High Strain Research Articles

Fluorine‐Effect‐Enabled Photocatalytic 4‐Exo‐Trig Cyclization Cascade to Access Fluoroalkylated Cyclobutanes

AbstractCyclobutanes are popular structural units in bioactive compounds and versatile intermediates in synthetic chemistry, but their synthesis is challenging owing to high ring strain. In this study, a novel method for highly regio‐ and diastereoselective synthesis of fluoroalkylcyclobutanes bearing vicinal quaternary and tertiary stereocenters is realized by a photocatalytic 4‐exo‐trig cyclization cascade of thioalkynes or trifluoromethylalkenes. Density functional theory calculations reveal that a unique fluorine effect, arising from hyperconjugative π→σ*C‐F interactions, accounts for the regio‐reversed radical addition at the sterically hindered alkene carbon, which facilitates an unprecedented 4‐exo‐trig ring closure. This chemistry enables the direct and controllable construction of medicinally valuable quaternary‐carbon‐containing cyclobutanes from readily available raw materials, nicely complementing the existing methods.

Fluorine-Effect-Enabled Photocatalytic 4-Exo-Trig Cyclization Cascade to Access Fluoroalkylated Cyclobutanes.

Cyclobutanes are popular structural units in bioactive compounds and versatile intermediates in synthetic chemistry, but their synthesis is challenging owing to high ring strain. In this study, a novel method for highly regio- and diastereoselective synthesis of fluoroalkylcyclobutanes bearing vicinal quaternary and tertiary stereocenters is realized by a photocatalytic 4-exo-trig cyclization cascade of thioalkynes or trifluoromethylalkenes. Density functional theory calculations reveal that a unique fluorine effect, arising from hyperconjugative π→σ*C-F interactions, accounts for the regio-reversed radical addition at the sterically hindered alkene carbon, which facilitates an unprecedented 4-exo-trig ring closure. This chemistry enables the direct and controllable construction of medicinally valuable quaternary-carbon-containing cyclobutanes from readily available raw materials, nicely complementing the existing methods.

Compression behaviour of self-compacting concrete under dynamic loading at different ages

Self-compacting concrete (SCC) is widely used in reinforced concrete buildings, owing to its ability to consolidate by weight and its lack of requirement for external vibration. Reinforced concrete buildings can be subjected to high strain rate loading during the early days of construction or in their service life. Thus, it is critical to understand the behaviour of concrete under high strain rate loadings at different ages. Minimal studies have previously focused on the early-age behaviour of concrete under high strain rates. This study tries to fill this gap. It focuses on the behaviour of M40 grade SCC under three levels of strain rate loading at ages of 1, 3, 7, 14 and 28 d. The split-Hopkinson pressure bar (SHPB) was used to test 45 SCC specimens of diameter 100 m and thickness 50 mm at high strain rates, ranging from 30 s−1 to 110 s−1, and the determined compressive strength, peak strain and elastic modulus results are compared with quasistatic test results of SCC specimens. The dynamic increase factor (DIF) determined in the SHPB experiment is compared with the CEB-fib code model. The results indicate that the DIF reduces as the concrete's strength and age increase.

New design of materials, order and thicknesses of an aircraft windshield behaviour layers to increase its resistance against repeated bird impacts

Abstract There are instances when an aircraft encounters a bird’s flock or faces a heavy hailstorm, causing the windshield to sustain consecutive impacts. Therefore, the investigation of windshield resistance against repeated impacts is crucial. In this research, various tests such as tensile, split Hopkinson pressure bar (SHPB), and three-point bending are conducted to extract the mechanical properties of the materials used in a five-layers windshield under high strain rates. Using this information, the bird impact on the windshield is simulated using the smooth particle hydrodynamics (SPH) method, and the results are compared with real bird impact test outcomes, and the validation of this simulation is confirmed. The simulation of two consecutive bird strikes indicates the current windshield lacks sufficient resistance against successive dual impacts; in such scenarios, the second bird penetrates the windshield after breaking it and tearing the interlayer. Considering new materials and thicknesses for each windshield layer, a Taguchi experimental design method is employed to examine various layer arrangements with different materials and thicknesses. The configurations in which the windshield can withstand a maximum of three bird impacts in succession are identified. Subsequently, using the “the smaller, the better” criterion in the Taguchi optimisation approach, the configuration that not only prevents bird penetration but also minimises the maximum strain in the inner layer is selected as the desired outcome. Thus, a new five-layer windshield with new materials and thicknesses is presented, which is resistant to the repeated collision of up to three birds, tearing in the interlayer and bird penetration does not happen.

Effect of strain rate and temperature on dynamic compressive behavior of HfBeTiZrCuNi high entropy bulk metallic glass

This study investigated the high-temperature dynamic mechanical properties of Hf-based high entropy bulk metallic glass (HE-BMG). Uniaxial dynamic compressive tests of Hf-based HE-BMG were conducted at elevated temperatures (from 298 to 800 K) under a high strain rate (from 1000 to 5000 s−1) by a split Hopkinson pressure bar (SHPB) device with a high-temperature system, and the failed specimens were analyzed in terms of microstructures and fracture modes. The dynamic test results show that the maximum compressive stress and the total strain decrease with increasing strain rate and temperature, exhibiting significant strain rate and temperature sensitivity. Three different fracture modes were observed with increasing strain rates, while heating the temperature could promote the transition process of the fracture modes. When the adiabatic or heating temperature reaches above the crystallization temperature, the embrittlement caused by metallic glass crystallization makes the fracture mode change. The mechanical behavior of Hf-based HE-BMG at high temperatures and high strain rates could be attributed to the combination of adiabatic heating and embrittlement.

Formation of nanocrystalline and nanolaminate structures in a twinning induced plasticity Ti-12Mo alloy: The role played by {332} 〈113〉 twinning

Grain refinement is an effective strategy to strengthen metastable β titanium alloys. {332}<113> twinning, a typical deformation mode, its role on grain refinement still remains unelucidated. Here, we produced a gradient nanostructured layer with a depth of 800 μm in a metastable twinning induced plasticity β-Ti-12Mo (wt.%) alloy by means of surface mechanical rolling treatment. We found that {332}<113> deformation twinning, mainly dominated the deformation at moderate strain and strain rates, refining coarse grains into submicro-structures. With increasing strain and strain rates, dislocation slip instead of {332}<113> twinning prevailed. These dislocations were first arranged into extended boundaries and then into laminated structures to coordinate deformation. Eventually, shear banding and fragmentation of laminates result in the formation of nanocrystalline with size of 34 ± 8 nm. The nanostructured Ti-12Mo alloy exhibited the high hardness of 4.9 GPa at subsurface. The surface hardness decreased to 4.4 GPa which was mainly caused by the inhibition of stress-induced martensitic transformation α″ and the occurrence of its reversal transformation due to adiabatic heating induced by the high strain rate. This work expands our knowledge on strengthening β titanium alloys by {332}<113> twinning induced grain refinement at different deformation conditions.

Nano-Sized rGO-Encapsulated TiO2 Nanowire-Filled PDMS cone type dielectric elastomer actuator operating at low applied electric field

Dielectric elastomer actuators (DEAs) have versatile applications in soft robotics, medical devices, and environmental monitoring, making them a highly anticipated area for future applications. On the other hand, developing DEAs exhibiting high strain at low voltages remains challenging. This paper reports a strategy for enhancing the actuating performance of polydimethylsiloxane (PDMS) at low voltages by preparing a hybrid filler comprised of TiO2 nanowires (TiO2 NWs), polydopamine (PDA), and nano-sized reduced graphene oxide (nrGO). This hybrid filler, merging the virtues of these three materials, was added at 15 parts per hundred of rubber (phr), resulting in a 2.3-fold increase in the dielectric permittivity of PDMS while mitigating the increase in loss tangent and enhancing efficiency. Actuators fabricated using this composite exhibited the highest deformation at 10 phr, reaching approximately 27.31 % (at 28 V/µm), representing a remarkable 15.2-fold improvement compared to pure PDMS. Moreover, even at a low voltage of 1.6 V/µm, they displayed a substantial actuated strain of 2 %. This novel strategy for manufacturing hybrid fillers is a promising example of enhancing the performance of DEAs, offering innovative solutions for future technological advancements.

Enrichment of corn and alfalfa silage with γ-aminobutyric acid through inoculation with a screened high producing Lentilactobacillus buchneri strain

This study aimed to enrich corn and alfalfa silages with γ-aminobutyric acid (GABA) by utilizing high GABA-producing Lentilactobacillus buchneri. Eleven strains were screened and L. Buchneri YM9 was distinguished for its superiority in GABA production, and it was subsequently applied as an inoculant on whole-crop corn and alfalfa silage. The silage treatments were control (without inoculant), AH35 (non-GABA producing strain), YM9 (high-GABA producing strain), and 40788 (commercial GABA producing strain). The results revealed that in corn silage, pH significantly declined at the initial ensiling stage (3–7 days), with the control having the lowest pH after 90 days. The control also exhibited the highest lactic acid, while L. buchneri treatments had elevated acetic acid. Similar trends were observed in alfalfa silage, with 30 % dry matter (DM) showing lower pH and higher organic acids. YM9-inoculated corn silage had higher DM loss, reduced water-soluble carbohydrates (WSC), but increased crude protein (CP) content. YM9 and 40788 treatments in whole-crop corn silage had lower glutamate (Glu) content post-ensiling, signifying effective GABA production. YM9 treatment maintained stable and higher glutamate decarboxylase (GAD) activity, resulting in the highest GABA accumulation in corn silage (1.97 g/kg DM). Likewise, YM9 and 40788 demonstrated significantly higher GABA content in 30 % (7.6 and 6.51 g/kg DM) and 40 % (5.23 and 5.32 g/kg DM) DM alfalfa silage. Beyond enhancing fermentation and nutrient preservation, YM9 strain shows promise in enriching whole-crop corn and alfalfa with ample GABA concentration, potentially exerting anticipated biological functions when consumed by animals.

High strain rate testing of hybrid TPMS structures

High strain rate testing of hybrid TPMS structures

Experimental and numerical analysis of NdFeB magnets under static and dynamic loading conditions

Neodymium iron boron (NdFeB) magnets, known for their superior magnetic properties, are pivotal in various high-performance applications, ranging from electric motors to wind turbines. The durability and reliability of these devices significantly depend on the mechanical integrity of NdFeB magnets under various stress conditions. In this work, the mechanical behavior and failure processes of NdFeB magnets are experimentally studied by in-door tests. We specifically examine the failure behavior of these magnets when subjected to dynamic loads, employing the Split Hopkinson Pressure Bar test both with and without initial loading perpendicular to the pressure bar direction. Furthermore, to complement the experimental findings, the experiments are numerically reproduced with a hybrid finite-discrete element method titled Continuous-Discontinuous Element Method (CDEM). Within the CDEM framework the Johnson-Holmquist 2 constitutive model is considered for the material under high strain rate loading conditions. Most material parameters are determined by experimental data and theoretical analysis. This research not only enhances our understanding of the properties of NdFeB magnets but also provides valuable insights for engineers and researchers aiming to improve the material’s resilience and durability.

Impact Toughness Analysis and Numerical Simulation of Coral Aggregate Concrete at Various Strength Grades: Experimental and Data Investigations

This paper comprehensively investigates the dynamic mechanical properties of concrete by employing a 75 mm diameter Split Hopkinson Pressure Bar (SHPB). To be detailed further, dynamic compression experiments are conducted on coral aggregate seawater concrete (CASC) to unveil the relationship between the toughness ratio, strain rate, and different strength grades. A three-dimensional random convex polyhedral aggregate mesoscopic model is also utilized to simulate the damage modes of concrete and its components under varying strain rates. Additionally, the impact of different aggregate volume rates on the damage modes of CASC is also studied. The results show that strain rate has a significant effect on CASC, and the strength grade influences both the damage mode and toughness index of the concrete. The growth rate of the toughness index exhibits a distinct change when the 28-day compressive strength of CASC ranges between 60 and 80 MPa, with three times an increment in the toughness index of high-strength CASC comparing to low-strength CASC undergoing high strain. The introduction of pre-peak and post-peak toughness highlights the lowest pre-to-post-peak toughness ratio at a strain rate of approximately 80 s−1, which indicates a shift in the concrete’s damage mode. Various damage modes of CASC are under dynamic impact and are consequently defined based on these findings. The LS-DYNA finite element software is employed to analyze the damage morphology of CASC at different strain rates, and the numerical simulation results align with the experimental observations. By comparing the numerical simulation results of different models with varying aggregate volume rates, it is reported that CASC’s failure mode is minimized at an aggregate volume rate of 20%.

Satisfactory Tensile Strength and Strain of Recyclable Polyurethane with a Trimaleimide Structure for Thermal Self-Healing and Anticorrosive Coatings.

Bismaleimide (BMI) is often used as the cross-linking reagent in Diels-Alder (D-A)-type intrinsic self-healing materials (DISMs) to promote the connectivity of damaged surfaces based on reversible D-A bond formation on the molecular scale. Until now, although DISMs have exhibited great potential in the applications of various sensors, electronic skin, and artificial muscles, it is still difficult to prepare DISMs with satisfactory self-healing abilities and high tensile strengths and strains at the same time, thus largely limiting their applications in self-healing anticorrosive coatings. Herein, symmetrical trimaleimide (TMI) was successfully synthesized, and trimaleimide-structured D-A self-healing polyurethane (TMI-DA-PU) was prepared via the reversible D-A reaction (cycloaddition of furan and maleimide). As a DISM, TMI-DA-PU exhibits apparently higher self-healing efficiency (98.7%), tensile strength (25.4 MPa), and strain (1378%) compared to bismaleimide-structured D-A self-healing polyurethane (BMI-DA-PU) (self-healing efficiency, 90.2%; tensile strength, 19.3 MPa; strain, 1174%). In addition, TMI-DA-PU shows a high recycling efficiency (>95%) after 4 cycles of recycling. A series of characterizations indicate that TMI provides more monoene rings as the self-healing sites, forms denser cross-linked structures compared to BMI, and is, thus, more appropriate to be used for DISM applications. Moreover, the barrier abilities of coatings can be semi-quantitatively expressed by the impedance value at 0.01 Hz (|Z|0.01Hz). The |Z|0.01 Hz value of the TMI-DA-PU coating is 3.93 × 109 Ω cm2 on day 0, which is significantly higher than that of the BMI-DA-PU coating (6.76 × 108 Ω cm2 on day 0), indicating that the denser rigid cross-linked structure of TMI results in the small porosity in the TMI-DA-PU coating, thus effectively improving the anticorrosion performance. The construction of DISMs with the structure of TMI demonstrates immense potential in self-healing anticorrosive coatings.

Dynamic deformation behavior of single phase VNbTa medium-entropy alloys

In this study, the deformation behavior of body-centered-cubic (BCC) VNbTa medium-entropy alloy (MEA) was studied under different strain rates ranging from 10−3 s−1 to 5000 s−1 using screw-driven testing machine and split Hopkinson pressure bar (SHPB), respectively. The alloy presents an outstanding synergy of strength and plasticity without any adiabatic shear bands even at a strain rate of 5000 s−1. Moreover, the yield strength of the alloy displays an obvious strain rate dependence, increasing by ∼94.4% from 842 MPa at 10−3 s−1 to 1637 MPa at 5000 s−1. The strain rate sensitivity (SRS) factor m and highest temperature rise under dynamic loading is calculated to be 0.2991 and 182 K, respectively, which means a strong strain rate hardening and thermal softening resistance. Microstructure evolution analyses demonstrate a transition of deformation mechanism from single dislocation slip controlling in low strain rate to a synergy of mechanical twinning and dislocation slip in high strain rate. Therefore, the excellent dynamic mechanical properties could be attributed to the synergistic effects of the strong strain rate hardening and thermal softening resistance, the mechanical twins, and the cell structures and microbands derived from dislocation slip controlling. In addition, the dynamic deformation behavior of VNbTa could also be described by a classical Johnson-Cook model. Combining the excellent cryogenic temperature mechanical properties (tensile strength of ∼1930 MPa and fracture elongation ∼27%), the present work further indicates that the VNbTa MEA has great potential for engineering applications under some extreme circumstances.

Influence of high-strain-rate compression and subsequent heat treatment on (TiNbZr)89(AlTa)11 refractory high-entropy alloys: Dynamic-mechanical behavior and microstructural changes

This study explored the dynamic-mechanical behavior of a novel low-density (TiNbZr)89(AlTa)11 refractory high-entropy alloy (RHEA) across strain rates ranging from 1.0 × 103 to 3.5 × 103 s−1. A significant increase in the yield and ultimate compressive strengths with rising strain rates up to 3.0 × 103 s−1 was observed and attributed to enhanced dislocation activities and stress-induced microstructural transformations. The formation of the B2 phase and Zr5Al3 precipitates was found to be crucial in bolstering the alloy strength at high strain rates. Beyond strain rates of 3.0 × 103 s−1, a decrease in strength occurred due to thermal softening and strain localization. Microstructural analyses at 3.5 × 103 s−1 revealed grain refinement, the development of micro shear bands, and dislocation tangles, which were indicative of dynamic recrystallization. Besides, the findings also revealed that the post-dynamic compression heat treatment further enhanced the hardness and microstructural stability of the alloy. These results highlight the potential of the (TiNbZr)89(AlTa)11 RHEA for applications requiring materials with high strength-to-weight ratios, particularly in dynamically loaded environments. It is expected that the results of this study will further advance our fundamental understanding of the behavior of RHEAs under extreme conditions, thereby opening new avenues for material innovation.

Research on damage behavior of silicone rubber under dynamic impact

Viscoelastic rubber materials are widely used in various vibration reduction structures of military and construction machinery. The complex driving and working conditions make the mechanical structure suffer severe impact, which leading to the damage or lose efficacy of the important viscoelastic elements. In order to reveal the dynamic mechanical properties of silicone rubber after impact, the Uniaxial compression tests of silicone rubber under different high strain rates were carried out with the separated Hopkinson pressure bar (SHPB) dynamic impact experiment, and the original Zhu-Wang-Tang (ZWT) constitutive model was modified by combining logarithmic law and power function law. The dynamic impact simulation model of silicone rubber was established using the modified ZWT-rate-dependent constitutive model, and the dynamic impact damage behavior of silicone rubber was studied under the condition of high strain rate, and the microscopic damage analysis was carried out on the experimental silicone rubber samples by scanning electron microscopy (SEM). The results show that the silicone rubber has obvious strain rate effect and strong deformation resistance at high strain rate. The modified ZWT-rate-dependent constitutive model can be used to obtain the constitutive expression of unified parameters, which can better describe the dynamic mechanical properties of silicone rubber at high strain rates. After dynamic impact compression, a damage line zone appears in the silicone rubber sample. There is a certain rule between the position of the line zone and the loading strain rate and the friction coefficient of the end face, and the silicone rubber is significantly affected by the friction effect of the end face.

The High Temperature Strength of Single Crystal Ni‐base Superalloys – Re‐visiting Constant Strain Rate, Creep, and Thermomechanical Fatigue Testing

The present work takes a new look at the high temperature strength of single crystal (SX) Ni‐base superalloys. It compares high temperature constant strain rate (CSR) testing, creep testing, and out‐of‐phase thermomechanical fatigue (OP TMF) testing, which represent key characterization methods supporting alloy development and component design in SX material science and technology. The three types of tests are compared using the same SX alloy, working with precisely oriented &lt;001&gt;‐specimens and considering the same temperature range between 1023 and 1223 K, where climb controlled micro‐creep processes need to be considered. Nevertheless, the three types of tests provide different types of information. CSR testing at imposed strain rates of 3.3 × 10−4 s−1 shows a yield stress anomaly (YSA) with a YSA stress peak at a temperature of 1073 K. This increase of strength with increasing temperature is not observed during constant load creep testing at much lower deformation rates around 10−7 s−1. Creep rates show a usual behavior and increase with increasing temperatures. During OP‐TMF loading, the temperature continuously increases/decreases in the compression/tension part of the mechanical strain‐controlled cycle (±0.5%). At the temperature, where the YSA peak stress temperature is observed, no peculiarities are observed. It is shown that OP‐TMF life is sensitive to surface quality, which is not the case in creep. A smaller number of cycles to failure is observed when reducing the heating rate in the compression/heating part of the mechanical strain‐controlled OP‐TMF cycle. The results are discussed on a microstructural basis, using results from scanning and transmission electron microscopy, and in light of previous work published in the literature.

High temperature and high strain rate properties of brazed honeycomb liner material Haynes 214

Abradable honeycomb sealing systems are essential for gas turbine efficiency. Experimental data on the rubbing performance of Haynes 214 metal sheets brazed with the nickel-chromium-silicon filler metal BNi-5 is presented. The brazing layer in the double foiled honeycomb sections turned out to have a major impact on rubbing behavior. Damage on the rotor was analyzed with a large chamber scanning electron microscope and energy-dispersive X-ray spectroscopy. The results demonstrate a significant influence of the brazing process on the mechanical properties, especially after exposure to 1000 °C. A hard aluminum nitride phase formed in the brazed metal sheets can cause severe damage to the rotor.

Development of IPMC actuators with high bending uniformity and orientation

Ionic polymer-metal composite (IPMC) actuators have attracted considerable scientific interest in the field of robotics and artificial muscles due to their low operating voltage, high strain capacity, and lightweight. However, the non-uniform bending of IPMC actuators affects their control accuracy and limits their potential applications. In this work, the surface voltage of IPMC actuators was measured and the internal electric field distribution was numerically computed. It was concluded that the non-uniform bending is mainly due to the non-uniform distribution of hydrated cations inside the IPMC as a result of the inhomogeneous electric field. The bending uniformity is improved by sputtering a gold layer on the surface of the IPMC actuator, and a support strip is introduced to limit the bending of the IPMC in the width direction, resulting in an improvement of its pointing characteristics. It is found that the bending uniformity of IPMC improved by 35.27% and 119.48% by sputtering at an input voltage of 2.5 V and 5 V respectively. When the input voltage is fixed at 2.5 V and 5 V, the bending in the width direction is reduced by 75.68% and 93.12% with the support structure, respectively.

In-situ synchrotron diffraction analysis of deformation mechanisms in an AA5083 sheet metal processed by modified equal-channel angular pressing

Severe plastic deformation (SPD) is a process to significantly improve the mechanical properties of materials by grain refinement. For forming at room temperature (RT), higher strengths can thus be achieved; for increased temperatures (HT), greater elongations can be achieved. This great potential has been chiefly applied only on laboratory scale due to a lack of industrial process design. Equal-channel angular pressing (ECAP) offers the possibility to integrate these advantages in industrial processes. This paper investigates a modified ECAP process for aluminum AA5083 sheet metal. Two passes of ECAP for sheet metal and an additional heat treatment were used. To study the material deformation on a micro-scale, in-situ synchrotron measurements at DESY (Hamburg) were performed to analyze the evolution of lattice strains and dislocation densities during tensile testing. The mechanical properties of the ECAP-processed sheet material reveal an increase in yield strength and a decrease in elongation at RT. Higher strains can be measured for the processed material at elevated test temperatures. In-situ diffraction results show a changed behavior of the ECAP sheet material compared to the reference material for both temperature regimes. These changes are based on the increased defect density in the material, which leads to increased strength at RT. At HT, dynamic recrystallization occurs during tensile testing, and the prevailing deformation mechanisms reconfigure. Electron backscatter diffraction (EBSD) and micrographs are used to interpret and supplement the observations. The findings provide the basis for the in-depth understanding of the deformation behavior of the material and help to apply the ECAP process on an industrial scale.

Enhanced 3D printing and crack control in melt-grown eutectic ceramic composites with high-entropy alloy doping

As a 3D printing method, laser powder bed fusion (LPBF) technology has been extensively proven to offer significant advantages in fabricating complex structured specimens, achieving ultra-fine microstructures, and enhancing performances. In the domain of manufacturing melt-grown oxide ceramics, it encounters substantial challenges in suppressing crack defects during the rapid solidification process. The strategic integration of high entropy alloys (HEA), leveraging the significant ductility and toughness into ceramic powders represents a major innovation in overcoming the obstacles. The ingenious doping of HEA particles preserves the eutectic microstructures of the Al2O3/GdAlO3(GAP)/ZrO2 ceramic composite. The high damage tolerance of the HEA alloy under high strain rates enables the absorption of crack energy and alleviation of internal stresses during LPBF, effectively reducing crack initiation and growth. Due to increased curvature forces and intense Marangoni convection at the top of the molt pool, particle collision intensifies, leading to the tendency of HEA particles to agglomerate at the upper part of the molt pool. However, this phenomenon can be effectively alleviated in the remelting process of subsequent layer deposition. Furthermore, a portion of the HEA particles partially dissolves and sinks into the molten pool, acting as heterogeneous nucleation particles, inducing the formation of equiaxed eutectic and leading primary phase nucleation. Some HEA particles diffuse into the lamellar ternary eutectic structures, further promoting the refinement of eutectic microstructures due to increased undercooling. The innovative doping of HEA particles has effectively facilitated the fabrication of turbine-structured, conical, and cylindrical ternary eutectic ceramic composite specimens with diameters of about 70 mm, demonstrating significant developmental potential in the field of ceramic composite manufacturing.