High-pressure Metamorphism Research Articles

Tectonic evolution of the early Paleozoic intraplate orogen in the South China Block: Insights from Ductile Shear Zones in North Wuyishan

The ductile shear zones within the North Wuyishan domain are key to understand the tectonic evolution of the South China Block (SCB). This study integrates a multifaceted approach, including field observations, thin section analysis, quartz electron backscatter diffraction (EBSD), zircon U-Pb dating, and mica 40Ar/39Ar dating, to elucidate the deformation history of these shear zones in North Wuyishan. The research identifies a two-stage deformation process of early Paleozoic. The initial D1 phase is marked by a top-to-SW thrusting shear, with associated felsic veins dated to the Ordovician period (447 ± 10 Ma to 459 ± 4 Ma), correlating with high-grade metamorphism and partial melting. The later D2 phase is characterized by NE-striking foliation and lineation, indicative of sinistral strike-slip shear, dated to the early Devonian (412 Ma) and early Carboniferous (∼354 Ma). The D1 phase suggests early crustal thickening and melting within the Cathaysia block, while D2 indicates a transpressional regime during post-orogenic adjustment. The geological features of the SCB, notably the absence of arc magmatism, ophiolitic mélange, and high-pressure metamorphism, comply with an intracontinental rift closure model as previously proposed. This model supports the hypothesis that the Early Paleozoic intracontinental orogeny in the SCB was likely a far-field consequence of a continental collision between the SCB-North Vietnam and South Vietnam blocks near the east Gondwana supercontinent.

Late Jurassic High-Pressure Metamorphism of Variscan I-Type Granitoids in the Northern Part of the Pelagonian Unit (Republic of North Macedonia)

Abstract The high P/T metamorphic Pelagonian Unit in the Republic of North Macedonia comprises (1) a Variscan basement consisting of gneisses, schists and minor meta-mafic rocks, which are all intruded by I-type granitoids and rare related dikes; (2) a metamorphosed sedimentary sequence of Permian to Lower Triassic age, and (3) a sequence of calcite and dolomite marbles resulting from Late Triassic to Middle Jurassic carbonate sediments. All these rocks underwent a common high-P/T metamorphism of Late Jurassic age. This paper deals with the metamorphism of the Variscan I-type granitoids which contained the igneous mineral assemblage plagioclase I + alkali feldspar I + quartz I + biotite I + titanite I + allanite I + zircon I + apatite I ± magnetite I. During Late Jurassic high-P/T metamorphism, these undeformed granitoids were thoroughly metamorphosed under isotropic pressure conditions as documented by undeformed granitic textures that are overgrown by metamorphic minerals such as garnet II, epidote II, and phengite II. Various, eventually metasomatic mineral reactions took place in different textural positions: (1) Former igneous plagioclase grains became completely transformed to Na-rich plagioclase IIa (An09–14) containing numerous small grains of epidote IIa and phengite IIa. Either this transformation was an allochemical one and was accompanied by the syn-metamorphic introduction of an aqueous fluid phase containing Fe, Mg and K or, alternatively, the more Ca-rich parts of plagioclase I became considerably sericitized before high-P/T metamorphism, and the resulting mixture of more Na-rich relic plagioclase with its sericite-rich domains became later metamorphosed under high-P/T conditions. In the first case, an aqueous phase is needed during metamorphism, while in the second case high-P/T metamorphism might have proceeded under H2O-undersaturated conditions; (2) igneous alkali feldspar I was changed to albite-poor orthoclase II or microcline II; (3) igneous Ti-rich biotite I reacted with plagioclase to metamorphic garnet II + Ti-poorer biotite II + titanite II + phengite II + quartz II ± epidote II ± rutile II, which is rimmed by Ttn II. At textural positions, where igneous plagioclase I was not available, igneous biotite I was transformed to Ti-poorer biotite II + titanite II ± ilmenite-hematite II; (4) during uplift, high-P/T metamorphic rutile II became marginally overgrown by titanite II ± ilmenite II; (5) igneous allanite I grains stayed unaltered, but when located near to former plagiocase I, they became partially rimmed by metamorphic epidote II. Equilibrium phase diagram calculations showed that the observed metamorphic paragenesis (plagioclase II + K-rich feldspar II + biotite II + garnet II + epidote II + phengite II + garnet II + quartz II + rutile II + titanite II) is only stable under H2O-unsaturated conditions. The I-type granitoids and their metamorphic country rocks were metamorphosed under high-P/T conditions of 1.3 to 1.5 GPa and 560 to 590 °C.

A rapid transition from subduction to Barrovian metamorphism: geochronology of mafic–ultramafic relicts of oceanic crust in the Central Alps, Switzerland

Relicts of subducted oceanic lithosphere provide key information for the tectonic reconstructions of convergent margins. In the Central Alps, such relicts occur as isolated mafic–ultramafic lenses within the migmatites of the southern Adula nappe and Cima-Lunga unit. Analysis of the major-, minor-, and accessory minerals of these ophiolitic relicts, combined with zircon and rutile U–Pb ages and zircon oxygen isotopes, allows the reconstruction of different stages of their complex evolution. The mafic–ultramafic suite in Valle di Moleno consists of chlorite-harzburgites associated with metarodingites and retrogressed eclogites. Relic omphacite and kyanite in retrogressed eclogites provide evidence for subduction-related metamorphism. Increasing XPrp in the garnet mantle towards the rim documents heating during high-pressure metamorphism up to 800–850 °C. Polyphase inclusions and chemical zoning in garnet suggest fluid-assisted melting during high-pressure metamorphism dated at 31.0 ± 0.9 Ma. In Val Cama, chlorite-harzburgites, metarodingites and calcsilicate-metasediments occur. Detrital zircon ages in the metasediment suggest a Mesozoic deposition. The metarodingite-metaperidotite-metasediment association and the low δ18O signatures of zircon (δ18O 3.0–3.7‰), inherited from seafloor metasomatism of the protoliths, show that the rocks are derived from former altered oceanic crust. Amphibolite facies metamorphism related to the Central Alps Barrovian evolution in Val Cama occurred at 28.8 ± 1.5 Ma. The combined data from Moleno and Cama indicate a rapid transition (~ 2 Ma) from subduction to collisional metamorphism with corresponding exhumation rates of 3–6 cm/year. Fast exhumation tectonics may have been favored by slab break-off or slab extraction. U–Pb dating of rutile from both localities yields ages of ~ 20 Ma, suggesting that these rocks remained at amphibolite-facies conditions for about 10 Ma and underwent a second fast exhumation of 3 cm/year associated with vertical movements along the Insubric line.

Earth’s metamorphic secular evolution accessed by rutile

Rutile provides crucial insights into the evolution of plate tectonics and variations in tectonomagmatic modes over Earth’s history primarily because rutile predominantly tracks higher-pressure metamorphism (>1.0–1.2 GPa). Comparison of rutile age and compositional data with diverse proxies tracks the presence of low temperature/pressure (T/P) metamorphic conditions, enabling the tracing of plate tectonics onset and evolution. We present a new compilation of rutile U-Pb ages that lag zircon ages by approximately 50 Myr, potentially indicating cooling ages of metamorphic belts. The earliest rutile age peak (ca. 1.8 Ga) aligns with the oldest evidence for low T/P metamorphic conditions. This coincides with a shift in the T/P distribution of rutile whereas the T/P of Archean rutile forms a tight normal distribution. In the Paleoproterozoic, the rutile T/P distribution is skewed to lower T/P, following the broader pattern of the full metamorphic record. The degree of lower T/P skew increases through time until the lower T/P population dominates the rutile record from the Neoproterozoic to the present. These data further highlight shifts in dominant metamorphic modes that can be tied to the evolution of the tectonic system, with early Archean metamorphism being associated with plume-driven vertical tectonics or hot, shallow subduction and post-Archean metamorphism being associated with progressive less plume-driven vertical tectonics and colder, steeper subduction. Although the frequency of rutile is lower during the Mesoproterozoic, the rutile T/P during this time follows the progressive skewing pattern from the Paleoproterozoic to the present and is likely inconsistent with a phase of interrupted tectonics characterized by stagnant lid.

Investigation of the mineralogical composition and origin analysis of black jadeite

Abstract Analyzing black jadeite variety is helpful not only to distinguish black jadeite from the common omphacite jadeite, but also to learn the origin of jadeite by studying these special specimens. The basic gemological properties, mineral composition, structural characteristics, spectroscopic features, and color-causing mechanisms of black jadeite were studied through testing methods such as Polarizing microscope, X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy. Recent studies have confirmed the distinct crystalloblastic textures of black jadeite—namely columnar, granular, and fibrous—alongside its characteristic fracture structures. This research further identifies the presence of secondary minerals, primarily opaque black impurities consisting of a graphite and disordered graphite mixture, as revealed by Raman spectroscopy and X-ray diffraction analyses. These analyses have elucidated that the variable distribution of graphite mixtures contributes to differing degrees of light absorption, thereby forming various shades of black, a critical factor in the gemstone’s coloration. This study suggests that these carbonaceous materials are a byproduct of the carbonization of organic matter within metamorphic fluids, subsequently forming dispersed graphite structures within the mineral matrix and its fractures, indicative of multi-stage metamorphic processes. Additionally, the identification of graphite supports the theory that jadeite’s protolith originated from the subduction processes of the Neotethys Ocean, accompanied by metasomatism and high-pressure metamorphism of olivinite.

Two episodes of Early Palaeozoic high-pressure metamorphism in North Balkhash ophiolite zone (Central Kazakhstan, western Central Asian Orogenic Belt): Evidence for tectonic evolution of Junggar–Balkhash Ocean

The structure of serpentinite mélange of the North Balkhash ophiolite zone (Central Kazakhstan; west Central Asian Orogenic Belt) is ascertained to be high-grade formations assigned to epidote-glaucophane eclogites and garnet blueschists, and their varieties. The rocks follow a clockwise ‘subduction-type’ evolution with the estimated near–peak metamorphic conditions of 1.6–1.9 GPa and 500–560 °C. 40Ar39Ar phengite ages of ∼491 Ma and ∼ 465 Ma obtained for the eclogites and garnet blueschists, respectively, are interpreted to reflect the near-peak to shortly retrograde stages of rock evolution and to record the late Cambrian and Middle Ordovician episodes of high-pressure re-equilibration in the North Balkhash zone. Protoliths of the eclogites were N-MORB-like mafic rocks, which comprised structurally different (from the lower gabbroic to the upper dolerite/basalt) parts of pre-late Cambrian oceanic crust and were formed in the spreading centre setting at the expense of depleted mantle source. Protoliths of the garnet blueschists and associated rocks were represented by volcanogenic–sedimentary, predominantly mafic, complexes (tuffaceous sandstones, greywackes), an accumulation of which and subsequent involvement into subduction occurred at ∼478–465 Ma in the intra-oceanic (fore-arc) setting. Zircon core ages indicate formation of the source of the protoliths of the garnet blueschists occurred in the 509–478 Ma range. A comprehensive correlation of the metamorphic and igneous formations of the North Balkhash zone with those assigned to the adjacent complexes of the southern part of the West Junggar area (NW China) suggested their mutual Early Palaeozoic tectonic evolution within the Junggar–Balkhash Ocean.

Mineral precipitation sequence from multi-stage fluids released by eclogite during high-pressure metamorphism

Abstract Arc magmas above subduction zones hold abundant fluid-mobile elements attributed to fluids released from the dehydrating subducted oceanic crust. However, the quantity of trace elements in the fluids and their evolution with the metamorphic processes during subduction and exhumation are still unclear. The precipitation sequence of vein minerals preserves the nature of multi-stage high-pressure (HP) metamorphic fluids and the fingerprint of mass exchange in deep subduction zones. In this contribution, we conducted detailed petrological studies and phase equilibria modeling on a unique HP omphacite-rich vein and its host eclogite from the Chinese southwestern Tianshan. The host eclogite consists mainly of garnet, omphacite, epidote, glaucophane, phengite, quartz, and rutile. Garnet in the eclogite records prograde subduction and early exhumation characterized by decompression heating at P-T conditions of ~2.4–2.6 GPa and 460–540 °C. The embedded omphacite-rich vein has similar mineral assemblage to the host eclogite. Garnet grains in this vein are predominantly distributed along or intersect the vein wall, which record similar eclogite-facies metamorphic conditions to that of the host eclogite. Omphacite is dominant in the vein, while epidote and glaucophane occur interstitially. Phase equilibria modeling reveals a sequential growth of garnet-dominated, omphacite-dominated, and epidote-dominated assemblages from fluids originating from the breakdown of different hydrous minerals. These lines of evidence suggest that the formation of multi-stage HP fluids are a continuous long-term process with a spontaneously short-distance transport and sequential mineral precipitation. Calculated fluid compositions demonstrate that the fluids released by lawsonite breakdown during exhumation have great potential to modify the trace element systematics of arc magmas. Our findings reveal the nature and evolution of multi-stage HP metamorphic fluids from internal sources during subduction and exhumation of oceanic crust, providing valuable insights into the chemical compositions of arc magmas.

On the Rhodopean protoliths and their Middle Jurassic to Early Cretaceous evolution. A review

The Rhodope Massif represents a large high-grade metamorphic complex situated in the Balkan Peninsula, straddling the border between Bulgaria and Greece. Geological studies carried out during the last thirty years clearly established that the complex is composed of three major lithotectonic units characterized by differing protolith ages and Alpine thermotectonic evolution. The Rhodope Massif consists of Upper and Lower terranes representing continental fragments composed mainly of pre-Mesozoic magmatic rocks and covered by Early Mesozoic sedimentary sequences. These two entities are separated by an Intermediate Terrane comprising a Jurassic magmatic arc and its host rocks tectonically intercalated with Jurassic ophiolitic fragments together with the Early Mesozoic sediments. Detailed analyses of the previously published geochronological data revealed that the three main tectonic terranes were juxtaposed in the Late Jurassic–Early Cretaceous during the continental collision and northward subduction of the Lower and Intermediate terranes. These rocks experienced Middle Jurassic to Early Cretaceous high-pressure metamorphism, followed by high-temperature one accompanied by anatexis. At that time, the Upper Terrane was metamorphosed and deformed only partially. Being part of the European margin, this terrane represented an upper continental plate during the subduction, and therefore is not considered as a part of the Alpine Rhodope metamorphic complex. It is important to note that, although most of the present-day fabric and major tectonic zones in the Rhodope metamorphic complex are younger than Early Cretaceous, and therefore they postdate the geological evolution discussed in this study, they often reactivate the old boundaries between the main terranes and units.

Rapid development of spiral garnets during subduction zone metamorphism revealed from high-resolution Sm-Nd garnet geochronology

Abstract Multiple studies have applied zoned garnet geochronology to place temporal constraints on the rates of metamorphism and deformation during orogenesis. We report new high-resolution isotope dilution–thermal ionization mass spectrometry Sm-Nd isochron ages on concentric growth zones from microstructurally and thermodynamically characterized garnets from the Betic Cordillera, southern Spain. Our ages for the garnet core (13.64 ± 0.31 Ma), mantle (13.41 ± 0.37 Ma), and rim (13.34 ± 0.45 Ma) indicate rapid garnet growth and are consistent with published garnet ages interpreted to reflect high-pressure metamorphism in the region. Thermodynamic analysis indicates garnets grew during subduction at ~1.5–2.0 GPa and 570–600 °C. The core to rim duration of spiral garnet growth was just a few hundred thousand years. While other zoned garnet studies have shown similar rapid growth in subduction zone settings, this is the first documentation of such rapid growth of a spiral garnet. Combining this garnet growth duration with the magnitude of spiral inclusion trail curvature, we compute a strain rate of ~10−13 s−1, an order of magnitude faster than all previous spiral garnet studies. We interpret that these spiral garnets recorded a rapid pulse of deformation and strain during the final stages of subduction and incipient exhumation.

Île Dumet (Armorican Massif, France) and its glaucophane eclogites: the little sister of Île de Groix

Abstract. Blueschist-facies rocks are scarce within the Variscan orogen. Two main occurrences are known in the Armorican Massif (NW France), at Île de Groix and Bois-de-Céné. Another glaucophane occurrence was discovered in 1988 but went unnoticed; it is located on Île Dumet, an uninhabited island off the coast of southern Brittany, in the estuary of the river Vilaine. Orthogneiss occurs on the SW half of the island; the original granitoid magma had intruded mica schists on the NE half, where numerous 1 to 10 m long boudins of mafic rocks occur. These lenses are typically retrogressed into plagioclase-bearing amphibolite, but a few contain remnants of glaucophane-bearing eclogite, which also occurs as numerous loose blocks along the NE coast of the island, suggesting that the best-preserved eclogites lie in situ offshore in that direction. The glaucophane eclogites contain garnet, omphacite, quartz, amphibole, clinozoisite/epidote, minor phengite, paragonite, rutile and rare apatite. Prograde metamorphic evolution is indicated by garnet crystals zoned from Mn-rich cores to Mg-richer rims (typically (core→rim): Alm44→58 Prp1→12 Grs33→29 Sps22→1) and amphibole grains with glaucophane nuclei and Ca–Na-amphibole overgrowths that show sharp transitions, supporting evolution through a solvus, as predicted by the thermodynamic modelling. Modelling of the P–T conditions using the P–T pseudosection technique indicates a peak of metamorphism at about 620 ∘C and 16 kbar. The retrograde evolution of the metabasites is evidenced by the late formation of albite, titanite and ferro-actinolite. The surrounding mica schists, composed of quartz, garnet, phengite, paragonite and chlorite, were also largely retrogressed during exhumation. The orthogneiss of the SW part of the island does not show clear evidence of high-pressure metamorphism, since the magmatic feldspars are still preserved, similarly to the orthogneiss of Les Sables Rouges on the island of Groix. Île Dumet and the western part of the Vilaine estuary represent a blueschist-facies equivalent to Île de Groix (Brittany) and Bois-de-Céné (Vendée) on the mainland. All three occurrences occupy the centres of wide synforms whose concentric units are, from rims to core (i.e. from base to top), (a) a high-T migmatitic basement; (b) Cambro-Ordovician metasediments and acid metavolcanites (“porphyroids”); and (c) blueschist-facies mica schists and metabasites, serpentinites, and minor orthogneisses derived from a pre-Variscan oceanic accretionary prism. There are about 10 similar occurrences within the Ibero-Armorican Arc, forming a discontinuous high-pressure belt, but most of them have remained unnoticed due to a high degree of retrogression.

Melting of Subducted Continental Crust in the Cimmerian Collisional Orogenic Belt, NE Iran

Abstract The subduction of continental crust in orogenic belts that are not associated with high-pressure metamorphism is still poorly understood. The Late Triassic postcollisional granitic rocks of NE Iran are related to the convergence between the Central Iran terrane and the Turan terrane on the southern margin of the Eurasian continent. They intruded into the Paleo-Tethyan suture between the Central Iran and Turan terranes. Granitoids of the Torbat-e-Jam pluton were emplaced at ca. 217 Ma, and their moderately high SiO2 (>64 wt. %), low MgO contents (mostly <2 wt. %), slightly depleted Sr-Nd, and zircon Hf isotopes suggest partial melting of a juvenile crust. Granodiorites from NW and SE Mashhad were emplaced at ca. 217 and 200 Ma, and their geochemical features and enriched Sr-Nd and zircon Hf isotopes suggest melting of continental crust. Inherited zircon cores in both the NW and SE Mashhad intrusions have dominant age peaks of ca. 540 and 770 Ma, similar to the age spectrum of adjacent Paleozoic sediments derived from the Central Iran terrane, but distinct from Triassic sediments sourced from the Turan terrane. The inherited zircon cores cannot be explained by crustal contamination during magma ascent, rather the age pattern of inherited zircon cores coincides with major magmatic events in the Central Iran terrane and fingerprint their source, suggesting partial melting of the subducted Central Iran continental crust. This study suggests that the melting of subducted continental crust can occur in simple collisional belts, rather than being confined to ultrahigh-pressure metamorphic orogenic belts.

Ultramafic pseudotachylytes in high-pressure metamorphogenic peridotite from Luobusha, Tibet: a record of crustal paleo-earthquakes

In this paper, we report an occurrence of ultramafic pseudotachylytes, providing fault-rock evidence of paleo-earthquakes, from the Luobusha ophiolite complex in the Yarlung Zangbo suture zone. The pseudotachylytes form hairline-thin aphanitic veinlets and vein networks bounded by micro-damage zones cutting through the host harzburgite, forming flow banding in some places. The pseudotachylyte veins are dominated by close-knit ultrafine-grained minerals consisting of olivine, orthopyroxene, serpentine, spinel, and magnetite, cemented by an extremely fine matrix. As the primary component of the pseudotachylyte veins, olivine occurs as microphenocryst showing zoning from core to rim and as irregularly shaped microlite immersed in the interstitial material. Zoned crystals of olivine developed with Mg-rich cores and more Fe-rich rims. Microlite diagnosis of crystallization in a quenched melt includes dendritic, skeletal, and poikilitic olivine crystals, which are typical of ultramafic pseudotachylyte. The olivine microlites contain higher amounts of Ca, Al, and Cr but a lower Ni content compared with the host harzburgite olivine. Irregularly shaped chrome-spinel crystals are chemically zoned as well, indicating an Fe-rich rim overgrowth. Ni sulfide droplets interspersing among the matrix imply melt occurrence. The presence of a micro-fibrous and micro-vesicular interstitial matrix also indicates a melting-related origin. Ultracataclastite veins associated with pseudotachylyte transecting serpentine are observed, which convey that heat was generated during rapid comminution and injection. The characteristic petrography, microtextures, and chemical inhomogeneities meet the criteria of ultramafic pseudotachylyte and reveal a mixed genesis via a combination of crushing and melting. The development of extremely tiny globular prograde serpentine inclusions (∼100 nm) in the olivine microlites is ascribed to the dehydration reaction of serpentine to olivine within the pseudotachylyte. The Luobusha metamorphogenic peridotite was subjected to serpentinization after having emplaced in the crust and subsequently to high-pressure metamorphism. The pseudotachylytes were generated in the crust after the high-pressure metamorphism and did not descend to a greater depth. Flash ultra-comminution associated with frictional heating may release fluids via localized heat-driven prograde reactions in the crust.

Pressure–temperature–time path of ultrahigh-pressure metamorphic terranes constrained by zircon petrochronology: A case study of orthogneisses from the northern Sulu belt, China

Reconstruction of pressure–temperature–time (P–T–t) path of volumetrically-dominant orthogneisses in deeply subducted continental crusts is challenging due to their simple amphibolite-facies mineral assemblages. To provide new insights into this issue, a detailed study of mineral inclusions, trace elements and U-Pb ages within robust zircon containers, together with titanite U-Pb dating and petrology were conducted on ultrahigh-pressure (UHP) orthogneisses from the northern Sulu belt. The following P–T–t conditions of three metamorphic stages were constrained: (i) cathodoluminescence (CL)-grey zircon cores (ca. 238–237 Ma) with flat heavy rare earth element (HREE) patterns include garnet, phengite and omphacite that yield estimated P–T conditions of 2.3–2.8 GPa/730–800 °C, corresponding to prograde high-pressure (HP) metamorphism before the UHP peak. (ii) CL-dark zircon mantles (ca. 224 Ma) contain multiphase solid inclusions of plagioclase + K-feldspar + quartz and show extremely low Th/U ratios (≤0.08) and negative Eu anomalies, demonstrating their crystallization from hydrous melt at 2.0–1.8 GPa/890–820 °C during HP eclogite-facies exhumation. In addition, titanite grains are characterized by high LREE contents (1939–5239 ppm), Th/U ratios (0.37–0.81) and crystallization temperatures (830–801 °C), suggesting their peritectic origin. The lower intercept age (220 ± 4 Ma) of titanite is broadly consistent with the ages of the zircon mantles, indicating that they both crystallized from the melt at the same stage. (iii) CL-bright zircon rims (ca. 212–211 Ma) preserve low-pressure mineral inclusions of plagioclase, K-feldspar and quartz, and they show low Th/U ratios (0.03–0.12) and steep HREE patterns with negative Eu anomalies, witnessing amphibolite-facies overprinting at 1.0–0.8 GPa/610–550 °C. Combined with the metamorphic peak conditions of 3.2 GPa/840 °C at ca. 232 Ma constrained by previous studies from the same area, the P–T–t path of the northern Sulu UHP belt is reconstructed. The data reflects two-stage exhumation of this terrane, including an early-stage (5.8 km/m.y.) and a later-stage slower (3.1 km/m.y.) exhumation processes. The faster exhumation during early decompression was probably enhanced by extensive melting activity recorded by the CL-dark zircon mantles from the orthogneisses.

Electron probe petrochronology of monazite- and garnet-bearing metamorphic rocks in the Saxothuringian allochthonous domains (Erzgebirge, Granulite and Münchberg massifs)

Abstract In the Saxothuringian Zone, a unique assemblage of high- to ultra-high-pressure and ultra-high-temperature metamorphic units is associated with medium- to low-pressure and temperature rocks. The units were studied in a campaign with garnet and monazite petrochronology of gneisses, micaschists and phyllites, and monazite dating in granites. P–T path segments of garnet crystallization were reconstructed by geothermobarometry and interpreted in terms of the monazite stability field, EPMA Th–U–Pb monazite ages and garnet Y + HREE zonations. One can recognize (1) Cambrian plutonism (512–503 Ma) with contact metamorphism in the Münchberg Massif. Subordinate monazite populations may indicate a (2) widespread but weak Silurian (444–418 Ma) thermal event. A (3) Devonian (389–360 Ma) high-pressure metamorphism prevails in the Münchberg and Frankenberg massifs. In the ultra-high-pressure and high-pressure units of the Erzgebirge the predominant (4) Carboniferous (336–327 Ma) monazites crystallized at the decompression paths. In the Saxonian Granulite Massif, prograde–retrograde P–T paths of cordierite-garnet gneisses can be related to monazite ages from 339 to 317 Ma. A (5) local hydrothermal overprint at 313–302 Ma coincides partly with post-tectonic (345–307 Ma) granite intrusions. Such diverse monazite age pattern and P–T time paths characterize the tectono-metamorphic evolution of each crustal segment involved in the Variscan Orogeny.

Metamorphic P–T–t evolution deciphered from episodic monazite growth in granulites of the Chencai Complex and implications for the Early Paleozoic Orogeny, West Cathaysia terrane, South China

Abstract The Early Paleozoic Orogeny in eastern South China has been highly controversial. It has been alternatively interpreted to have formed in an intra-plate setting driven by far-field tectonic forces or at plate boundaries involving subduction–collision. The West Cathaysia terrane in the core of the orogen is characterized by extensive magmatism, intense deformation and especially high-grade metamorphism. Identifying early Paleozoic high-pressure (HP) metamorphism and establishing a complete P–T–t path from the high-grade metamorphic rocks could help us understand the tectono-thermal evolution process and nature of the Early Paleozoic Orogeny. Here, we present results from a felsic granulite from the Chencai Complex in the northeastern West Cathaysia terrane. Petrographic evidence, mineral compositions and phase equilibria modelling indicate that the granulite underwent a pre-peak HP stage with P–T conditions of 13.3–14.7 kbar/696–718°C and low geothermal gradients of 13–14°C km −1 , and a peak high-temperature stage with P–T conditions of 9.7–11.0 kbar/785–820°C. A clockwise P–T path involving pre-peak decompressional heating, post-peak near-isothermal decompression and near-isobaric cooling processes was constrained for the HP felsic granulite. In situ monazite U–Pb geochronology combined with previous results date these metamorphic processes at c. 440, c. 425 and c. 400 Ma, respectively. Our new metamorphic and geochronological data from the HP felsic granulite support the case that the Early Paleozoic Orogeny was a typical collisional one.

Time constraints on the geological evolution of the main sedimentary basins and tectono-magmatic events on Livingston Island, South Shetland Archipelago, Antarctica: a review

The Lower Cretaceous to Miocene South Shetlands Islands’ volcanic arc is a result of the subduction of the Phoenix Oceanic Microplate (part of the Pacific Plate) beneath the Antarctic Peninsula. The magmatic activity on Livingston Island has been going on for a long time: since the Early Cretaceous to the present. The evolution of the volcanic arc resulted in the formation of various sedimentary basins and paleoenvironments (turbiditic to shallow marine and continental) that formed varied sedimentary successions and tholeiitic to potassium calc-alkaline subduction-related magmatic rocks. Considering the magmatic activity on Livingston Island, a general trend of rejuvenation can be observed from the WNW (Byers Peninsula) to the ESE (to Hannah Point, Point Williams and further to the Hurd Peninsula and the Tangra Mountain). The rejuvenation of the magmatic rocks in the direction of the thrust plate can be explained as an effect of a flattening subduction that was active from the Early Cretaceous (135 Ma) up to around 90–70 Ma. The mixed ages of the dikes and small intrusions in the Hurd Peninsula are most probably due to periods of rotation and probably beginning of а slab-roll back. A regional Paleocene–Eocene (65–47 Ma) compressional episode that caused a low temperature to high-pressure metamorphism is registered on Smith and Elephant islands. The regional metamorphism was followed by a vast extension between 50–30 Ma that culminated with the opening of the Drake Passage around 34–30 Ma. The magmatic response of that regional scale extension was the intrusion of the Eocene Barnard Point Pluton (46–40 Ma) and dikes with youngest ages of around 30 Ma. The major uplift phase and the exhumation of the Tangra Mountain happened between 22–16 Ma as indicated by the Ap FT thermochronology. The last magmatic event on the island produced the contrastingly different in composition Quaternary alkaline mafic rocks that occupy the area between Innot Point and Burdick Peak. This episode is interpreted as related to a process of crustal extension that culminated in asthenospheric upwelling and rifting along the Bransfield Strait. The latter is due to a slab roll-back that led to the break-up of the South Shetlands from the Antarctic Peninsula and consequent subduction termination.

Высокобарический метаморфизм в харбейском метаморфическом комплексе (Полярный Урал)

Glaucophane-bearing rocks — indicators of high-pressure metamorphism — were earlier found in the Polar Urals in the Neoproterozoic deposits of the Nyarovey series, in the northern part of the Marunkeu eclogite-amphibolite-gneiss complex, and in the foot of the ultramafic massifs of the Main Ural Fault (MUF) zone. We have discovered high-pressure rocks in the western endocontact of the Kharbey amphibolite-gneiss complex, where they are represented by garnet-glaucophane, garnet-glaucophane-barroisite rocks and garnet-barroisite amphibolites formed during progressive zonal metamorphism. From the western boundary of the complex to the east, temperature gradually increases from 400—480 °C (for garnet-glaucophane rocks) to 495—570 °C (for garnet-glaucophane-barroisite rocks and garnet-barroisite amphibolites) at a pressure of 11—16 kbar. We determined that the high-pressure metamorphism had an areal distribution within the Kharbey metamorphic complex and, apparently, marked the Paleozoic subduction-collision processes of formation of Uralides.

High-pressure metamorphism of Precambrian continental crust in the southwestern part of the Central Asian Orogenic Belt (South Kazakhstan and North Tien Shan) and tectonic implications for the evolution of the Palaeo-Asian Ocean

AbstractIn this study, we investigated the high-pressure (HP) metamorphism of the Precambrian continental crust exposed in the Zheltau terrane in South Kazakhstan (Koyandy complex) and the Chu-Kendyktas terrane in the North Tien Shan of Kyrgyzstan (Aktyuz, Kemin and Kokdzhon complexes) within the SW part of the Central Asian Orogenic Belt. HP quartz–feldspar lithologies of the Koyandy complex consist of migmatized kyanite-bearing garnet–mica paragneisses, garnet–kyanite paragneisses and their derivatives associated with eclogites. Paragneisses demonstrate prograde evolution involving mica dehydration melting and producing magnesium-rich garnet, kyanite and K-feldspar at the near-peak to retrograde stages at pressures of 15–18.5 kbar and temperatures of 800–870°C. The widespread growth of micas in these rocks reflects lower stages of retrogression at P = 10–12 kbar and T = 720–770°C. The age distributions of the cores of detrital zircon grains from the paragneisses indicate a predominance of Neoproterozoic and minor occurrence of Mesoproterozoic and Palaeoproterozoic sources of their protoliths. The ages of ∼487–485 Ma obtained from the zircon rims of the paragneisses reflect the timing of their HP metamorphic re-equilibration. These age clusters are consistent with the age estimates obtained from the rims of zircons in the eclogite-bearing garnet gneisses of the adjacent Aktyuz complex in the North Tien Shan. The P–T paths and zircon ages obtained from the high-grade quartz–feldspar gneisses of the Zheltau and Chu-Kendyktas terranes are thus interpreted to indicate involvement of the crustal material derived from the Precambrian basement (magmatic zircons aged ca. 844 Ma) and its Ediacaran–Cambrian sedimentary cover (detrital zircons with maxima at 1 Ga and 800–600 Ma) in the latest Cambrian subduction processes induced by the closure of the oceanic basins assigned to the Palaeo-Asian Ocean.

Detrital garnet petrology challenges Paleoproterozoic ultrahigh-pressure metamorphism in western Greenland

Abstract. Modern-style plate tectonics is characterised by the global operation of cold and deep subduction involving blueschist facies and ultrahigh-pressure metamorphism. This has been a common process since the Neoproterozoic, but a couple of studies indicate similar processes were active in the Paleoproterozoic, at least on the local scale. Particularly conspicuous are extreme ultrahigh-pressure conditions of ∼ 7 GPa at thermal gradients < 150 ∘C GPa−1 proposed for metamorphic rocks of the Nordre Strømfjord shear zone in the western part of the Paleoproterozoic Nagssugtoqidian Orogen of Greenland. By acquiring a large dataset of heavy minerals (n = 52 130) and garnet major-element composition integrated with mineral inclusion analysis (n=2669) from modern sands representing fresh and naturally mixed erosional material from the metamorphic rocks, we here intensely screened the area for potential occurrences of ultrahigh-pressure rocks and put constraints on the metamorphic evolution. Apart from the absence of any indications pointing to ultrahigh-pressure and low-temperature–high-pressure metamorphism, the results are well in accordance with a common Paleoproterozoic subduction–collision metamorphic evolution along a Barrovian-type intermediate temperature and pressure gradient with a pressure peak at the amphibolite–granulite–eclogite-facies transition and a temperature peak at medium- to high-pressure granulite-facies conditions. In addition, we discuss that all “evidence” for ultrahigh-pressure metamorphism proposed in the literature for rocks of this area is equivocal. Accordingly, the Nordre Strømfjord shear zone is not an example of modern-style plate tectonics in the Paleoproterozoic or of very low thermal gradients and extreme pressure conditions in general.

Timescales and mechanisms of felsic lower continental crust formation: Insights from U-Pb geochronology of detrital zircon (Malenco Unit, eastern Central Alps)

Burial of supracrustal sedimentary material is one of the processes that contribute to the formation of the lower continental crust. We investigate the rate of this process in Permian lower continental crust from the Malenco Unit (eastern Central Alps) by constraining the age of protolith deposition and subsequent high-grade metamorphism of felsic, garnet-rich granulites. Detrital zircon cores, many of which are small (<50 μm), were dated by SIMS and yield concordant dates ranging from 387 ± 21 Ma (2σ) to 2380 ± 16 Ma, with the vast majority of the dates falling in the range 450–1000 Ma. For the seven cores in each sample that gave the youngest concordant dates, replicate analyses were carried out. None of these cores had all measured U-Pb dates agree within error, indicating significant disturbance by the Permian granulite facies metamorphism. A 206Pb/238U age of 424 ± 6 Ma for a core with two overlapping replicate analyses is the best available constraint on the maximum depositional age of the sedimentary protolith. This maximum depositional age also coincides with the first significant population in the probability density plot of detrital core dates, which is a double peak at ∼425 Ma and ∼450 Ma.Zircon detrital cores are separated from metamorphic overgrowths by a small seam of zircon that is riddled with tiny inclusions of quartz, biotite and muscovite. The first generation of metamorphic zircon rims has a 206Pb/238U age of 272.9 ± 2.8 Ma, displays steep heavy rare earth element (HREE) patterns and a moderate negative Eu-anomaly, and returns Ti-in-zircon temperatures of 740–780 °C. The second generation of metamorphic rims has a 206Pb/238U age of 263.8 ± 2.6 Ma, a flat HREE pattern and a pronounced negative Eu-anomaly, and gave Ti-in-zircon temperatures of 780–810 °C. Collectively these observations indicate that the first zircon rim formed on the prograde path at the onset of partial melting where muscovite was present but the rocks contained little garnet and no K-feldspar. Therefore, the metapelites resided at lower amphibolite facies, subsolidus conditions up until the intrusion of a Permian gabbro, which was emplaced shortly after the formation of the first generation of metamorphic zircon and caused heating to granulite facies conditions and widespread partial melting. There is no record of high-pressure metamorphism preceding granulite facies conditions, indicating that felsic lower crust in the Malenco unit was not formed by relamination.The Malenco unit was situated at the north-eastern active margin of Gondwana 420 Ma ago. Subduction-related accretion of sediments at lower crustal levels shortly after their deposition could explain the formation of this felsic lower crust that resided at subsolidus conditions for up to 100 My prior to Permian extension, gabbro intrusion and granulite facies metamorphism.