An investigation of the trace element geochemistry and geothermobarometry of amphibolites and banded iron-formations (BIF) of the Anshan Group, and of associated amphibolite-facies orthogneisses in the Anshan area of Liaoning Province of NE China has been carried out with a view to understanding the petrogenesis and evolution of this Archaean high-grade terrain which is unique for its abundance of BIF. The Anshan supracrustal group, which has a Sm-Nd isochron age of 2.79 Ga, comprises BIF, metavolcanic amphibolites, quartzites, phyllites and schists. The BIF (actinolite-cummingtonite-magnetite-quartz-stilpnomelane) occurs in kilometre-long beds up to 80 m thick, which contain very low contents of total REE, CO2, S, Cu, Pb, Zn, Mn, Ni, P, Ti, V and Cr; δS34 is near chondritic and δO18 approximates the calculated primary δO18 of SiO2 deposited from Archaean sea-water. The amphibolites (hornblende-plagioclase ± quartz ± epidote ± tourmaline) form beds up to 1 km thick, range from quartz- to olivine- and hyperthene-normative and have low Zr and Ti abundances and trace element patterns that are most similar to those of basalts derived from sub-continental mantle or to those of modern island-arc tholeiites. Metasediments are muscovite-tourmaline quartzites, quartz-muscovite-chlorite phyllites, quartz-biotite-muscovite-garnet-staurolite schists, quartz-garnet-biotite schists, quartz-garnet-cumming-tonite-gedite rocks and quartz-K-feldspar-plagioclase-biotite-sillimanite gneisses. The Tiejiashan orthogneisses, which have Rb-Sr and Pb-Pb isotopic ages of 2.83-2.86 Ga, probably represent basement to the Anshan Group. They range from granites to trondhjemites and consist of quartz, plagioclase, biotite and microcline. The Anshan orthogneisses have a Sm-Nd isochron age of 2.53 Ga and range in composition from granites to tonalites. They intruded the Anshan supracrustals with the result that the BIF and associated supracrustal rocks now form lenses of up to several kilometres in the gneisses. The most common assemblage is quartz-K-feldsparplagioclase-biotite. Both the Tiejiashan and Anshan gneisses have high Sr, Rb, and K/Sr and low Ca, and thus are similar to amphibolite-facies gneisses in many high-grade terrains, and to modern volcanic-arc granites. Geothermometry of metasediments suggests that T increased from 500–550°C in the south to 600°C in the north of the area. These temperatures are consistent with the presence of amphibolites, sillimanite in gneisses, and staurolite in schists. No assemblages are suitable for estimating pressure. Combined geological, geochronological and geochemical data suggest to us that the Anshan Group was deposited in a shallow-water basin on or against a continental margin or basement and close to a magmatic arc. During the accretion events associated with the 2.5 Ga Anshan orogeny, arc-driven granitic rocks intruded the basin and engulfed the supracrustal rocks, leaving the BIF, etc., as enclaves in ductile orthogneisses.
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