High-performance Insulation Research Articles

Climate Change and Building Renovation: The Impact of Historical, Current, and Future Climatic Files on a School in Central Italy

Climate change significantly affects the operating environment of buildings. These changes impact both energy efficiency and occupants’ comfort and remain crucial even in building restoration, where design decisions typically rely on historical data, yet performance depends on anticipated future scenarios. The present work evaluates the impact of different climate datasets on dynamic energy simulations for an educational building in Central Italy, focusing on estimating heating demands across historical, current, and future climatic scenarios. The assessment considers both the building’s current state and potential energy-efficient retrofits. Initially, various meteorological datasets, including measured and model-generated data, are selected to predict key weather parameters. The analysis reveals the potential and limitations of regional climate models (RCMs) in estimating these variables, with the MM5 dataset emerging as the most reliable. Subsequently, the energy performance of the reference building and its vulnerability to climate change are assessed. Our results show significant differences in energy demand based on construction periods, with the oldest section consuming 29% to 54% more energy monthly than the newer sections. Moreover, using non-representative climatic files can lead to prediction errors of up to 199%. Finally, the building’s energy behaviour is analysed under future climate conditions by generating typical meteorological years (TMYs) for 2030, 2050, and 2070. This analysis evaluates the energy requirements for both existing and retrofitted building configurations. The findings confirm that retrofit interventions with high-performance insulation and upgraded windows significantly enhance the building’s energy efficiency and resilience to future climate conditions, leading to annual energy savings of 50% to 57%.

Seismic behavior and failure analysis of prefabricated foamed concrete composite walls for passive houses

In view of the lack of research on the failure mode and seismic behavior of high-performance insulation walls utilizing lightweight concrete as the structural material, this study presents experimental findings from a seismic behavior investigation of prefabricate foamed concrete composite walls (PFCCWs) for passive house in China. The PFCCWs incorporate low thermal conductivity and high-strength foamed concrete, polyurethane, decorative magnesium straw slabs to provide excellent thermal and mechanical properties for prefabricated passive houses in hot summer and cold winter area. The seismic behavior of PFCCWs under different influence factors were elaborated using quasi-static test data and observation of external damage. The lightweight and porous nature of foamed concrete leads to significant crack formation during failure. The findings suggest that the skin effect of magnesium straw slabs and polyurethane impedes crack development and improve the load-bearing capacity with ductility enhancement. Additionally, reducing the aspect ratio and substituting post-cast column concrete with common concrete are effective to improve the seismic behavior. The window opening changes the worst damage area of the wall and notably weakens the seismic behavior. The enhanced integrity of cast-in-place wall leads to the difference in the failure mechanism and increases in load-bearing and deformation capacities. Meanwhile, design suggestions for the foamed concrete insulation walls are also proposed by comparing the failure mode and hysteretic response of various wall types.

Effect of alumina or zirconia particles on the performance of lead-free BCZT piezoceramics

The barium titanate derivative Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) offers high dielectric and piezoelectric performance but has poor mechanical properties. Ceramic composite materials combining BCZT with tougher Al2O3 or ZrO2 could be the solution to the inherent brittleness of electroceramics. This work focuses on BCZT with 1–5 vol.% addition of reinforcing phase dispersed in the microstructure. While hardness was improved in all composites, especially in ZrO2-reinforced BCZT, toughness was positively affected only by Al2O3. The chemical reactivity of BCZT during sintering resulted in the formation of new barium aluminate phases at the grain boundaries and possibly also within the grains, which affected the electrical properties of the composites. The addition of zirconia resulted in the formation of BaZrO3 or Ba(Zr,Ti)O3, which is a natural part of the BCZT solid solution and shifts the phase composition towards relaxor behaviour. ZrO2-reinforced composites exhibited higher permittivity but lower ferroelectric properties, accompanied by a substantial Curie temperature decrease.

A fabrication of universal multifunctional coating with excellent adhesion on the surface of solid rocket motor insulation materials through a surface activation strategy based on multiple interaction forces

In this work, a novel universal multifunctional coating for insulation materials was prepared by using polyethyleneimine as the coating substrate, low-temperature molten glass powders and MXene as additives. Meanwhile, the universal coating was tightly adhered to the surface of the insulation materials through a surface activation strategy based on the synergistic effects of hydrogen bonding, electrostatic adsorption, and chemical bonding. The shear strength data showed that the adhesion between the universal coating and the three types of insulation material were higher than that of most commercial adhesives. In the case of EPDM, for example, the adhesion of the coating is 4.17 (epoxy glue), 1.04 (chemlok) and 1.67 (Neoprene) times that of commercial adhesives, respectively. In addition, the universal coating showed good heat resistance and thermal insulation, and formed a complete and dense char on the surface after exposure to flame. The maximum mass loss temperatures of the three coated insulation materials were 2.8, 6.5, and 9.3°C higher than the original samples, respectively. Thermal insulation tests showed that the coated insulation materials reduced the average top surface temperature by 29.68%, 40.84% and 29.06%, respectively, compared to the original samples. The results of anti-migration tests showed that the prepared universal coatings displayed generally superior anti-migration properties to the insulation materials, with equilibrium migration concentrations reduced by up to more than 80% compared to the original samples, which is better than the previous products of the same type. In addition, the application potential of the advanced multifunctional insulation materials obtained from the preparation was evaluated, resulting in an increase of more than 35% in peel strength and more than 20% in shear strength for all insulation materials with propellants. This work provides a simple and environmentally friendly generalized strategy to develop high performance insulation materials for aerospace fields.

Introducing Y2O3 passivation layer for utilizing TiSiN electrode on ZrO2-based metal-insulator-metal capacitor applications

This study investigates the degradation and improvement of the dielectric properties of ZrO2-based metal-insulator-metal (MIM) capacitors using TiSiN electrodes. As dynamic random-access memory (DRAM) design rules scale down, the mechanical properties of TiSiN electrodes provide advantages over conventional TiN, but also introduce challenges due to Si diffusion into ZrO2 films, forming low-dielectric constant (k) Zr-silicate and defect-related dielectric degradation. We evaluate the dielectric properties of ZrO2 films on TiSiN electrodes and identify significant reductions in the dielectric constant and an increase in DC and AC non-linearity due to Zr-silicate formation. To mitigate these problems, a Y2O3 passivation layer is introduced between the TiSiN electrode and ZrO2 dielectric film. Physical and chemical analyses, including X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), confirm that Y2O3 passivation effectively suppresses Si diffusion, preventing formation of Zr silicate, and preserving the high-k tetragonal phase of ZrO2. Electrical measurements show that the Y2O3 layer significantly improves the dielectric constant and reduces non-linearity effects. Notably, even at a reduced ZrO2 thickness of 4 nm, a relatively high k value is maintained with Y2O3 passivation. This study concludes that the Y2O3 passivation layer is indispensable for maintaining high dielectric performance in ZrO2-based MIM capacitors with TiSiN electrodes, ensuring stability and efficiency in advanced DRAM applications.

Revelation of the high surface insulation performance of the electron-delocalized group through molecule self-assembly on alumina insulator

Surface modification of vacuum insulators is a promising way to improve their surface insulation performance but commonly used surface modification technologies in surface insulation area such as fluorination and plasmas treatment are unable to control the surface chemical components at the molecular level, which makes it hard to explore molecular groups with high surface insulation performance. In this paper, molecule self-assembly is introduced to control the surface molecular structure precisely and vacuum surface insulation performance of a special molecular structure electron-delocalized group is studied. Hexagonal phenyl group containing delocalized electrons and cyclohexyl group with the same hexagonal molecular structure but without delocalized electrons are grafted onto the surface of alumina insulators through molecule self-assembly. Secondary electron emission yield test shows that phenyl group endows alumina insulators lower SEY than cyclohexyl group. Correspondingly, phenyl group grafted alumina insulators show higher surface insulation performance than cyclohexyl group. The results indicate that group containing delocalized electrons can endow insulators higher surface insulation characteristics.

Double envelope vacuum insulation panel to contribute to the long-term thermal insulation performance

Vacuum insulation panels (VIPs) have a potential to be used for retrofitting thermal insulation to existing buildings from the viewpoint of low thermal conductivity, small thickness, and light weight. However, in order to realize vacuum insulation panels applicable to building thermal insulation, it is necessary to overcome the challenge of maintaining the low pressure at which high thermal insulation performance can be achieved for several decades. The authors propose double envelope VIPs to maintain this long-term high thermal insulation performance. The double envelope VIP is fabricated by creating a single envelope VIP, wrapping the VIP with core materials, and then inserting it into the envelope for vacuum sealing. By applying the double envelope VIPs, the pressure difference and the permeation of gas in the inner VIP can be drastically reduced, resulting in a longer VIP lifetime. In this paper, the gas permeabilities of the gas barrier envelopes are experimentally estimated. Then, the pressure ageing in the double envelope VIP is calculated. The inner pressure of double envelope VIP after 50 years is 5.4 Pa for the envelope of aluminium composite film, indicating that low pressure can be maintained long-term. Next, the authors carry out accelerated test, in which the double envelope VIPs are placed in a chamber at 80oC and removed every two weeks to measure the effective thermal conductivity. Even after 141 weeks, one sample with a getter agent on the inside and a desiccant agent on the outside indicates only 10.5 % decrease in the thermal resistance. From this result, the long-term high thermal insulation performance can be obtained by fabricating double envelope VIPs.

Stretching Aligned Hydrogen Bonding Network to Evoke Mechanically Robust and High-Energy-Density P(VDF-HFP) Dielectric Film Capacitors.

Polymer-based dielectric film capacitors are essential energy storage components in electronic and power systems due to their ultrahigh power density and ultra-fast charge storage/release capability. Nonetheless, their relatively low energy density does not fully meet the requirements of power electronics and pulsed power systems. Herein, a scalable composite dielectric film based on a ferroelectric polymer with edge hydroxylated boron nitride nanosheets (BNNS-OH) is fabricated via the construction of a hydrogen bonding network and stretching orientation strategy. The presence of hydroxyl groups on boron nitride aids in forming a robust hydrogen bonding network within the ferroelectric polymer, leading to a significant increase in Young's modulus and superior dielectric performance. Furthermore, the stretching process aligns the BNNS-OH and the hydrogen bonding network along the drawing direction via covalent and hydrogen bonding interaction, resulting in a remarkable tensile strength (109MPa), breakdown strength (688 MVm-1), and energy density (28.2 Jcm-3), outperformingmostrepresentative polymer-based dielectric films. In combining the advantages of a simple preparation process, extraordinary energy storage performance, and low-cost raw materials, this strategy is viable for large-scale production of polymer-based dielectric films with high mechanical and dielectric performance and opens a new path for the development of next-generation energy storage applications.

The thermal conductivity of graphite composite insulation boards: A theoretical and experimental study

Graphite composite insulation boards (GCIB) have emerged as a promising solution in the construction industry, offering a combination of fire resistance, high temperature stability, and excellent insulation properties. As their usage continues to increase, it is crucial to develop and validate a more accurate theoretical model for the effective design and optimization of building insulation systems. Traditional models including series and parallel models are employed for estimating the thermal conductivity of GCIB but revealed higher relative errors and lower theoretical calculation accuracy. Therefore, the primary objective is to design and validate a more efficient theoretical model for thermal conductivity prediction in GCIB. This paper investigates the thermal conductivity of GCIB under varying composition ratios by designing a novel Parallel-Series Parallel (PSP) approach. The PSP model is designed based on a single basic cell where the graphite polystyrene particles are employed as the matrix material while cement, vitrified microspheres, and silica fume are used as inclusion materials. Then, the thermal conductivity unit is divided into three parallel heat conduction subunits where the matrix materials and inclusion materials in the three subunits are integrated in a series-parallel manner to provide a more realistic representation of the heat transfer mechanisms within the composite. For a comprehensive assessment, the study encompasses theoretical analysis, empirical assessment, and finite element (FE) simulations to illustrate its thermal properties. The predicted thermal conductivity reveals perfect consensus in comparison with the FE and experimental test outcomes by achieving lower relative errors of 2.7 %∼3.8 % and 1.9 %∼ 3.0 % respectively. The model validated through numerical simulations and sample experiments illustrates a significant improvement in accuracy of about 76.4 %∼94.3 % when compared to traditional series and parallel methods. Prominently, the findings indicate that the thermal conductivity of GCIBs declines considerably as the volumetric ratio of graphite polystyrene particles (Ф1/Ф3) increases and stabilizes when the proportion reaches 10, emphasizing the importance of optimizing material composition to enhance the thermal performance of GCIB. Overall, the validated PSP model by accurately determining the thermal conductivity of GCIB serves as a reliable tool for designing and optimizing high-performance insulation materials, contributing to energy efficiency and sustainability in building and construction industries.

All-natural, thermally conductive, flame-retardant electrical insulating lignocellulose-mica composite film fabricated via in-situ mineralization

Miniaturized, integrated, and functional electronic devices generate a large amount of heat accumulation during operation, which significantly affects the reliability, durability, and safety of electronic devices. In severe cases, it may even lead to fires. Therefore, the development of insulation composite materials with thermal conductivity and flame-retardant properties is particularly important. In this study, we propose an in-situ mineralization strategy to prepare insulation composite materials with thermal conductivity and flame-retardant properties. By dissolving and preparing a gel film, Al3+ and Zn2+ retained inside the lignocellulose are in situ mineralized to form Al(OH)3 and ZnO, and introducing inorganic blocks with high insulation performance (industrial waste mica tailings and synthetic mica). The prepared film has excellent tensile strength (117.4 MPa), low dielectric loss, high dielectric strength (83.8 kV mm−1), high insulation resistance, four times higher thermal conductivity than the unmineralized film, and excellent flame-retardant properties. Meanwhile, the environmental impact of the composite film is much lower than that of petrochemical-based plastic films and can easily degrade under natural conditions within 32 days. It is a composite material that meets the standards of the new electrical insulation field, and the in-situ mineralization strategy can also provide ideas for the preparation of high-performance lignocellulose-based materials.

Towards wafer-scale growth of two-dimensional cerium dioxide single crystal with high dielectric performance

Towards wafer-scale growth of two-dimensional cerium dioxide single crystal with high dielectric performance

Ionic Surfactant-Assisted PVDF Nanofabrics with High Dielectric and Excellent Piezoelectric Performance

Ionic Surfactant-Assisted PVDF Nanofabrics with High Dielectric and Excellent Piezoelectric Performance

Thermodynamic modelling of low fill levels in cryogenic storage tanks for application to liquid hydrogen maritime transport

One of the key challenges in transporting liquid hydrogen (LH2) in bulk onboard carriers is the requirement for high performance insulation to reduce the heat transfer and cargo boil-off losses. After unloading their cargo, carriers on the return voyage may retain a small amount of liquid (heel) to keep tanks relatively cold, as well as to chill down to the tanks prior to cargo loading. Therefore, there is an aim to reduce net heat transfer into the tank while minimising the required volume of heel. While practices are relatively mature in the liquefied natural gas (LNG) industry, it is not clear how this may differ for future LH2 carriage. In this study, a new analytical, lumped-mass model was proposed to predict vapour stratification and tank warm-up. A 40,000 m3 double-walled LH2 spherical tank was considered with vacuum perlite and polyurethane foam (PUF) insulation, and the effects of tank pressurisation and fill level on cumulative heat gain were investigated. The model pointed to key differences between the two insulation types. Heat gain in the vacuum perlite tank was not predicted to be sensitive to changes in fill level, while heat gain in PUF tank was predicted to be less sensitive to pressurisation. In each case, pressurisation was predicted to enable reductions in heel boil-off which offset any associated increase in cumulative heat gain. In comparing LNG and LH2, the model pointed to a slower thermal response of the LH2 tanks. Consequently, the increase in inner shell temperature was not expected to lead to significant reductions in environmental heat transfer into the tank. The findings of this study point to potential operational differences in the management of LNG and LH2 heel during the ballast voyage as well as considerations for vacuum insulated tanks.

Flexible and Thermally Insulating Porous Materials Utilizing Hollow Double-Shell Polymer Fibers.

The global climate change is mainly caused by carbon dioxide (CO2) emissions. To help reduce CO2 emissions and conserve thermal energy, sustainable materials based on flexible thermal insulation are developed to minimize heat flux, drawing inspiration from natural systems such as polar bear hairs. The unique structure of hollow double-shell fibers makes it possible to achieve low thermal conductivity in the material while retaining exceptional elasticity, allowing it to adapt to insulation systems of any shape. The layered system of porous mats reaches a thermal conductivity coefficient of 0.031 W∙m⁻¹∙K⁻¹ and enables to reduce the heat transfer. The results achieved using scanning thermal microscopy (SThM) correlate with the simulated heat flow in the case of individual fibers. This research study brings new insights into the energy efficiency of domestic environments, thereby addressing the growing demand for sustainable and high-performance insulation materials for saving energy loss and reducing pollution footprint.

Super-flexible and low-shrinkage polyimide aerogel composites with excellent thermal insulation: Boosted by SiO2 micron aerogel powder

Polyimide (PI) aerogel composites were synthesized using 4,4′-diaminodiphenyl ether (ODA) and 1,3-bis(4-aminophenoxy)neopentane (BAPN) as diamine monomers, and biphenyl-3,3′,4,4′-tetracarboxylic dianhydride (BPDA) as dianhydride monomers. This study examined the impact of varying proportions of SiO2 micron aerogel powder and the addition of BTC on the properties of the composites. The prepared composites showed ultra-high flexibility (180° folded) with the thickness of 3–4 mm, high thermal stability (95 % weight retention at 501 °C) and thermal insulation performance with ultralow thermal conductivity of 0.033 W/(K·m).

Multiple Phase Structures and Enhanced Dielectric Properties of Side-Chain Liquid Crystalline Polymer Containing Unique Biaxial Mesogen with Large Dipole Moment

To achieve all-organic polymer with high dielectric performances, we have designed a novel side-chain liquid crystalline polymer (P7) with strong polar mesogen of (Z)-4-(2-cyano-2-phenylvinyl)benzonitrile (CSCN) attached to polycyclooctene backbone. The bis-cyano-substituted CSCN is board-shaped and exhibits a large dipole moment (8.54 D) which tilts ∼34.2° away from its molecular long axis. Consequently, CSCN shows unique dual molecular anisotropy: one from biaxial shape anisotropy and the other from polarization anisotropy. The complex phase behaviors of P7 were investigated employing mainly the techniques of differential scanning calorimetry and X-ray diffraction. Four liquid crystal (LC) phases are identified as K0, K1, K2 and K3, which are SmA, highly-ordered biaxial SmA, B5-like and B7-like, respectively, with the thermal stability increased in sequence. The experimental results indicate that the different LC phases are arisen from the competition and balance between π-π stacking and dipole-dipole interaction. While the face-to-face π-π stacking is dominant in K0 and K1, optimizing the dipole-dipole interaction causes the CSCN mesogens within the smectic layer to tilt and rotate, resulting in K2 and K3. We further investigated the dielectric properties of P7 films using polarization-electric field loops test. The dielectric constant (εr) of P7 is found to be LC structure dependent, which is increased when the LC phase is varied from K0 to K3. With an average εr of 9.7 achieved in K3 and the low dielectric loss (tan δ = 0.001), P7 film offers a promising material in advanced applications like energy storage and electronic devices.

Plate-type metastructure with low-frequency sound insulation and high stiffness properties

According to the mass law, it is impossible to increase sound transmission loss (STL) of conventional structures at low frequencies without increasing their weight. Metastructures are capable to break the limits of the mass law at low frequencies. However, many existing sound insulation metastructures need to be constructed using a host structure with low-stiffness properties, such as a thin plate and a thin membrane. As a result, the metastructures normally have large exposed areas with low-stiffness characteristics and are unable to bear heavy loads, which limits their practical applications. In this work, we propose a high-stiffness plate-type metastructure (HSPM) with both low-frequency sound insulation performance and high stiffness properties. The STL performance of the HSPM is demonstrated analytically, numerically and experimentally, indicating that the HSPM can deeply break the mass law at low frequencies. Owing to the simple construction, high stiffness properties, and high sound insulation performance at low frequencies, the proposed HSPM has promising applications in practical noise control engineering.

Analysis and Discussion on High Insulation Performance of 20 kV Generator Motor Stator in the Large Pumped Storage Unit

Abstract The terminal voltage of 400 MW 500 r/min generator motor in a large pumped storage power station is 20 kV, in which the height of stator core is 3400 mm and the stator bar adopts less glue VPI (Vacuum Pressure Impregnating) process. The characteristic of this generator motor is high voltage level, large external size and high technical requirements. As the pumped storage unit with the highest voltage level that has been put into operation in China, its stator system of 20 kV generator motor shows excellent insulation performance during the test process. This paper analyzes and discusses from two perspectives of development and installation, and summarizes the key technologies in the process, which can be used for further reference in similar projects.

Natural fiber-based multifunctional aerogel with advanced oil absorption property and high thermal insulation performance

Designing an ultra-light and controllable structure for multifunctionality of low-cost aerogels is of great significance but remains a huge challenge because of the limitations of structural processability and mechanical vulnerability. Herein, we demonstrated a facile approach to synthesize a low-cost, ultralight, elastic, and highly recyclable superabsorbent from renewable fibers via environmentally friendly physical bonding and freeze-drying. Our approach introduces skin-core structure polyester (SPFs) into natural agriculture plant kapok, through which fibers entanglement and bonding to construct aerogel with adjustable hierarchical structure and desirable shapes. The resultant composite aerogel can be easily modified by organosilane, demonstrating durable superhydrophobicity (158.5°), advanced absorption capacity (128.4 g/g), good mechanical performance, self-cleaning, and thermal insulating (0.020 W/(m·K)). Therefore, the sustainable and multifunctional composite fibrous porous aerogels are potential materials for oil absorption applications and thermal management.

Advancing building fire safety through heat resistant and flame retardant hybrid silicone sealant

Rapid urbanization and population growth have led to a significant transformation in the urban landscape, characterized by the proliferation of high-rise buildings. However, this urban development has brought about new challenges, particularly in terms of fire safety. The escalating risk of disasters, especially fires, underscores the critical importance of implementing effective fire safety measures across all building types, necessitating legislative reforms. Despite their crucial role in ensuring structural integrity, sealants have often been overlooked in building safety standards, resulting in a lack of comprehensive regulations. The research addresses these challenges by focusing on the development of fire-resistant silicone sealants designed to enhance the fire resistance of building materials. These sealants were formulated independently, incorporating three fire retardants and four heat-resistant agents. While metal oxide flame retardants generally exhibited excellent performance, excessive mixing led to surface deformation and reduced workability. Optimal combinations of flame retardants and heat-resistant agents were identified, with the FR2 specimen demonstrating promising fire resistance performance. Full-scale fire performance tests conducted on FR2 revealed a maximum temperature difference of 40.6 °C between heated and unheated surfaces over a 2-h period, indicating high thermal insulation performance. These findings validate the efficacy of the proposed method and offer significant enhancements to building safety, thereby mitigating fire damage in urban environments.