Abstract The type-II GaP0.3Sb0.7/InP0.7Sb0.3 nanoscale heterostructure is modelled and simulated for its optical properties in near-infrared lasing applications. The optical gain of GaP0.3Sb0.7/InP0.7Sb0.3 type-II heterostructure is analyzed under different external values of electric fields, temperatures and well widths at room temperature 300 K. The complete structure is grown on InP substrate. The effects of a varied temperature (290 K–320 K), quantum well width (2 nm, 3 nm, and 4 nm) and applied electric field (20 kV cm−1–8 0 kV cm−1) are explored regarding the band alignment, wavefunction, band dispersion, matrix elements, gain and wavelength. The Luttinger-Kohn model is utilized to compute the band structure. The gain computation involves the evaluation of the 6 × 6 k·p Hamiltonian matrix. The proposed heterostructure at 2 nm quantum well width exhibits a high optical gain of 14998 cm−1 in x-polarization and 16572 cm−1 in y-polarization for injected carrier concentration of 4 × 1012 cm2. Under variable temperature and electric field, a significant optical gain is achieved in x, y and z input polarizations. This heterostructure is regarded as new because of its very high optical gain in NIR regime, that makes it beneficial for optoelectronics.
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