High-temperature Behavior Research Articles

High-Temperature Oxidation and Phase Stability of AlCrCoFeNi High Entropy Alloy: Insights from In Situ HT-XRD and Thermodynamic Calculations.

The high-temperature oxidation behaviour and phase stability of equi-atomic high entropy AlCrCoFeNi alloy (HEA) were studied using in situ high-temperature X-ray diffraction (HTXRD) combined with ThermoCalc thermodynamic calculation. HTXRD analyses reveal the formation of B2, BCC, Sigma and FCC, phases at different temperatures, with significant phase transitions observed at intermediate temperatures from 600 °C-100 °C. ThermoCalc predicted phase diagram closely matched with in situ HTXRD findings highlighting minor differences in phase transformation temperature. ThermoCalc predictions of oxides provide insights into the formation of stable oxide phases, predominantly spinel-type oxides, at high p(O2), while a lower volume of halite was predicted, and minor increase observed with increasing temperature. The oxidation behaviour was strongly dependent on the environment, with the vacuum condition favouring the formation of a thin, Al2O3 protective layer, while in atmospheric conditions a thick, double-layered oxide scale of Al2O3 and Cr2O3 formed. The formation of oxide scale was determined by selective oxidation of Al and Cr, as further confirmed by EDX analysis. The formation of thick oxide in air environment resulted in a thick layer of Al-depleted FFC phase. This comprehensive study explains the high-temperature phase stability and time-temperature-dependent oxidation mechanisms of AlCrCoFeNi HEA. The interplay between surface phase transformation beneath oxide scale and oxides is also detailed herein, contributing to further development and optimisation of HEA for high temperature applications.

The effect of TiSi2 healing improver in self-healing ability of ceramics

A method to enhance the temperature range in which continuous self-healing fiber-reinforced ceramics (shFRCs) can self-heal is proposed to obtain a new high-temperature structural material. The effect of TiSi2 oxidation on self-healing was investigated using SiC, a typical self-healing agent, and TiSi2, which oxidizes at a lower temperature than SiC. Mixtures of SiC and TiSi2 powders were prepared by wet-mixing, and changes in their high-temperature oxidation behavior were investigated using thermogravimetry/differential thermal analysis. The oxidation of TiSi2 at 1000 °C enhanced the oxidation rate of SiC by 2–3 times. A shFRC consisting of an Al2O3 matrix, an interface layer of SiC and TiSi2, and Al2O3 fiber bundles was fabricated by slurrying and filament-winding. The strength recovery of the shFRC following three-point bending was investigated, and results indicated that the prepared material recovered 50 times faster than conventional shFRCs at 1000 °C. The self-healing improver described in this study can promote the oxidation of self-healing agents via its reaction heat. Thus, this improver may be applied as a practical component of self-healing materials.

High-temperature corrosion testing of titanium beryllides in the presence of water vapor and oxygen

Beryllium-based intermetallics are promising materials for the blankets of future fusion reactors and have potential applications in other areas of the nuclear industry, such as fission reactor reflectors and space technology. Understanding the high-temperature corrosion behavior of these materials in a noble gas medium containing chemically active impurities is essential for evaluating their suitability and guiding their application.This study investigates the high-temperature corrosion of titanium beryllide Be12Ti in the form of plate and grinded samples, produced by JSC “Ulba Metallurgical Plant” (Ust-Kamenogorsk, Kazakhstan). The corrosion tests were conducted under non-isothermal vapor-gas mixture (Ar + D2O or Ar + H2O flowing atmospheres) purging conditions using thermogravimetric (TG) analysis, differential scanning calorimetry (DSC), and mass-spectrometry of the gas phase.As a result of the corrosion tests, new experimental data on thermal effects have been obtained, describing the corrosion processes of Be12Ti samples across a wide range of temperatures and various heating rates in the presence of water vapor in the purge gas. The dependencies of sample mass change under heating conditions have been determined, and the characterization results of the samples before and after high-temperature corrosion tests are presented.Corrosion of titanium beryllides, both for Be12Ti plate and grinded samples, follows similar mechanisms. At around 500 °C, the mass of the samples begins to increase, and hydrogen isotopes are released. The test results indicate that corrosion of titanium beryllides with varying surface inhomogeneities proceeds similarly within the temperature range of 500–900 °C, showing a linear dependence on temperature.The results revealed significant insights into the oxidation mechanisms and the formation of corrosion products, which are crucial for optimizing the material's performance in fusion reactor environments.

Carbon Dioxide Oil Repulsion in the Sandstone Reservoirs of Lunnan Oilfield, Tarim Basin

The Lunnan oilfield, nestled within the Tarim Basin, represents a prototypical extra-low-permeability sandstone reservoir, distinguished by high-quality crude oil characterised by a low viscosity, density, and gel content. The effective exploitation of such reservoirs hinges on the implementation of carbon dioxide (CO2) flooding techniques. This study, focusing on the sandstone reservoirs of Lunnan, delves into the mechanisms of CO2-assisted oil displacement under diverse operational parameters: injection pressures, CO2 concentration levels, and variations in crude oil properties. It integrates analyses on the high-pressure, high-temperature behaviour of CO2, the dynamics of CO2 injection and expansion, prolonged core flood characteristics, and the governing principles of minimum miscible pressure transitions. The findings reveal a nuanced interplay between variables: CO2’s density and viscosity initially surge with escalating injection pressures before stabilising, whereas they experience a gradual decline with increasing temperature. Enhanced CO2 injection correlates with a heightened expansion coefficient, yet the density increment of degassed crude oil remains marginal. Notably, CO2 viscosity undergoes a substantial reduction under stratigraphic pressures. The sequential application of water alternating gas (WAG) followed by continuous CO2 flooding attains oil recovery efficiency surpassing 90%, emphasising the superiority of uninterrupted CO2 injection over processes lacking profiling. The presence of non-miscible hydrocarbon gases in segmented plug drives impedes the oil displacement efficiency, underscoring the importance of CO2 purity in the displacement medium. Furthermore, a marked trend emerges in crude oil recovery rates as the replacement pressure escalates, exhibiting an initial rapid enhancement succeeded by a gradual rise. Collectively, these insights offer a robust theoretical foundation endorsing the deployment of CO2 flooding strategies for enhancing oil recovery from sandstone reservoirs, thereby contributing valuable data to the advancement of enhanced oil recovery (EOR) technologies in challenging, low-permeability environments.

High-temperature corrosion behavior of 316 H stainless steel in lead-bismuth eutectic containing cesium

The influence of Cs on the corrosion of 316 H stainless steel pipework when exposed to liquid lead–bismuth eutectic (LBE) coolant, specifically LBE containing 0.5 wt% Cs at high temperature, is investigated. The addition of Cs in LBE can significantly accelerate the corrosion of 316 H stainless steel. Cs in LBE first destroys the Cr2O3 film on the surface of the stainless steel and reacts with Cr23C6 enriched at grain boundaries. Finally, the reaction between Cs and FeCr2O4 creates pores in inner oxide layer (IOL), thus destroying the protection provided to 316 H stainless steel by the IOL.

The high-temperature oxidation behavior and mechanism in a powder metallurgy Ni-based superalloy featuring δ-Nb3Al addition

The high-temperature oxidation behavior and mechanism in a powder metallurgy Ni-based superalloy featuring δ-Nb3Al addition

Tailoring oxidation resistance of Cantor alloy by addition of Ta and Al

High-entropy alloys are widely investigated for applications in the nuclear engineering field, the aerospace sector, and various other high-temperature applications. High-temperature oxidation behaviour is a typical issue in such applications. In the current work, an effort is made to tailor the oxidation behaviour of Cantor alloy (CoCrFeMnNi) in the air at 1000 °C with the addition of Ta and Al. Both CoCrFeMnNiTa as well as CoCrFeMnNiAl alloys exhibit considerable resistance to oxide scale spallation as well as develop multi-layered complex oxide scales. CoCrFeMnNiTa primarily forms rutile-type CrTaO4 oxide, which drastically reduces the inward diffusion of oxygen and nitrogen and suppresses the escape of other alloying elements. Nonetheless, the better result is obtained through the Al addition, as evidenced by the comparatively lower oxidation rate constant of CoCrFeMnNiAl in comparison to CoCrFeMnNiTa alloy. This is attributed to the superior oxidation resistance for CoCrFeMnNiAl could be related to the emergence of distinctive Cr2O3 and Al2O3 scales. Additionally, the oxide scale of CoCrFeMnNiTa was not completely smooth and showed some spallation whereas the oxide scales of CoCrFeMnNiAl remained smooth, continuous, and had stronger oxide-substrate interface adhesion.

A New Constitutive Model Based on Taylor Series and Partial Derivatives for Predicting High-Temperature Flow Behavior of a Nickel-Based Superalloy.

Ni-based superalloys are widely used in aerospace applications. However, traditional constitutive equations often lack the necessary accuracy to predict their high-temperature behavior. A novel constitutive model, utilizing Taylor series expansions and partial derivatives, is proposed to predict the high-temperature flow behavior of a nickel-based superalloy. Hot compression tests were conducted at various strain rates (0.01 s-1, 0.1 s-1, 1 s-1, and 10 s-1) and temperatures (850 °C to 1200 °C) to gather comprehensive experimental data. The performance of the new model was evaluated against classical models, specifically the Arrhenius and Hensel-Spittel (HS) models, using metrics such as the correlation coefficient (R), root mean square error (RMSE), sum of squared errors (SSE), and sum of absolute errors (SAE). The key findings reveal that the new model achieves superior prediction accuracy with an R value of 0.9948 and significantly lower RMSE (22.5), SSE (16,356), and SAE (5561 MPa) compared to the Arrhenius and HS models. Additionally, the stability of the first-order partial derivative of logarithmic stress with respect to temperature (∂lnσ/∂T) indicates that the logarithmic stress-temperature relationship can be approximated by a linear function with minimal curvature, which is effectively described by a second-degree polynomial. Furthermore, the relationship between logarithmic stress and logarithmic strain rate (∂lnσ/∂lnε˙) is more precisely captured using a third-degree polynomial. The accuracy of the new model provides an analytical basis for finite element simulation software. This helps better control and optimize processes, thus improving manufacturing efficiency and product quality. This study enables the optimization of high-temperature forming processes for current superalloy products, especially in aerospace engineering and materials science. It also provides a reference for future research on constitutive models and high-temperature material behavior in various industrial applications.

High-temperature erosion behavior of Al2O3 reinforced Inconel625 high velocity oxy-fuel sprayed and direct-aged composite coatings

In this study, Inconel625+30%Al2O3 (IN30AL) blended powders were sprayed on a commercially used boiler steel ASTM SA210 GrA1 using high-velocity oxy-fuel approach (HVOF). The microstructure, mechanical properties and elevated temperature erosion behavior of post-processed coatings and as-sprayed IN30ALcoatings were investigated. The elevated temperature erosion studies on IN30AL coatings both as-sprayed and post-processed were investigated at 900 °C temperature at two impact angles 30° and 90° using standard high temperature erosion test rig. Phase composition, interface of substrate/coating, and morphologies of eroded coatings were examined using x-ray diffraction, x-ray maps, scanning electron microscope, & energy dispersive spectrometer techniques. Compared with the as-sprayed IN30AL coatings, the heat-treated coatings have refined microstructure, better mechanical properties which improve the elevated temperature erosion resistance of IN30ALcoatings.

Effects of Y doping on phase structure, mechanical properties and sintering behavior of (Yb1-xYx)2SiO5 environmental barrier coating materials

Yb2SiO5 is one of the most widely studied environmental barrier coating materials due to its excellent high-temperature phase stability and resistance to water oxygen corrosion. In this paper, a series of (Yb1-xYx)2SiO5 (x = 0, 0.1, 0.2, 0.3, 0.4) ceramics were fabricated by high-temperature solid state sintering at 1550 °C. The effects of Y doping concentration on phase composition, mechanical properties, thermal conductivity and high-temperature sintering behavior of Yb2SiO5 ceramics were investigated in detail. The results show that all the (Yb1-xYx)2SiO5 ceramic specimens are composed of single X2-Yb2SiO5 phase with relative high compactness. The introduction of Y gives rise to the reduction of the thermal conductivity of Yb2SiO5 and the value of cell parameters and volume of (Yb1-xYx)2SiO5 is proportional to the Y3+ doping concentration. Among the five (Yb1-xYx)2SiO5 ceramics, (Yb0.9Y0.1)2SiO5 possesses the lowest brittleness index and its average fracture toughness is 2.85 MPa m1/2, which is about 10 % higher than pure Yb2SiO5. In addition, (Yb0.9Y0.1)2SiO5 has good high temperature phase stability from room temperature to 1450 °C and the grain size of (Yb0.9Y0.1)2SiO5 is basically unchanged after sintering at 1400 °C for 100 h. We believe that (Yb0.9Y0.1)2SiO5 is one of the most promising candidate materials for environmental barrier coatings.

Effect of Ag on High-Temperature Oxidation Behavior of Mg–6.5Gd–5.6Y–0.1Nd–0.01Ce–0.4Zr Alloy

Effect of Ag on High-Temperature Oxidation Behavior of Mg–6.5Gd–5.6Y–0.1Nd–0.01Ce–0.4Zr Alloy

Microstructure and high-temperature tribological behaviours of nano-HfC reinforced Inconel 625 composite coating by plasma-transferred arc welding

The study involved plasma arc transfer welding (PTAW) for preparing coatings of Inconel 625 alloys that contained different amounts of nano-sized hafnium carbide (nano-HfC) particles. The impact of nano-HfC on the microstructure evolution and mechanical properties of PTAWed Inconel 625 were investigated. The research reveals that nano-HfC decomposes during the high-temperature plasma arc process and then react with O element to generate nano-HfO2. These HfO2 can serve as nucleation sites for MC carbides, which restricts the growth of secondary dendrite arms, leading to a more disordered grain growth direction. Simultaneously, the decomposition of HfC can increase the C/Nb ratio of the matrix, effectively suppressing Laves phase formation while encouraging the development of MC carbides. Compared with IN625, the wear rate of composites at room temperature and 600 °C were decreased. Notably, at 600 °C, the wear rate of the coating with 0.5 wt% HfC is the lowest among all the samples, as reflected by a noteworthy reduction in wear rate of 50 %. This is mainly attributed to the refinement of γ matrix, reduction of Laves phase as well as precipitation of the fine-sized MC carbides. This work illustrates that adding nano-HfC is an effective way to improve the wear resistance of the PTAWed Inconel 625.

Effect of Ta on the high temperature oxidation behavior of Mo-based bulk metallic glasses

Mo-based bulk metallic glasses (BMGs) exhibited very high thermal stability and showed promising applications in high-temperature fields. However, their high-temperature oxidation resistance remains unsatisfactory. In this work, the effect of Ta (0–6 at.%) on the high-temperature oxidation behavior of MoCoB BMG was systematically investigated. The oxidation kinetics of MoCoB BMG and Ta-bearing Mo-based BMGs generally followed a parabolic law at 873–973 K, and the rate constants increased with the increasing temperature. The oxidation products of MoCoB BMG were primarily composed of CoMoO4 and MoO3, and the oxides of Ta-bearing Mo-based BMG were mainly CoMoO4, MoO3, CoTa2O6, and Ta2O5. The addition of Ta can significantly promote adhesion between the substrate and the external oxide layer, forming a dense spinel layer with a diffusion barrier that provides good oxidation resistance to the Mo-based BMG. The thin oxidation layer of Mo44Co34Ta6B16 was only about 13 μm after oxidation at 973 K for 120 h.

High-temperature tribological behavior of high-entropy sublattice oxide, nitride, and diboride coatings

The tribological performance of sputtered (Al,Cr,Nb,Ta,Ti)N, ▪ , and ▪ coatings on steel substrates was compared against TiN in dry ball-on-disk and scratch tests in ambient air at 20°C, 400°C and 700°C. The (Al,Cr,Nb,Ta,Ti)N and TiN perform similar in all tests, with (Al,Cr,Nb,Ta,Ti)N showing higher oxidation and abrasion resistance. The adhesion of (Al,Cr,Nb,Ta,Ti)N is superior to TiN at 20°C, but worse at elevated temperature due to an earlier onset of recovery processes that increase the mismatch in coefficient of thermal expansion with the substrate. The ▪ is the most abrasion resistant coating at room temperature owing to its high hardness, but suffers from oxidation in hot air. Scratch tests yield a similar adhesion strength to TiN at 20°C, but the anisotropic lattice expansion and shrinkage of the hexagonal structure at elevated temperatures lead to early delamination in the scratch test. The ▪ also adheres poorly on the steel, resulting in quick delamination during all tests.

Microstructure and mechanical response of as-built and solution-annealed LPBF Hastelloy X under high-temperature fatigue loading

This study investigates the microstructural characteristics and the high-temperature mechanical behavior of Hastelloy X, fabricated via laser powder-bed fusion (LPBF) technology. Hastelloy X, a solid solution-strengthened nickel-based superalloy known for its high strength and oxidation resistance at elevated temperatures, has gained significant interest for the fabrication of complex aerospace components through LPBF technology. The study initially focuses on the impact of solution annealing heat treatment at 1227 °C on the alloy microstructure, based on scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigations. It then explores the fatigue and cyclic deformation response of the alloy at 750 °C across different strain ranges, comparing the as-built and solution-annealed conditions. To understand the observed differences in the cyclic mechanical response of as-built and solution-annealed LPBF HX, for a particular condition, a set of dedicated tests have been performed and interrupted at selected numbers of cycles in the different stages of the mechanical response. At each interruption point, specimens have been examined by TEM to provide an in-depth understanding of the effect of dislocation microstructural evolution on the high-temperature cyclic mechanical response of the alloy.

New lightweight high-entropy alloy coatings: Design concept, experimental characterization, and high-temperature oxidation behaviors

Lightweight high-entropy alloy (HEA) coatings by laser cladding (LC), which combines the advantages of high-entropy alloys and laser cladding, are potential materials for high-temperature applications. Al20Cr5Fe50Mn20Ti5 and Al25Cr20Fe20Mn15Ti20 HEAs were designed, and the calculated thermal parameters were close to the Ni-based alloy substrate (Inconel 718). Based on this, Al20Cr5Fe50Mn20Ti5 and Al25Cr20Fe20Mn15Ti20 HEA coatings were fabricated by LC on the substrates. The main phase structures of the two designed HEAs are the BCC + L21 phase, as revealed by the CALculation of PHAse Diagrams (CALPHAD). The high-temperature oxidation properties of the coatings were systematically investigated using isothermal oxidation tests. The oxidation activation energies of both coatings were 154.8 and 133.4 kJ/mol. Combined with molecular dynamics (MD) simulation, the clustering mechanism of Al and Ti elements was revealed in the formation of the L21 phase, whereas the high proportion of Ti elements increased the vacancy concentration, which was not conducive to oxidation resistance. Through this study, lightweight HEA coatings with excellent high-temperature performance can be designed and developed in the Al-Cr-Fe-Mn-Ti HEA system.

Study on the High-Temperature Mechanical Behavior and Parameters of Joints: a Case of a Prefabricated Frame Tunnel

Study on the High-Temperature Mechanical Behavior and Parameters of Joints: a Case of a Prefabricated Frame Tunnel

Evaluation of high-temperature oxidation behaviour of ATF claddings during severe accidents in nuclear power plants

This work aims to evaluate the oxidation behavior and kinetics of ADSS B#51 alloy in high-temperature air and to investigate the effect of the T-ramping rate on the kinetics of ADSS B#51. Using Thermogravimetric Analyzer (TGA), the high-temperature oxidation test was performed isothermally in air at 1000 °C, 1150 °C, and 1300 °C and for T-ramping tests at 1 °C/min, 4 °C/min, 40 °C/min. We estimated weight gains of the alloy in T-ramping condition and compared with measured value. It was concluded that the oxidation rates of the alloy during T-ramping were higher than those estimated by using parameters determined from the isothermal tests. In addition, surface oxide characterization using SEM-EDS demonstrated a complex surface oxide. Where the surface oxide and the oxide compositions were randomly distributed and not following any specific pattern. The findings showed that T-ramping oxidation kinetics parameters are in between the oxidation kinetics parameters of the steady-state region and transient region of isothermal oxidation, but closer to the transient region.

Role of heat treatment conditions in the high-temperature deformation behavior of laser-powder bed fused Fe–Cr–Ni–Al maraging stainless steel

The present research investigates the high-temperature behavior of laser powder bed fused (LPBF) Fe–Cr–Ni–Al maraging stainless steel (equivalent to PH13–8Mo). Fully dense PH13–8Mo samples are printed using an EOS M290 printer, and the effect of different heat treatments on high-temperature behavior and microstructure development is investigated. The material is studied under as-printed (AP), austenitized aged (AA, austenitized at 900 °C for 1 h followed by aging at 530 °C for 3 h), and direct-aged (DA, aged at 530 °C for 3 h) conditions. Uniaxial compression tests are conducted using a Gleeble® 3500 thermal-mechanical simulator at 400 °C and 500 °C at a quasi-static strain rate of 0.0001 s−1 to a final true strain of 0.2, while the microstructure characterization is performed using Electron Backscatter Diffraction and Transmission Electron Microscopy. At room temperature, the AA sample shows the highest hardness (strength), but at temperatures of 400 °C and 500 °C, the DA sample possesses the highest strength. Interestingly, the AP sample exhibits comparable strength to the DA sample at 500 °C, which could indicate for applications at these high temperatures, LPBF-PH13-8 Mo does not require any heat treatment.

Effect of hydrogen content on the high-temperature compressive deformation behavior and microstructure evolution of TC17 alloy

Thermo-hydrogen process (THP) has been an important research direction of the titanium alloy heat treatment process. However, the effect of THP on the thermal deformation behavior and microstructure evolution of TC17 alloy during hot compression has not been investigated. In this study, a series of isothermal compression experiments were carried out on hydrogenated TC17 alloy specimens in the temperature range covering the α+β phase region and β phase region of TC17 alloys with different hydrogen contents, to investigate the effect of hydrogen on the high-temperature flow behavior and microstructure evolution. The results show that the primary α phase of the hydrogenated TC17 alloy is significantly reduced. Observing the XRD pattern, the substitutional solution effect of hydrogen causes the β phase lattice to expand, resulting in a shift of the β phase toward a small angle as the hydrogen content increases. The flow stress shows a tendency to decrease and then increase with increasing hydrogen content. This is attributed to the softening effect of hydrogen on the α phase and the hardening effect on the β phase. This also leads to the deformation activation energy showing the same trend. When the hydrogen content increases to 0.4 wt%, the activation energy decreases to the lowest point by about 24 %. Finally, the appropriate hydrogen concentration can effectively reduce the destabilization region in the hot working map and expand the processing window of TC17 alloy.