Waste High-density Polyethylene Research Articles

Experimental Investigation on the Properties of Concrete Containing Waste HDPE Plastic and Copper Slag as Coarse and Fine Aggregates Replacement

Resource concerns have become apparent globally, particularly in the construction sector due to the exploitation of resources for developing globalized infrastructures. This has led to challenges, especially in sourcing construction materials. Consequently, numerous studies have focused on waste management strategies with eco-efficient parameters, particularly in the realm of construction aggregates. While previous research has explored alternatives for these aggregates, there remains ample opportunity for further investigation on the effectiveness and potential of alternative materials in construction projects to promote sustainable resource management. The research aims to fill this gap by examining the impact of using alternatives for both fine and coarse aggregates, specifically copper slag and waste HDPE. This study investigates the effects of partially incorporating waste HDPE plastic and Copper slag on the strength and sustainability of concrete, with the goal of evaluating their viability as sustainable alternatives in construction materials in the construction sector. Three percentages of High-Density Polyethylene (HDPE) Plastic (10%, 20%, and 30%) and Two Percentages (30% and 40 %) of copper slag were incorporated with the weight of Coarse aggregate and Fine aggregate respectively. Comparisons of conventional concrete with concrete incorporating HDPE waste & copper slag as coarse aggregate and fine aggregates were conducted. From investigation it was found that concrete incorporating 10% of HDPE and 40% of copper slag cured for 7 and 28 days had 10% increase in compressive strength compared to the nominal mix and flexural strength 25% and 40% more than nominal mix. The concrete incorporating 10% of HDPE and 30% of copper slag had 18% reduction in split tensile strength for cylinders cured for 7 days and 55% increase in split tensile strength for cylinders cured for 28 days.

Effect of Graphite Nanoadditives on the Behavior of a Diesel Engine Fueled with Pyrolysis Fuel Recovered from Used Plastics.

Plastic waste accumulation is a significant threat to the environment and humans. Pyrolysis is a promising method for recycling plastic waste since all of the yields are useful, reducing the associated environmental risks of plastic waste. Energy recovery from used plastic waste can help restore ecosystems by utilizing waste as fuel while addressing the environmental problem of plastic disposal. This study experimentally investigates the application of oil obtained by the pyrolysis of waste high-density polyethylene (HDPE) as a viable energy source for diesel engines, offering a unique solution to the issues of plastic waste and energy sustainability. The catalytic pyrolysis method was employed to convert used HDPE plastics into a fuel called used polymer pyrolysis oil (UPO). The UPO was blended at 20% and 40% on a volume basis with mineral diesel. The graphite nanoadditives of 50 and 100 ppm were doped to enhance the properties of the UPO20 blend. The results showed that UPO20n100 blends exhibited a 2.79% increase in brake thermal efficiency and an 11.6% reduction in specific fuel consumption compared to diesel. Utilizing the UPO20n100 blend as a diesel engine fuel resulted in reductions of hydrocarbon, carbon monoxide, and smoke emissions by 8.9%, 9.9%, and 8.9%, respectively, compared with diesel operation. These findings provide a pathway for reducing plastic pollution and reliance on fossil fuels, with significant implications for the development of sustainable energy solutions. Additionally, this study presents a novel application of graphite nanoadditives in fuel blends prepared from used plastics, highlighting their significant impact on enhancing engine efficiency and reducing emissions.

Effect of high-density-polyethylene (HDPE) and waste tire rubber (WTR) on laboratory performance of styrene butadiene styrene (SBS) modified asphalt

To reduce the cost of SBS modified asphalt, we incorporated waste high-density polyethylene (HDPE) and waste tire rubber (WTR) as partial substitutes for SBS modifier. The performance parameters for HDPE, WTR, and SBS synergistic modified asphalt were designed using the response surface method. Specifically, modified asphalt groups with excellent conventional properties were identified through penetration, softening point, and ductility tests. The high/low-temperature rheological properties and anti-aging properties of the selected modified asphalt were investigated. The modification mechanism of the composite modified asphalt was studied using fluorescence microscopy (FM). Subsequently, a cost analysis of the modified asphalt was conducted. Based on the aforementioned studies, we recommend a composition of 1.5% SBS, 3% HDPE, and 10% WTR, which demonstrated superior performance compared to 4% SBS modified asphalt. Furthermore, the cost of the modified asphalt was found to be 13.3% lower than that of SBS modified asphalt.

Fractional distillation of waste plastic pyrolysis oil for isolating narrow hydrocarbons cuts

Pyrolysis of polyolefins generates a large amount of olefins, which can serve as a valuable feedstock for the synthesis of chemicals. Nevertheless, their effective utilization requires refining owing to their diverse carbon distribution. This study performed a comprehensive GC×GC analysis of pyrolysis oils derived from waste polypropylene (PP) and waste high-density polyethylene (HDPE). The chemical composition of PP pyrolysis oil exhibited a high content of iso-olefins, whereas HDPE pyrolysis oil contained mainly alpha-olefins. Experimental batch distillation of PP pyrolysis oil yielded narrow hydrocarbon cuts with iso-olefins content exceeding 70 wt%. In contrast, distillation of HDPE resulted in cuts with more than 25 wt% alpha-olefins content. To perform ASPEN simulations, the physical properties (density, viscosity) of the oil were determined, two ways for obtaining boiling curves (ASTM D2887 and ASTM D86) were compared and two property methods (Peng-Robinson and Soave-Redlich-Kwong) were compared. It was concluded that the ASTM D2887 boiling curve and the Peng-Robinson property method present better experimental agreement for pyrolysis oils using the Theil’s Inequality Coefficients test. Based on the validated batch simulation, continuous distillation process schemes for isolating narrow carbon cuts in the refinery atmospheric tower indicate that a side draw configuration provides a better yield of (19.1 wt%) compared to a dedicated separate distillation column of (11.9 wt%) for the same number of trays, while the dedicated column allows the possibility to achieve higher purity.

Combined effect of silica fume and various fibers on fresh and hardened properties of concrete incorporating HDPE aggregates

Recycling of waste plastics has become essential to mitigate their detrimental impact on the environment. However, it can be used in the construction sector to fulfill construction needs and conserve natural resources. Previous research has demonstrated that incorporating plastic aggregate reduces the strength properties of concrete; hence, there is a need to improve its strength properties. In this study, high-density polyethylene (HDPE) plastic is incorporated in aggregate form, as a partial substitute for natural coarse aggregates (NCA) at volumetric ratios of 10 %, 30 %, and 50 %. Various strength enhancement techniques, including the addition of macro synthetic fibers (MSF), steel fibers (SF), and substituting 20 % of cement with silica fume, were employed. The results indicated that workability of concrete is improved with an increase in the content of HDPE coarse aggregates (HCA). Furthermore, concrete containing 30 % HCA performed better in terms of strength compared to concrete with 10 % and 50 % HCA. The findings demonstrate that concrete containing fibers performs better than concrete without fibers. The utilization of 0.75 % MSF and 1 % SF dosage leads to a 93 % improvement in splitting tensile strength, a 72 % improvement in flexural strength, and a 48 % improvement in compressive strength for concrete containing 30 % HCA. Using scanning electron microscopy, it was found that incorporating HCA weakens the internal matrix. However, the addition of a precise amount of fibers and pozzolanic materials resulted in improvements in microstructure. The significance of this research lies in the utilization of HDPE waste materials in concrete by simultaneous usage of different fibers.

A comprehensive approach to physical recycling of hazardous waste HDPE industrial drums: Overcoming challenges in safety and foam interference

The regeneration of hazardous waste plastics are prerequisites for the sustainable development, and treatment of waste high density polyethylene (HDPE) industrial drums poses a significant challenge in the field of waste plastic recycling. In this study, a multi-step collaborative system was established for the decontamination and classification process of hazardous waste industrial drums. The yield of recycled HDPE particles exceeds 80 wt%. Through multiple experimental verifications, the optimal addition amount of antifoaming agent is 0.6 wt%, achieving the best balance between antifoaming effect and consumption. The motion process of antifoaming agent microdroplets in a static mixer was simulated. And also, through large-scale statistical analysis, the stability and reliability of physical properties and environmental safety of recycled HDPE particles were verified, supporting their reuse in various fields. In sum, this study proposes a feasible physical recycling strategy for hazardous waste HDPE industrial drums, and provides basic data from industrial practice and technical insights.

Prolonged Lifespan of Superhydrophobic Thin Films and Coatings Using Recycled Polyethylene.

High-density polyethylene (HDPE) waste poses a significant environmental challenge due to its non-biodegradable nature and the vast quantities generated annually. However, conventional recycling methods are energy-intensive and often yield low-quality products. Herein, HDPE waste is upcycled into anti-aging, superhydrophobic thin films suitable for outdoor applications. A two-layer spin-casting method combined with heating-induced crosslinking is utilized to produce an exceptionally rough superhydrophobic surface, featuring a root mean square (RMS) roughness of 50 nm, an average crest height of 222 nm, an average trough depth of -264 nm, and a contact angle (CA) of 148°. To assess durability, weathering tests were conducted, revealing the films' susceptibility to degradation under harsh conditions. The films' resistance to environmental factors is improved by incorporating a UV absorber, maintaining their hydrophobic properties and mechanical strength. Our research demonstrates a sustainable method for upcycling waste into high-performance, weather-resistant, superhydrophobic films.

Revitalizing high-density polyethylene (HDPE) waste: from environmental collection to high-strength hybrid yarns

Plastic products are used in large quantities. However, the fact that plastics do not degrade in nature for many years causes environmental pollution. Addressing this issue, the study focuses on recycling the widespread high-density polyethylene (HDPE) plastic waste. In this study, HDPE waste was collected randomly from the environment, mirroring real-world scenarios. Then, the waste was transformed into granules. Afterward, washing and drying processes were carried out. HDPE filaments of different linear densities were successfully produced from the waste plastic granules. Tensile tests revealed that the breaking strength of the filaments from waste plastic was lower than that of virgin HDPE filaments, highlighting the challenges of recycling. Hybrid yarns were formed by twisting the filaments with cotton yarn to improve the mechanical properties of the filaments from waste plastic. Remarkably, statistical analysis demonstrated that the breaking load values of the hybrid yarns from waste plastic were statistically equivalent to those made from virgin polymer. This outcome indicated that the hybrid yarns made from waste HDPE plastic were as strong as those made from virgin HDPE polymer. In addition, both hybrid yarns exhibited a breaking load 36% higher than the reference extra-twisted cotton yarn. The hybrid yarn formation made filaments produced from waste plastic a valuable component of the high-strength hybrid yarn. Overall, this study shows that recycling HDPE plastics can lead to the production of high-strength hybrid yarns, which can contribute to reducing plastic waste pollution.

Effect of the incorporation of plastic waste on the mechanical properties of composite materials

Through this scientific research, we have tried to study the effect of the incorporation of plastic waste on the mechanical properties of concrete, in order to obtain good concrete with high resistance at a lower cost. To carry out this work, we adopted the following steps: Knowledge of the properties of concrete, which contains plastic waste of High Density Polyethylene (HDPE). Thus, the natural aggregate was replaced by concrete formulated with plastic waste in partial substitution varying between 0%, 10% and 20%. In all the concrete mixtures, the components, water, cement, gravel 3/8 and 8/15 and sand 0/3, remained constant while the HDPE waste varied according to the substitution rate. Through this process, the mechanical properties of concrete in fresh and hardened states were determined. The analysis of the results of the study allowed us to know the incorporation of plastic waste and its effect on the behaviour of the manufactured concrete. The results showed that the density of concrete made from plastic waste is lighter than the reference concrete without waste (C0), which contains only natural aggregates, in a fresh state. In the case of hardening, the results showed a decrease in the compressive strength of composite concrete produced from plastic waste compared to (C0) the reference concrete. In the study's second part, a numerical model for precision and effectiveness is constructed using the finite element (FE) method. Furthermore, manufacturing experiments are scheduled to use computer simulations that account for labour, materials, tests, and time. The nonlinear stress-strain relationship for time-dependent concrete deformations and tension cracks presents a challenge for concrete modelling. ANSYS software is used to use three-dimensional nonlinear finite elements in order to determine this kind of complex mechanical behavior.

Performance evaluation of SBS-modified asphalt mixtures incorporating waste tire rubber and HDPE

Based on the functional complementarity of waste tire rubber (WTR) and waste high-density polyethylene (HDPE) in asphalt, this study presents a novel approach that simultaneously utilizes WTR and HDPE for modification and substitution of styrene-butadiene-styrene (SBS) modified asphalt. Through experiments on three major indicators, the dosage ratios of the three polymers are scientifically designed using the response surface methodology, and four different ratios of SBS-HDPE-WTR are selected to prepare modified asphalt mixtures. Performance evaluations are conducted on various pavement properties, including high-temperature stability, low-temperature crack resistance, water stability, fatigue resistance, and aging resistance, by comparing them to the reference 4% SBS-modified asphalt mixture. The results demonstrate that the addition of WTR significantly improves the elastic properties and fatigue resistance of the mixture, while the addition of HDPE enhances its high-temperature stability and aging resistance. The SBS-HDPE-WTR asphalt mixtures, designed with appropriate ratios, exhibit superior high-temperature stability, low-temperature crack resistance, and fatigue resistance. Therefore, the use of these waste materials in asphalt mixtures offers a sustainable and environmentally friendly solution for the construction industry.

Studies on partial replacement of waste high density polyethylene (HDPE) and polypropylene (PP) plastic with fine aggregate (FA) on mechanical, durability and thermal properties of M30 and M40 grade concrete

The aim of the present paper is to incorporate two different waste plastic materials that is High-Density Polyethylene (HDPE) and Poly-Propylene (PP), were replaced with Fine Aggregate (FA) at a 10% by 2.5% increment. The widespread formation of HDPE and PP waste plastics has become a major environmental issue, endangering ecosystems and human health. Traditional disposal techniques, such as landfills and incineration, lead to pollution and resource depletion. Incorporating these polymers into concrete provides a long-term solution that reduces environmental effect while improving material qualities. The Different tests conducted are compressive strength (3, 7, 28 and 60 days) (150 × 150x150 mm), flexural strength (3, 7, 28 and 60 days) (100 × 100x500 mm), acid attack (28, 56 and 90 days) (100 × 100x100 mm), sulphate attack (28, 56 and 90 days) (100 × 100x100 mm), and thermal conductivity (180 mm dia x 20 mm thick). The compressive strengths of 40.52 MPa and 38.41 MPa for PP and HDPE material were observed in M30-grade concrete, respectively. Similarly, for M40-grade concrete, 43.6 MPa and 41.8 MPa are for PP and HDPE material, respectively. The optimum percentages of 5% and 7.5 for PP and HDPE material, respectively, can be replaced in concrete for flexural strength in both M30 and M40 grades. The least percentage loss in acid attack was observed at 28 days for both HDPE and PP material, but for 56 days and 90 days, the percentage loss of weight was significantly less (< 5%). The sulphate attack for both M30 and M40 grade concrete showed less than 10% percentage loss in weight after 90 days. Thermal conductivity (k) was also reduced by 30–35% for both HDPE and PP material, with 10% replacement in concrete for M30 and M40 grades. The use of Waste HDPE and PP material can be used to improve the mechanical, durability & thermal property of M30 and M40 grade concrete under controlled conditions.

Pyrolytic Conversion of Waste High-Density Polyethylene to Wax: Temperature Optimization and Characterization of Wax

The formation of wax from waste high-density polyethylene by thermal decomposition through pyrolysis is examined in this work. To get wax from waste high-density polyethylene, the thermal cracking reaction is run in a semi-batch pyrolysis reactor at 550 °C, 600 °C, and 650 °C. The yield percentage, melting point, specific gravity, and penetration degree of wax varied depending on the temperature. At 600 °C, waste high-density polyethylene yielded the highest wax output (87.25%) with a 0.7768 specific gravity, a 59 °C melting point, and an 81.8 mm penetration degree. The fourier transform infrared spectroscopy (FTIR) analysis concluded the presence of aliphatic hydrocarbon compounds (alkane, alkene, alcohol, and cycloalkane), which is also confirmed by gas chromatography-mass spectrometry (GC-MS) analysis. The innovation in this study lies in the systematic exploration and optimization of temperature conditions for wax production from waste high-density polyethylene (HDPE) bottles.

Adsorption of CO2 and H2 on the polymer-based membrane from High-density Polyethylene (HDPE) Plastic

High-density polyethylene (HDPE), a widely used polymer globally, notably found in plastic bags, presents an environmental concern due to its non-biodegradable nature. Transforming non-biodegradable HDPE waste into a valuable resource presents a formidable ecological challenge. This research aims to study CO2 and H2 gases toward HDPE-based membranes through the adsorption process with pressure and temperature variation. The highest CO2 and H2 adsorption capacities of 14.19 mmol.g−1 (62.43 %wt) and 18.04 mmol.g−1 (3.61 %wt) were obtained by pressure feeding 3 bar at 30°C. The adsorption capacity decrease as the temperature increase. At an adsorption temperature of 50°C, the adsorption capacity of CO2 and H2 decrease, respectively by 75.86 % and 69.81 %. The adsorption kinetics were evaluated using pseudo-first order, pseudo-second order, and intraparticle diffusion models. The kinetic study shows that adsorption at 30°C follows the pseudo-second order. The adsorption at elevated temperatures reveals the intraparticle diffusion mechanism, indicating that the gas is adsorbed directly into the polymer matrix. Thermodynamic results include enthalpy of adsorption (ΔH), standard entropy of adsorption (ΔS), energy Gibbs (ΔG), and energy activation (Ea). ΔH CO2 and H2 are -22.339 and -23.654 kJ mol−1, respectively, which indicates that the process is exothermic and physisorption. The ΔS value shows that the irregularity and randomness of gas movement during the adsorption process, with the respective values for CO2 and H2 are -0.069 and -0.072 kJ mol−1K−1, respectively. ΔG for adsorption of CO2 and H2 with increasing temperature becomes less spontaneous, which results in decreased adsorption capacity. Ea of CO2 is greater than H2, so the adsorption capacity of CO2 is smaller than H2. The thermodynamic study shows that the adsorption process is preferable at lower temperatures.

The Role of Zeolite (Microporous Crystalline Aluminosilicates) In Catalytic Pyrolysis of Waste High- and Low-Density Polyethylene Bags for Production of Fuel and Chemicals: A Review

This review provides a state-of-the-art summary of the role which zeolite plays as a catalyst via pyrolysis as a way of recovering fuels and chemicals from waste high and or low density polyethylene bags. It also highlighted the two types of zeolite (natural or synthetic) which are used as a two-stage pyrolysis−catalysis in giving a free waxing product to pure fuel and chemicals which can be subjected to further analyzing and or upgrading. As yield of oil/wax decreased with the addition of a zeolite as catalyst from 44 and 51 wt.%, (depending on the waste high density polyethylene “HDPE” or low density polyethylene bags “LDPE” and other factors). However, the composition of the pyrolysis−catalysis oils significantly increased in aromatic hydrocarbon content accordingly. In addition, the composition of the oils shifted from high molecular weight hydrocarbons (C16+) to fuel range hydrocarbons (C5−C15), with a high content of single-ring aromatic hydrocarbons such as benzene, toluene, ethylbenzene, xylenes, and styrene. This process shows great potential for production of fuels or chemicals, and also addresses the urgent issue of waste HDPE and or LDPE disposal.

Blending action of pyrolysis oil/diesel fuel featured with hydrogen on compression ignition engine performance and emission analysis

Waste high-density polyethylene (HDPE) is a non-biodegradable toxic, and harmful material. To maintain environmental sustainability, the waste HDPE involves alternative fuel extraction. The main objective of this study is to extract the alternative oil fuel from the source of the waste HDPE through pyrolysis with a reactor temperature of 300–550 °C and study the compression ignition (CI) engine performance and emission behavior. ASTM standards evaluate the physical and chemical properties of oil fuel, and its results showed that 40 and 43 °C flash and fire point temperatures, better Cetane number of 49, and a good calorific value of 43.17 MJ/kg. The CI engine performance and its emission behavior are experimentally studied with different blending ratios of HDPE oil: hydrogen: diesel fuel like 0:0:100 (D), 0:5:95 (5HD), and 10:5:85 (10B5HD). With this output, results of 10B5HD exhibited better engine performance like better brake power (BP–6.78 kW), optimum brake specific fuel consumption (BSFC-0.52 kg/kWh), improved brake thermal efficiency (BTE-28.78%) and reduced emission behavior including carbon monoxide (CO-0.43%) and carbon dioxide (CO2-24 ppm), hydrocarbon (HC-5.4%) and nitrogen oxide (NOx-760 ppm). Based on these results, 10B5HD performed better than diesel fuel and was utilized in future alternative fuel applications.

An Aspen plus process simulation model for exploring the feasibility and profitability of pyrolysis process for plastic waste management

Plastics, integral to various human activities, have led to a surge in production, posing substantial challenges in waste management. The persistent non-biodegradability of plastics, taking over a century to decompose, necessitates exploration into technologies for their conversion into sustainable fuels. Pyrolysis, an oxygen-free thermal decomposition process, emerges as a promising avenue for producing liquid fuels from plastic waste. This study's primary objective is to create and validate an Aspen Plus simulation model, enabling techno-economic evaluation and sensitivity analysis of pyrolysis for converting waste plastics into liquid fuels. Critical parameters—temperature, retention time, and particle size—are examined for their impact on product yield and quality. The methodology involves model development, validation, and subsequent simulations with various waste plastic types under different pyrolysis conditions. Experimental investigation using waste high-density polyethylene (HDPE) in an auger reactor yielded an oil yield of 61.29%, char yield of 10.98%, and syngas yield of 27.73% at 525 °C. Post-validation against this data, the model explored four plastic types, revealing significant influences of plastic type and reactor temperature on product yields. Polystyrene (PS) at 500 °C produced the highest oil content at 83.69%, with temperature affecting yield before secondary cracking. Techno-economic evaluation for a pyrolysis plant processing 10,000 tons of waste HDPE annually indicated a minimum selling price (MSP) of $302.50/ton, a net present value (NPV) of $12,594,659.7, and a 1.03-year payback period. This study provides crucial insights for designing an economically viable and sustainable pyrolysis process, guiding further research and industrial implementation.

The study of High-Density Polyethylene (HDPE) waste utilization into particle board

This research discusses related to one of the processing of waste, especially HDPE waste. HDPE waste is another alternative besides wood to make particle board. HDPE particle board takes advantage of these properties to provide a strong and durable alternative. The use of HDPE particle board provides significant benefits in the context of sustainability and the environment. In the manufacture of particle board in this study there were differences in temperature variations, so the variable in this study was temperature. Sample A has a temperature of 130° and sample B has a temperature of 160°. The particle board is pressed for 20 minutes using a hot press machine using 1 x 1 m molding. Testing of this HDPE particle board includes testing of physical properties, namely in the form of Density and chemical testing in the form of Acidity resistance and Alkalinity resistance. The standards in this study refer to SNI 03-2105-2006 regarding Particle Boards, SNI 01-7201-2006 regarding Plywood and block boards with beautiful paper faces, and ASTM D543. The density test showed a value of 0.90 gr/cm3 in the average sample A and 0.75 gr/cm3 in the average sample A. The results of the ANOVA analysis on the Density test showed that there was a significant difference between each sample and each treatment. the results of the t-Test showed that the treatment of sample A did not meet the standard, while the treatment of sample B met the SNI 03-2105-2006 standard. The acidity and alkalinity resistance were tested visually with the results that the temperature at 130° was more susceptible to reaction than the temperature at 160° Objectives: To find out the result of Density test, Acidity, and Alkalinity resistance of HDPE Particle Board is it already fulfill the standard ; To determine the temperature that has the most significant impact on the performance of HDPE Particle Board. Method and results: 1) Process of making the Particle Board, the process are include material preparation, material weighing, shredding, cleaning, drying, and pressing. 2) Sample Testing, the treatment that used is about variation of temperature. Variable that be used in this study consist of Density, Acidity, &amp; Alkalinity. 3) Data Analysis, by using ANOVA Single Factor and t-Test. Conclusion: The results of Density test by t-Test analysis showed that the treatment of sample A did not meet the standard, while the treatment of sample B already fulfill the SNI 03-2105-2006. In Acidity and Alkalinity resistance there are indicators according to SNI 01-7201-2006 in the form of softening and open cracks in several samples. Density test results show the variable B (160°) is at 0.75 gr/cm3 and already fulfil the standard. Visual test results of Acidity and Alkalinity resistance show the variable B (160°) is more resistant to the effects of acids and bases. So that the optimal variable is at a temperature of 160°.

Effects of waste high-density polyethylene (HDPE) on asphalt binder and airfield mixes

ABSTRACT Flexible airport pavements may require polymer-modified asphalt binder for their asphalt concrete (AC) mixes to withstand heavy gear loading and slow traffic moving in taxiways and aprons. Waste plastics could be repurposed as a possible alternative to Styrene–butadiene-styrene (SBS) modifiers. In this study, the feasibility of using granulated recycled high-density polyethylene (HDPE) waste was evaluated as an asphalt binder modifier for airfield pavements. A base asphalt binder was modified with waste HDPE to obtain a Superpave performance grade (PG) of 70-22. Adding waste HDPE would increase binder’s stiffness and bond to aggregate, it slightly improved ductility and elasticity; but less than SBS polymer-modified binders. The AC mixes prepared with waste HDPE-modified binder showed less potential for rutting and cracking compared control AC mixes with PG 64-22. However, the rutting and cracking potential was higher when compared to their SBS-modified PG 70–22 counterparts. On the other hand, AC mixes containing waste HDPE-modified binder were less susceptible to moisture-induced damage. It appears that using waste HDPE-modified binder is feasible where improving adhesion and resistance to moisture-induced damage AC mixes are needed and embrittlement and elastic recovery are not critical, while meeting rutting and cracking potential regional thresholds.

Comparative Analysis of Kerosene Grade Fuel from Pyrolysis of HDPE and LDPE Waste Plastics

To curb the menace of plastic waste and energy crisis, this study investigated the conversion of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) grades of plastics to kerosene. Plastics sourced from dumpsites within Port Harcourt metropolis in Rivers State, Nigeria were shredded and pyrolyzed (thermally degraded under inert condition at a temperature range of 350-400oC). The obtained hydrocarbon liquid was distilled using distillation column at a temperature range of 150-270oC and characterised to evaluate the physico-chemical parameters such as flash point, density, copper corrosion, and calorific value and compared against the acceptable standard. The result showed that these properties were within the permissible limit. However, the sulphur content and smoke point of HDPE and LDPE were above and below the limits, respectively. The GC-MS and GC-FID results of kerosene samples obtained from both grades of plastics indicates that the product comprised C9 to C17 grades.

Initiative to Increase the Circularity of HDPE Waste in the Construction Industry: A Physico-Mechanical Characterization of New Sustainable Gypsum Products

The annual production of plastic waste worldwide has doubled in just two decades, with approximately 390 million tonnes of plastic waste now being generated. In this context, the construction industry must move towards the development of new, more sustainable materials made under circular economy criteria. In this work, a physico-mechanical characterisation of gypsum composites with the incorporation of high-density polyethylene (HDPE) waste, replacing 2–4–6–8–10% by volume of the original raw material, has been conducted. The results show how the incorporation of these plastic wastes improves the water resistance of the gypsum material without additions, as well as producing a decrease in thermal conductivity and greater resistance to impact. On the other hand, it has been found that, as the percentage of recycled raw material added increases, the mechanical resistance to bending and compression decreases, leading to fracture due to a lack of cohesion between the matrix and the waste. Nevertheless, in all the cases studied, mechanical strengths higher than those established by the EN 13279-2 standard were obtained. Thus, the results confirm the viability of these secondary raw materials to be used in the development of new products for sustainable building, especially in the design of prefabricated panels for false ceilings.