High Power Density Research Articles

Borate modified Co-free LiNi0.5Mn1.5O4 cathode material: A pathway to superior interface and cycling stability in LNMO/graphite full-cells

Cobalt-free LiNi0.5Mn1.5O4 (LNMO) holds great promise as a next-generation cathode material for high-energy and high-power density lithium-ion batteries (LIBs), making it a key contender for large-scale energy storage systems (ESS) and transportation applications. Despite its potential, the commercial utilization of LNMO has been impeded by its rapid capacity deterioration attributed to an unstable LNMO/electrolyte interface caused by the intrinsically high operating voltage of LNMO. Here, we present a pragmatic and scalable strategy to improve the LNMO/electrolyte interface through borate-based surface coating of the LNMO. Optimizing the coating process yielded high-rate capability and stable LNMO/electrolyte interface analyzed by extended float tests. Borate-LNMO materials show superior cycling stability at 25 °C and 45 °C, attributed to a robust cathode electrolyte interphase (CEI) formation. The bare LNMO and 0.25-B2O3-LNMO demostrated a cycling stability of around 41.20 % and 62.50 % respectively after 1000 cycles in LNMO/graphite full-cells. Post-mortem X-ray photoelectron spectroscopy (XPS) analysis revealed fewer side reaction products on borate-LNMO cathodes compared to bare LNMO. Additionally, scanning electron microscopy (SEM) revealed a thicker and denser solid-electrolyte interphase (SEI) on cycled graphite anodes from bare LNMO cells, while a thin and robust SEI was observed on graphite from borate-LNMO cells. Finally, we have conclusively demonstrated that the primary aging mechanism in LNMO/graphite full cells stems from the instability at the LNMO/electrolyte or/and graphite/electrolyte interface, rather than material-related degradation phenomenon. These compelling outcomes underscore the potential of cathode material surface coating in general and especially of borate coating on LNMO as a promising and cost-effective enabler for the use of LNMO in next-generation LIBs.

Solar microwave fabric paper on the key technology for making our future satellite and skin surfaces for aircraft, eliminating APU’s

Solar-Microwave Fabric (SMF) is a mass-produced, thin, flexible membrane upon which is imprinted various combinations of solar cells, microwave patch antennas, and analog control devices. This is for applications such as solar power collection, power transmission, communication, and defense. It can be folded into a compact volume for transport and then unfurled for its operation. In its most sophisticated form, the SMF features the full complement of printed devices: solar cells, patch antennas, transceivers, and retro-directive phased array capability. This most mature capability can be applied to the Power-Star in section 1.6 (Figure 46) space solar power satellite, and to ground installations for combined solar power and air defense. The SMF has various modes of operation of, Solar Power Collection, Communications, Distribution & Defensive systems. Ultimately the Power/ Comm/Defense has one side printed as an “active” mode of power transmission whereby radiation is broadcast to a non-cooperative target and the return from the target is used as the beacon for the direction of a high-power density beam with focusing (vaporization). This could be applied for both ground-based power collection and air/space defense. World’s 1st exposure to: US Patent 11,251,658, Japan Patent 6,987,935.

Hydrothermal preparation of N and O-rich porous carbon microspheres and their capacitance properties

In this paper, N and O-rich porous activated carbon (N-O/AC) microsphere with various pore sizes was prepared by thermal and KOH activation of g-C3N4@graphene oxide (CN@GO) microsphere. CN@GO microsphere was pre-prepared through a hydrothermal method directly from glucose and melamine, which resulted into high content and uniform doping of O and N in the final product. CN@GO microsphere was composed of GO/CN/GO sandwich nanochips, forming a porous structure with various pore sizes. The obtained N-O/AC has high energy density (33.19 Wh/kg) and high power density (499.93 W/kg), in company with excellent cyclic stability (remaining 98.64 % after 1000 cycles). The N-O/AC derived from the hydrothermal method provides a low-cost way of constructing porous carbon matrix composites with pseudo-capacitance.

Recent Progress Using Graphene Oxide and Its Composites for Supercapacitor Applications: A Review

Supercapacitors are prospective energy storage devices for electronic devices due to their high power density, rapid charging and discharging, and extended cycle life. Materials with limited conductivity could have low charge-transfer ions, low rate capability, and low cycle stability, resulting in poor electrochemical performance. Enhancement of the device’s functionality can be achieved by controlling and designing the electrode materials. Graphene oxide (GO) has emerged as a promising material for the fabrication of supercapacitor devices on account of its remarkable physiochemical characteristics. The mechanical strength, surface area, and conductivity of GO are all quite excellent. These characteristics make it a promising material for use as electrodes, as they allow for the rapid storage and release of charges. To enhance the overall electrochemical performance, including conductivity, specific capacitance (Cs), cyclic stability, and capacitance retention, researchers concentrated their efforts on composite materials containing GO. Therefore, this review discusses the structural, morphological, and surface area characteristics of GO in composites with metal oxides, metal sulfides, metal chalcogenides, layered double hydroxides, metal–organic frameworks, and MXene for supercapacitor application. Furthermore, the organic and bacterial functionalization of GO is discussed. The electrochemical properties of GO and its composite structures are discussed according to the performance of three- and two-electrode systems. Finally, this review compares the performance of several composite types of GO to identify which is ideal. The development of these composite devices holds potential for use in energy storage applications. Because GO-modified materials embrace both electric double-layer capacitive and pseudocapacitive mechanisms, they often perform better than pristine by offering increased surface area, conductivity, and high rate capability. Additionally, the density functional theory (DFT) of GO-based electrode materials with geometrical structures and their characteristics for supercapacitors are addressed.

Self‐Adjustment of Intrinsic Reaction Intermediate on Atomically Dispersed Co2–N6 Binuclear Sites Achieving Boosted Electrocatalytic Oxygen Reduction Performance

AbstractIsolated dual‐atom catalysts (DACs) have sparked enormous research enthusiasm in new energy community due to their great potentials to substitute the state‐of‐the‐art Pt‐based catalysts. Nevertheless, explicitly unraveling the underlying catalytic mechanisms is of critical significance for performance enhancement, yet remains a huge challenge. Herein, the study reports a reliable hard template‐mediated strategy to accomplish the construction of atomically isolated binuclear Co2‐N6 sites stabilized by ultrathin hollow carbon nanospheres (abbreviated as Co2‐DAs@CHNSs). Systematic spectroscopy characterization and theoretic calculations uncover that the Co2‐N6 sites follow a self‐adjusting mechanism caused by the intrinsic OH intermediate. The involvement of the ‐OH energy‐level modifier is found to induce the electron redistribution and alternation of antibonding orbital fillings for the generated Co2‐N6‐OH site, leading to reduced potential‐determining step (PDS) energy barrier, and thus boosted intrinsic activity. Consequently, the well‐managed Co2‐DAs@CHNSs afford outstanding oxygen reduction reaction (ORR) activity with a half‐wave potential of 0.87 V in alkaline electrolyte, overmatching the Pt benchmark. Furthermore, the Co2‐DAs@CHNSs‐assembled aqueous and all‐solid‐state rechargeable zinc–air batteries (ZABs) demonstrate high power density, large specific capacity, and robust stability. The findings offer an innovative avenue to rationally manipulate the electronic structures of active sites for DACs via a powerful self‐ligand modification strategy.

Fine and dense bismuth electrocatalysts achieving high power density and cycling stability in vanadium flow batteries

Developing electrode materials that can work efficiently at high current densities while maintaining excellent stability is critical for reducing the unit cost of vanadium flow batteries (VFB). Herein, we report a Bi nanoparticles (∼10 nm) decorated thermal-active graphite felt (Bi@TGF) electrode fabricated through a simple polyvinylpyrrolidone guided approach. Fine and dense Bi electrocatalysts not only play an important role in catalyzing V2+/V3+ redox reaction, but also effectively suppress hydrogen evolution side reaction. As a result, the VFB assembled with Bi@TGF as negative electrode exhibits excellent rate performance (energy efficiency of 81.5 % at 200 mA cm−2) and extremely high peak power density (1023 mW cm−2 at 1250 mA cm−2). Moreover, Bi@TGF electrode demonstrates outstanding durability in 2500-cycle ultralong charge-discharge testing at 300 mA cm−2, with energy (voltage) efficiency retention rate of 99.2 % (98.9 %). The stable cycling ability of Bi@TGF under high operating current density endows its potential application in long-duration and high power density VFB.

Anode-Free Aqueous Aluminum Ion Batteries.

Aqueous aluminum ion batteries (AAIBs) possess the advantages of high safety, cost-effectiveness, eco-friendliness and high theoretical capacity. However, the Al2O3 film on the Al anode surface, a natural physical barrier to the plating of hydrated aluminum ions, is a key factor in the decomposition of the aqueous electrolyte and the severe hydrogen precipitation reaction. To circumvent the obnoxious Al anode, a proof-of-concept of an anode-free AAIB is first proposed, in which Al2TiO5, as a cathode pre-aluminum additive (Al source), can replenish Al loss by over cycling. The Al-Cu alloy layer, formed by plating Al on the Cu foil surface during the charge process, possesses a reversible electrochemical property and is paired with a polyaniline (cathode) to stimulate the battery to exhibit high initial discharge capacity (175 mAh g-1), high power density (≈410Wh L-1) and ultra-long cycle life (4000 cycles) with the capacity retention of ≈60% after 1000 cycles. This work will act as a primer to ignite the enormous prospective researches on the anode-free aqueous Al ion batteries.

Highly Stretchable Polyurethane Porous Membranes with Adjustable Morphology for Advanced Lithium Metal Batteries.

A highly flexible, tunable morphology membrane with excellent thermal stability and ionic conductivity can endow lithium metal batteries with high power density and reduced dendrite growth. Herein, a porous Polyurethane (PU) membrane with an adjustable morphology was prepared by a simple nonsolvent-induced phase separation technique. The precise control of the final morphology of PU membranes can be achieved through appropriate selection of a nonsolvent, resulting a range of pore structures that vary from finger-like voids to sponge-like pores. The implementation of combinatorial DFT and experimental analysis has revealed that spongy PU porous membranes, especially PU-EtOH, show superior electrolyte wettability (472%), high porosity (75%), good mechanical flexibility, robust thermal dimensional stability (above 170 °C), and elevated ionic conductivity (1.38 mS cm-1) in comparison to the polypropylene (PP) separator. The use of PU-EtOH in Li//Li symmetric cell results in a prolonged lifespan of 800 h, surpasing the longevity of PU or PP cells. Moreover, when subjected to a high rate of 5 C, the LiFePO4/Li half-cell with a PU-EtOH porous membrane displayed better cycling performance (115.4 mAh g-1) compared to the PP separator (104.4 mAh g-1). Finally, the prepared PU porous membrane exhibits significant potential for improving the efficiency and safety of LMBs.

Broadband and ascendant nonlinear optical properties of the wide bandgap material GaN nanowires

Gallium nitride (GaN) nanowire, as a type of wide bandgap nanomaterial, has attracted considerable interest because of its outstanding physicochemical properties and applications in energy storage and photoelectric devices. In this study, we prepared GaN nanowires via a facile chemical vapor deposition method and investigated their nonlinear absorption responses ranging from ultraviolet to near-infrared in the z-scan technology under irradiation by picosecond laser pulses. The experiment revealed that GaN nanowires exhibit remarkable nonlinear absorption characteristics attributed to their wide bandgap and nanostructure, including saturable absorption and reverse saturable absorption. When compared to bulk GaN crystals, the nanowires provide a richer and more potent set of nonlinear optical effects. Furthermore, we conducted an analysis of the corresponding electronic transition processes associated with photon absorption. Under high peak power density laser excitation, two-photon absorption or three-photon absorption dominate, with maximum modulation depths of 73.6%, 74.9%, 63.1% and 64.3% at 266 nm, 355 nm, 532 nm, and 1064 nm, respectively, corresponding to absorption coefficients of 0.22 cm/GW, 0.28 cm/GW, 0.08 cm/GW, and 2.82 ×10−4 cm3/GW2. At lower peak energy densities, GaN nanowires demonstrate rare and excellent saturation absorption characteristics at wavelength of 355 nm due to interband transitions, while saturable absorption is also observed at 532 nm and 1064 nm due to band tail absorption. The modulation depths are 85.2%, 41.9%, and 13.7% for 355 nm, 532 nm, and 1064 nm, corresponding to saturation intensities of 3.39 GW/cm2, 5.58 GW/cm2 and 14.13 GW/cm2. This indicates that GaN nanowires can be utilized as broadband optical limiters and high-performance pulse laser modulating devices, particularly for scarce ultraviolet optical limiters, and saturable absorbers for ultraviolet and visible lasers. Furthermore, our study demonstrates the application potential of wide bandgap nanomaterials in nonlinear optical devices.

NiC2O4 nanorods embellished NiCo layered double hydroxide nanoflowers with enhanced electrochemical performances for hybrid supercapacitor

Designing and constructing a high performance and multi-component nickel-based material is preferable for efficient energy storage devices. In this study, we reasonably designed a composite material, NiC2O4/NiCo layered double hydroxide (LDH), composed of 1D NiC2O4 nanorods and 3D NiCo-LDH nanoflowers self-assembled from nanosheets via a hydrothermal method. This causes NiCo-LDH nanoflowers to stretch out, increasing the specific surface area (up to 47 m2 g−1), improving contact with the electrolyte and providing abundant active sites, speeding up the transfer of protons. The excellent double redox reactions of NiC2O4 and NiCo-LDH expedite the reaction kinetics and boost electrochemical activities, resulting in high energy densities of 37.6 Wh kg−1 and high power densities of 809.8 W kg−1 for the NiC2O4/NiCo-LDH||AC hybrid supercapacitor devices. Furthermore, DFT calculations indicate NiC2O4/NiCo-LDH enhance the adsorption ability of OH−. And the improved electrochemical performance of NiC2O4/NiCo-LDH is due to partial electrons transfer through the interface.

Recent progress in metal oxide-based electrode materials for safe and sustainable variants of supercapacitors.

A significant amount of energy can be produced using renewable energy sources; however, storing massive amounts of energy poses a substantial obstacle to energy production. Economic crisis has led to rapid developments in electrochemical (EC) energy storage devices (EESDs), especially rechargeable batteries, fuel cells, and supercapacitors (SCs), which are effective for energy storage systems. Researchers have lately suggested that among the various EESDs, the SC is an effective alternate for energy storage due to the presence of the following characteristics: SCs offer high-power density (PD), improvable energy density (ED), fast charging/discharging, and good cyclic stability. This review highlighted and analyzed the concepts of supercapacitors and types of supercapacitors on the basis of electrode materials, highlighted the several feasible synthesis processes for preparation of metal oxide (MO) nanoparticles, and discussed the morphological effects of MOs on the electrochemical performance of the devices. In this review, we primarily focus on pseudo-capacitors for SCs, which mainly contain MOs and their composite materials, and also highlight their future possibilities as a useful application of MO-based materials in supercapacitors. The novelty of MO's electrode materials is primarily due to the presence of synergistic effects in the hybrid materials, rich redox activity, excellent conductivity, and chemical stability, making them excellent for SC applications.

SPEED: an integrated, smartphone-operated, handheld digital PCR Device for point-of-care testing

This study elaborates on the design, fabrication, and data analysis details of SPEED, a recently proposed smartphone-based digital polymerase chain reaction (dPCR) device. The dPCR chips incorporate partition diameters ranging from 50 μm to 5 μm, and these partitions are organized into six distinct blocks to facilitate image processing. Due to the superior thermal conductivity of Si and its potential for mass production, the dPCR chips were fabricated on a Si substrate. A temperature control system based on a high-power density Peltier element and a preheating/cooling PCR protocol user interface shortening the thermal cycle time. The optical design employs four 470 nm light-emitting diodes as light sources, with filters and mirrors effectively managing the light emitted during PCR. An algorithm is utilized for image processing and illumination nonuniformity correction including conversion to a monochromatic format, partition identification, skew correction, and the generation of an image correction mask. We validated the device using a range of deoxyribonucleic acid targets, demonstrating its potential applicability across multiple fields. Therefore, we provide guidance and verification of the design and testing of the recently proposed SPEED device.

Side Reactions/Changes in Lithium-Ion Batteries: Mechanisms and Strategies for Creating Safer and Better Batteries.

Lithium-ion batteries (LIBs), in which lithium ions function as charge carriers, are considered the most competitive energy storage devices due to their high energy and power density. However, battery materials, especially with high capacity undergo side reactions and changes that result in capacity decay and safety issues. A deep understanding of the reactions that cause changes in the battery's internal components and the mechanisms of those reactions is needed to build safer and better batteries. This review focuses on the processes of battery failures, with voltage and temperature as the underlying factors. Voltage-induced failures result from anode interfacial reactions, current collector corrosion, cathode interfacial reactions, overcharge, and over-discharge, while temperature-induced failure mechanisms include SEI decomposition, separator damage, and interfacial reactions between electrodes and electrolytes. The review also presents protective strategies for controlling these reactions. As a result, the reader is offered a comprehensive overview of the safety features and failure mechanisms of various LIB components.

Research on electronic optical monitoring technology and system design for vacuum electron beam welding process

Electron beam welding technology is increasingly used in industrial manufacturing due to its high power density and the purity of welded joints. In vacuum environments, traditional optical and machine vision monitoring methods are susceptible to contamination by metal vapors, which hinders the monitoring effect. Due to the limitations of optical monitoring methods, electronic optical imaging technology is a new alternative monitoring method that has been introduced into the electron beam processing in recent years, but the complexity of the industrial electron beam welding environment makes it relatively less studied in the field of electron beam welding. In this study, a YAG scintillator detector is proposed to collect the backscattered electron information generated by the interaction of electrons with the sample, and an FPGA real-time processing system is used to realize the weld quality monitoring in the industrial electron beam welding processes. The distribution law of backscattered electrons in space is simulated by Monte Carlo method, and the results show that the number of distribution in the 40°∼60° angle region is more, the backscattering coefficient increases with the increase of the incident angle of the electron beam, and the backscattering coefficient of the samples with large atomic numbers is relatively high. The field monitoring experiments show that the designed system exhibits good sensitivity to the characteristic morphology, and the imaging resolution reaches more than 200 μm, and the weld hole defects are clearly visible. A good linear correlation between the current change curve during scanning and the actual shape profile is shown, while the image resolution is better when the spot current is 1 mA.

Atomically dispersed Iridium on Mo2C as an efficient and stable alkaline hydrogen oxidation reaction catalyst

Hydroxide exchange membrane fuel cells (HEMFCs) have the advantages of using cost-effective materials, but hindered by the sluggish anodic hydrogen oxidation reaction (HOR) kinetics. Here, we report an atomically dispersed Ir on Mo2C nanoparticles supported on carbon (IrSA-Mo2C/C) as highly active and stable HOR catalysts. The specific exchange current density of IrSA-Mo2C/C is 4.1 mA cm−2ECSA, which is 10 times that of Ir/C. Negligible decay is observed after 30,000-cycle accelerated stability test. Theoretical calculations suggest the high HOR activity is attributed to the unique Mo2C substrate, which makes the Ir sites with optimized H binding and also provides enhanced OH binding sites. By using a low loading (0.05 mgIr cm−2) of IrSA-Mo2C/C as anode, the fabricated HEMFC can deliver a high peak power density of 1.64 W cm−2. This work illustrates that atomically dispersed precious metal on carbides may be a promising strategy for high performance HEMFCs.

Research on the kinetics characteristics and in-cylinder combustion of opposed rotary piston engine for different power output modes

As a new type of internal combustion engine, opposed rotary piston (ORP) engine has the advantages of simple structure and high working frequency, and can achieve high power density. Consequently, it stands as an ideal power source for hybrid power systems and unmanned aerial vehicles. The ORP engine has different power output modes, corresponding to different piston rotation and volume evolutions of combustion chamber. However, the effect of power output modes on kinetics characteristics and in-cylinder combustion of ORP engines are still uncovered. In this paper, the kinematic model of an ORP engine is established for scenarios involving power output by different shafts (Shaft 1 and Shaft 3). Meanwhile, the piston rotation patterns and cylinder volume variations are investigated correspondingly. Further, three-dimensional numerical model of the ORP engine is established, enabling analysis of in-cylinder combustion characteristics, engine performance, as well as nitrogen oxides (NOx) emissions. The results indicate that the volume variations of all cylinders follow a consistent pattern under the power output by Shaft 3. A pair of opposed cylinders features longer durations of intake and expansion strokes, and shorter durations of compression and exhaust strokes, the other pair of combustion chambers is the opposite under the power output by Shaft 1. The engine demonstrates a charging efficiency of 95.36 %, with corresponding indicated thermal efficiency and indicated power output of 38.08 % and 40.9 kW, respectively. The two adjacent cylinders present significantly different operation processes in the case of the power output by Shaft 1, achieving charging efficiencies of 94.29 % and 89.11 %, respectively, with the indicated thermal efficiency of 34.49 % and 31.60 %. The corresponding minimum indicated specific fuel consumption under the two power output modes are 211.7 g/kW∙h and 243.7 g/kW∙h, respectively, accompanied by NOx emission factors of 25.3 g/kW∙h and 17.6 g/kW∙h. With the given range of ignition timing, a trade-off relationship exists between the engine performance and NOx emissions. The power density of the case of power output by Shaft 3 is superior to that of Shaft 1.

Performance Analysis of Liquid-to-Air Heat Exchanger of High-Power Density Racks

Abstract The ability of traditional room-conditioning systems to accommodate expanding information technology loads is limited in contemporary data centers, where the storage, storing, and processing of data have grown quickly as a result of evolving technological trends and rising demand for online services, which has led to an increase in the amount of waste heat generated by IT equipment. Through the implementation of hybrid air and liquid cooling technologies, targeted, on-demand cooling is made possible by employing various techniques, which include but are not limited to in-row, overhead, and rear door heat exchanger cooling systems. One of the liquid cooling techniques will be examined in this study based on different conditions for high-power density racks (+50 kW). This paper investigates the cooling performance of a liquid-to-air in-row CDU in a test rack containing seven thermal test vehicles under various conditions, focusing on cooling capacity and HX effectiveness under different supply air temperatures. This test rig has the necessary instruments to monitor and analyze the experiments on both the liquid and the air sides. Moreover, another experiment is conducted to assess the performance of the CDU that runs under different control fan schemes, as well as how the change of the control type will affect the supply fluid temperature and the TTV case temperatures at 10%, 50%, and 100% of the total power. Finally, suggestions for the best control fan scheme to use for these units are provided at the conclusion of the study.

Dynamically stable radiation pressure propulsion of flexible lightsails for interstellar exploration

Meter-scale, submicron-thick lightsail spacecraft, propelled to relativistic velocities via photon pressure using high-power density laser radiation, offer a potentially new route to space exploration within and beyond the solar system, posing substantial challenges for materials science and engineering. We analyze the structural and photonic design of flexible lightsails by developing a mesh-based multiphysics simulator based on linear elastic theory. We observe spin-stabilized flexible lightsail shapes and designs that are immune to shape collapse during acceleration and exhibit beam-riding stability despite deformations caused by photon pressure and thermal expansion. Excitingly, nanophotonic lightsails based on planar silicon nitride membranes patterned with suitable optical metagratings exhibit both mechanically and dynamically stable propulsion along the pump laser axis. These advances suggest that laser-driven acceleration of membrane-like lightsails to the relativistic speeds needed to access interstellar distances is conceptually feasible, and that their fabrication could be achieved by scaling up modern microfabrication technology.

Seamless multi‐mode switching controller of four‐switch buck–boost converter based on integrated natural trajectory method

SummaryWith the characteristics of high efficiency and high power density, the four switch buck–boost (FSBB) converter is widely used in electric vehicles, direct current microgrids, and so forth. However, how to achieve smooth switching between different modes of FSBB has always been a hot issue in the theoretical and engineering fields. In this paper, considering the dynamic performance and output voltage or inductance current deviation, a control algorithm with integrated natural trajectory method is designed to realize the switching of different modes of FSBB converter. The proposed control algorithm is based on the theory of large signal natural locus and average natural locus. The normalized phase locus of inductance current and output voltage divides the phase plane into five regions and performs large signal or average switching operations in different regions. Theoretical analysis shows that the proposed control algorithm can achieve the balance between the dynamic performance and output voltage or inductance current deviation of FSBB converter in different mode switching. Finally, the performance of the proposed control algorithm is verified by experiments results.

Application of supramolecular hydrogel in supercapacitors: Opportunities and challenges

AbstractSupercapacitors (SCs) are studied and used in various fields due to their high power density, fast charging/discharging rate, as well as long cycle life. Compared to other traditional electrode and electrolyte materials, supramolecular hydrogels have great advantages in the application of SCs due to their excellent properties. Unlike covalent bonds, supramolecular systems are assembled through dynamic reversible bonds, including host–guest interactions, ion interactions, electrostatic interactions, hydrogen bonding, coordination interactions, etc. The resulting supramolecular hydrogels show some special functions, such as stretching, compression, adhesion, self‐healing, stimulus responsiveness, etc., making them strong candidates for the next generation of energy storage devices. This paper reviews the representative progress of electrodes, electrolytes, and SCs based on supramolecular hydrogels. Besides, the properties of supramolecular hydrogels, such as conductivity, extensibility, compressibility and elasticity, self‐healing, frost resistance, adhesion, and flexibility, are also reviewed to highlight the key role of excellent properties of hydrogel materials in SCs. In addition, this article also discusses the challenges faced by current technologies, hoping to continue promoting future research in this field.