This study proposes a new passive thermal-control device utilizing phase-change materials (PCMs) that require minimal active thermal support, such as heaters, to achieve a high-performance and high-reliability power supply for nanosatellites and other space applications. This study evaluated two different PCMs as candidate materials for the device and compares their performances as thermal control devices. One was a solid–solid PCM based on vanadium dioxide doped with tungsten (VWO2), and the other was a microencapsulated PCM containing n-paraffin (NPH-MPCM). For integration into nanosatellites, it is essential to form a PCM as solid blocks. This report adopted a solidification method using epoxy resin (EP) as the binder and determined the optimal block composition for each PCM. The thermal-insulation properties of both PCM blocks in vacuum and low-temperature environments were evaluated and found to be almost equivalent. Considering that the latent heat of VWO2 is only approximately one-fifth that of NPH-MPCM, the practical application of VWO2 as a PCM was demonstrated. Furthermore, VWO2 exhibits a phase-change temperature hysteresis of 4 °C, which is significantly smaller than the 23 °C of NPH-MPCM. This characteristic is expected to help maintain a more constant temperature for power supplies in earth-orbiting micro/nanosatellites. Moreover, lithium-ion battery cells were incorporated into both VWO2-based and NPH-MPCM-based PCM blocks, and their charge–discharge behaviors were evaluated. Only the VWO2-based PCM block could maintain appropriate temperatures to ensure stable charge–discharge operation. Vacuum resistance results suggested that the VWO2-based PCM block is well-suited as a temperature-stabilizing device for electric power supplies in nanosatellites.
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