The wide field of view (WFV) imaging system of the GaoFen-6 (GF-6) satellite processes four popular spectral bands [blue, green, red, and near-infrared (NIR)] and four new spectral bands (costal, yellow, and two red edges). However, the corresponding reference spectral bands for these eight spectral bands from one reference sensor are insufficient in the cross-calibration process of the WFV; therefore, current cross-calibration methods should be improved. To address this problem, the Moderate-Resolution Imaging Spectroradiometer (MODIS), which has high radiometric performance with the aid of an onboard calibration system, is used as a reference sensor, and cross-calibration methods using the top of atmosphere (TOA) and the bottom of atmosphere (BOA) bidirectional reflectance distribution function (BRDF) models are developed and compared. The results reveal that the cross-calibration results in eight spectral bands with the BOA BRDF model that can obtain higher consistency with the official calibration coefficients (OCCs) compared with the TOA BRDF model. In addition, after various influencing factors are comprehensively analyzed, the spectral band adjustment factor (SBAF) correction in the shortwave infrared (SWIR) spectral bands can be neglected; moreover, by using five spectral bands (blue, green, red, NIR, and SWIR) of the MODIS sensor, the BOA BRDF model and the cubic polynomial interpolation method provide optimal cross-calibration schemes for WFV sensor. The total radiometric cross-calibration uncertainties of the proposed cross-calibration methods with the BOA BRDF model and the TOA BRDF model are less than 5.73% and 6.32%, respectively.