The Witu Islands are Quaternary volcanoes that overlie the deepest (about 300–580 km) part of the New Britain Benioff zone. The islands are about 100 km south of the transcurrent-divergent plate boundary that crosses the Bismarck Sea, and they surmount the southeastern end of the Willaumez-Manus Rise. The rocks are olivine- and quartz-normative tholeiitic basalts, low- and high-SiO2 andesites, dacites, and rhyolites. Alkaline rocks that overlie the deep (greater than 300 km) parts of other Benioff zones have not been found in the Witu Islands. Compared to the Witu Islands rocks, those with similar SiO2 contents from New Britain volcanoes that overlie progressively shallower parts of the Benioff zone to the south, are, for example, generally poorer in Na+K, Ti, and P, and higher in Ca and Al. There are similar progressive changes in trace-element abundances, but Zr and Nb contents are distinctly richer in Witu Islands rocks.87Sr/86Sr values range between 0.70311 and 0.7038, which are typical for rocks from New Britain as a whole and from other island arcs in the southwest Pacific. Two143Nd/144Nd values of 0.512211 and 0.512271, taken together with the Sr isotopic results, define a source region equivalent to those for oceanic-island basalts; there is no evidence for sea-water contamination of the sources.