Thermal sprayed Cr3C2-NiCr coatings are widely used to protect industrial components from ambient or elevated erosive degradation. Various thermal spraying techniques such as plasma spray, detonation spray (DS), high velocity oxy-fuel (HVOF) and high velocity air-fuel spray (HVAF) are widely used to deposit Cr3C2-NiCr coatings. The choice of thermal spraying technique governs the inflight particle velocity and temperature, resulting in unique coating microstructural features, characteristics and erosion performance. In this study, Cr3C2-NiCr coatings are deposited through HVAF, DS and axial plasma spray. A comprehensive comparative analysis was performed to understand the process-structure-property relationship of Cr3C2-NiCr coatings, which correlated with the room and high temperature erosion performance. HVAF spray deposited Cr3C2-NiCr coatings with preferred microstructural features and properties, ensuring superior (high/room temperature) erosive resistance. Cr3C2-NiCr coatings deposited via DS spray performed second best, while plasma sprayed exhibited defective microstructure with inferior mechanical properties, resulting in substandard erosion performance.
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