The processes of ammonia recovery from ammonia nitrogen containing wastewater by air stripping in the laboratory-scale and the pilot-scale rotating packed bed (RPB) were simulated by the Aspen with the module of RADFRAC. For a more accurate description of the model, a variety of correlations for the RPB were introduced into the Aspen by the FORTRAN, such as the gas-liquid mass transfer rate, the liquid holdup, the heat transfer rate and the effective gas-liquid interfacial area, etc. The predicted data of ammonia recovery rate were consistent with the experimental results. To further optimize the operating conditions of ammonia recovery, the research also covered the effects of high gravity factor, gas to liquid ratio, pH and temperature on ammonia recovery rate. The promising results had suggested the established model could serve as a powerful tool to simulate the processes of ammonia recovery from the ammonia nitrogen containing wastewater by air stripping in the laboratory-scale and the pilot-scale RPB.