High Magmatic Water Content Research Articles

The origin of hydrous, high-δ18O voluminous volcanism: diverse oxygen isotope values and high magmatic water contents within the volcanic record of Klyuchevskoy volcano, Kamchatka, Russia

Klyuchevskoy volcano, in Kamchatka’s subduction zone, is one of the most active arc volcanoes in the world and contains some of the highest δ18O values for olivines and basalts. We present an oxygen isotope and melt inclusion study of olivine phenocrysts in conjunction with major and trace element analyses of 14C- and tephrochronologically-dated tephra layers and lavas spanning the eruptive history of Klyuchevskoy. Whole-rock and groundmass analyses of tephra layers and lava samples demonstrate that both high-Mg (7–12.5 wt% MgO) and high-Al (17–19 wt% Al2O3, 3–6.5 wt% MgO) basalt and basaltic andesite erupted coevally from the central vent and flank cones. Individual and bulk olivine δ18O range from normal MORB values of 5.1‰ to values as high as 7.6‰. Likewise, tephra and lava matrix glass have high-δ18O values of 5.8–8.1‰. High-Al basalts dominate volumetrically in Klyuchevskoy’s volcanic record and are mostly high in δ18O. High-δ18O olivines and more normal-δ18O olivines occur in both high-Mg and high-Al samples. Most olivines in either high-Al or high-Mg basalts are not in oxygen isotopic equilibrium with their host glasses, and Δ18Oolivine–glass values are out of equilibrium by up to 1.5‰. Olivines are also out of Fe–Mg equilibrium with the host glasses, but to a lesser extent. Water concentrations in olivine-hosted melt inclusions from five tephra samples range from 0.4 to 7.1 wt%. Melt inclusion CO2 concentrations vary from below detection (<50 ppm) to 1,900 ppm. These values indicate depths of crystallization up to ~17 km (5 kbar). The variable H2O and CO2 concentrations likely reflect crystallization of olivine and entrapment of inclusions in ascending and degassing magma. Oxygen isotope and Fe–Mg disequilibria together with melt inclusion data indicate that olivine was mixed and recycled between high-Al and high-Mg basaltic melts and cumulates, and Fe–Mg and δ18O re-equilibration processes were incomplete. Major and trace elements in the variably high-δ18O olivines suggest a peridotite source for the parental magmas. Voluminous, highest in the world with respect to δ18O, and hydrous basic volcanism in Klyuchevskoy and other Central Kamchatka depression volcanoes is explained by a model in which the ascending primitive melts that resulted from the hydrous melt fluxing of mantle wedge peridotite, interacted with the shallow high-δ18O lithospheric mantle that had been extensively hydrated during earlier times when it was part of the Kamchatka forearc. Following accretion of the Eastern Peninsula terrains several million years ago, a trench jump eastward caused the old forearc mantle to be beneath the presently active arc. Variable interaction of ascending flux-melting-derived melts with this older, high-δ18O lithospheric mantle has produced mafic parental magmas with a spectrum of δ18O values. Differentiation of the higher δ18O parental magmas has created the volumetrically dominant high-Al basalt series. Both basalt types incessantly rise and mix between themselves and with variable in δ18O cumulates within dynamic Klyuchevskoy magma plumbing system, causing biannual eruptions and heterogeneous magma products.

A North-South Transect across the Central Mexican Volcanic Belt at 100 W: Spatial Distribution, Petrological, Geochemical, and Isotopic Characteristics of Quaternary Volcanism

Within the Zita¤ cuaro^Valle de Bravo (ZVB) region of the central Mexican Volcanic Belt (MVB), three lava series have erupted during the Quaternary: (1) high-K2O basaltic andesites and andesites; (2) medium-K2O basaltic andesites, andesites and dacites; (3) high-TiO2 basalts and basaltic andesites.The dominant feature of the first two groups is the lack of plagioclase accompanying the various ferromagnesian phenocrysts (olivine, orthopyroxene, augite, and hornblende) in all but the dacites. This absence of plagioclase in the phenocryst assemblages of the high-K2O and medium-K2O intermediate lavas is significant because it indicates high water contents during the stage of phenocryst equilibration. In contrast, the high-TiO2 group is characterized by phenocrysts of plagioclase and olivine.The spatial distribution of these three lava series is systematic.The southern section of the ZVB transect, 280^330 km from the Middle AmericaTrench (MAT), is characterized by high-K2Omelts that are relatively enriched in fluidmobile elements and have the highest Sr/Sr ratios. Medium-K2O basaltic andesite and andesite lavas are present throughout the transect, but those closest to theMATareMgO-rich (3 5^9 4 wt%) and have phenocryst assemblages indicative of high magmatic water contents (3 5^6 5 wt % water) and relatively low temperatures (950^10008C). In marked contrast, the northern section of the ZVB transect (380^480 km from the MAT) has high-TiO2, high field strength element (HFSE)-enriched magmas that have comparatively dry (51 5 wt % magmatic water) and hot (1100^12008C) phenocryst equilibration conditions. The central section of the ZVB transect (330^380 km from the MAT) is a transition zone and produces moderately light rare earth element (LREE) and large ion lithophile element (LILE)-enriched, medium-K2O lavas with phenocryst assemblages indicative of intermediate (1 5^3 5 wt %) water contents and temperatures. The high-K2O series compositions are the most enriched in LILE and LREE, with a narrow range of radiogenic Sr/Sr from 0 704245 to 0 704507, Nd/Nd values ranging from 0 512857 to 0 512927 (eNd1⁄4 4 27^5 63), and Pb/Pb values from 38 248 to 38 442, Pb/Pb values from 15 563 to 15 585, and Pb/Pb values from 18 598 to 18 688. The medium-K2O series compositions are only moderately enriched in the LILE and LREE, with a broader range of Sr/Sr, but similar Nd/Nd and Pb/Pb values to those of the high-K2O series. In contrast, the high-TiO2 series compositions have little enrichment in LILE or LREE and instead are enriched in the HFSE and heavy rare earth elements (HREE). The high-TiO2 lavas are isotopically distinct in their lower and narrower range of Nd/Nd. The isotopic variations are believed to reflect the upper mantle magma source regions as the low content of phenocrysts in most lavas precludes significant upper crustal assimilation or magma mixing, other than that represented by the presence of quartz xenocrysts (52 vol. %) with rhyolitic glass inclusions, which are found in many of these lavas.The systematic spatial variation in composition of the three lava series is a reflection of the underlying subduction-modified mantle and its evolution.

Geologic Evolution of the Escondida Area, Northern Chile: A Model for Spatial and Temporal Localization of Porphyry Cu Mineralization

A program of geologic mapping and lithogeochemical and geochronological sampling has been carried out over a 745-km2 area of the Atacama Desert surrounding the porphyry Cu deposits at Escondida, Zaldivar, and Chimborazo (Cordillera de Domeyko, northern Chile). The purpose of this study was to examine the regional tectonic and magmatic setting of this preeminent porphyry Cu district for evidence of features or processes that might explain the giant scale of mineralization at Escondida and provide predictive tools for exploration in other areas. The geologic history of this area as recorded by exposed rocks begins with voluminous, intermediate to felsic Permo-Carboniferous volcanism (La Tabla Formation), and these rocks appear to constitute the crystalline basement throughout much of the porphyry belt of northern Chile. Geochemically, they are I-type in character, but the parental magmas were relatively dry, and thus did not generate effective magmatic-hydrothermal systems (few significant ore deposits are known to be associated with them). Andean cycle arc magmatism began in the Triassic, centered on the La Negra magmatic arc (now located near the Chilean coast). Farther inland, near Escondida, back-arc processes led to the eruption of intermediate to felsic lavas and tuffs and the deposition of marine sediments in rift basins. Closure of these basins in the Late Cretaceous resulted in deformation of the volcano-sedimentary sequences and was followed by emplacement of small alkali gabbro stocks and dikes. The axis of arc magmatism moved eastward in the Paleocene (Central Valley arc) and produced widespread calc-alkaline intermediate to felsic volcanism through to the Eocene. East- to northeast-directed convergence maintained a dextral transpressive regime during this period, and early movements in the West Fissure zone, a corridor of orogen-parallel faults that runs the length of the Cordillera de Domeyko (over 1,000 km), reflect this couple. At the end of the Eocene, however, stresses in the arc appear to have relaxed, and by the late Oligocene, strike-slip movement along the West Fissure zone had reversed to sinistral. This period of stress relaxation at the end of the Eocene period coincided with the voluminous emplacement of dioritic magmas at shallow crustal levels and also with porphyry development. Six samples of hornblende from these diorites yield 40Ar/39Ar dates between 38.28 ± 0.32 and 36.94 ± 0.46 Ma (2 σ ). Porphyry emplacement at Escondida, Zaldivar, and Chimborazo was coeval with this dioritic magmatism at ~38 Ma. Where plutonism was intense, the dioritic magma is interpreted to have evolved by processes of assimilation and fractional crystallization to more felsic compositions characteristic of the ore-forming porphyry intrusions. Whole-rock trace element data indicate that hornblende fractionation was an important control on chemical evolution of the diorites and attests to high-magmatic water contents (>4 wt % H2O). Volatile saturation would have occurred during further differentiation of these magmas, evidence for which is provided by the porphyry ore deposits. Porphyry emplacement was localized within a broad zone of intersection between the West Fissure zone and a regionally extensive northwest-trending structural corridor (the Archibarca lineament). It is proposed that the geometry of this junction was conducive to the formation of transtensional pull-apart structures during relaxation or reversal of dextral shear on the West Fissure zone. Such dilational structures would have focused the ascent and pooling of magma in the upper crust and maximized the potential for formation of magmatic-hydrothermal ore deposits. The formation of giant porphyry systems such as Escondida is, therefore, considered to be the result of a fortuitous coincidence of processes, including generation of suitable volumes and compositions of magma, appropriate lithospheric stress conditions, and structural focusing of emplacement; in addition, the development of thick supergene enrichment blankets has been critical to the economic value of these deposits. None of these contributory processes are in themselves unusual or rare, but because they are largely independent of one another, their constructive cooperation in ore formation is not necessarily repeatable at different places and at different times, thus explaining the relative rarity of giant porphyry deposits.

Petrology of Volc�n Tequila, Jalisco, Mexico: disequilibrium phenocryst assemblages and evolution of the subvolcanic magma system

Volcan Tequila is an extinct stratovolcano in the western Mexican Volcanic Belt that has erupted lavas ranging from andesite to rhyolite during the last 0.9 Ma. Following an early period of rhyolitic volcanism, the main edifice of the volcano was constructed by central vent eruptions that produced ∼ 25 km3 of pyroxene-andesite. At about 0.2 Ma central activity ceased and numerous flows of hornblende-bearing andesite, dacite, and rhyodacite erupted from vents located around the flanks of the volcano. Bimodal plagioclase phenocryst rim compositions in lavas from both the main edifice and the flanks indicate that magma mixing commonly occurred shortly prior to or during eruption. Compositions of endmember magmas involved in mixing, as constrained by whole-rock major and trace element abundances, phenocryst compositions, and mineral-melt exchange equilibria, are similar to those of some lavas erupted from the central vent and on the flanks of the volcano. Estimated pre-eruptive temperatures for hornblende-bearing lavas (970°–830°C) are systematically lower than for lavas that lack hornblende (1045°–970°C), whereas magmatic H2O contents are systematically higher for hornblende-bearing lavas. In addition to stabilizing hornblende, high magmatic water contents promoted crystallization of calcic plagioclase (An70–82). Frequent injections of magma into the base of the subvolcanic plumbing system followed by eruption of mixed magma probably prevented formation of large volumes of silicic magma, which have caused paroxysmal, caldera-forming eruptions at other stratovolcanoes in western Mexico. The later stages of volcanic activity, represented by the flank lavas, indicate a change from a large magma storage reservoir to numerous small ones that developed along a NW-trending zone parallel to regional fault trends. Sr and Nd isotopic data for lavas from the Tequila region and other volcanoes in western Mexico demonstrate that differentiated calc-alkaline magmas are formed primarily through crystal fractionation of mantle-derived calc-alkaline basalt coupled with assimilation of crustal material.

Explosive Deep Water Basalt in the Sumisu Backarc Rift

Eruption of 1-million-year-old tholeiitic basalt >1800 meters below sea level (>18 megapascals) in a backarc rift behind the Bonin arc produced a scoriaceous breccia similar in some respects to that formed during subaerial eruptions. Explosion of the magma is thought to have produced frothy agglutinate which welded either on the sea floor or in a submarine eruption column. The resulting 135-meter-thick pyroclastic deposit has paleomagnetic inclinations that are random at a scale of <2.5 meters. High magmatic water content, which is about 1.3 percent by weight after vesiculation, contributed to the explosivity.

Minette lavas and associated leucitites from the western front of the Mexican Volcanic Belt: petrology, chemistry, and origin

During the late Pliocene, K-rich minette and leucitite lavas erupted in the western Mexican Volcanic Belt near the town of Los Volcanes, a region which is located much closer to the Middle America Trench than the main line of currently active andesite stratovolcanoes. During this period the tectonic regime in western Mexico was highly complex due to the simultaneous occurrence of active subduction of the young Rivera Plate, and rifting caused by crustal extension. Most of these basic lavas contain phenocrysts of phlogopite, augite and apatite, along with microphenocrysts of leucite and Fe-Ti oxide. Olivine is absent from all but two of the flows: one an olivine leucitite, and the other a felsic minette. The phlogopite phenocrysts and high whole rock Fe2O3/FeO ratios which are characteristic of this suite record evidence of high magmatic water contents and oxygen fugacities. All of these rock types are highly enriched in the large ion lithophile and light rare earth elements, with Sr≤5100 ppm, Ba≤4800 ppm and Ce≤330 ppm. They are also mildly enriched in the high field strength elements (e.g. Zr 260–700 ppm) and display the strong relative enrichment of the LILE over the HFSE that is characteristic of magmas erupted in convergent margins. Consideration of high pressure phase equilibria in the Mg2SiO4-CaMgSi2O6-KAlSiO4-SiO2 system shows that the minettes from this region are not related through fractional crystallization to the more MgO-rich, olivinebearing minettes which have erupted in other parts of the western Mexican Volcanic Belt during the Quaternary. This conclusion is consistent with both the trace element geochemistry of these lavas and with the results of fractional crystallization models. Instead, the data suggests that these high-K magmas were derived from a source region which consists predominantly of phlogopite, clinopyroxene and apatite, and which has formed through hydrous enrichment of the subarc mantle in response to subduction.