ABSTRACT Observations of polarization position angle ($\theta$) standards made from 2014 to 2023 with the High Precision Polarimetric Instrument (HIPPI) and other HIPPI-class polarimeters in both hemispheres are used to investigate their variability. Multiband data were first used to thoroughly recalibrate the instrument performance by bench-marking against carefully selected literature data. A novel co-ordinate difference matrix (CDM) approach – which combines pairs of points – was then used to amalgamate monochromatic ($g^\prime$ band) observations from many observing runs and re-determine $\theta$ for 17 standard stars. The CDM algorithm was then integrated into a fitting routine and used to establish the impact of stellar variability on the measured position angle scatter. The approach yields variability detections for stars on long time-scales that appear stable over short runs. The best position angle standards are $\ell$ Car, o Sco, HD 154445, HD 161056, and $\iota ^1$ Sco, which are stable to $\le$0.123$^\circ$. Position angle variability of 0.27–0.82$^\circ$, significant at the 3$\sigma$ level, is found for 5 standards, including the Luminous Blue Variable HD 160529 and all but one of the other B/A-type supergiants (HD 80558, HD 111613, HD 183143, and 55 Cyg), most of which also appear likely to be variable in polarization magnitude (p) – there is no preferred orientation for the polarization in these objects, which are all classified as $\alpha$ Cygni variables. Despite this we make six key recommendations for observers – relating to data acquisition, processing and reporting – that will allow them to use these standards to achieve $\lt $ 0.1$^\circ$ precision in the telescope position angle with similar instrumentation, and allow data sets to be combined more accurately.
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