High Organic Content Research Articles

The Effect of Chicken Bones Powder Adsorbent Mass and its Contact Time on Reducing Color Concentration in Peat Water Treatment

Peat water is surface water or ground water which is found abundantly in tidal, swampy and lowland areas. It has a reddish-brown color, with an acerbic taste (high acidity), and has a high organic content. Peat water can be treated using the adsorption method. Adsorption is a physical phenomenon in which the molecules of the adsorbed material are attracted to a solid surface, which acts as an adsorbent. In this study, the authors used the adsorption method to reduce the color concentration of peat water using activated chicken bones powder as an adsorbent and observing the changes that occur when mass of powder to the amount of 0.1, 0.2, 0.3, 0.4, 0.5, 1.0, 1.5 and 2.0 grams were added to 50 ml of peat water with contact time that varied from 20, 30, 40, 50 and 60 minutes. From this study, we conclude that the optimum yield was obtained when the mass and contact time were at 0.5 grams and 40 minutes, which yield a percentage of reduction of 95.59%, wherein the initial color concentration of peat water at 337.816 was reduced to 14.89 Pt-Co, which is in line with the standard color for clean water as specified in a Regulation by the Minister of Health of the Republic of Indonesia No. 492/MENKES/PER/IV/2010, which state the standard color for clean water is 15 Pt-Co.

An innovative formulation to improve spent coffee characteristics as soil fertilizer: Nutrient, chemical characterization and effects on plant germination

Spent coffee grounds (SCG) possess high organic content and various essential nutrients. However, their direct use as a fertilizer is limited due to high acidity, phenolic content, and C/N ratio. Therefore, in this study, SCG-based fertilizer (SCGf) was developed by mixing the raw SCG (SCGr) and zein through a granulation process and was compared with the SCGr. According to the obtained results, in SCGf, a reduction in the C/N ratio from 22.9 to 10.9, improved flowability from fair to good, an increase in the concentration of elements (N, C, S), nutrients (ash, fats, proteins), macrominerals (Ca, Mg, P, K, Na), microminerals (Cu, Fe, Mn, Zn), total polyphenolic content (TPC), total flavonoid content (TFC), and antioxidant activities (AOA) was noted. Additionally, a decrease in total organic acids, total chlorogenic acids, and was also observed in SCGf. Regarding phytotoxicity test results obtained by using Sinapis alba, Sorghum saccharatum, and Lepidium sativum and treating them with 2.5%, 5%, and 10% of SCGf and SCGr, better germination was observed for SCGf in S. alba (5%, 10%), L. sativum (2.5%, 5%). However, in L. sativum, 5% of SCGr and 10% of both SCGr and SCGf completely inhibited seed germination. For S. saccharatum, higher germination rates were observed for SCGf (2.5%, 10%), and at 5%, a comparable effect of both SCGf and SCGr was noted. SCGf gave the longest root length at all concentrations in all plants except for 2.5% in S. alba. In conclusion, this study addresses the effective use of SCG for sustainable agriculture while mitigating environmental impacts.

Effect of culture history and carbon sources on polyhydroxyalkanoates production in activated sludge systems

ABSTRACT Polyhydroxyalkanoates (PHAs) are important and completely biodegradable alternatives to regular plastics, and they can be produced by activated sludge systems during wastewater treatment. Wastewaters with high organic content are being used for PHA production, which is an important resource recovery option. In this context, the effect of sludge retention time and different carbon sources, such as acetate, peptone-mixture and industrial wastewater (containing acetic acid (AA), lactic acid (LA) and propionic acid (PA)), on PHA storage was investigated. Oxygen utilisation rate (OUR) profiles were generated in respirometric tests and were evaluated by activated sludge modelling. Results showed that high storage (AA: 70%; LA: 49%; PA: 60% and industrial wastewater: 52%) was achievable in the feast phase even when the biomass was fed with a high organic acid content substrate to which it is not acclimated.

Fate of per- and polyfluoroalkyl substances at a 40-year dedicated municipal biosolids land disposal site

The fate of per- and polyfluoroalkyl substances (PFAS) was evaluated at a site where municipal biosolids have been applied annually for 38 years as a waste management strategy. Soil cores (1.8 m in 30-cm sections), groundwater from four wells, and biosolids applied in 2022 were analyzed for PFAS (54 targeted, 17 semi-quantified) using liquid chromatography high resolution mass spectrometry including suspect screening. Total PFAS concentrations decreased with soil depth from 1700 ng/g to 2.06 ng/g. PFAS distribution in 2022 biosolids were 60 mol% perfluoroalkyl acid (PFAA) precursors and intermediates. The surface soil was dominated by long-chain PFAAs (67–76 mol%) reflecting precursor degradation after biosolids application. Presence of semi-quantified intermediates further reflects precursor degradation in surface soil. Long-chain PFAAs diminished with depth while short-chain PFAAs increased with up to 98 and 96 mol% short-chain PFAAs in the bottom depth and groundwater, respectively. PFAS distribution with depth is consistent with chain-length dependent sorption-impacted transport and the high organic carbon content of the surface soil (15.2 % OC) which subsequently decreased with depth (~2–3 % OC at >60 cm). High organic carbon content in the upper horizon is likely from decades of high biosolids application rates, which contributed to minimizing leaching of long-chain PFAS. While the well within the dedicated land disposal is not drinking water, for comparison only, PFAS concentrations in this well only marginally exceeded the EU drinking water directive for total PFAS and a few individual short-chain PFAS, but did exceed tenfold, the USEPA drinking water standard for PFOA.

Effect of the main components in gasification wastewater on the surface properties of coal water slurry

AbstractCoal water slurry is an advanced and efficient clean coal technology; using gasification wastewater to prepare coal water slurry can recycle wastewater and improve energy utilization efficiency. As the complex substances in wastewater have a great influence on the slurry properties, the effects of organic matter, metal ions, and ammonia nitrogen in gasification wastewater on the surface properties of coal water slurry are studied in this paper in order to provide new ideas for slurry mechanism of coal water slurry prepared from wastewater. Results show the following: (a) Compared with ordinary coal water slurry, the concentration of coal water slurry prepared from wastewater with high organic content increased by 2.9%, while the concentration of coal water slurry prepared from wastewater with high ammonia nitrogen content decreased by 2.1%. (b) The contact angles of coal water slurry prepared with phenols, alcohols, and urethane are reduced by 2.8°, 6.3°, and 1.5°, respectively, so organic matter can change the hydrophilicity of coal particles and affect slurryability. (c) Mg2+ and Ca2+ have basically no effect on slurry. Fe3+ reduces the absolute value of Zeta potential by 33.1, and Cu3+ increases that by 22.8, as they affect the slurryability by changing the surface potential of coal particles and the absorption of additives. (d) Ammonia nitrogen influences the slurryability by changing the pH value of the slurry. The conclusion of the influence mechanism of organic matter, metal ions, and ammonia nitrogen in wastewater on slurryability can provide a technical reference for the selection of suitable wastewater to prepare coal water slurry.

Potato and dairy industry side streams as feedstock for fungal and plant cell cultures

Utilization of industrial side streams as nutrient source for cellular agriculture is a promising option to improve the sustainability of the production processes. The aim of the study was to evaluate usability of two liquid food industry side streams, potato cell fluid and acid whey, as nutrient source for production of food ingredients with plant cell cultures (arctic bramble (Rubus arcticus L.) and tobacco BY-2 (Nicotiana tabacum L.)) and filamentous fungi (Paecilomyces variotii, Rhizopus oligosporus and Trichoderma reesei). The side streams were found to contain various sugars and other potential nutrients suitable for the studied organisms. The side streams were used as a sole nutrient source (fungi) or as a replacement of selected nutrients in the growth media (fungi and plant cells) in flask scale cultivations. Acid whey was successfully used as a growth medium for filamentous fungi, but it inhibited plant cell growth presumably due to high organic acid content (14 g/l). Potato side stream was found suitable as a fungal and plant cell growth media supplement, and it was used together with glucose for filamentous fungi, or as a partial replacer of macronutrients for plant cells, in bioreactor cultivations yielding high fungal (up to 36 g/l dry weight) and good plant cell (9.5 g/l dry weight) biomass production. Analyses of the produced biomasses revealed good nutritional value in terms of amino acid (17–27 % of dry matter) and dietary fiber (23–30 % of dry matter) contents, giving good premises for utilization in human nutrition.

Comparing occurrence of per- and polyfluoroalkyl substances (PFAS) in municipal biosolids and industrial wastewater sludge: A City of Los Angeles study

Biosolids and sludge are what remain after the liquid fraction of wastewater is separated during wastewater treatment. These high organic content matrices are known to contain organic contaminants, a few of which are the hazardous and environmentally persistent per- and polyfluoroalkyl substances (PFAS). The current study investigates whether sludge from a treatment facility serving mostly industrial establishments and biosolids from a facility serving mostly domestic dwellings retain these ‘forever chemicals’ similarly. Using 31 markers covering different classes of PFAS, the sludge was found to contain higher levels of PFAS (869 ± 791 ng/g; 21 of 31) than biosolids (31 ± 7 ng/g, 11 of 31). The most abundant overall was perfluorooctane sulfonic acid (PFOS), mostly in sludge (range: 71–1300 ng/g versus 0–18 ng/g in biosolids). The large PFAS concentration variability in sludge was seasonal and sinusoidal. Sludge, additionally, contained all long chain PFAS, precursors (mostly surfactant ingredients and their transformation byproducts) and short chain PFAS (perhaps because of higher moisture content). By regression, the sludge is shown to consistently contain twice as much PFAS as biosolids when the same amounts are exposed to increasing levels of PFAS. Factors observed to cause differential PFAS retention between sludge and biosolids were moisture (98.6 % and 72.1 %, respectively), chain length, input quality (industrial versus residential) and functional group. Sulfonic acids for instance are one C atom shorter than carboxylates with similar occurrence in sludge and biosolids. More studies are needed to define the roles that organic carbon of sludge/biosolids, water chemistry, temperature and factors not considered here play in partitioning PFAS between the two matrices with respect to inputs. Existing Koc values could not help in explaining observed trends, but the ratio of biosolids-to-influent concentrations was found to correlate positively with PFAS size. Using influent in the ratio, and not effluent, is novel. SynopsisSludge and biosolids are soil amendments; they contain hazardous and persistent PFAS. Methods of decoupling PFAS from these matrices start with understanding matrix-driven PFAS partitioning as shown here.

Improving Okra Production by Poultry Manure Application in Highland Acid Oxisols of Dschang, Western Cameroon

Problem Statement: Low yields of crops in Sub-saharan Africa are often associated with low soil fertility. However, due to high cost and negative environmental impact of chemical fertilizers, using cheap and readily available organic manures such as poultry manure (PM) has become indispensable. Aim: To evaluate the effect of different rates of PM on soil fertility and the performance of Okra (Abelmoschus esculentus) in the Cameroon Western Highlands. Methodology: The study was carried out in the field and in the laboratory. The experimental plot (191.25 m2) in the field was designed in a randomized complete block design with six treatments and three replications: 0 t ha-1 of PM (To), 3 t ha-1 of PM (T1), 6 t ha-1 of PM (T2), 9 t ha-1 of PM (T3), 12 t ha-1 of PM (T4), and 250 kg of NPK 12-14-19 (T5). Soil samples were analyzed in the laboratory by standard procedures before and after treatment. Results: Treatment T0 had a clay loam texture, acidic pH (5.4), relatively high organic carbon content (1.92%), moderate total nitrogen (0.33%) and moderate available phosphorus (36.07 mg kg-1). The exchangeable complex revealed high K+ (1.02 cmol kg-1), low Ca2+ (2.60 cmol kg-1) and Mg2+ (1.04 cmol kg-1), average Na+ (0.33 cmol kg-1). After treatment, soil pHH2O, available phosphorus and exchangeable K, Ca, and Mg increased after harvest whereas Na decreased for all the treatments. The effect of the treatments on growth parameters was such that T3>T4>T1>T5>T2>T0. The global trend of yield parameters was such that T3>T4>T5>T1>T0>T2. Economically, treatments T3, T4, and T5 were profitable and recommendable for popularization, with a benefit-to-cost-ratio (BCR) >2. The most economically viable treatment was T3 with a profit rate (PR) of 601.66% and a BCR value of 7.02, while T2 was the least economically viable treatment with a negative PR of -32.14% and a BCR of -33.67. Conclusion: Farmers in Western highlands can produce okra profitably and sustainably using PM at a rate of 9 tha-1f.

Preparation of ZIF-67 derived Co3O4 composite non-homogeneous catalysts with cerium oxide for the efficient degradation of Rhodamine B

The textile printing and dyeing industry produces a significant amount of wastewater, which is challenging to degrade due to its high organic concentration, complex composition, and high chromaticity. This type of wastewater is considered one of the most difficult to treat. In recent years, advanced catalytic oxidation based on sulfate radicals (SO4−) can efficiently degrade printing and dyeing wastewater. Seeking non-homogeneous catalysts for the activation of the radicals is the key problem to be solved nowadays. In this study, Ce/Co-ZIF precursor was obtained by stirring and precipitation, and the ZIF-67-derived non-homogeneous catalyst of Co3O4 and CeO2 was successfully synthesised by calcination for the efficient catalytic degradation of Rhodamine B (RhB) dye. The morphological structure and elemental distribution of the non-homogeneous catalysts were observed using SEM, TEM, XRD, and XPS. Additionally, the factors that affect the degradation of RhB dye were investigated. These factors were adjusted individually, from CeO₂ loading, pH, material dosing, to persulfate (PS) dosing, and it was determined that the rate of RhB degradation also increased from the initial 92 % to a value of 97.1 %. It was found that under the optimal conditions of a CeO2 loading percentage of 0.44, pH of 7, and composite material and potassium persulfate dosage of 5 mg and 0.4 g/L, respectively, the catalytic system achieved a degradation rate of 97.5 % of RhB dye within 30 min. Then the non-homogeneous catalyst could still maintain the good catalytic degradation effect after 5 cycles of regeneration experiments. Therefore, the ZIF-Co3O4@CeO2 non-homogeneous catalyst has a good potential for wastewater treatment and provides a new way for the application of high performance catalysts in the future.

Insight into the impact of environmental factors on heavy metal adsorption by sodium alginate hydrogel: Inspiration on applicable scenarios

Sodium alginate (SA) emerges as a promising adsorbent for the remediation of heavy metal-polluted wastewater. However, the systematic investigations on how and the extent to which the various compositions in real water matrices impact its performance were essential but rare when considering its use. Here, we explored the effect of common environmental factors on Cu(II) adsorption by an as-synthesized SA-based hydrogel (SAH). The result showed that high concentration of organics (above 10 mg L−1) had a negative influence on heavy metal removal (decreased by 9.45 % at least), while inorganic ion, turbidity and antibiotics at relatively low concentrations exhibited a negligible even promoting effect (increased by 9.8 % with the presence of 5 mg L−1 Nor). Based on above results and corresponding mechanism analyses, the possible applicable and unsuitable scenarios of SAH can be predicted. SAH could be a great candidate for treating heavy metal-polluted water such as river and lake water, while it is not a good option for electroplating or livestock wastewater which contains high concentration of organic matters. Besides, the operating conditions including pH (5.0 for Cu(II), 6.0 for Ni(II)), contact time (24 h), temperature (298 K) et al. were also determined. Overall, this work provides theoretical guidance and operational strategies for promoting the practical application of SA adsorbent in water treatment.

Study on the relationship between shale organic matter development and paleowater depth—A new understanding of the condensed section

Recent studies dispute the long-standing belief that highly organic-rich shales are predominantly linked to condensed section (CS) at the maximum flooding surface (MFS), proposing instead that they more commonly develop in shallow waters along basin margins. This hypothesis, however, has not been thoroughly investigated. Our study, focusing on the pivotal regions of the Longmaxi Formation and the Chang 7 Member for marine and continental shale exploration in China, integrates sequence stratigraphy with analyses of total organic carbon (TOC) and elemental geochemistry to pinpoint the environments conducive to the formation of organic-rich shales. The most organic-rich intervals, specifically the bottom of the Longmaxi Formation and the mid-to-lower Chang 73 sub-member, are located within the transgressive systems tract (TST), showing higher TOC levels in the middle to lower TST, compared to the CS of the MFS. The formation of high organic matter shale is related to warm, humid, and dysoxic shallow waters with minimal terrigenous influx and high primary productivity. We found a pronounced inverse relationship between organic matter concentration and water depth, with deeper waters promoting the decomposition and recycling of organic matter during sedimentation, thereby diminishing the TOC content. Moreover, volcanic activity also affected the organic enrichment in the Chang 7 Member. With high primary productivity, organic matter tends to accumulate in dysoxic slope zones. Consequently, high-organic content shale intervals are generally situated in shallow, dysoxic water environments, suggesting that the CS of the MFS may actually represent organic-poor intervals with limited source rock potential. The results of this study are of great significance for shale oil and gas exploration in China, and provide a new direction for the discovery of shale oil and gas sweet spots.

Silica‐Rich Sol‐Gel Ink for Two‐Photon Direct Laser Writing of Microscale Structures and Optical Elements

AbstractInnovative materials enable two‐photon polymerization for precise additive fabrication of intricate optical components. Existing polymeric inks suffer from poor optical performance due to their high organic content. Silica‐rich sol‐gel ink (75 wt%, under ambient conditions) is presented for high‐precision three‐dimensional (3D) printing of microscale structures and optical devices. A photoinitiator with high‐efficiency nonlinear absorption is introduced to initiate two‐photon polymerization. Utilizing a commercial direct laser writing system, 3D‐printing is demonstrated including the optimization of printing parameters and ink characterization. The optical performance of the printed microscale elements using the new sol‐gel ink surpasses commercially available polymeric inks on key metrics: Printed elements exhibit extremely low surface roughness, 3nm; visible and near‐IR light transmission is greater than 90%; Printed elements present enhanced mechanical and chemical resistance to common organic solvents; Structures exhibit low isotropic shrinkage, <10%; Elements withstand continuous‐wave laser intensities exceeding 7 × 105 W cm−2. Direct writing onto an optical fiber tip with no need for surface functionalization is presented, with the demonstration of a tall waveguide taper (≈1:5 aspect ratio) with low losses and modal crosstalk, and a freestanding photonic lantern mode multiplexer. The new ink can be utilized in a variety of applications and across many materials, requiring compact, durable, and complex optical elements.

Paleoenvironmental factors controlling organic-rich formations deposition in the Babouri-Figuil Basin (Northern Cameroon)

The Babouri-Figuil Basin is an intracratonic basin (half-graben) in northern Cameroon that is genetically connected to the Benue Trough from Nigeria, and is an area of interest in terms of petroleum prospectivity. Recent studies highlighted the presence of organic-rich formations in the basin. However, none of these works have identified factors that governed the accumulation of organic matter (OM) in the sediments. The main objective of this work is the characterization of these formations through palynofacies and organic geochemical techniques (total organic carbon - TOC, total sulfur, insoluble residue and biomarkers), in order to determine the organic facies, their depositional environments and the main drivers for organic enrichment in the basin. The current study reveals that black shale and massive claystone lithologies constitute the main organic-rich formations in the basin, with TOC reaching up to 26.08 wt%, being characterized by a dominance of bacterially-derived amorphous OM. Palynofacies and biomarker data revealed that these formations are positively associated with anoxic conditions and a partly highly saline and stratified lake water column. The deposition of organic-rich formations in the Babouri-Figuil Basin was mainly controlled by restriction conditions which developed in connection with the regional tectonic framework. The Lower Cretaceous rifting episode in the West and Central African Rift System (WCARS) basins led to the formation of accommodation space, a reduction in water levels, and the development of anoxic conditions within the basin, facilitating the deposition of organic-rich formations. Therefore, the organic enrichment of the Babouri-Figuil Basin has been predominantly controlled by its tectonic evolution, particularly during the syn-rift phase. This phase created favorable conditions for the deposition and preservation of OM, including the establishment of anoxic conditions. Additionally, the paleoclimate (arid conditions), the development of bacterial biomass, and the basin's paleogeography all played a significant role in this process. The organic-rich formations of the Babouri-Figuil Basin show characteristics of prospective petroleum source rocks (high organic content, high proportion of oil-prone kerogen, significant thickness and lateral extension). The combination of organic-rich formations with sandstone deposits above and extensive claystone/shale deposits on top can indicate the presence of an oil play in the basin. A detailed study with broader sampling is needed to investigate thoroughly the variation of organic facies and the influence of paleoenvironmental factors that control the deposition of thick source rock intervals.

Generation, characterization, and toxicological assessment of reference ultrafine soot particles with different organic content for inhalation toxicological studies

Ultrafine particles (UFP) are the smallest atmospheric particulate matter linked to air pollution-related diseases. The extent to which UFP's physical and chemical properties contribute to its toxicity remains unclear. It is hypothesized that UFP act as carriers for chemicals that drive biological responses. This study explores robust methods for generating reference UFP to understand these mechanisms and perform toxicological tests.Two types of combustion-related UFP with similar elemental carbon cores and physical properties but different organic loads were generated and characterized. Human alveolar epithelial cells were exposed to these UFP at the air-liquid interface, and several toxicological endpoints were measured. UFP were generated using a miniCAST under fuel-rich conditions and immediately diluted to minimize agglomeration. A catalytic stripper and charcoal denuder removed volatile gases and semi-volatile particles from the surface. By adjusting the temperature of the catalytic stripper, UFP with high and low organic content was produced.These reference particles exhibited fractal structures with high reproducibility and stability over a year, maintaining similar mass and number concentrations (100 μg/m3, 2.0·105 #/cm3) and a mean particle diameter of about 40 nm. High organic content UFP had significant PAH levels, with benzo[a]pyrene at 0.2 % (m/m). Toxicological evaluations revealed that both UFP types similarly affected cytotoxicity and cell viability, regardless of organic load. Higher xenobiotic metabolism was noted for PAH-rich UFP, while reactive oxidation markers increased when semi-volatiles were stripped off. Both UFP types caused DNA strand breaks, but only the high organic content UFP induced DNA oxidation.This methodology allows modification of UFP's chemical properties while maintaining comparable physical properties, linking these variations to biological responses.

Performance evaluation and microbial community analysis of a continuous stirred tank reactor–anaerobic ceramic membrane bioreactor system for practical swine wastewater treatment

To treat swine wastewater from a practical piggery, a continuous stirred tank reactor (CSTR)–anaerobic ceramic membrane bioreactor (AnCMBR) was operated for 201 days. A high chemical oxygen demand (COD) removal efficiency of 95 % and biogas production rate of 0.31 L/L·d were achieved at an organic loading rate (OLR) of 1.19 g-COD/L·d. Although the free ammonia concentration reached a maximum of 200 mg/L during the last operational phase, no evident inhibitory effect on AnCMBR performance was observed. Microbial community analyses indicated that six bacterial phyla were responsible for the hydrolysis, acidification, and fermentation of organics and environmental stabilization. Hydrotrophic methanogenic archaea were dominant, indicating that the main methane production pathway involved the use of H2 and CO2 as substrates. The results demonstrated that CSTR–AnCMBR systems exhibit excellent organics removal performance and energy recovery at high organic concentrations and possess strong anti-shock ability. Thus, they represent alternative green and sustainable anaerobic technologies for practical swine wastewater treatment.

Assessment of Different Organic Manures on Morphological and Floral Attributes of Marigold (Tagetes erecta L.)

Aims: The organic content in manure helps soil retain moisture, increases gas exchange, and introduces beneficial bacteria, loosens clayey soil, promoting root growth. Soil with a higher organic content is more resistant to erosion and produces superior crops. Using organic manure decreases farming's environmental impact. Unlike synthetic fertilizers, it recycles waste materials, nourishes the soil, and nurtures crops. Methods: This experiment was carried out during Rabi 2023-24 at the Organic Research farm Kargunwan ji, Jhansi, Department of Horticulture, Institute of Agricultural Sciences, Bundelkhand University Jhansi (Uttar Pradesh). African Marigold (Tagetes erecta L.) cultivar ‘Hazara’ was sown under randomized block design (RBD) with 09 treatment viz., Control, FYM at 10t/ha, FYM at 20t/ha, Compost 10t/ha, Compost 20t/ha, Poultry manure10t/ha, Poultry manure20t/ha, Vermicompost 10t/ha and Vermicompost 20t/ha with 3 replication accommodating spacing (40 × 45) cm2, plot size (2.5 × 2.5) m = 5.0 m2 with total gross experimental area of (23.5 x 9.6) m = 225.06 m2. Results: Results shows that at harvest, increasing the organic doses at recommended doses clearly expressed maximum morphological characters and floral attributes and was reported under the treatment T9 (vermicompost 20t/ha) followed by treatment T8 (vermicompost 10t/ha) and T6 (poultry manure 10t/ha). The minimum plant height was noticed with the treatment T7 (Water spray). Conclusion: The results clearly revealed that on application of organic manure in marigold had a positive and significant impact on morphological characters and floral attributes in Marigold. Thus it is recommended to opt for organic cultivation in place of in organic cultivation.

Rice yield and water productivity in response to water-saving irrigation practices in China: A meta-analysis

Various water-saving irrigation (WSI) practices (e.g., dry cultivation, intermittent irrigation, controlled irrigation, shallow-wet irrigation, and rain-gathering irrigation) have been applied to rice cultivation mitigate water scarcity in China. However, in previous studies, these WSI practices have shown different water savings and yield increases, mainly due to different application conditions. A meta-analysis was applied to investigate the responses of the actual evapotranspiration (ETact), irrigation water (IW), rice yield (Y), and water productivity (WP) to WSI practices in different conditions, and 956 data sets were selected from 108 published papers. The results showed that, compared to traditional flood irrigation, rain-gathering irrigation decreased ETact and IW by 25.41 % and 55.7 % respectively, and increased WP greatly by 14.26 % while having a slight decrease in Y. Except for dry cultivation, all WSI practices increased WP by 4.72–14.26 % compared to traditional flood irrigation. The effects of different soil qualities on rice water consumption and production vary; medium soils with high organic content and a pH below 6.5 are better for rice growth. As for rice seasons, WSI practices had the least impact on ETact in middle rice, with an average reduction of 5.84 %, followed by early rice (–12.66 %) and late rice (–18.81 %). Higher mean annual temperature and more precipitation led to more Y under WSI practices. Differences in the effects of mean annual temperature and mean annual precipitation on WP were not significant. Our meta-analysis provides more insight into the effects of water-saving irrigation practices on rice water consumption, yield, and water productivity at various experimental sites. In general, there is considerable variation in the responses of Y and WP to different water-saving irrigation practices, and more evaluation of aspects such as rice seasons, soil properties, and meteorological conditions is needed for optimizing WSI in practice.

Evaluation of energy potential of MSW in the Tamale metropolis, Ghana: An assessment of solid waste characteristics and energy content

ABSTRACT In the present investigation, a thorough examination of waste composition was undertaken in the Tamale Metropolis, Ghana. The methodology employed was carefully designed, incorporating both commercial and residential sectors as well as various socioeconomic classes. Source-based sampling of waste materials covered a range of locations, including households, markets, hotels, and restaurants, while socioeconomic-based categorization followed the zoning of the metropolis. Waste audit sampling involved collecting a total of 90 batches of solid waste over the three-month period from August to October 2023. The primary objectives were to physically characterize the waste and evaluate its chemical properties through proximate and ultimate analysis of waste fractions, aiming to determine the waste-to-energy potential and compatibility with waste-to-energy technologies. The study revealed that the Tamale Metropolis generates 176.1 tons/day of Municipal Solid Waste (MSW) at a rate of 0.47 kg/capita/day. Organic matter constituted the majority (44.9%), followed by inert, miscellaneous, and plastic waste at 20% each. The remaining 14.3% comprised paper, metal, glass, leather, and textile components. Notably, the hospitality sector exhibited the highest organic matter content at 62.3%, contrasting with average households and markets at 44.9% and 13.1%, respectively. Moisture content ranged from 5.4% to 12.6%, volatile solids from 21.8% to 77.2%, and gross calorific values from 7.9 MJ/kg to 28.9 MJ/kg. Household waste demonstrated the highest energy content at 6693.8 kcal/kg, followed by hotels/restaurants (2003.94 kcal/kg) and markets (1883.62 kcal/kg). This study’s findings offer valuable insights that can inform the development of effective policies by regulatory bodies such as the Public Utility Regulatory Commission (PURC) and the Ghana Ministry of Energy, as well as city authorities like the Tamale Metropolitan Assembly and the Environmental Protection Agency. These insights can be used to address waste and energy challenges in the metropolis. Implications: The findings reveal critical insights with substantial implications for stakeholders and regulatory bodies. It emphasizes the waste-to-energy potential of various waste fractions, highlighting the need for sustainable municipal waste management strategies. Particularly, the high organic content in the hospitality sector presents significant energy recovery opportunities. For bodies like the Public Utility Regulatory Commission and the Ghana Ministry of Energy, this data is crucial for developing policies that support waste-to-energy technologies. Additionally, the Tamale Metropolitan Assembly and the Environmental Protection Agency can use these insights to improve local waste management practices, customizing interventions to address specific sectoral waste composition. The study also underlines the importance of ongoing monitoring to ensure the effectiveness of these strategies over time.

Performance of catalytic wet oxidation on thermochemical aqueous effluents assessed by FT-ICR MS

Aqueous phase (AP) is frequently observed in bio-oil from biomass thermochemical conversion or as an upgrading coproduct. However, AP contains high organic content that can be toxic and that must be reduced or removed to be then treated in existing wastewater plants. A promising method to upgrade these APs is the catalytic wet peroxide oxidation (CWPO) that was applied here on APs of both hydrothermal liquefaction and pyrolysis bio-oils from softwood and hardwood. Efficiency of the CWPO was assessed by investigating the molecular composition of raw and treated APs by ultra-high-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) with electrospray ionization (ESI) in negative- and positive-ion modes. Combination of FT-ICR MS and multivariate statistical analyses evidenced efficiency of the process with new compounds resulting from the oxidative depolymerization, characterized by lower unsaturation degree and molecular weight, and higher oxygen atom count. Refractory compounds were also observed, which are notably characterized by high unsaturation degrees. Interestingly, both detection modes were shown to be complementary for the understanding of the CWPO process. ESI (-) allowed to assess the completion of the oxidation process in detecting carboxylic acid conversion products and to specifically evidence refractory products. ESI (+) was informative on the CWPO process, especially on the conversion of the basic compounds, with the decrease of the detected species. Eventually, softwood AP was shown to be more reluctant to CWPO than the hardwood one.

Online Raman spectroscopy for quantitative detection and characterization of aerosolized soot.

Ex-situ Raman spectroscopy is a well-established method for the structural characterization of soot but necessitates a sampling step before analysis is made. This work studied the potential to perform Raman spectroscopic measurements of soot directly in the combustion exhaust gases, i.e., online Raman measurements. Two types of soot were produced from a Mini-CAST soot generator, one immature with high organic content and one mature with low organic content. Also, two different measurement configurations were used, a 90-degree and a backscattering configuration, as well as different polarization combinations of the laser radiation and the detected photons. Spectrally resolved Raman signals were successfully recorded and analyzed for the two soot types showing differences between the characteristic D and G peaks as well as the photoluminescence signal. Additionally, the Raman cross section was determined for both soot types and found to be higher for the immature soot. It was also found that a horizontally polarized laser excitation and a 90-degree collection angle had the best potential to reduce the interference from ambient gases. This study can be seen as a first step towards remote sensing of soot.