Recently, considerable progress has been made in understanding the early universe by loop quantum cosmology. Modesto et al. investigated the loop quantum black hole (LQBH)using improved semiclassical analysis and they found that the LQBH has two horizons, an event horizon and a Cauchy horizon, just like the Reissner—Nordström black hole. This paper focuses on the dynamical evolution of a massless scalar wave in the LQBH background. By investigating the relation between the complex frequencies of the massless scalar field and the LQBH parameters using the numerical method, we find that the polymeric parameter P makes the massless scalar field decay more quickly and makes the ground scalar wave oscillate slowly. However, the polymeric parameter P causes the frequency of the high harmonic massless scalar wave to shift according to its value. We also find that the loop quantum gravity area gap parameter α0 causes the massless scalar field to decay more slowly and makes the period of the massless scalar field wave become longer. In the complex ω plane, the frequency curves move counterclockwise when the polymeric parameter P increases and this spiral effect is more obvious for a higher harmonic scalar wave.