High Temperature Proton Exchange Research Articles

Independent Analysis of Real-Time, Measured Performance Data From Microcogenerative Fuel Cell Systems Installed in Buildings

Pacific Northwest National Laboratory (PNNL) is working with industry to independently monitor up to 15 distinct 5 kW-electric (kWe) combined heat and power (CHP) high temperature (HT) proton exchange membrane (PEM) fuel cell systems (FCSs) installed in light commercial buildings. This research paper discusses an evaluation of the first six months of measured performance data acquired at a 1 s sampling rate from real-time monitoring equipment attached to the FCSs at building sites. Engineering performance parameters are independently evaluated. Based on an analysis of the first few months of measured operating data, FCS performance is consistent with manufacturer-stated performance. Initial data indicate that the FCSs have relatively stable performance and a long-term average production of about 4.57 kWe of power. This value is consistent with, but slightly below, the manufacturer's stated rated electric power output of 5 kWe. The measured system net electric efficiency has averaged 33.7%, based on the higher heating value (HHV) of natural gas fuel. This value, also, is consistent with, but slightly below, the manufacturer's stated rated electric efficiency of 36%. The FCSs provide low-grade hot water to the building at a measured average temperature of about 48.4 °C, lower than the manufacturer's stated maximum hot water delivery temperature of 65 °C. The uptime of the systems is also evaluated. System availability can be defined as the quotient of total operating time compared to time since commissioning. The average values for system availability vary between 96.1 and 97.3%, depending on the FCS evaluated in the field. Performance at rated value for electrical efficiency (PRVeff) can be defined as the quotient of the system time operating at or above the rated electric efficiency and the time since commissioning. The PRVeff varies between 5.6% and 31.6%, depending on the FCS field unit evaluated. Performance at rated value for electrical power (PRVp) can be defined as the quotient of the system time operating at or above the rated electric power and the time since commissioning. PRVp varies between 6.5% and 16.2%. Performance at rated value for electrical efficiency and power (PRVt) can be defined as the quotient of the system time operating at or above both the rated electric efficiency and the electric power output compared to the time since commissioning. PRVt varies between 0.2% and 1.4%. Optimization to determine the manufacturer rating required to achieve PRVt greater than 80% has been performed based on the collected data. For example, for FCS Unit 130 to achieve a PRVt of 95%, it would have to be down-rated to an electrical power output of 3.2 kWe and an electrical efficiency of 29%. The use of PRV as an assessment metric for FCSs has been developed and reported for the first time in this paper. For FCS Unit 130, a maximum decline in electric power output of approximately 18% was observed over a 500 h period in Jan. 2012.

고온 양자교환법으로 제작된 LiNbO3도파로의 굴절률 분포

저손실의 높은 편광 소멸비를 갖는 LiNbO<TEX>$_3$</TEX> 도파로를 만들기 위하여 고온 양자교환 방법을 이용하였다. 이 방법으로 제작된 도파로의 굴절률 특성을 분석하기 위하여 프리즘 결합기 방법으로 도파 모드를 측정하고 IWKB(inverse WKB) 방법을 사용하여 표면 굴절률 변화와 깊이에 대한 굴절률 분포 특성을 관찰하였다. 이러한 방법으로 고온 양자교환법의 주요 인자인 양자교환 온도, LS 농도, 양자교환 시간에 대한 굴절률 변화를 분석하였다. The high temperature proton exchange (HTPE) method was used to fabricate optical waveguides based on LiNbO<TEX>$_3$</TEX>, which gives rise to low propagation loss and high polarization extinction ratio. To characterize the refractive index distribution of the fabricated waveguides, the guided modes of each waveguide were observed using the prism coupling method and then the refractive index profile was calculated by the inverse WKB method with the least square fitting. Finally, we showed how the HTPE parameters such as the temperature of PE, the concentration of lithium additive, and the time of PE effect the refractive index profile.

LiNbO/sub 3/ optical waveguide fabrication by high-temperature proton exchange

An efficient method, the high-temperature proton exchange (HTPE), to fabricate high-quality LiNbO/sub 3/ optical waveguides is studied. The new proton exchange source, the stearic acid diluted by lithium stearate, is proposed for HTPE process. The known soft proton exchange (SPE) process can be realized by HTPE. There are no phase transitions when the /spl alpha/-phase waveguides are fabricated by SPE. This phase presents the same crystalline structure as that of LiNbO/sub 3/ and, as expected, maintains the excellent nonlinear and electrooptical properties of the bulk material. The kinetics of HTPE is studied.