High-temperature Resistance Research Articles

Investigations of the Interface Design of Polyetheretherketone Filament Yarn Considering Plasma Torch Treatment

Taking advantage of its high-temperature resistance and elongation properties, conductive-coated polyetheretherketone (PEEK) filament yarn can be used as a textile-based electroconductive functional element, in particular as a strain sensor. This study describes the development of electrical conductivity on an inert PEEK filament surface by the deposition of metallic nickel (Ni) layers via an electroless galvanic plating process. To enhance the adhesion properties of the nickel layer, both PEEK multifilament and monofilament yarn surfaces were metalized by plasma torch pretreatment, followed by nickel plating. Electrical characterizations indicate the potential of nickel-coated PEEK for structural monitoring in textile-reinforced composites. In addition, surface energy measurements before and after plasma torch pretreatment, surface morphology, nickel layer thickness, chemical structure changes, and mechanical properties were analyzed and compared with untreated PEEK. The thickness of the Ni layer was measured and showed an average thickness of 1.25 µm for the multifilament yarn and 3.36 µm for the monofilament yarn. FTIR analysis confirmed the presence of new functional groups on the PEEK surface after plasma torch pretreatment, indicating a successful modification of the surface chemistry. Mechanical testing showed an increase in tensile strength after plasma torch pretreatment but a decrease after nickel plating. In conclusion, this study successfully developed conductive PEEK yarns through plasma torch pretreatment and nickel plating.

Microstructural and mechanical investigation of dissimilar U-groove weld of IN 718/ASS 304L employing ERNiCr-3 filler

This study investigates the dissimilar welding of Inconel 718 (IN 718) and austenitic stainless steel 304L (ASS 304L) using Gas Tungsten Arc Welding (GTAW) with Ni-based filler ERNiCr-3. IN 718 is valued for its high-temperature stability, oxidation, and corrosion resistance, while ASS 304L offers excellent ductility, formability, and corrosion resistance. The objective is to evaluate the impact of ERNiCr-3 on the weld’s metallurgical and mechanical attributes. The materials, prepared with U-groove edges, were optimized for manual multi-pass welding. Microstructural analysis revealed an austenitic matrix with dispersed Ti(CN) and NbC precipitates, enhancing strength through dispersion-strengthening mechanisms, with no solidification cracking due to Nb presence. FESEM/EDS and colour mapping identified elemental migration and stable carbide formation at the weld interfaces. Mechanical testing revealed uniform hardness within the weld zone and tensile resistance of 510 MPa, underscoring the robustness of ERNiCr-3 weld metal. These results indicate that ERNiCr-3 is highly effective for producing superior quality dissimilar welds amidst IN 718/ASS 304L, making it suitable for applications in elevated-temperature and mechanically demanding environments.

Ultra-Efficient Heat Transport Across a "2.5D" All-Carbon sp2/sp3 Hybrid Interface.

Single- and few-layer graphene-based thermal interface materials (TIMs) with extraordinary high-temperature resistance and ultra-high thermal conductivity are very essential to develop the next-generation integrated circuits. However, the function of the as-prepared graphene-based TIMs would undergo severe degradation when being transferred to chips, as the interface between the TIMs and chips possesses a very small interfacial thermal conductance. Here, a "2.5D" all-carbon interface containing rich covalent bonding, namely a sp2/sp3 hybrid interfaces is designed and realized by a plasma-assisted chemical vapor deposition with a function of ultra-rapid quenching. The interfacial thermal conductance of the 2.5D interface is excitingly very high, up to 110-117 MWm-2 K-1 at graphene thickness of 12-25 nm, which is even more than 30 % higher than various metal/diamond contacts, and orders of magnitude higher than the existing all-carbon contacts. Atomic-level simulation confirm the key role of the efficient heat conduction via covalent C-C bonds, and reveal that the covalent-based heat transport could contribute 85 % to the total interfacial conduction at a hybridization degree of 22 at %. This study provides an efficient strategy to design and construct 2.5D all-carbon interfaces, which can be used to develop high performance all-carbon devices and circuits.

Research Progress on the Relationship Between Microstructure and Properties of AISI 321 Stainless Steel

AISI 321 stainless steel is widely used in chemical pipelines and nuclear power, prompting research on its high-temperature performance and corrosion resistance. This review focuses on the effects of alloy elements, second-phase particle formation, and heat treatment processes on the microstructure and properties of AISI 321 stainless steel. Fine tuning of alloying elements can affect the mode and effect of dynamic recrystallization, altering the high-temperature flow deformation of AISI 321 stainless steel. In order to achieve phase equilibrium, the relationship between corrosion resistance and high-temperature creep behavior and high-temperature mechanical behavior in the presence of second-phase particles was also analyzed. This review outlines the basic heat treatment procedures for improving material properties, providing a new perspective for solution treatment and improving corrosion resistance. In addition, the latest research progress on other factors affecting the high-temperature performance of AISI 321, such as coatings, was briefly introduced.

First Principles Calculation of the Influence of Alloying on the Phase Stability, Elasticity, and Thermodynamic Properties of the MoNbTiVX (X = Al/Cr) Refractory High-Entropy Alloy

In response to the poor wear resistance and high-temperature oxidation resistance of titanium alloys during service, a series of lightweight refractory high-entropy alloys (RHEAs) can be designed for the laser cladding coating of titanium alloy surfaces, with due consideration of the compositional and structural characteristics of titanium alloys. Firstly, the structural stability, mechanical and thermal properties of four lightweight RHEAs (MoNbTiV, AlMoNbTiW, CrMoNbTiV, and AlCrMoNbTiV) with equal atomic ratios were designed and calculated using first principles combined with quasi-harmonic approximation (QHA). The results indicate that all four RHEAs are stable BCC, exhibiting elastic anisotropy and ductility. The lightest density is 6.409 g/cm3. Adding Al/Cr can cause structural distortion and affect its mechanical properties. Their Young’s moduli are in the following order: AlCrMoNbTiV > MoNbTiV > CrMoNbTiV > AlMoNbTiV. The thermal expansion coefficients of the four RHEAs and titanium alloys are very close, with a difference in linear expansion coefficient of less than 1.16 × 10−5/K. Meanwhile, the metallurgical bonding of four types of RHEA coatings was successfully achieved on a Ti-6Al-4V(TC4) substrate through laser cladding technology, and all coatings exhibited a unique BCC solid solution phase.

PlFabG improves high-temperature resistance in herbaceous peony by increasing saturated fatty acids

The herbaceous peony (Paeonia lactiflora Pall.) is renowned for its striking flowers, which are highly valued in the cut flower industry. However, in the middle and lower reaches of the Yangtze River, the elevated summer temperatures negatively affect the plant's flowering capacity in the subsequent year. 3-oxoacyl-ACP reductase (FabG) is a component of the type II fatty acid synthesis (FAS II) system, where it plays a role in facilitating the production of saturated fatty acids. However, its role in conferring resistance to high-temperature stress remains unclear. In order to investigate the function of PlFabG in dealing with high-temperature stress, we isolated PlFabG from P. lactiflora. The gene contains an open reading frame (ORF) of 780 bp, which encodes 259 amino acids. Quantitative real-time PCR (qRT-PCR) analysis showed that the expression levels of PlFabG increased with prolonged exposure to high temperature. Additionally, plants overexpressing PlFabG maintained a relatively healthy phenotype under high-temperature stress, whereas plants with silencing PlFabG exhibited more severe leaf scorching and wilting under the same conditions. Various physiological indices indicated that PlFabG reduced reactive oxygen species (ROS) accumulation and enhanced the saturation of photosystem II. Most importantly, PlFabG helped P. lactiflora withstand high-temperature stress by increasing the proportion of saturated fatty acids, thereby maintaining cell membrane integrity. These findings elucidate the beneficial role of PlFabG in enhancing plant tolerance to high temperature and provide a strong theoretical support for the development of high-temperature tolerance in transgenic P. lactiflora.

Effect of quaternary binder slag-based geopolymer slurries on mechanical durability and microstructural properties of green prepacked composites

This study conducts a detailed investigation into the effects of slag-based quaternary binder geopolymer slurries on the physico-mechanical properties, high temperature resistance, and microstructural characteristics of prepacked composites. This research employs a strategic combination of aluminosilicate precursors, including metakaolin (MK), pumice powder (Pum), and perlite powder (Per), which are blended with slag in varying mix proportion to identify and optimizing the composite’s performance. In the key finding reveal that samples containing 20 % of MK achieved superior performance, displaying the lowest porosity and water absorption rates. The oven-dry density of the mixtures demonstrated a marked improvement with the inclusion of MK, increasing from a range of 2150–2230 kg/m3 in 0 % MK mixture to 2250–2350 kg/m3 in those with 20 % MK. Post heat curing, the compressive strength peaked at 31.12 MPa in the mixture comprising 20 % MK, 20 % pumice, and 10 % perlite; however, this strength reduced to 11.92 MPa when subjected to a temperature of 600℃. In high temperature resistance tests, the combination of 20 % MK and 10 % perlite resulted in a minimal mass loss of 4 % at 600℃, indicating a robust resistance to thermal degradation. Furthermore, the 24-h water capillary absorption displaying lowest water absorption rates. This study provides a critical advancement in the use of natural pozzolans for developing high-performance, slag based geopolymer slurries. The enhanced high-temperature strength and reduced water absorption underscore the potential of these materials to deliver durable and sustainable solution for the construction industry, particularly in application requiring superior thermal resistance and longevity.

Road Performance of Cold Repaired Asphalt Mixture with New Green Maintenance Materials

Cold patched asphalt mixture plays a crucial role in road maintenance, providing flexibility and the ability to quickly recover from harsh weather conditions. This article conducts in-depth research on the performance of cold patched asphalt mixture through multiple experiments, with special attention paid to the influence of diluent content and curing conditions on its performance. The experimental results show that using a mixture of green curing agents is feasible, and the diluent content is one of the main factors affecting the physical properties of cold patched asphalt. The optimal content of asphalt diluent was determined to be 25% through mass evaporation experiments and rotational viscosity experiments. Meanwhile, it was found that single component polyurethane prepolymers and SBS curing agents have a negative impact on the adhesion of cold patched asphalt, but have an improving effect on its strength, high-temperature resistance, and water stability. After comparing the performance of cold patched asphalt mixtures under different curing conditions, it was found that the performance of cold patched materials with long-term curing was better. Finally, this study determined the optimal dosage ratio of base asphalt, bio oil diluent, and single component polyurethane prepolymer as 100:25:12, providing technical support for the design and application of cold patched asphalt concrete pavement under high adverse weather conditions.

A Remote Monitoring System for Wind Speed and Direction Based on Non-Contact Triboelectric Nanogenerator

Wind speed and wind direction sensors are crucial sensor categories in the Internet of Things (IoT), particularly vital in fields such as meteorological monitoring, construction engineering, transportation engineering, and ocean engineering. However, power supply remains a key limiting factor for the widespread application of these sensors in large-scale sensor networks. In this paper, a self-powered, non-contact wind speed and direction sensor based on the triboelectric nanogenerator (SD-TENG) is proposed. The optimized wind speed measurement structure has a start-up wind speed as low as 0.2m/s and exhibits good linearity in the range of 0.2-29m/s. Additionally, the sensor demonstrates high temperature and humidity resistance, with a voltage attenuation of 2.4% at 45°C ambient temperature and 9.8% at 95% relative humidity. For wind direction measurement, the design of non-uniform electrodes enhances the recognition capability of different channels. To meet the demands of remote monitoring, we have designed an advanced signal processing circuit that can directly convert the raw output of a wind speed sensor into wind speed information and upload it to a cloud platform via a host. This system not only records and displays wind speed data in real-time but also features historical data storage and alarm functionalities, enhancing the intelligence and automation levels of wind speed monitoring. Additionally, users can access and analyze wind speed data through both computer and mobile devices, ensuring the system's efficiency and reliability. This work provides crucial technical support for the advancement of smart cities, clean energy, and environmental monitoring, thereby promoting the application and dissemination of IoT technology in the environmental field.

Performance Restoration of Aged SBS-Modified Asphalt in RAP via Dry-Process SBS modifier Diffusion at the Interface of Aggregate-Aged Asphalt-Virgin Asphalt

To address and recycle more RAP (Reclaimed Asphalt Pavement), dry-process SBS(Styrene-Butadiene-Styrene) modifier was applied in hot in-place recycling. Molecular simulation and laboratory experiments were conducted to investigate the diffusion behavior of dry-process SBS modifier on RAP surfaces and its effects on the properties of recycled asphalt and recycled asphalt mixtures (RAM). Molecular simulation results revealed that after the diffusion of dry-process SBS on RAP surfaces, the fractured and aged SBS molecules in the aged asphalt were replenished, leading to a 59.49% enhancement in the interface energy between aged asphalt and aggregates. Dry-process SBS exhibited bidirectional diffusion between RAP and virgin asphalt, with a preference for the intact SARA components of Virgin asphalt. The diffusion coefficient of the dry-process recycling system was significantly higher compared to conventional wet-process recycling, achieving a higher degree of fusion (DOB) between virgin and aged asphalt. Laboratory experiments demonstrated that dry-process recycling was more effective in restoring the performance of aged SBS-modified asphalt compared to wet-process recycling. At high RAP contents (80%, 100%), the asphalt mixtures from wet-process recycling failed to meet specifications for high-temperature permanent deformation resistance, low-temperature cracking resistance, and resistance to water damage. However, using 10% dry-process SBS modifier by mass of aged asphalt in RAP enabled 100% RAP content asphalt mixtures to meet specifications.

Efficient carburization of high-entropy alloys from polyethylene microplastics using a green mechanochemical process to obtain excellent wave absorbing performance

Polyethylene as a major white pollutant has a significant negative impact on the environment and the human health. Beneficial recycling of polyethylene through mechanochemical processes not only can eliminate environmental hazards, but also enable some beneficial industrial applications. In this work, polyethylene was used as the raw materials of carburization of FeCoNiMn high-entropy alloys (HEAs) by a green mechanochemical method. The phase structure, magnetic properties, high-temperature oxidation resistance, corrosion resistance and electromagnetic-wave absorbing performance of the obtained carburized HEAs were investigated in detail. The carburized-FeCoNiMn HEAs exhibited excellent corrosion resistance, suggesting great application potential for use in harsh environments. Besides, the impedance matching was optimized and the electromagnetic-wave absorption bandwidth was expanded by this carburization process. Specifically, the reflection loss of C10 (FeCoNiMnC0.1) at 8.88 GHz reached −65.07 dB at a thickness of 2.79 mm, and both the C50 (FeCoNiMnC0.5) and C90 (FeCoNiMnC0.9) exhibited a maximum absorption bandwidth of 5.45 GHz. This work provides a new concept of utilizing common microplastic pollutants to achieve efficient carburization of HEAs by a green mechanochemical process.

Rheological Properties and Modification Mechanism of Emulsified Asphalt Modified with Waterborne Epoxy/Polyurethan Composite

In research aimed at improving the brittleness of WER (waterborne epoxy)-modified emulsified asphalt, commonly encountered issues are that the low-temperature performance of this type of asphalt becomes insufficient and the long curing time leads to low early strength. Matrix-emulsified asphalt was modified with WPU (waterborne polyurethane), WER, and DMP-30 (accelerator). Firstly, the performance changes of modified emulsified asphalt at different single-factor dosages were explored through conventional performance tests and assessments of its adhesion, tensile properties, and curing time. Secondly, based on a response surface methodology test design, the material composition of the composite-modified emulsified asphalt was optimized, and its rheological properties were analyzed by a DSR test and a force–ductility test. Finally, the modification mechanism was explored by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The results show that WER can improve the adhesion strength of modified emulsified asphalt and greatly reduce elongation at break. WPU can effectively improve the elongation at break of composite-modified emulsified asphalt, but it has a negative impact on adhesion strength. DMP-30 mainly affects the curing time of modified emulsified asphalt; EPD (composite modification) can effectively improve the high-temperature rutting resistance of matrix-emulsified asphalt, and its low-temperature performance is significantly improved compared with WER-modified emulsified asphalt. The EPD modification process mainly consists of physical blending. In the case of increasing the curing rate, it is recommended that the contents of WER and WPU be lower than 10% and 6%, respectively, to achieve excellent comprehensive performance of the composite modification.

Effect of laser cladding layers on microstructure and mechanical properties of NiCoCrAlY bond coat

The NiCoCrAlY alloy is usually used as a bonding layer material in thermal barrier coatings (TBCs) system. Owing its excellent high-temperature oxidation resistance and corrosion resistance, it plays a crucial role in maintaining the structural integrity and functionality of TBCs. Laser cladding technology is a flexible and efficient processing technique for the manufacturing of NiCoCrAlY bond coat, with the characteristics of precisely control the layers of the laser cladding and further modulate the quality of the bond coat. Therefore, the investigation on the influence of cladding layers on the microstructure and mechanical properties of the bond coat is of great significance for improving the service performance and lifetime of aircraft engines. To this end, the scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and X-ray diffraction (XRD) were used in this study to explore the influence of cladding layers on the microstructure and mechanical properties of the NiCrAlCoY bond coat. The results indicate that the microstructure of the cladded alloy can be divided into substrate, heat-affected zone, and cladded zone. The hardness of both the heat-affected zone and the cladded zone increases as the number of cladding layers increases, while the hardness of the substrate maintains constant. In addition, as the number of laser cladding layers increases, so does the residual stress of the cladded alloy.

Enhancing high-temperature wear resistance of plasma-sprayed NiCrBSi coatings with nanodiamond reinforcement

High-temperature wear causes industrial components to degrade quickly, leading to reduced efficiency, frequent breakdowns, and costly repairs. Thermal spraying is a surface modification technique employed to address these wear issues by shielding the component using protective coatings. In this study, the high-temperature wear behavior of plasma-sprayed NiCrBSi coatings reinforced with Nanodiamond (ND) particles was systematically evaluated. The coatings were reinforced with 1 wt% and 2 wt% ND, and their tribological performance was assessed under varying thermal conditions. Tribological tests were conducted using a ball-on-disk setup at elevated temperatures of 473 K, 673 K, and 873 K for 60 min. The experimental results demonstrated a significant improvement in the wear response and frictional characteristics of the NiCrBSi coatings with the incorporation of ND particles. Specifically, the NiCrBSi coating reinforced with 2 wt% ND exhibited a significantly lower wear volume loss and a reduced coefficient of friction when compared to the pure NiCrBSi coating. At 873 K, the NiCrBSi-2ND coating demonstrated a 64 % reduction in wear volume loss and 85 % decrease in the coefficient of friction, compared to the pure NiCrBSi coating. The incorporation of NDs greatly enhanced the lubrication and hardness of the NiCrBSi-2ND coating as well as improved the adhesion of wear debris to the newly exposed wear track. The high thermal conductivity of NDs enhanced heat transfer to the coatings, facilitating the formation of a protective tribo layer at elevated temperatures, which improved the wear resistance of the NiCrBSi-2ND coating. These findings underscore the potential of ND as a reinforcing agent to significantly enhance the durability and efficiency of NiCrBSi coatings in extreme thermal environments.

High-temperature crack resistance of yttria-stabilized zirconia coatings enhanced by interfacial stress transfer

High-temperature crack resistance of yttria-stabilized zirconia coatings enhanced by interfacial stress transfer

Thrombin Immobilized on Magnetic Core-Shell Mesoporous Silica Nanoparticles for Screening of the Enzyme Inhibitors From Notopterygium Incisum.

Thrombin was immobilized on magnetic core-shell mesoporous silica nanoparticles (Fe3O4@nSiO2@mSiO2) for the first time and used to screen enzyme inhibitors from extracts of Notopterygium incisum. The immobilized thrombin was characterized by Fourier-transform infrared spectroscopy, transmission electronic microscopy, thermal gravimetric analysis, and vibrating sample magnetometry. The results demonstrated that the immobilized thrombin possessed good thermal stability and high-temperature resistance for feasible storage and reuse. Two ligands, notopterol (1) and isoimperatorin (2) were fished out from the extract of N. incisum using the immobilized thrombin. They inhibited thrombin with IC50 values of 59.35±1.420 and 107.8±1.660µM, respectively. This is the first report of thrombin-inhibitory activity associated with notopterol and isoimperatorin. Meanwhile, the inhibition mechanism of both compounds was investigated by enzyme kinetic analysis and molecular docking. The method used enables rapid screening for thrombin inhibitors from medicinal plants, providing an efficient tool for the discovery of anti-thrombotic active compounds.

Analysis of bio-based epoxy resins: Impact of amine hardeners on thermal, thermomechanical, optical and electrical properties of epoxidized resveratrol with high Tg

Epoxidized resveratrol (RES) has been cured with different amines in order to compare their possibilities to obtain high-temperature resistance of bio-based epoxy resins. Materials obtained from the bio-based monomer present glass transition temperatures (Tg) among the highest ever reported for an epoxy-amine curing system, with extremely high char residue, making them excellent candidates for extremely high-temperature applications. Particularly, epoxidized RES stoichiometrically cured with 4,4′-sulfonyldianiline (DDS) reached 297 °C, measured as the tan δ peak by DMTA, and two other materials, using 4,4′-methylenedianiline (DDM) and 4,4′-diaminodicyclohexylmethane (CAA) as curing agents, exceeded 300 °C. In fact, the material begins to degrade before the chains are fully relaxed, so they are thermosetting that never go completely into the rubbery state. Additionally, this resin improves the direct current (DC) insulating character (~1015 Ωcm) while decreasing the optical band gap (~2 eV) when compared to other epoxy resins available, which is of great interest for photovoltaic applications. Moreover, some of the materials presented a very high char residue proportion when heated (>40 wt% at 800 °C under nitrogen atmosphere), presenting good fire-retardant properties.

Microstructure Refinement of Bulk Inconel 718 Parts During Fabrication with EB-PBF Using Scanning Strategies: Transition from Bidirectional-Raster to Stochastic Point-Based Melting

Inconel 718 is a widely popular aerospace superalloy known for its high-temperature performance and resistance to oxidation, creep, and corrosion. Traditional manufacturing methods, like casting and powder metallurgy, face challenges with intricate shapes that can result in porosity and uniformity issues. On the other hand, Additive Manufacturing (AM) techniques such as Powder Bed Fusion (PBF) and Direct Energy Deposition (DED) can allow the creation of intricate single-part components to reduce weight and maintain structural integrity. However, AM parts often exhibit directional solidification, leading to anisotropic properties and potential crack propagation sites. To address this, post-processing treatments like HIP and heat treatment are necessary. This study explores the effects of the raster and stochastic spot melt scanning strategies on the microstructural and mechanical properties of IN718 parts fabricated using Electron Beam Powder Bed Fusion (EB-PBF). This research demonstrates that raster scanning produces columnar grains with higher mean aspect ratios. Stochastic spot melt scanning facilitates the formation of equiaxed grains, which enhances microstructural refinement and lowers anisotropy. The highest microstructural values were recorded in the raster-produced columnar grain structure. Conversely, the stochastic melt-produced transition from columnar to equiaxed grain structure demonstrated increased hardness with decreasing grain size; however, the hardness of the smallest equiaxed grain structure was slightly less than that of the columnar grain structure. These findings underscore the vital importance of scanning strategies in optimizing the EB-PBF process to enhance material properties.

Enhancing thermo-mechanical and moisture properties of 3D-Printed concrete through recycled ultra-fine waste glass powder

This paper presents a novel approach to enhancing 3D printed concrete (3DPC) by incorporating ultra-fine glass powder (UFGP), focusing on its mechanical properties and high-temperature resistance. Investigation like fresh properties, basic physical properties, residual compressive strength after exposure to 400 °C and 800 °C, hygric properties such as water vapor diffusion resistance, liquid water transport, and moisture buffering capacity were performed the observe the effect of UFGP replacement ratio on 3DPC, which demonstrates significant improvements, highlighting the potential of UFGP to elevate 3DPCs’ performance. Results showed significant improvements, particularly with a 20% UFGP mix, which showed the lowest compressive strength loss (9.0% at 400 °C and 53.7% at 800 °C). Additionally, the water vapor diffusion resistance factor for the 20% UFGP mix was measured at 65.03. These results suggest that incorporating UFGP in 3DPC enhances thermal resilience and mechanical properties, offering a solution for high-temperature construction. This study contributes to sustainable construction by emphasizing the importance of mechanical resilience for structural integrity under extreme temperatures.

Towards a sustainable thermodynamic optimization solution for preparing unburned low-carbon bricks from low-activity tailings

Basalt tailings, as an important type of solid waste in the mining industry and quarries, are mainly stacked in the open air or buried, causing huge potential harm to the environment and society. In this work, we propose a sustainable and promising utilization method for such low alkali activated tailings. A thermodynamic optimization solution and a design model for unburned low-carbon bricks composed entirely of solid waste were established, and the macro-microscopic mechanisms of hydrate formation and durability were comprehensively analyzed. Firstly, the thermodynamic reaction kinetics of the full chemical composition of basalt tailings modulated by fly ash were used to investigate the effects of different reaction material ratios on hydration products. Then, a new optimization design method of chemical thermodynamics model of alkali excitation was proposed. Further, the hydration mechanism of geopolymer was qualitatively and quantitatively analyzed via test of mechanics, XRD, FTIR, SEM and AFM. The calculation results were very consistent with experimental research, and the basalt-based fly ash-modulated geopolymer brick through optimization met the requirements of durability, especially from the viewpoint of excellent high-temperature resistance. Finally, the life cycle assessment (LCA) method was adopted to analyze the carbon emission reduction potential of current eco-friendly bricks. The carbon emissions were approximately 15.6 % of that of sintered shale hollow bricks and 19.4 % of that of aerated concrete building blocks. Thermodynamic optimization design of alkali activated low-activity tailings unburned bricks technology is one-stone-for-two-birds strategy, which can effectively optimize the process of making bricks from tailings.