Bonding in the ground state of C{}_{2} is still a matter of controversy, as reasonable arguments may be made for a dicarbon bond order of 2, 3, or 4. Here we report on photoelectron spectra of the C{}_{2}^{-} anion, measured at a range of wavelengths using a high-resolution photoelectron imaging spectrometer, which reveal both the ground {X}^{1}{Sigma}_{mathrm{g}}^{+} and first-excited {a}^{3}{Pi}_{{mathrm{u}}} electronic states. These measurements yield electron angular anisotropies that identify the character of two orbitals: the diffuse detachment orbital of the anion and the highest occupied molecular orbital of the neutral. This work indicates that electron detachment occurs from predominantly s-like (3{sigma}_{mathrm{g}}) and p-like (1{pi }_{{mathrm{u}}}) orbitals, respectively, which is inconsistent with the predictions required for the high bond-order models of strongly sp-mixed orbitals. This result suggests that the dominant contribution to the dicarbon bonding involves a double-bonded configuration, with 2pi bonds and no accompanying sigma bond.
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