High-pressure Rate Research Articles

High-Pressure Rate Rules for Ether Alkylperoxy Radical Isomerization.

The first isomerization reaction of an alkylperoxy (RO2) radical holds significant importance in low-temperature oxidation, as it governs the branching ratios of the hydroperoxyalkyl (QOOH) radicals, which influence the competition between the chain-propagation and chain-branching reactions. In this study, we systematically calculated high-pressure rate rules for the RO2 isomerization reaction of monoethers, exploring 5-, 6-, 7-, and 8-membered ring transition states. Primary, secondary, and tertiary carbon sites, where both the abstracting peroxy group and the abstracted hydrogen are located, were considered, with particular emphasis on distinguishing between secondary carbons adjacent (alpha) and nonadjacent to the ether functional group. Using the G4//B3LYP/6-311++G(2df,2pd) level of theory and the transition state theory, we estimated the rate constants and the Arrhenius coefficient for over 120 possible isomerization reactions. We examined the effect of ring size and ring atoms, revealing that 6- and 7-membered ring isomerizations were generally the fastest. The impact of the ether functional group on transition states was investigated by comparing reactions with identical ring size, peroxy, and radical positions, but with the ether functional group positioned either outside (i.e., out) or inside (i.e., in) the transition state ring, leading to differences in the rate constants. When comparing to analogous alkane rate constants, differences of up to an order of magnitude were observed, underscoring the need for caution when assigning rate rules by analogy. We applied our rate constants in the di-iso-butyl ether kinetic model and evaluated their influence on low-temperature chemistry finding that they altered the branching ratios by up to a factor of 9, highlighting the significance of site-specific rate constants for more accurate low-temperature modeling.

An experimental and mechanism study on the pyrolysis of sulfur mustard

Experimental studies on the pyrolysis of sulfur mustard (HD) were conducted from 673 to 1473 K using Py-GC/MS combined with two separate columns. The HD pyrolysis rate exceeded 99 % at a pyrolysis time of approximately 2 seconds above 1073 K. The pyrolysis products of HD mainly include ethylene, vinyl chloride, carbon disulfide, thiophene, hydrogen chloride and hydrogen sulfide. The main reaction mechanism of HD pyrolysis was investigated using quantum chemistry methods combined with the TST/VTST theory. At 673 K, the initial reaction pathway of HD primarily involves an intramolecular HCl elimination and the cleavage of the C-S bond. The radical reactions will dominate the pyrolysis of HD once radical pool is formed. The reaction pathways of the important radical intermediates were analyzed, and the formation mechanisms of the main pyrolysis products were investigated. Theoretically, the high-pressure limit rate constants for the major reactions were calculated. This study contributes to a deeper understanding of the HD pyrolysis mechanism and provides a theoretical and data foundation for the destruction of HD.

Computational boundary improvement and performance optimization of the flue gas waste heat cascade utilization system of the ultra-supercritical 1000 MW generator set

Abstract There is no uniform performance test rule and standard calculation method for efficiency improvement of a system that utilizes waste heat from flue gas and it is mainly carried out through turbine parameters, without considering boiler system performance. Given the above problem, in this paper, the steam turbine, boiler and waste heat from the flue gas step-up utilization system are calculated by establishing a thermal model of ultra-supercritical secondary reheating 1000 MW unit. At the same time, unit design data and field performance test results are used for verification. Analysis comparing simulation outcomes with experimental data revealed that the discrepancies in the heat consumption rate per unit, the efficiency of the boiler, and the rate of coal consumption for power generation peaked at a marginal variance of 0.2%. The optimum operating parameters of the system for low-grade flue gas recovery in a cascading manner are obtained through variable operating condition calculations. The optimum value of high-pressure bypass feed-water flow rate is 52 kg/s at 970 MW operating condition. At the same time, the difference between high-pressure bypass effluent and high plus effluent temperatures should be controlled to be close to 0°C, and the optimal value of low-pressure bypass condensate flow rate is 53 kg/s. As the flow of flue gas in the bypass increases, the efficiency of heat exchange in the bypass economizer also increases, resulting in greater absorption of heat in the utilization apparatus for flue gas waste heat, leading to a more effective energy-saving outcome. However, it is necessary to regulate the temperature of both the primary and secondary air to levels that exceed the minimum requirements for the safe functioning of the coal mill.

Calculating the number of radial cracks around a wellbore fractured by liquid CO2 phase transition blasting technology

Integrating liquid CO2 phase transition blasting (LCPTB) technology with hydraulic fracturing (HF) methods can help reduce wellbore damage, create multiple radial fractures, and establish a complex fracture network. This approach significantly increases the recovery efficiency of low-permeability oil and gas fields. Accurately calculating the number of fractures caused by LCPTB is necessary to predict production enhancement effects and optimize subsequent HF designs. However, few studies are reported on large-scale physical model experiments in terms of a method for calculating the number of fractures. This study analyzed the initiation and propagation of cracks under LCPTB, derived a calculation formula for crack propagation radius under stress waves, and then proposed a new, fast, and accurate method for calculating the number of fractures using the principle of mass conservation. Through ten rock-breaking tests using LCPTB, the study confirmed the effectiveness of the proposed calculation approach and elucidated the variation rule of explosion pressure, rock-breaking scenario, and the impact of varying parameters on number of fractures. The results show that the new calculation method is suitable for fracturing technologies with high pressure rates. Recommendations include enlarging the diameter of the fracturing tube and increasing the liquid CO2 mass in the tube to enhance fracture effectiveness. Moreover, the method can be applied to other fracturing technologies, such as explosive fracturing (EF) within HF formations, indicating its broader applicability and potential impact on optimizing unconventional resource extraction technologies.

Numerical simulation study on growth rate and gas reaction path of InN-MOCVD with Close-Coupled showerhead reactor

Numerical study on the influence of the carrier gas (H2 and N2), V/III ratio, inlet temperature, and pressure on gas reaction path and growth rate of indium nitride (InN) thin film in metal–organic chemical vapor deposition (MOCVD) with close-coupled showerhead (CCS) reactor was conducted. It was found that the concentrations of precursor for InN film and nanoparticle determine the growth rate and gas reaction path. InN exhibits greater difficulty in undergoing pyrolysis reactions compared to AlN and GaN. Under the conditions of this study, the gas reaction path of InN-MOCVD be dominated by adduct/amide formation path. When H2 is used as the carrier gas, the effect of H radicals on gas reactions is relatively minor, while the effect of NH2 radicals generates more nanoparticles, and significant changes in flow fields are observed compared to using N2 as the carrier gas. Under the conditions of low V/III ratio, low inlet temperature, high pressure, and low gas flow rate, the growth rate is relatively high, but the growth uniformity is decreased. There are different reasons for the effects of the above parameters, such as, altering TMIn flow to change V/III ratio and precursor concentration, varying temperature gradient due to changes in inlet temperature, and increased the particle collision frequency and residence time due to high pressure and low gas flow rate.

A rigid microfluidic chip for high-throughput fluorescence-activated cell sorting

Fluorescence-activated cell sorting (FACS) holds great promise for the separation of single cells or cell populations according to specific light scattering and fluorescent characteristics. Here, we present a new perspective on microfluidic FACS (μFACS) with predictable geometry, which meets the requirements of high-throughput analysis and sorting. Instead of the widely applied elastic polydimethylsiloxane (PDMS), a rigid epoxy resin chip was rapidly fabricated and irreversibly encapsulated to eliminate channel deformation (tenfold reduction) and enhance performance while meeting high pressure (>600 kPa) and high flow rate application scenarios. Fluorescence discrimination and particle differentiation were additionally validated in a self-contained μFACS system using calibration microspheres and mammalian cells. The μFACS chip and system were integrally optimized to achieve a minimum interval (0.58 ms) with a mean flow rate of 1.5 m/s. Ultimately, event recording and automated sorting were accomplished in real time while achieving a sorting efficiency of 87% at cell throughput of 8,000 events/s. This rigid chip for high-throughput μFACS, which is independent of the physical properties of cells could pave the way for cell screening in plasma samples for personalized medicine.

Experimental Investigation of the Effect of Fault Reactivation Induced by Water Injection

An understanding of fault reactivation induced by water injection is of great significance for geothermal energy development and utilization. We conducted a series of water injection shear tests on low-permeability granite samples that each contained a single saw-cut fault under locally undrained conditions. Slip characteristics were analyzed by varying the fluid pressurization rate, confining pressure, and stress state of the fault to understand fault reactivation. The experimental results demonstrated that at a high pressurization rate, a higher local fluid pressure was needed to reactivate the fault than had been estimated theoretically, and the required fluid pressure increased with an increase in pressurization rate. The fluid pressurization rate and confining pressure both controlled the slip mode of the fault. The slip mode changed from dynamic slip to quasi-static slip at a high pressurization rate, and the peak slip rate of dynamic slip increased with an increasing pressurization rate. The fault showed significant stick-slip characteristics under a high confining pressure, as fault locking and reactivation phenomena occurred repeatedly. Faults with different initial stress states had little influence on the slip mode after the onset of slip.

The effect of temperature on injection-induced shear slip of laboratory faults in sandstone

Fluid injection into subsurface reservoirs may cause existing faults/fractures to slip seismically. To study the effect of temperature on injection-induced fault slip, at a constant confining pressure of 10 MPa, we performed a series of injection-induced shear slip experiments on critically stressed sandstone samples containing saw-cut fractures (laboratory-simulated faults) under varying fluid pressurization rates (0.1 and 0.5 MPa/min, respectively) and temperatures (25, 80, and 140 °C, respectively). At 25 °C, slow fault slip events with a peak slip velocity of about 0.13 μm/s were observed on a tested sample in response to a low fluid pressurization rate of 0.1 MPa/min. In contrast, fluid injection with a high pressurization rate of 0.5 MPa/min caused fault slip events with a peak slip rate up to about 0.38 μm/s. In response to a given fluid pressurization rate, several episodes of slip events with a higher slip velocity were induced at an elevated temperature of 140 °C, indicating an appreciable weakening effect at elevated temperatures. We also experimentally constrained the rate-and-state frictional (RSF) parameters at varying effective normal stresses and temperatures by performing velocity-stepping tests. The obtained RSF parameters demonstrate that for a relatively high normal stress, increasing temperature tends to destabilize fault slip. Post-mortem microstructural observations reveal that elevated temperatures promote the generation of abundant fine-grained gouge particles associated with injection-induced shear slip. Our experiments highlight that injection-induced fault slip is affected by temperature-related wear production over the fault surface.

Combustion performance modulation and agglomeration inhibition of HTPB propellants by fine Al/oxidizers integration

Modulation of burning rates and inhibition of aluminum agglomeration in solid propellants have generated considerable research interest in the field of energetic materials. In this paper, integrated Al/oxidizer composites have been prepared by a spray-drying technique, which offer intimate contact between the fuel and oxidizers. The morphologies, thermal stability, density, heats of explosion and combustion performance of the resulted solid propellants containing these Al-based composites were systematically investigated, where the condensed combustion products (CCPs) analysis and the agglomeration behavior of Al particles have been focused. After well control of the Al/oxidizers structure, 9 % higher explosion heat, 58 % higher pressurization rate and 65 % stronger flame radiation intensity were achieved in comparison to the conventional solid propellants with the same formulation. The burn rate of the propellants can also be well controlled by using different type of Al/oxidizers composites, in the range of 3.6–5.9 mm s−1 under 0.5 MPa and 9.2–10.9 mm s−1 under 15 MPa. More importantly, very low burn rate pressure exponent of 0.1 within 0.5–15 MPa was obtained. Inspired by decreasing size of CCPs, the evolution of Al on the burning surface was studied and the agglomeration inhibition was observed, whose potential mechanism was then proposed and elucidated.

The Effects of Noise Pollution on the Prevalence of High Blood Pressure and Abnormal Pulse Rate on Workers in select Industries in Nnewi

This study investigates the impact of noise pollution on the prevalence of high blood pressure and abnormal pulse rate among workers in selected industries in Nnewi, Nigeria. Utilizing a cross-sectional design, the research encompassed 250 workers exposed to varying levels of noise pollution. Data on blood pressure, pulse rate, and noise exposure were collected and analyzed using descriptive and inferential statistics. The findings reveal a significant correlation between prolonged exposure to high noise levels and increased instances of high blood pressure and abnormal pulse rates among the participants. These outcomes underscore the critical need for stringent noise control measures and regular health monitoring in industrial settings to mitigate the adverse health effects associated with noise pollution. This research contributes to the body of knowledge on occupational health, emphasizing the importance of creating a safer work environment to enhance workers' wellbeing.

Theoretical kinetic studies on intramolecular H-migration reactions of peroxy radicals of diethoxymethane.

Diethoxymethane (DEM), a promising carbon-neutral fuel, has high reactivity at low temperatures. The intramolecular hydrogen migration reaction of the DEM peroxy radicals can be viewed as a critical step in the low temperature oxidation mechanism of DEM. In this work, multistructural transition state theory (MS-TST) was utilized to calculate the high-pressure limit rate constants of 1,5, 1,6 and 1,7 H-migration reactions for DEM peroxy radicals. In addition to the tunneling effects and anharmonic effects, the intramolecular effects, including steric hindrance, intramolecular hydrogen bonding and conformational changes in reactants and transition states, are also considered in the rate constant calculations. The calculated energy barriers and rate constants demonstrated the substantial impact of intramolecular effects on the kinetics of H-migration reactions in DEM peroxy radicals. Specifically, the distinct configurations of transition states could potentially influence the reaction kinetics. The pressure-dependent rate constants are computed using system-specific quantum RRK theory. The calculated results show that the falloff effect of 1,5 and 1,6 H-migration reactions is more pronounced than that of the 1,7 H-migration reaction. The thermodynamics and kinetics presented in this study could be instrumental in understanding the low-temperature oxidation mechanism of DEM and might prove crucial for future research on comprehensively analyzing the autoignition behavior.

A theoretical model for the oblique impact of fragments

A portion of the casing charge's fragments would strike the target plate and ricochet when it exploded close to or inside a steel structure, like a ship or manufacturing facility. Considering the high pressure, high temperature, and high strain rate during the impact, the kinematic characteristics of the ricochet fragment, such as ricochet velocities and ricochet angle, are challenging to describe using the existing methods. In this study, a novel theoretical model of ricochet fragment kinematics under oblique impact was proposed, and the corresponding initial assumptions and application conditions were presented. A series of oblique impact experiments was conducted to obtain the differences in kinematic characteristics under various impact velocities and impact angles. The parameters of the proposed theoretical model were determined. The accuracy of the theoretical model was verified by using 921A hull steel target plate. The average relative error and standard deviation of ricochet velocity were 7.4 % and 2.3 %, respectively, and the mean relative error and standard deviation of the ricochet angle are 11.2 % and 1.1 %, respectively. The results showed that the theoretical model can predict the ricochet velocity well, and the error of ricochet angle increased due to the different pile-up effect of different strength target plates, but it was still within the reasonable range. In addition, the effects of the impact velocity and angle on the ricochet velocity and angle were analyzed. When the impact angle was small, the ricochet angle and velocity were affected by both impact velocity and angle. When the impact angle increased to a certain Angle (>64.2°), the ricochet velocity only increased linearly with the impact velocity. The ricochet angle increased with the increase in the impact angle. When the impact velocity was less than 400 m/s, the ricochet angle increased with the increase in the impact velocity. When the velocity is greater than 400 m/s, the ricochet angle decreased with the increase in the impact velocity. When the impact angle was greater than 57° and the impact velocity was greater than 400 m/s, the ricochet angle was almost only related to the impact angle. The results indicate that the proposed model has good accuracy and can have high application value in terminal effects, safety engineering, and structural defense fields.

On the decomposition mechanism of propanal: rate constants evaluation and kinetic simulations

The reactivity of aldehydes has been the subject of considerable interest in chemical kinetics, with propanal often chosen as the representative species. Despite its relevance, the reactivity of propanal is currently estimated from analogy and fitting of experimental data measured in limited temperature and pressure ranges, while the few literature theoretical studies have focused more on the exploration the potential energy surface (PES) than on the estimation of rate constants. The purpose of this work is to reinvestigate the propanal decomposition kinetics using the ab initio transition state theory based master equation approach with the intent of: (1) Determining accurate rate constants of key reaction channels; (2) Updating and validating an existing kinetic model by simulating available experimental data on propanal pyrolysis. It is found that propanal decomposition at the initial stages of pyrolysis occurs through four unimolecular barrierless reactions to form CHO + C2H5, CH2CHO + CH3, CH3CHCHO + H, and CH3CH2CO + H, and a termolecular pathway leading to the formation of C2H4 + CO + H2. High pressure rate constants were determined for each barrierless reaction channel using Variable Reaction Coordinate Transition State Theory and used to estimate phenomenological temperature and pressure dependent channel specific rate constants integrating the 1 dimensional master equation over the whole PES. The decomposition rate constants so determined are in agreement with the few available experimental data and significantly faster than previous literature estimates. The estimated kinetic parameters were finally implemented into the CRECK kinetic mechanism, leading to an improved agreement with shock tube pyrolysis data from the literature.

Preparation of microstructure controllable Al/WO3/F2603 MICs by droplet microfluidic technology to improve combustion performance

The microstructure of metastable intermolecular composites (MICs) is crucial for their energy release and combustion performance. In this paper, Al/WO3/F2603 composites with controllable microstructure were prepared by droplet microfluidic technology. The microstructure control method of composite materials based on droplet microfluidic technology (DMT) was studied. Particles with controllable size, shape, composition, structure and function were prepared by droplet template, and the formation mechanism of particle microstructure was introduced. The Al/W/F-2 composites with high-quality spherical encapsulation have excellent flow properties and wettability. The ignition delay, combustion time and pressure output of the composites were monitored by a combustion and pressure test system. Compared with the physically mixed samples, the Al/W/F-x composites prepared by DMT have shorter ignition delay, shorter combustion duration, and higher pressurization rate. The analysis of combustion products showed that the encapsulated Al/W/F-x composites reduced the sintering and agglomeration of reactants and promoted the combustion efficiency. The results show that the characteristic structure design of the composite material can establish the interface synergy, enhance the thermal mass transfer between the components, and thus reduce the ignition delay and improve the combustion performance. DMT can realize the controllable preparation of composite microstructure, which provides a reference for the design and preparation of other composite materials.

Corrosion Analysis and Prevention of Tubing Nipples in Four Wells

A high-temperature and high-pressure gas field in an oil field requires the use of super 13 chromium material due to corrosive environments. In the recent production process, there have been four consecutive cases of corrosion, fracture, and perforation of tubing nipples, which have brought enormous economic losses to the oilfield. This article analyzes the failure causes of these four tubing nipples and proposes preventive measures. In this paper, the macroscopic morphology, chemical composition, mechanical properties, metallography, and microscopic morphology of four failed tubing nipples have been analyzed. Combined with the field service conditions and string structure of the tubing nipples, it is believed that the failure of the tubing nipples is mainly due to the connection of carbon steel and stainless steel materials, forming a typical galvanic corrosion galvanic cell. The geometric and environmental factors of the materials exacerbate this corrosion. Eventually, severe galvanic corrosion occurred on the inner surface of the tubing nipple, resulting in severe wall thinning or partial perforation, and four tubing nipples failed. The failed tubing nipples in Wells A, B, and C have erosion marks, which are caused by the action of high pressure and high flow rate fluids in the well; The inner surface of the tubing nipple in Well D is rusty yellow, mainly due to the corrosion of its inner wall caused by the acid fracturing fluid injected earlier. At the same time, the string structure of four wells shows that the tubing nipple is located at the variable diameter node of the string. When the fluid in the well flows from the large hole into the smaller hole, the fluid in the well will change there, and its flow rate and pressure will also increase, further exacerbating the erosion in this area. With the development of deep wells containing carbon dioxide in oil fields and the application of carbon dioxide injection secondary oil recovery technology, the use of 13Cr martensitic stainless steel is also increasing. In order to avoid the occurrence of similar accidents that will bring huge economic losses to the oil field, it is recommended that the material of the pipe string (including accessories) of such wells be confirmed using a portable direct reading spectrometer before entering the well.

Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications

The Criegee intermediates (CIs), formed through ozone oxidation of unsaturated hydrocarbons, can undergo reactions with various carbonyl compounds in the atmosphere. In this study, we have investigated the 1,3-cycloaddition reaction of n-butyraldehyde with the simplest Criegee intermediate, CH2OO, using the OH laser-induced fluorescence (LIF) method. The experiments were conducted over a temperature and pressure range of 283–318 K and 5–100 Torr, respectively. Our results reveal that the bimolecular rate constant of the reaction is dependent on both temperature and pressure. Specifically, the measured rate constants at 100 Torr are (3.51 ± 0.63), (2.97 ± 0.53), (2.70 ± 0.49), and (2.52 ± 0.45) × 10−12 cm3 molecule−1 s−1 at temperatures of 283, 298, 308, and 318 K, respectively, with a total error of 18%. By fitting the pressure-dependent rate constants according to the Lindemann mechanism, we obtained a high-pressure limit rate constant of (3.05 ± 0.55) × 10−12 cm3 molecule−1 s−1 at 298 K. The Arrhenius plot of the temperature-dependent rate constants yields an activation energy of (−1.71 ± 0.30) kcal mol−1 and a pre-exponential factor of (1.66 ± 0.24) × 10−13 cm−3 s−1 (total error). Furthermore, our findings indicate that the title reaction exhibits a more pronounced temperature-dependent effect compared to that of CH2OO with water dimer and SO2, as well as that of OH with n-butyraldehyde. This observation suggests that the significance of title reaction in the atmosphere increases at lower temperature.

A plasma-based pressure pulse generator for simulating pellet-cladding mechanical interaction during reactivity-initiated accident.

This paper describes the characteristics of a plasma-based pressure pulse generator and its potential use as a simulator for studying pellet-cladding mechanical interaction (PCMI) during reactivity-initiated accidents (RIAs). In this device, a transient pressure pulse is generated by rapid heating and expansion of hot, dense plasma inside a nuclear fuel cladding. Thus, the parameters of a pressure pulse, such as peak pressure and pressure rise-rate, can be controlled by modifying the electrical parameters of a pulse discharge circuit. The pulse discharge circuit utilizes a capacitor bank comprising several energy storage capacitors connected in parallel and a high-power solid-state switch. A pressure loading system is attached as a load to the pulse discharge circuit. The power and energy delivered to the load are calculated by measuring the voltage and current waveforms at one end of the loading system. A piezoelectric sensor is connected at the other end of the loading system to simultaneously measure the pressure pulse inside the cladding tube. Preliminary experiments are carried out with a stainless-steel tube to characterize the performance of the device as well as with a pre-hydrided ZIRLO™ cladding tube to demonstrate the potential of the device as a simulator for studying the failure characteristics of the cladding as a result of an RIA. The high pressurization rate of the device is expected to offer unique advantages for studying the PCMI mechanism.

Cushing Index Based on Cushing Signs to Predict In-Hospital Death and Early Intervention for Minor Head Injury.

Abstract A considerable number of patients with mild traumatic brain injury have been known to "talk and die." Serial neurological examinations, however, have been the only method of determining the necessity of repeat computed tomography (CT), and no validated method has been available to predict early deterioration of minor head injury. This study aimed to evaluate the association between hypertension and bradycardia, a classic sign of raised intracranial pressure (Cushing reflex) on hospital arrival and determine the clinical consequences of minor head injury after blunt trauma. We created a new Cushing Index (CI) by dividing the systolic blood pressure by the heart rate (equaling the inverse number of the Shock Index, a score for hemodynamic stability) and hypothesized that a high CI would predict surgical intervention for deterioration and in-hospital death among patients with minor head injury. To test our hypothesis, a retrospective observational study was conducted using a nationwide trauma database. Accordingly, adult blunt trauma with minor head injury (defined as a Glasgow Coma Scale of 13-15 and Abbreviated Injury Scale score of ≥2 in the head) who were transported directly from the scene by ambulances were included. Among the 338,744 trauma patients identified in the database, 38,844 were eligible for inclusion. A restricted cubic spline regression curve for risks of in-hospital death was created using the CI. Thereafter, the thresholds were determined based on inflection points of the curve, and patients were divided into low-, intermediate-, and high-CI groups. Patients with high CI showed significantly higher in-hospital mortality rates compared with those with intermediate CI (351 [3.0%] vs. 373 [2.3%]; odds ratio [OR] = 1.32 [1.14-1.53]; p < 0.001). Patients with high index also had a higher incidence of emergency cranial surgery within 24h after arrival than those with an intermediate CI (746 [6.4%] vs. 879 [5.4%]; OR = 1.20 [1.08-1.33]; p < 0.001). In addition, patients with low CI (equal to high Shock Index, meaning hemodynamically unstable) showed higher in-hospital death compared with those with intermediate CI (360 [3.3%] vs. 373 [2.3%]; p < 0.001). In conclusion, a high CI (high systolic blood pressure and low heart rate) on hospital arrival would be helpful in identifying patients with minor head injury who might experience deterioration and need close observation.

High-pressure drop rates in solid-state batch one-step scCO2 foaming of acrylic polymers: A way to stabilize the structure of micro-nano foams

One-step solid-state batch scCO2 foaming is used with the target of achieving acrylic polymer micro-nano foams. Foaming is triggered by an average pressure drop (APDR), covering two decades, from 0.3 to 30 MPa.s−1. This study principally addresses the combined beneficial effects of block copolymer addition (BCP, here denoted as MAM) and high APDR. Numerous subtle kinetic parameters actually interplay and compete in the production of the final foams. In particular, the material effective temperature, the effective glass transition temperature of the plasticized system and the instantaneous PDR are physical quantities each having their own kinetics during foaming. The resulting foam morphologies are quantified by SEM microscopy and image analysis. A high APDR and the presence of BCP are shown to play a key role in the final structure of the foams. Over the scrutinized range of saturation temperature (40 °C to 60 °C i.e. rather ‘low’ temperatures in the CO2 supercritical state), the APDR is the main factor for significantly reducing cell size and increasing nuclei density in foams from neat PMMA. In the block copolymer approach, increasing the APDR is of secondary importance as the targeted reduction of the porosity dimensions and augmentation of nuclei density are mostly the consequence of MAM presence. In this latter case, increasing the APDR still promotes the ‘efficiency’ of the BCP nucleants. A real efficient nucleation activity of MAM additive is observed at a very high APDR (30 MPa.s−1), leading to monomodal homogeneous distribution of tiny pores in nearly nanosized foams. At lower APDR, an interesting reproducible double porosity (foams containing intra-wall and inter-wall pores) is detected in PMMA/MAM systems. In such double porosity foams, benefits from the Knudsen effect achieved within well expanded local domains (showing micron-sized pores) may remain meaningful thanks to a locally poorly expanded nanoporous thick solid skeleton encapsulating these local domains. Thereby, the radiative thermal conduction can be minimized and does not override the conductive component at the sample scale. This work provides further insight on acrylic polymer BCP foams influenced by different kinetics.

Investigating the influence of plastic waste oils and acetone blends on diesel engine combustion, pollutants, morphological and size particles: Dehalogenation and catalytic pyrolysis of plastic waste

Most research into the treats of plastic wastes have concentrated mainly on single-exposure pathways or products. These practices fail to acknowledge that the complications of carbon particles from engines are produced not only by diesel but by any plastic oils due to the vast amount of contaminants. With the potential to significantly weaken the impact of contaminants, the present study investigates the effects of dehalogenation and catalytic pyrolysis on plastic waste, as well as the risks associated with plastic oil blends on diesel engine. Different types of washing were conducted to effectively dehalogenate plastic waste. After pretreatment, odor compounds were analyzed using GC–MS. Subsequently, various types of pretreated plastic samples underwent catalytic pyrolysis with a 5:1 ratio of HDPE to Al2O3·2SiO2·2H2O. Differences in physico-chemical properties and hydrocarbon compounds of oils were determined. Experiments were performed using different fuel blends in a diesel engine under steady-state conditions, and their effects on combustion, emissions, morphology, and size particles were analyzed. The results show that sample B exhibited a lower toxicity level of 1,3-butadiene compared to other samples, while acetone and terpenes represented the second and third-highest emission levels in flakes, respectively. Sample C started to degrade at low temperatures (<300 °C) due to carbon addition from ethyl acetate solvent into the tertiary carbon chain of the flakes. DAP3 fuel achieved a higher reaction due to its degree of unsaturation and lower viscosity, resulting in the formation of smaller fuel droplets at high injection pressure and heat release rate (HRR). Higher emission levels were observed by DAP1 and D100, exceeding the Euro 5/6 standard limits. However, DAP3 fuel resulted in an average reduction of ∼17.14% and 21.86% in CO and smoke emissions, respectively, accompanied by a slight decrease in NOx and HC levels. Conversely, there were inconsistencies in the emission results observed with DAP2. Compared to D100, both DAP1 and DAP2 exhibited a significant accumulation and coarse particles in the PM10 forms at a peak of ∼83 nm. Whereas the DAP3 showed a smaller mobility Dp with a low nucleation particle peak, which was prone to absorb the unburned HC soot and later change to accumulation mode particles.