High-pressure X-ray Research Articles

High-pressure X-ray crystallographic investigation of chalcogen bonding

High-pressure X-ray crystallographic investigation of chalcogen bonding

High-pressure structural phase transition on Bi14MoO24

In situ high-pressure powder synchrotron X-ray diffraction studies on tetragonal Bi14MoO24 have been carried out up to 11.5 GPa at room temperature. A tetragonal (I4/m) to monoclinic (C2/m) structural phase transition has been identified around 5 GPa and possible evidence for a second phase transition is observed at the highest pressure of this study. Both phase transitions are reversible upon decompression. The evolution of the lattice parameters, axial ratio, and volume under pressure have been determined for both the low pressure tetragonal and high-pressure monoclinic phases. A volume collapse of 2.7% observed at the tetragonal to monoclinic phase transition indicates it to be of first-order character. The phase transition involves a shear deformation perpendicular to the b-axis and a displacement of the Mo atoms along the b-axis. The details of the mechanism of the tetragonal-monoclinic transition are discussed. The bulk modulus of the low-pressure tetragonal and high-pressure monoclinic phases have been estimated to be 67(7) GPa and 64(3) GPa, respectively. The linear compressibilities of both phases show an anisotropic response to pressure. The obtained results are compared with the high-pressure behavior of its isomorph counterpart Bi14CrO24 and with high-temperature behavior on Bi14MoO24.

Coexistence of zigzag antiferromagnetic order and superconductivity in compressed NiPSe3

NiPSe3 is regarded as a bandwidth-controlled Mott insulator, distinct from the widely studied Mott insulating magnetic graphene MPSe3 (M = Mn and Fe) family. By employing high-pressure synchrotron X-ray diffraction, we observe two structural transitions as a function of pressure. With the help of first-principles calculations, we discover the antiferromagnetic (AFM) moment directions of NiPSe3 switch from out-of-plane to in-plane and the honeycomb layers slide relative to each other at the first structural transition. The in-plane AFM order persists until the second structural transition, whereupon the two-dimensional (2D) structure assumes a more three-dimensional (3D) character. A bandwidth-controlled Mott insulator-metal transition (IMT) occurs between the two structural transitions at Pc ~ 8.0 GPa, concomitant with the emergence of superconductivity with Tc ~ 4.8 K. The superconductivity in NiPSe3 emerging in the 2D monoclinic phase coexists with the in-plane AFM order and continues into the 3D trigonal phase. Our electronic structure calculations reveal that the IMT and superconductivity in NiPSe3 are both related to the enhanced Se2− 4p and Ni2+3d electronic hybridizations under pressure. From these results, we construct a temperature-pressure electronic phase diagram of NiPSe3, revealing interesting relationships between magnetism and superconductivity.

Pressure-driven structural transition in CoNi-based multi-principal element alloys

Pressure-driven phase transition in metals has been a hot topic because it is an effective means to induce fresh phase, benefit of tuning the properties of materials. Herein, CoNiFe, CoNiCr, and CoNiV multi-principal element alloys (MPEAs) were investigated by an in situ high-pressure x-ray diffraction technique. It is found that the pressure-induced phase transition from face-centered cubic to hexagonal close-packed phase occurs at 15.60, 13.84, and 8.20 GPa, respectively. The atomic size misfit of CoNiFe, CoNiCr, and CoNiV MPEAs is estimated to be 0.653%, 2.077%, and 3.013%, respectively, illustrating that the lattice distortion degree is increasing. The increase in lattice distortion can decrease the initial phase-transition-pressure because lattice distortion could reduce the strain to nucleate Shockley partial dislocation, which promotes the formation of a stacking fault (SF) stack of three atomic layers with hcp stacking. However, the quantitative calculation of stacking fault probability α as a function of pressure demonstrates that the probability of SF formation gradually increases in order of CoNiFe, CoNiCr, and CoNiV, which is in line with the critical pressure of phase transition decreasing orderly. Furthermore, the first peak in the pair distribution function curve after entirely decompression not fully reverts to its initial state, proving the densification of MPEAs under pressure. These findings provide an innovative light for understanding pressure-induced phase transitions in MPEAs.

High-pressure X-ray diffraction for visualization of transient intermediates in the tryptophan synthase mechanism

High-pressure X-ray diffraction for visualization of transient intermediates in the tryptophan synthase mechanism

Equation of state of ammonia dihydrate up to 112 GPa by static and dynamic compression experiments in diamond anvil cells

Understanding the high-pressure behavior of ammonia hydrates is relevant for modeling the interior of solar and extrasolar icy bodies. We present here the results of high-pressure x-ray diffraction studies on ammonia-dihydrate (ADH) at room temperature (298 K) up to 112 GPa, employing both static and dynamic compression experiments performed in diamond anvil cells. The derived pressure-volume (P-V) compression curves are in excellent agreement regardless of the compression technique. In contrast to early theoretical predictions, our results indicate the stability of the disordered molecular alloy (DMA) phase, a body centered cubic (bcc) structure, and the absence of self-ionization in the investigated pressure range. By combining the P-V data from seven different compression runs, we derive the first equation of state for ADH-DMA based on the third-order Birch-Murnaghan formalism with best-fit parameters: ${V}_{0}=23.96\ifmmode\pm\else\textpm\fi{}0.03$ (${\AA{}}^{3}$/molecule), ${B}_{0}=9.95\ifmmode\pm\else\textpm\fi{}0.14$ GPa, and ${B}_{0}^{\ensuremath{'}}=6.59\ifmmode\pm\else\textpm\fi{}0.03$. The instantaneous bulk modulus directly derived from the quasicontinuous compression curves displays a smooth increase upon compression that further supports the absence of structural transitions.

Pressure effect on the electrical properties and pressure-induced phase transitions in a three-dimensional Dirac semimetal BaAgBi

High pressure is an effective and clean method for tuning lattice structures and electronic states. In this study, we report on the crystal growth and experimental study of the pressure effect on the three-dimensional Dirac semimetal BaAgBi. Within the pressure range of 51.8 GPa studied in this work, BaAgBi remained metallic and no superconductivity was observed down to 1.6 K. The resistance is primarily governed by the electron-phonon and s-d electron-electron scattering. High-pressure synchrotron X-ray diffraction experiments indicated the presence of two high-pressure phases below 50 GPa, and the crystal structures were proposed to be Pnma and Pca21, respectively. By refining the high-pressure X-ray data, we plotted the pressure dependence of unit cell volumes and obtained the bulk modulus for all three phases.

Magnetic ordering in terbium at high pressures and low temperatures

We have investigated magnetic ordering in the heavy lanthanide terbium (Tb) for pressures up to 70 GPa and temperatures down to 20 K by synchrotron x-ray diffraction at the Advanced Photon Source, Argonne National Laboratory. The x-ray diffraction studies were complemented by neutron diffraction studies at the Spallation Neutron Source, Oak Ridge National Laboratory. We focused on the higher-pressure phases of Tb, such as the double hexagonal close-packed (dhcp, above 16 GPa), distorted face-centered cubic (hR24, above 30 GPa), and orthorhombic (oF16, above 51 GPa) phases. We observed the phenomenon of spontaneous magnetostriction in the dhcp and hR24 phases, where magnetic ordering at low temperatures gives rise to subtle splitting in x-ray diffraction peaks. The neutron diffraction study of the dhcp phase at 20 GPa revealed magnetic peaks that can be assigned a propagation vector k=(12,0,12), and a magnetic ordering temperature that is consistent with the magnetostriction effect observed with x-ray diffraction. The high-pressure and low-temperature x-ray diffraction study at 70 GPa in the collapsed oF16 phase did not show any evidence of magnetostriction, indicating a significant decrease in the magnetic moment of the 4f-shell due to band broadening at ultra-high compression.

Switching On/Off of a Solvent Coordination in a Au(I)-Pb(II) Complex: High Pressure and Temperature as External Stimuli.

The benzonitrile solvate {[{Au(C6F5)2}2{Pb(terpy)}]·NCPh}n (1) (terpy = 2,2':6',2″-terpyridine) displays reversible reorientation and coordination of the benzonitrile molecule to lead upon external stimuli. High-pressure X-ray diffraction studies between 0 and 2.1 GPa reveal a 100% of conversion without loss of symmetry, which is totally reversible upon decompression. By variable-temperature X-ray diffraction studies between 100 and 285 K, a partial coordination is achieved.

Survival of Zirconium-Based Metal-Organic Framework Crystallinity at Extreme Pressures.

Recent research on metal-organic frameworks (MOFs) has shown a shift from considering only the crystalline high-porosity phases to exploring their amorphous counterparts. Applying pressure to a crystalline MOF is a common method of amorphization, as MOFs contain large void spaces that can collapse, reducing the accessible surface area. This can be either a desired change or indeed an unwanted side effect of the application of pressure. In either case, understanding the MOF's pressure response is extremely important. Three such MOFs with varying pore sizes (UiO-66, MOF-808, and NU-1000) were investigated using in situ high-pressure X-ray diffraction and Raman spectroscopy. Partial crystallinity was observed in all three MOFs above 10 GPa, along with some recovery of crystallinity on return to ambient conditions if the frameworks were not compressed above thresholds of 13.3, 14.2, and 12.3 GPa for UiO-66, MOF-808, and NU-1000, respectively. This threshold was marked by an unexpected increase in one or more lattice parameters with pressure in all MOFs. Comparison of compressibility between MOFs suggests penetration of the pressure-transmitting oil into MOF-808 and NU-1000. The survival of some crystallinity above 10 GPa in all of these MOFs despite their differing pore sizes and extents of oil penetration demonstrates the importance of high-pressure characterization of known structures.

Pressure-induced nonmonotonic cross-over of steady relaxation dynamics in a metallic glass

Relaxation dynamics, as a key to understand glass formation and glassy properties, remains an elusive and challenging issue in condensed matter physics. In this work, insitu high-pressure synchrotron high-energy X-ray photon correlation spectroscopy has been developed to probe the atomic-scale relaxation dynamics of a cerium-based metallic glass during compression. Although the sample density continuously increases, the collective atomic motion initially slows down as generally expected and then counterintuitively accelerates with further compression (density increase), showing an unusual nonmonotonic pressure-induced steady relaxation dynamics cross-over at ~3 GPa. Furthermore, by combining insitu high-pressure synchrotron X-ray diffraction, the relaxation dynamics anomaly is evidenced to closely correlate with the dramatic changes in local atomic structures during compression, rather than monotonically scaling with either sample density or overall stress level. These findings could provide insight into relaxation dynamics and their relationship with local atomic structures of glasses.

Pressure- and Rate-Dependent Mechanoluminescence with Maximized Efficiency and Tunable Wavelength in ZnS: Mn2+, Eu3.

Mechanoluminescence (ML) has received widespread attention because of potential application in stress sensors and imaging. However, pursuing highly efficient ML remains a challenge due to multifactorial limitations such as pressure and loading rate. Here, we systematically investigate pressure- and rate-dependent ML in Mn2+ and Eu3+ co-doped ZnS in a gigapascal pressure range by using a high-pressure dynamic diamond anvil cell and microsecond time-resolved fluorescent methods and demonstrate the giant tunability in both ML efficiency and wavelength. Compressed from ambient pressure to 11 GPa at different compression rates, ZnS: Mn2+, Eu3+ exhibits a volcano shape in ML emission efficiency with an optimum at ∼3.5 GPa and ∼211.1 GPa/s, at least 1000-fold higher than that measured in the MPa range. The pressure-dependent ML is accompanied with a tunable yellow-to-red emission color change. A combination of high-pressure X-ray diffraction and photoluminescence measurements reveals that the pressure- and rate-dependent ML behavior derives from pressure-induced strengthening of the crystal piezoelectric field and enhanced interaction between the host lattice and doped ions with a significant change of the energy level of the Mn ion. Significantly, the highly efficient ML of ZnS: Mn2+, Eu3+ at the GPa level is reproducible under a compression-decompression process and can be manipulated on a micron scale, implying great potential in mechanical-optical energy conversion and application in dynamic pressure imaging, stress sensors, and multicolor displays.

Pressure-Induced Structural Phase Transition of Co-Doped SnO2 Nanocrystals

Co-doped SnO2 nanocrystals (with a particle size of 10 nm) with a tetragonal rutile-type (space group P42/mnm) structure have been investigated for their use in in situ high-pressure synchrotron angle dispersive powder X-ray diffraction up to 20.9 GPa and at an ambient temperature. An analysis of experimental results based on Rietveld refinements suggests that rutile-type Co-doped SnO2 undergoes a structural phase transition at 14.2 GPa to an orthorhombic CaCl2-type phase (space group Pnnm), with no phase coexistence during the phase transition. No further phase transition is observed until 20.9 GPa, which is the highest pressure covered by the experiments. The low-pressure and high-pressure phases are related via a group/subgroup relationship. However, a discontinuous change in the unit-cell volume is detected at the phase transition; thus, the phase transition can be classified as a first-order type. Upon decompression, the transition has been found to be reversible. The results are compared with previous high-pressure studies on doped and un-doped SnO2. The compressibility of different phases will be discussed.

Effect of nonhydrostatic pressure on the superconducting kagome metal CsV3Sb5

High-pressure single-crystal x-ray diffraction experiments reveal that the superconducting kagome metal ${\mathrm{CsV}}_{3}{\mathrm{Sb}}_{5}$ transforms from hexagonal ($P6/mmm$) to monoclinic ($C2/m$) symmetry above 10 GPa if nonhydrostatic pressure conditions are created in a diamond anvil cell with silicon oil as the pressure-transmitting medium. This is contrary to the behavior of ${\mathrm{CsV}}_{3}{\mathrm{Sb}}_{5}$ under quasihydrostatic conditions in neon, with the hexagonal symmetry retained up to at least 20 GPa. Monoclinic distortion leaves the kagome planes almost unchanged, but deforms honeycomb nets of the Sb atoms. While the onset of the distortion almost coincides with the reentrance of superconductivity, our ab initio density-functional calculations reveal only minor changes in the electronic structure compared to the quasihydrostatic case. In particular, Fermi surface reconstruction driven by the formation of interlayer Sb-Sb bonds is observed in both monoclinic and hexagonal ${\mathrm{CsV}}_{3}{\mathrm{Sb}}_{5}$ structures at high pressures and comes out as the likely cause for the reentrant behavior.

Joint experimental and theoretical study of bulk Y2O3 at high pressure

We report a joint experimental and theoretical study of the structural and vibrational properties of C-type bulk Y2O3 under hydrostatic compression. The combination of high-pressure X-ray diffraction and Raman scattering experimental measurements with ab initio theoretical calculations on bulk Y2O3 allows us to confirm the cubic (C-type) – monoclinic (B-type) – trigonal (A-type) phase transition sequence on the upstroke and the trigonal-monoclinic phase transition on the downstroke. This result reconciles with the results already found in related rare-earth sesquioxides of cations with similar ionic radii as Y, such as Ho2O3 and Dy2O3, and ends with the controversy regarding the existence of the intermediate monoclinic phase between the cubic and trigonal phases in pure bulk Y2O3 on the upstroke. As a byproduct, the good agreement between experimental and calculated results allows us to use extensive theoretical data to discuss the structural and vibrational behavior of the three phases of Y2O3 under compression, thus allowing a more detailed understanding of the effect of pressure on rare-earth sesquioxides than previous studies.

High-pressure phase of cold-compressed bulk graphite and graphene nanoplatelets

We have studied the high-pressure vibrational and structural behavior of bulk graphite and graphene nanoplatelets at room temperature by means of high-pressure Raman spectroscopic and x-ray diffraction probes. We have detected a clear pressure-induced structural transition in both materials, evidenced by the appearance of new Bragg peaks and Raman features, deviating from the starting hexagonal graphitic structure. The high-pressure phase is identified as a partially disordered orthorhombic structure, consisting of mixed $s{p}^{2}$- and $s{p}^{3}$-type bonding. Our experimental findings serve as direct evidence for the existence of a metastable transient modification in cold compressed carbon, lying between the $s{p}^{2}$-type graphite and ${sp}^{3}$-type diamond allotropes.

Shear stress induced phase transitions of cubic Eu2O3 under non-hydrostatic pressures

Pressure-induced phase transitions in cubic Eu2O3 subjected to non-hydrostatic conditions have been studied by in situ high-pressure synchrotron angle dispersive x-ray diffraction and Raman scattering measurements up to 30.1 and 43.8 GPa, respectively. Both x-ray diffraction and Raman spectroscopy results indicate that the pressure-induced transition routines of cubic Eu2O3 depend on the nature of stress loading. In contrast to our previous high-pressure studies of cubic Eu2O3 under hydrostatic pressure, where cubic Eu2O3 transforms directly into a hexagonal structure, the x-ray diffraction data show that cubic Eu2O3 begins to transform into the monoclinic phase at a non-hydrostatic pressure of about 4.3 GPa, while the monoclinic to hexagonal phase transition is initiated at about 6.4 GPa. These phase transitions have also been confirmed by Raman spectroscopy; the hexagonal phase is stable up to at least 43.8 GPa; and the material decompressed from high pressures is composed of a monoclinic phase, showing that the cubic Eu2O3 to monoclinic phase transition is irreversible due to the constructive nature. Pressure coefficients of Raman peaks and Grüneisen mode parameters of cubic, monoclinic, and hexagonal phases followed under pressure were determined. Furthermore, this study provides evidence for the shear stress-induced cubic to monoclinic phase transition in cubic Eu2O3 and the corresponding mechanism.

High-Pressure Experimental and DFT Structural Studies of Aurichalcite Mineral

We report on high-pressure angle-dispersive synchrotron X-ray diffraction data of a natural Zn3.78(2)Cu1.22(2)(CO3)2(OH)6 aurichalcite mineral up to 7.6 GPa and ab initio total energy calculations of the aurichalcite structure with three different Zn-Cu stoichiometries (Zn:Cu ratios = 10:0, 8:2 and 6:4). A monoclinic-to-triclinic displacive second-order phase transition was found experimentally at 3 GPa. The experimental bulk modulus of the initial P21/m aurichalcite is B0 = 66(2) GPa, with a first-pressure derivative of B0′ = 9(2). A comparison with other basic copper and zinc carbonates shows that this B0 value is considerably larger than those of malachite and azurite. This relative incompressibility occurs despite the fact that aurichalcite features a layered structure due to the number of directed hydrogen bonds between carbonate groups and the cation-centered oxygen polyhedra forming complex sheets. The existence of different bond types and polyhedral compressibilities entails a certain anisotropic compression, with axial compressibilities κa0 = 3.79(5)·10−3 GPa−1, κb0 = 5.44(9)·10−3 GPa−1 and κc0 = 4.61(9)·10−3 GPa−1. Additional density-functional theory calculations on the C2/m hydrozincite-type structure with different Zn:Cu compositional ratios shows that the aurichalcite structure is energetically more stable than the hydrozincite one for compositions of Zn:Cu = 10:0, 8:2 and 6:4 at room pressure. The pure Zn aurichalcite phase, however, was predicted to transform into hydrozincite at 18 GPa, which suggests that the experimentally observed hydrozincite structure is a metastable phase.

Pressure-Induced Ferroelastic Transition Drives a Large Shape Change in a Ni(II) Complex Single Crystal.

Crystals with significant length reduction at an accessible low pressure are highly desirable for piezo-responsive devices. Here, we show a molecular crystal [Ni(en)3](ox) (en = ethylenediamine and ox = oxalate anion) that exhibits an abrupt shape change with a contraction rate of ∼4.7% along its c axis near the phase transition pressure of ∼0.2 GPa. High-pressure single-crystal X-ray diffraction and Raman spectroscopy measurements reveal that this material undergoes a first-order ferroelastic transition from high-symmetry trigonal P3̅1c to low-symmetry monoclinic P21/n at ∼0.2 GPa. The oxalate anions serve as unique components, and their disorder-order transformation and rotation of 90° through cooperative intermolecular hydrogen bonding triggered unconventional anisotropic microsize contraction under compression, which can be appreciated visually. Such a prominent directional deformation at a low pressure driven by molecular motors of oxalate anions provides insights for the design of novel molecular crystal-based piezo-responsive switches and actuators in deep-sea environments.

Superconductivity emerging from a pressurized van der Waals kagome material Pd3P2S8

Kagome materials have been reported to possess abundant and peculiar physical properties, which provide an excellent platform to explore exotic quantum states. We present a discovery of superconductivity in van der Waals material Pd3P2S8 composed of Pd kagome lattice under pressure. Pd3P2S8 displays superconductivity for those pressures where the semiconducting-like temperature dependence of the resistivity turns into a metallic one. Moreover, it is found that the increased pressure results in a gradual enhancement of superconducting transition temperature, which finally reaches 6.83 K at 79.5 GPa. Combining high-pressure x-ray diffraction, Raman spectroscopy and theoretical calculations, our results demonstrate that the observed superconductivity induced by high pressure in Pd3P2S8 is closely related to the formation of amorphous phase, which results from the structural instability due to the enhanced coupling between interlayer Pd and S atoms upon compression.