (LSCO) is a representative complex-oxide high-temperature superconductor (HTS) material. Our group utilizes this method to produce high-quality single-crystal HTS films with atomically smooth surfaces and interfaces. In addition, ALL-MBE enables us to engineer multilayer heterostructures with atomic precision. This allows the fabrication of tunnel junctions, various nanostructures, and other HTS devices of interest for superconducting electronics. We have synthesized over three thousand LSCO thin films in the past two decades. These films’ structural and electronic properties have been studied and characterized by various methods. Here, we distill the extensive experience we accumulated into a step-by-step protocol to fabricate atomically perfect LSCO films. The recipe includes substrate preparation, ozone generation and distillation, source calibration, the in situ monitoring of the film synthesis, post-growth annealing, and ex situ characterization. It discloses a reproducible way to fabricate single-crystal LSCO films for basic research and HTS electronic applications.

A low noise double-sided inductive method for measuring the critical current density of superconducting materials

The critical current density Jc is an important indicator of superconducting materials in practical applications. The third harmonic voltage method is a simple, efficient, and damage-free method for measuring Jc of high-temperature superconducting films. To this end, a double-sided measurement system was hereby proposed to reduce harmonic voltage noise, thereby more effectively measuring the Jc of high-temperature superconducting REBa2Cu3O7-δ (RE, rare earth element) films using the third harmonic voltage method. By integrating the electromagnetic shielding effect and the 2-coil measurement system, this system reduces the harmonic voltage noise in the pickup coil using the Meissner effect, thereby improving the signal-to-noise ratio. The experimental results show that when Jc is measured in the range of 100 Hz to 1000 Hz, the signal-to-noise ratio of the double-sided device increases by 10 dB to 20 dB, higher than that of the 2-coil measurement system. In addition, this new system increases the measurement bandwidth, and makes it possible to conduct low-frequency measurement in the future.

Method to improve critical current density measurement of superconducting materials

The critical current density Jc is an important indicator of superconducting materials in practical applications. And the third harmonic voltage method is a simple, efficient and damage-free method for measuring Jc of high-temperature superconducting films. In order to more effectively measure the Jc of high-temperature superconducting REBa2Cu3O7-δ films and improve the signal-to-noise ratio based on the third harmonic voltage method, a double-sided measurement method was hereby proposed. By integrating the electromagnetic shielding effect and the 2-coil measurement system, the Meissner effect was used to reduce the harmonic voltage noise in the pickup coil. Comparing the double-sided measurement system using the new method to the 2-coil measurement system, the signal-to-noise ratio increases by 10 dB to 20 dB in the case of a Jc measured in the frequency range from 100 Hz to 1000 Hz. The bullet points of the method can be listed as:•The noise in the pickup coil is reduced and the signal-to-noise ratio is improved in the frequency range from 100 Hz to 1000 Hz by using the Meissner effect.•The measurement bandwidth is increased, making it possible to conduct low-frequency measurement in the future by the double-sided measurement method.•The method provides an improvement direction for superconducting thin films with a high critical current density in the future.

A Scenario for the Critical Fluctuations near the Transition of Few-Bilayer Films of High-Temperature Cuprate Superconductors.

We study the critical fluctuations near the resistive transition of very thin films of high-temperature cuprate superconductors composed of a number N of only a few unit cells of superconducting bilayers. For that, we solve the fluctuation spectrum of a Gaussian-Ginzburg-Landau model for few-bilayers superconductors considering two alternating Josephson interlayer interaction strengths, and we obtain the corresponding paraconductivity above the transition. Then, we extend these calculations to temperatures below the transition through expressions for the Ginzburg number and Kosterlitz-Thouless-like critical region. When compared with previously available data in YBa2Cu3O7-δ few-bilayers systems, with N = 1 to 4, our results seem to provide a plausible scenario for their critical regime.

Progress in the Study of Vortex Pinning Centers in High-Temperature Superconducting Films.

Since the discovery of high-temperature superconductors (HTSs), significant progress in the fabrication of HTS films has been achieved. In this review, we intend to provide an overview of recent progress in how and why superconductivity can be enhanced by introducing nanoscale vortex pinning centers. The comprehensive control of morphology, dimension, orientation and concentration of artificial pinning centers (APCs) and the principle of vortex pinning are the focus of this review. According to the existing literature, HTSs with the best superconductivity can be obtained when one-dimensional (1D) and three-dimensional (3D) nanoscale APCs are combined for vortex pinning.

Numerical Optimization of Electromagnet Current Distribution in Superconducting Linear Acceleration System

An enhancement of the acceleration performance of a superconducting linear accelerator when injecting pellets into a helical fusion reactor has been investigated numerically. For this purpose, a numerical code using the finite element method was developed to analyze both the time evolution of a shielding current density in a high-temperature superconductor film and the dynamic motion of the film. In the present study, to optimize the shape of double magnets, a multi-objective optimization problem is solved using the non-dominated sorting genetic Algorithm-II. The results of the computations show that the optimization of the inner electromagnet is more effective in improving the pellet velocity than that of the outer electromagnet. In addition, we found that the pellet speed and energy efficiency have a trade-off relation. Therefore, it is possible to determine the preferred solution for the design of an acceleration magnet, whether focusing on the pellet speed or the energy efficiency. In other words, this relationship can be used to choose whether to emphasize velocity or efficiency in the design of SLA systems.

Performance Improvement of Symmetric Linear System Solver in Shielding Current Analysis of HTS Thin Film: Application of H-Matrix-Based Preconditioner

The conjugate gradient (CG) method with the acceleration technique of using both H-matrix arithmetic and H-matrix-based preconditioning is applied to the linear system that appeared in the shielding current analysis of the uncracked high-temperature superconducting film and its performance is investigated numerically. The computational results show that the proposed acceleration technique is extremely effective for improving the speed of the CG method.

Recent progress on high-temperature superconducting filters

Since the discovery of high temperature superconducting (HTS) materials in 1987, the performance of microwave filters such as insertion loss, selectivity, and out-band rejection has been significantly improved by utilizing HTS films. Nowadays, HTS filters have been widely used in wireless communications, space exploration, satellite communications, and several other fields. HTS filters with a special performance, such as wideband, dual-band or multiband, frequency tunable, and high power-handling capability have been designed and fabricated in recent years to meet the increasing requirements of practical applications and to further extend the application areas. This paper reviews the various types of above-mentioned HTS filters as well as the developments of novel design methodologies.

Synthesis of La2−xSrxCuO4 films via atomic layer-by-layer molecular beam epitaxy

Atomic layer-by-layer molecular beam epitaxy (ALL-MBE) is a sophisticated technique to synthesize high-temperature superconductor (HTS) materials. ALL-MBE produces single-crystal HTS films with atomically smooth surfaces and interfaces, as well as precise multilayer heterostructures engineered down to a single atomic layer level. This enables the fabrication of tunnel junctions, nanowires, nanorings, and other HTS devices of interest. Our group has focused on ALL-MBE synthesis and materials science of La2−xSrxCuO4 (LSCO), a representative HTS cuprate. In the past two decades, we have synthesized over three thousand LSCO thin films and characterized them by a range of analytical techniques. Here, we present in full detail a systematic process for the synthesis and engineering of atomically perfect LSCO films. The procedure includes the preparation of substrates, calibration of the elemental sources, the recipe for ALL growth of LSCO films without any secondary-phase precipitates, post-growth annealing of the films, and ex situ film characterization. This report should aid replication and dissemination of this technique of synthesizing single-crystal LSCO films for basic research as well as for HTS electronic applications.

Chemical Solution Deposition of Insulating Yttria Nanolayers as Current Flow Diverter in Superconducting GdBa2Cu3O7-δ Coated Conductors.

The primary benefit of a metallic stabilization/shunt in high temperature superconductor (HTS) coated conductors (CCs) is to prevent joule heating damage by providing an alternative path for the current flow during the HTS normal state transition (i.e., quench). However, the shunt presence in combination with unavoidable fluctuations in the critical current (Ic) of the HTS film can develop a localized quench along the CC’s length if the operational current is kept close to Ic. This scenario, also known as the hot-spot regime, can lead to the rupture of the CC if the local quench does not propagate fast enough. The current flow diverter (CFD) is the CC architecture concept that has proven to increase the conductor’s robustness against a hot-spot regime by simply boosting the quench velocity in the CC, which avoids the shunt compromise in some applications. This work investigates a practical manufacturing route for incorporating the CFD architecture in a reel-to-reel system via the preparation of yttrium oxide (Y2O3) as an insulating thin nanolayer (∼100 nm) on top of a GdBa2Cu3O7 (GdBCO) superconductor. Chemical solution deposition (CSD) using ink jet printing (IJP) is shown to be a suitable manufacturing approach. Two sequences of the experimental steps have been investigated, where oxygenation of the GdBCO layer is performed after or before the solution deposition and the Y2O3 nanolayer thermal treatment formation step. A correlated analysis of the microstructure, in situ oxygenation kinetics, and superconducting properties of the Ag/Y2O3/GdBCO trilayer processed under different conditions shows that a new customized functional CC can be prepared. The successful achievement of the CFD effect in the case of the preoxygenated customized CC was confirmed by measuring the current transfer length, thus demonstrating the effectiveness of the CSD-IJP as a processing method.

Anisotropic Scattering Caused by Apical Oxygen Vacancies in Thin Films of Overdoped High-Temperature Cuprate Superconductors.

There is a hot debate on the anomalous behavior of superfluid density ρ_{s} in overdoped La_{2-x}Sr_{x}CuO_{4} films in recent years. The linear drop of ρ_{s} at low temperatures implies the superconductors are clean, but the linear scaling between ρ_{s} (in the zero temperature limit) and the transition temperature T_{c} is a hallmark of the dirty limit in the Bardeen-Cooper-Schrieffer (BCS) framework [I. Bozovic etal., Nature (London) 536, 309 (2016)NATUAS0028-083610.1038/nature19061]. This dichotomy motivated exotic theories beyond the standard BCS theory. We show, however, that such a dichotomy can be reconciled naturally by the role of increasing anisotropic scattering caused by the apical oxygen vacancies. Furthermore, the anisotropic scattering also explains the "missing" Drude weight upon doping in the optical conductivity, as reported in the THz experiment [F. Mahmood etal., Phys. Rev. Lett. 122, 027003 (2019)PRLTAO0031-900710.1103/PhysRevLett.122.027003]. Therefore, the overdoped cuprates can actually be described consistently by the d-wave BCS theory with the unique anisotropic scattering.

Fabrication and transport properties of two dimensional Bi2Sr2Ca2Cu3O10+δ micro-bridge

Ultra-thin high-temperature superconducting films have attracted continuous interest due to their potential electronic applications, which also provide a unique platform of novel physics and properties in the two-dimensional limit. We, here, realized fabrication of two-unit-cell-thick micro-bridges from mechanically exfoliated ultra-thin Bi2Sr2Ca2Cu3O10+δ (Bi2223) single crystals and systematically investigated their transport properties. The two-dimensional superconducting nature is verified by the existence of the Berezinskii–Kosterlitz–Thouless transition, which is simultaneously revealed by current-voltage properties and the zero-field temperature dependence of resistance. Comparing with Bi2223 bulk crystal, a Bi2223 micro-bridge shows a slight lower upper critical field but pronounced improvement in the critical current density. Our findings indicate that the ultra-thin Bi2223 single crystal is highly prospective for both scientific investigations of unconventional superconductivity and applications of high Tc superconducting devices.

Determining the temperature-dependent London penetration depth in HTS thin films and its effect on SQUID performance

The optimum design of high-sensitivity Superconducting Quantum Interference Devices (SQUIDs) and other devices based on thin high-temperature superconductor (HTS) films requires accurate inductance modeling. This needs the London penetration depth λ to be well defined, not only at 77 K, but also for any operating temperature, given the increasingly widespread use of miniature low-noise single-stage cryocoolers. Temperature significantly affects all inductances in any active superconducting device, and cooling below 77 K can greatly improve device performance; however, accurate data for the temperature dependence of inductance and λ(T) for HTS devices are largely missing in the literature. We report here inductance measurements on a set of 20 different thin-film YBa2Cu3O7−x SQUIDs at 77 K with thickness t = 220 or 113 nm. By combining experimental data and inductance modeling, we find an average penetration depth λ(77)=391 nm at 77 K, which was independent of t. Using the same methods, we derive an empirical expression for λ(T) for a further three SQUIDs measured on a cryocooler from 50 to 79 K. Our measured value of λ(77) and our inductance extraction procedures were then used to estimate the inductances and the effective areas of directly coupled SQUID magnetometers with large washer-style pickup loops. The latter agrees better than 7% with experimentally measured values, validating our measured value of λ(77) and our inductance extraction methods.