Heavy Ion Research Articles

Comparison between the Effect of multi-walled carbon nanotubes and single walled carbon nanotubes in removing pb and cd in contaminated bio medical ash

Heavy metal contamination is a highly significant environmental issue. Primarily, this current study is focusing the application of developing Nano technologies which have capacity to remove or reduce toxins from the environment. The extraction and preconcentration abilities of both types of carbon nanotubes, multi-walled (MWCNTs) and single-walled (SWCNTs), were accomplished by using water-acid, acetate, and deghassed water acid EDTA solutions from neuteuche semi-total solid extract from anthropogenic and naturally in origine samples. The results of the study indicated that the adsorption rate was even faster when the solution temperatures were higher in both types of adsorbents. These increases were greater when multi-walled carbon was used. This may be due to the fact that in endothermic nature of adsorption the increase in temperature leads to a faster rate of adsorption. In order to understand the kinetics of Cadmium (II) and Lead(II) adsorption, analysis was executed utilizing the fractional power function model and Lagergren pseudo-first-order and pseudo-second-order methods. A pseudo-second-order model well described the adsorption kinetics of heavy metal ions onto both bioadsorbents. For both biosorbents, the adsorption capacity increased as the solution was heated. The percentage of Pb adsorbed on ultra-sonically assisted MWCNTs was 7.93%, for MWCNTs= 8.33%, 73.50% for swCNTs and 92.46% for amine-MWCNTs (Table 2). Similarly, the percentage of Cd adsorbed on ultra-sonically assisted MWCNTs was 67.92%, 29.30% for MWCNTs, 6.30% for swCNTs and 2.27% for amine-MWCNTs. As far as SWCNTs, they provided some interesting results in terms of adsorption capacity. For example, the adsorption capacity with respect to Pb was about 6.53% with SWCNTs 1, about 7.12% with SWCNTs 2, about 61.33% with SWCNTs 3, and about 79.31% with SWCNTs 4. Similarly, for Cd it was about 61.32% with SWCNTs 1, about 27.13% with SWCNTs 2, about 5.88% with SWCNTs 3, and about 1.53% with SWCNTs 4. The elution tests for single-walled carbon nanotubes and multiwalled carbon nanotubes have been carried out and the results have been shown as binding isotherms and pH effects in Figures 3 and 4. For the study of the adsorption capability of single-walled carbon nanotubes for metal ions, same order of binding to the metal ions has been observed for both the types of the carbon nanotubes-studied, lead (II) < cadmium (II). For multi-walled carbon nanotubes, however, the binding of metal ions was found to depend on the carbon nanotubes type and the binding order, as for carbon nanotubes, were found to be, lead (II) > cadmium (II). Nanotechnologies have facilitated the ability of researchers to address challenges more effectively. This research focuses on the development of Nanotechnologies for the purpose of remediating heavy metals, including cadmium and lead. These metals are considered highly toxic and require urgent attention.

Factorization of photon induced processes in ultra-peripheral heavy ion collisions

In this study, we investigate photon-photon scattering in ultra-peripheral heavy ion collisions (UPCs). We start by deriving an effective Lagrangian from first principles and then apply factorization techniques from Soft-Collinear effective theory (SCET). This approach allows us to decompose the photon-photon scattering cross-section into two primary factors: the generalized transverse momentum distributions (GTMDs) and the hard scattering amplitude. We further analyze the emission of soft photons by final state leptons, incorporating a soft function into the cross section through an evolution method. Our analysis yields detailed predictions for observable angular correlations among the final state leptons. Specifically, we calculate the angular correlations characterized by the azimuthal parameters 〈cos⁡2ϕ〉 and 〈cos⁡4ϕ〉, highlighting the influence of initial photons polarization and recoil effects from final state soft photons.

Electric conductivity of hot and dense nuclear matter

Transport coefficients play an important role in characterising hot and dense nuclear matter, such as that created in ultra-relativistic heavy-ion collisions (URHIC). In the present work we calculate the electric conductivity of hot and dense hadronic matter by extracting it from the electromagnetic spectral function, through its zero energy limit at vanishing 3-momentum. We utilise the vector dominance model (VDM), in which the photon couples to hadronic currents predominantly through the ρ meson. Therefore, we use hadronic many-body theory to calculate the ρ-meson's self-energy in hot and dense hadronic matter, by dressing its pion cloud with π-ρ, π-σ, π-K, N-hole, and Δ-hole loops. We then introduce vertex corrections to maintain gauge invariance. Finally, we analyze the low-energy transport peak as a function of temperature and baryon chemical potential, and extract the conductivity along a proposed phase transition line.

Experimental and calculated electronic stopping force determination of 24Cr, 28Ni and 22Ti ions crossing PVC and Mylar foils in the ion energy domain of LSS theory

Energy loss measurements for heavy ions (28Ni,24Cr and 22Ti) crossing thin polymeric foil such as PVC and Mylar in the energy range 0.1–0.3 MeV/n have been carried out utilizing the 6MV Tandem accelerator facility at iThemba-labs in Johannesburg (South Africa). These measurements deduced experimental stopping force data have been compared with those calculated using Lindhard, Scharff and Schiott formulation (LSS) and SRIM-2013 predictions. A large significant deviation has been observed between experimental values and those calculated by LSS formula. Based on physical postulate, we have developed a reasonably simple semi-empirical formula that takes in to account a mean residual projectile charge Z1¯ and suitable ξe factor which depend on Z1 and Z2. This new modified LSS formula has been tested and the calculated stopping force values generated by this formula are in close agreement with the measured ones.

Monte Carlo simulation of shielding materials in storage drums for 241Am-Be disused sealed radioactive sources

Disused Sealed Radioactive Sources (DSRS) containing neutron sources such as 241Am-Be require careful management due to neutron radiation. However, finding readily available and effective combination layer shielding materials for practical use to safely contain 241Am-Be can be challenging. The main objective of this study is to investigate the configuration of shielding materials and determine the maximum activity of 241Am-Be sources that can be safely stored in a 200-L drum. A three-layer shielding approach using a 200-L drum as a storage container, with sequential layers of lead (Pb), polyethylene (PE), and ordinary Portland concrete (OPC), achieves the lowest dose rates compared to other combination sequences, as shown by Monte Carlo simulations. With a fixed lead thickness and varying polyethylene and ordinary Portland concrete thicknesses, Monte Carlo simulations using the Particle and Heavy Ion Transport code System (PHITS) demonstrate that this drum design can safely accommodate activities ranging from 22.01 Ci to 72.92 Ci of 241Am-Be. The fitted model equation determines the required polyethylene thickness for any activity within this range. Additionally, case-based simulation results indicate that Indonesia's total inventory of 241Am-Be DSRS can be stored in three 200-L drums with a polyethylene thickness of 15 cm. This configuration meets international standards, ensuring the dose rate does not exceed 2 mSv/h at the surface and 0.1 mSv/h at 1 m from the drum's surface.

Indirect detection of lead(II), cadmium(II) and mercury(II) on a microfluidic electrophoresis chip.

Water environments contaminated by heavy metal ions present significant challenges because these pollutants do not degrade naturally, leading to their gradual bioaccumulation in animals and plants, which ultimately poses an insurmountable threat to human health. Therefore, rapid and accurate detection of heavy metal ions in water is of great significance for environmental protection and disease prevention. In this work, we developed a novel method based on microfluidic electrophoresis coupled with indirect chemiluminescence for the immediate detection of Cd(II), Pb(II) and Hg(II) heavy metal ions. The displacement of the Co(II) ions within the chemiluminescence mixture by the above migrating sample cations caused a measurable reduction in the background signal. The results showed that the detection limits of Cd(II), Pb(II) and Hg(II) ions under the best detection conditions were 5.83 × 10-8 M, 5.38 × 10-8 M and 2.09 × 10-8 M, respectively, which were 1-2 orders of magnitude lower than those of the indirect UV method and 1 order of magnitude lower than that of the indirect laser induced detection method. This method can provide a possibility for the rapid detection of multiple heavy metal ions in actual water environments.

Experimental subshell vacancies in a multiply ionised Sn atom by heavy ion impact

The adoption of Heavy Ion PIXE for elemental quantification remains limited by the lack of fundamental atomic parameters needed for the calculation of X-ray production cross section data. Widely adapted theoretical models used for approximating ionisation cross sections, as well as other atomic physical parameters such as X-ray fluorescence yields, are calculated based on single-hole vacancy production post ion-atom impact. This renders the use of conventional ‘protonic’ models invalid for heavy ion-atom collisions. The degree to which Multiple Ionisation (MI) manifests in different heavy ion-atom collision symmetries significantly modifies atomic physical parameters. This is due to the significant number of introduced spectator vacancies in higher subshells, especially where near-symmetry is approached and MI is more pronounced. Knowledge of the mean number of vacancies in upper subshells is thus important for modifying atomic parameters that are needed for the translation of ionisation to X-ray production cross sections. In the present study, MI effects for Sn L-shell X-rays were studied using characteristic X-ray energy shifts measured using a standard PIXE spectrometer induced by Si, Cu and I projectile ions with incident energies up to 0.75 MeV/u. MI satellite distributions were studied using a Wavelength dispersive X-ray spectrometer (WDS) for high resolution PIXE, induced by C and Si projectile ions with incident ion energies up to 1.25 MeV/u. The mean number of subshell vacancies in the M- and N- shell for energy shifted Sn Lα X-ray lines were determined using both standard and high resolution PIXE spectrometers.

Cyano-determined mercury (II) ion selective fluorescence assay over polymeric carbon nitride

Selective response is the key index to evaluate the performance of polymeric carbon nitride (PCN)-based heavy metal ion fluorescence sensors. Herein, to explore the role of cyano groups on selectivity, four kinds of PCN, including PCN-Cl, PCN-Ac, PCN-B and PCN-K were prepared by the molten salt method of sodium chloride and sodium acetate, the reduction method of sodium borohydride and the etching method of potassium hydroxide, respectively. These PCNs exhibited different surface cyano characteristics, but all of them had significant blue emission under ultraviolet excitation. It is proved that the assistant of sodium chloride or potassium hydroxide is an effective method to prepare PCNs with abundant surface cyano group. A series of fluorescence quenching experiments of metal ions showed that the cyano-rich degree of PCN is closely related to its selective response to mercury (II) ions. PCN-Cl and PCN-K emerged good selective quenching of mercury (II) ions, which may be related to the soft acid-soft base strong interaction between mercury (II) ions and cyano groups. Both PCN-Cl and PCN-K fluorescent probes for mercury (II) ions had a linear range of 5 ∼ 50 μmol L−1, and PCN-Cl exhibited a lower detection limit of 0.38 μmol L−1. This work confirmed the selective fluorescence response of cyano-rich PCN to mercury (II) ions, proposed the mechanism of selective fluorescence quenching response of mercury (II) ions, and provided a new idea for the design of efficient and accurate PCN-based fluorescence probes.

Construction of Stable 2D Cationic Breathing Ni-MOF for Cr(VI) Trapping and Electrochemical Sensing.

Pollution of surface water by heavy metal hexavalent chromium ions poses a serious threat to human health; herein, a two-dimensional (2D) cationic breathing Ni-MOF with free nitrate ions between the layers was designed and synthesized according to the characteristics of hexavalent chromium ions, {[Ni(L)2](NO3)2·5H2O}n (L = 1,3,5-tris[4-(imidazol-1-yl)phenyl]benzene). The flexible layer spacing of the 2D breathing Ni-MOF allows the exchange of NO3- by CrO42- without destroying the original structure. Electrostatic and hydrogen bonding interactions between CrO42- and Ni-MOF facilitate its exchange with NO3-. Moreover, CrO42- exhibits a higher binding energy with Ni-MOF compared to NO3-, and the hydrophobic channels of Ni-MOF favor CrO42- trapping due to its lower hydration energy. Consequently, Ni-MOF demonstrates both effective sorption and electrochemical sensing of Cr(VI), achieving a sensitivity of 2.091 μA μM-1 and a detection limit of 0.07 μM.

Effect of carbon dot on preparation of dual-functional Janus particles via photo-initiated seed swelling polymerization

With the development of industry, the detection and removal of heavy metal ions from water has received much attention. Janus particles are distinguished from many other materials by their unique structure and functionalization. We proposed a simple photo-initiated seed swelling polymerization method for preparing carbon dot-coated dual-functional Janus particles (Janus@CD), using glycyl methacrylate (GMA) as monomer and ethylene dimethacrylate (EDMA) as crosslinker. In order to modulate the particle morphology during the phase separation process, carbon dot (CD) was added to the reaction system. The results demonstrated that the presence of CD had a significant effect on the shape of Janus particles. Furthermore, Janus@CD could be directly applied in the adsorption and detection for MnO4−. The limit of detection (LOD) was 6.39 nmol L−1, and the maximum adsorption capacity was 23.9 mg g−1, in line with the Langmuir adsorption model. The adsorption equilibrium reached within 30 min. The results demonstrated that dual-functional Janus@CD would present great potential in the detection and enrichment for metal ions.

Visible-light-prompted photoelectrochemical sensors fabricated using Er3NbO7/P@g-C3N4/SnS2 nanocomposite for detecting mercury ion in environmental water samples

Photoelectrochemical (PEC) detection technology is key for fighting pollution, leveraging the photoelectric conversion of the photoelectrode material. A specialized photoelectrode was developed to detect Hg2+ ions with exceptional sensitivity, utilizing an anodic PEC sensor composed of Er3NbO7/P@g-C3N4/SnS2 ternary nanocomposite. Rare earth metal niobates (RENs) were chosen due to their underexplored potential, whose performance was enhanced through bandgap engineering and surface modification, facilitated by P@g-C3N4 as an immobilization matrix and SnS2, belonging to the I-IV semiconductors category fostering hybrid heterojunction formation for boasting optical properties and suitable redox potentials. Introducing Hg2+ into the system, a specific amalgamation reaction occurs between reduced Hg and Sn. This reaction obstructs electron transfer to the FTO electrode surface, leading to the recombination of charges. The proposed PEC sensor exhibited remarkable analytical performance for Hg2+ detection, high sensitivity, a detection limit of 0.019 pM, excellent selectivity, and a detectable concentration range of 0.002–0.15 nM. Additionally, it demonstrated good recovery and low relative standard deviation when analyzing Hg2+ in water samples, highlighting the potential application of the heterostructure in detecting heavy metal ions via PEC technology.

Evidence for universal flow and characteristics of early time thermalization in a scalar field model for heavy ion collisions

Evidence for universal flow and characteristics of early time thermalization in a scalar field model for heavy ion collisions

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Measurements of higher-order cumulants of multiplicity and net-electric charge distributions in inelastic proton–proton interactions by NA61/SHINE

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Novel utilization exploration for the dephosphorization waste of Ca–modified biochar: enhanced removal of heavy metal ions from water

Phosphorus-modified biochar has been proven to enhance the precipitation and complexation of heavy metal ions from wastewater. However, the current modification methods require large amounts of exogenous P and have high energy consumption. Hence, this study proposes and analyzes a strategy integrating biochar production, phosphorus wastewater treatment, dephosphorization waste recovery, and heavy metal removal. “BC-Ca-P” was derived from Ca-modified biochar after phosphorus wastewater treatment. The adsorption of Pb(II) by BC-Ca-P followed the Langmuir isotherm and pseudo–second–order kinetic models. The maximum adsorption capability of 361.20 mg·g−1 at pH 5.0 for 2 h was markedly greater than that of external phosphorous-modified biochar. The adsorption mechanisms were dominated by chemical precipitation and complexation. Furthermore, density functional theory calculations indicated that oxygen-containing functional groups (P-O and C-O) contributed the most to the efficient adsorption of Pb(II) onto BC-Ca-P. To explore its practical feasibility, the adsorption performance of BC-Ca-P recovered from an actual environment was evaluated. The continuous-flow adsorption behavior was investigated and well-fitted utilizing the Thomas and Yoon–Nelson models. There was a negligible P leakage risk of BC-Ca-P during heavy metal treatment. This study describes a novel and sustainable method to utilize dephosphorization waste for heavy metal removal.Graphical

New proxies for second-order cumulants of conserved charges in heavy-ion collisions within the EPOS4 framework

New proxies for second-order cumulants of conserved charges in heavy-ion collisions within the EPOS4 framework

Optical and structural transformations in polyethylene terephthalate (PET) films subjected to Ag[formula omitted]-ion implantation and subsequent Au[formula omitted]-ion irradiation

We report on the dual effects of ion implantation and swift heavy ion on the optical and structural characteristics of polyethylene terephthalate (PET) films using UV–Vis spectrophotometry, FTIR and X-ray diffraction measurements. Samples were first implanted with 150 keV Ag+-ions at different fluences of 1 ×1016, 5 ×1016, and 1 ×1017 ions/cm2, and thereafter irradiated with 30 MeV Au7+-ions at different fluences, while analysing elemental depth profile in situ on the Time of Flight Heavy Ions Elastic Recoil Detection (ToF-Hi-ERDA) instrument. The elemental depth profile measurements showed considerable atomic depletion of hydrogen from 36% down to below 6% and oxygen from 18% to about 5%. The proportion of carbon increased from 45% to over 87%. The optical bandgap decreased with increasing ion implantation fluence and reduced even further on irradiation with 30 MeV 197Au7+-ions. The most notable outcome of the implantation was the onset of the precipitation of gold nanoparticles (Au-NPs) in the PET matrix, marked by Localised Surface Plasmon Resonance effects, coincided with a relatively significant drop in the bandgap energy. This latter effect could only be best explained as the result of these Au-NPs in the PET. This suggests that optical bandgap tuning in polymer films, usually achievable through high fluence implantation at low energy (i.e., keV), could also be realized through low fluence irradiation with MeV energy ions. It is surmised that, for the noble metals, NP-induced bandgap modification in PET precludes the need for high fluence to achieve the same. This has the obvious advantage of bandgap alterations at much lower structural damage to the target polymer. As reported by FTIR results, one can observe structural changes with the formation of new chemical bonds on thin films. X-ray diffraction results exhibited one prominent peak corresponding to the (100) plane, which varies in intensity with increased implantation fluence, suggesting a change in the crystallinity of the PET. The decrease in (100) peak or crystallinity was well connected with the presence and decrease of 847, 970, and 1471 cm−1 peaks, which were assigned to the ethylene glycol molecular groups.

Selective electrosorption of heavy metal ions from wastewater with S-doped hierarchical porous carbon derived from waste Camellia oleifera shell

Capacitive deionization (CDI) has garnered significant attention in desalination and the removal of heavy metal ions. The quest for cost-effective and high-performance electrode materials is crucial to advance CDI applications. Herein, we report a sulfur-doped hierarchical porous carbon (SPC) derived from waste camellia oleifera shells via a sustainable hydrothermal carbonization process followed by KOH/ammonium salt activation. The optimized SPC-0.2 exhibits exceptional characteristics, featuring a high specific surface area of 1875 m2 g−1 and substantial sulfur doping at 8.65 %, leading to enhanced specific capacitance (161.3 F g−1) in a 1 M NaCl solution. Under optimal operating conditions (1.2 V, 10 mL min−1, 500 mg L−1 NaCl), the SPC-0.2 electrode achieves a notable desalination capacity of 26.64 mg g−1. In particular, the electrode can selectively remove >99 % of Cr3+ and Cu2+ ions (each 10 mg L−1) in a 100 mg L−1 NaCl solution. This high selectivity is attributed to the formation of sulfides via low adsorption energies between the doped sulfur atoms and the targeted heavy metal ions. Furthermore, the SPC-0.2 electrode demonstrates robust reusability and high efficiency in the actual water body. Collectively, our findings underscore the significant potential of the synthesized SPC as an electrode material for CDI, particularly in the selective capacitive removal of heavy metal ions from wastewater. This work not only contributes to the circular economy by using waste biomass, but also offers a viable solution for environmental remediation.

Fluorescence Carbon Dots from Blood-Berries for Sensing Cr6+ Ions in Water and Application in White Light Emitting Diode.

Conventional techniques for identifying heavy metal ions in water are laborious and time-consuming. Therefore, it is necessary to create innovative sensing technologies that can detect with greater sensitivity and speed. Although there have been reports of optical-based assays utilising fluorescent nanomaterials, these assays usually rely on variations in signal strength. However, this approach has significant drawbacks when it comes to environmental monitoring. Fluorescence carbon dots (CDs) have been prepared by facile synthesis from Blood berries. A homemade heavy metal optical detector is constructed to accurately identify heavy metal ions, exclusively Cr6+ ions in a water medium. Their optical emission signature varies based on the specific chromium ions in solution, and the emission intensity also changes depending on its concentration. The quenching behaviour is attributed to the interaction between the metallic cations and the fluorescent surface states of the carbon dots. Another application is the encapsulation of CDs in PVDF polymer to form a flexible film and use it as a phosphor for LED conversion.

Efficient adsorptive separation of Cu(II) from Ph by ZIF-8 constructed with sodium alginate polymer backbone

With the rapid development of industrialization, the removal of heavy metal ions and small organic molecules from wastewater has triggered a hot debate. ZIF-8 was grown on a sodium alginate backbone using an in situ growth technique, the core-shell P-SMG@ZIF-8 was synthesized. It was also characterized by FTIR, XRD, SEM, UV–Vis and XPS, and the optimal conditions and mechanism of adsorption were explored. At pH 2.0, a contact time of 200 min, and 298 K, removal of Cu(II) and Ph up to 80.2 %, 65.6 % by P-SMG@ZIF-8, adsorption behavior consistent with Langmuir model for pseudo-secondary rates, the saturated adsorption of Cu(II) and Ph could reach up to 83.5812 mg/g and 78.1779 mg/g, respectively. And the adsorbed P-SMG@ZIF-8 is easy to separate and reusable, which is a cost-effective and efficient natural product-based adsorption material.