High Cation Research Articles

Superionic lithium transport via multiple coordination environments defined by two-anion packing.

Fast cation transport in solids underpins energy storage. Materials design has focused on structures that can define transport pathways with minimal cation coordination change, restricting attention to a small part of chemical space. Motivated by the greater structural diversity of binary intermetallics than that of the metallic elements, we used two anions to build a pathway for three-dimensional superionic lithium ion conductivity that exploits multiple cation coordination environments. Li7Si2S7I is a pure lithium ion conductor created by an ordering of sulphide and iodide that combines elements of hexagonal and cubic close-packing analogously to the structure of NiZr. The resulting diverse network of lithium positions with distinct geometries and anion coordination chemistries affords low barriers to transport, opening a large structural space for high cation conductivity.

Organic Amendments to Short Rotation Coppice (SRC) Plantation Affect Species Richness and Metal Accumulation of Spontaneously Growing Herbaceous Plants

Excess potentially toxic metals (PTMs) in soils require ad hoc approaches to salvage. Hence, this study explored the shoot accumulation of cadmium (Cd), lead (Pb), and zinc (Zn) by herbaceous plants growing under previously established Salix and Populus clones Short Rotation Coppice (SRC) with compost and sewage sludge applications in an abandoned metallurgical site, Podlesí, Czech Republic; PTM decontamination of soils. Soils within the SRC experimental site and outside considered as control were analyzed for their chemical properties by multi-analytical techniques. Shoots of spontaneously growing herbaceous plants under trees in the site and without trees in control were determined for pseudo-total Cd, Pb, and Zn contents. Moderately to slightly acid soils, high cation exchange capacity, and C/N ratio supported mineralization and relative mobility of total Cd (7.7–9.76), Pb (1541–1929), and Zn (245–320 mg kg−1) in soils. Although soil amendments improved chemical properties, compost application supported higher species richness than sewage sludge. Over 95% of plants accumulated Cd and Zn above the WHO threshold and green fodder in the Czech Republic, with 36% Pb above the regional limit (40 mg kg−1). Approximately 100, 50, and 6% of herbaceous species had Cd, Pb, and Zn accumulation, respectively, higher than published average upper limits in plants (0.2 Cd, 10 Pb, and 150 Zn mg kg−1). Dicots recorded higher Cd content, Tenacetum vulgare (L.), Hypericum maculatum (Crantz), and Cirsium arvense (L.); Stachys palustris (L.), Lamium perpereum (L.), and Campanula patula (L.) for Pb; Glechoma hederaceae (L.), C. patula, and C. arvense for Zn in all treatments. Appropriate soil amelioration of SRC-supported PTM mobility and excess herbaceous species shoot accumulation, growth, and richness.

Accelerated Selective Li+ Transports Assisted by Microcrack-Free Anionic Network Polymer Membranes for Long Cyclable Lithium Metal Batteries.

Rechargeable Li metal batteries have the potential to meet the demands of high-energy density batteries for electric vehicles and grid-energy storage system applications. Achieving this goal, however, requires resolving not only safety concerns and a shortened battery cycle life arising from a combination of undesirable lithium dendrite and solid-electrolyte interphase formations. Here, a series of microcrack-free anionic network polymer membranes formed by a facile one-step click reaction are reported, displaying a high cation conductivity of 3.1 × 10-5 S cm-1 at high temperature, a wide electrochemical stability window up to 5V, a remarkable resistance to dendrite growth, and outstanding non-flammability. These enhanced properties are attributed to the presence of tethered borate anions in microcrack-free membranes, which benefits the acceleration of selective Li+ cations transport as well as suppression of dendrite growth. Ultimately, the microcrack-free anionic network polymer membranes render Li metal batteries a safe and long-cyclable energy storage device at high temperatures with a capacity retention of 92.7% and an average coulombic efficiency of 99.867% at 450 cycles.

Nano-Confined Effect and Heterojunction Promoted Exciton Separation for Light-Boosted Osmotic Energy Conversion.

The osmotic energy conversion properties of biomimetic light-stimulated nanochannels have aroused great interest. However, the power output performance is limited by the low light-induced current and energy conversion efficiency. Here, nanochannel arrays with simultaneous modification of ZnO and di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,20-bipyridyl-4,40-dicarboxylato) ruthenium (II) (N719) onto anodic aluminum oxide (AAO) to combine the nano-confined effect and heterojunction is designed, which demonstrate rectified ion transport behavior due to the asymmetric composition, structure and charge. High cation selectivity and ion flux contribute to the high power density of ≈7.33Wm-2 by mixing artificial seawater and river water. Under light irradiation, heterojunction promoted the production and separation of exciton, enhanced cation selectivity, and improved the utilization efficiency of osmotic energy, providing a remarkable power density of ≈18.49Wm-2 with an increase of 252% and total energy conversion efficiency of 30.43%. The work opens new insights into the biomimetic nanochannels for high-performance energy conversion.

Construction of Robust Organic–Inorganic Interface Layer for Dendrite‐Free and Durable Zinc Metal Anode

AbstractConstructing artificial interface layer is an effective approach to facilitate the utilization rate of zinc metal, but the practical application is still hindered by the inferior mechanical strength, low ionic conductivity, and poor stability. Herein, robust organic–inorganic layer (Nafion/BM@Zn) is coated on zinc metal through ultrasonic spraying method with boehmite and Nafion as the composite precursor. As demonstrated, the high cation selectivity and high hydrophilicity of Nafion, as well as the zincophilic property and layered structure of boehmite, synergistically contribute to the low nucleation barrier, uniform deposition, and fast transport kinetics of Zn2+ ions. As a result, the Nafion/BM@Zn anode exhibits superior reversibility with a high Coulombic efficiency of 99.9% for 9000 cycles in asymmetrical cells and durable cycling stability for 4200 h in symmetrical cells at 5 mA cm−2−1 mAh cm−2. Even in the seawater‐based electrolyte, the Nafion/BM@Zn anode still displays reversible deposition behavior for 820 h and high Coulombic efficiency of 99.91% for 2800 cycles at 5 mA cm−2−1 mAh cm−2. Furthermore, the corresponding Nafion/BM@Zn//NH4V4O10 cell presents high capacity of 258.4 mAh g−1 after 1500 cycles at 5 A g−1. This work provides a new design strategy for high‐efficiency interfacial layer of zinc metal anode.

A comparative study of ammonia solubility in imidazolium-based ionic liquids with different structural compositions

Four imidazolium-based ionic liquids (ILs) with two cations 1-pentyl-3-butylimidazolium [PBIM]+ and 1-benzyl-3-butylimidazolium tetrafluoroborate [BzBIM]+, and two anions tetrafluoroborate (BF4−) and trifluoromethanesulfonate (OTf−) were synthesized for NH3 solubility enhancement. The structural, thermal, and electrochemical stabilities, ionic conductivity, and viscosity of the four ILs, namely, [PBIM]BF4, [BzBIM]BF4, [PBIM]OTf, and [BzBIM]OTf, were investigated. Due to the intermolecular interaction of the benzyl group attached to the imidazolium ring, [BzBIM]+-based ILs exhibited higher thermal stability but lower ionic conductivity compared to [PBIM]+-based ILs. Further, the NH3 solubility in all ILs was measured using a custom-made setup at temperatures ranging from 293.15 to 323.15 K and pressures ranging from 1 to 5 bar. The effects of the cation and anion structures of ILs, as well as pressure and temperature, on the NH3 solubility in the ILs were also investigated. [PBIM]BF4 showed the best solubility because of its high free volume and low viscosity. Density functional calculations validated the superior NH3 solubility in [PBIM]BF4, attributable to the minimal reorganization of the [cation]anion complex geometry during the solvation process, yielding a low solvation free energy. The findings of this study suggest that ILs exhibit a high NH3 solubility capacity and cation and anion structures considerably affect the NH3 solubility in ILs.

Wooded biocorridors substantially improve soil properties in low-altitude rural benchlands

This study examines soil properties in 30- and 60-year-old agricultural biocorridors and provides a comparative overview with neighbouring farmland. Both mixed and undisturbed soil samples were collected from six farmland/biocorridor study areas to assess a wide spectrum of physical, hydrophysical, chemical and biological soil properties. Biocorridor soils were characterised by higher water retention capacities, porosity, aeration and soil carbon stock, the latter increasing with depth. On the other hand, biocorridor bulk density under forest vegetation cover was lower, indicating progressive soil restoration. Slightly lower soil reactions in biocorridor soils disproved the hypothesis that nutrient-rich soils under biocorridors would form substrates with a high base cation content, leading to soil acidification. Biological activity, expressed through respiration coefficients, was generally low due to unfavourable physical conditions (clayey or silty-clay substrates), with the lowest levels in biocorridors. Nevertheless, biocorridor soil microbiota displayed more effective utilisation of organic matter as a carbon and nitrogen source, with lighter-textured soils tending to show more effective organic matter utilisation after excluding the influence of land use. Our results confirm biocorridors as an important landscape component, contributing to both soil stability and local revitalisation of soil environments and further emphasising their potential as climate-change mitigation tools in their role as carbon sinks.

Unique switching mode of HfO2 among fluorite-type ferroelectric candidates

The primary uniqueness of HfO2 is its indispensible covalent bonding nature, though its high cation coordination number reflects a typical ionic compound.

KARAKTERISASI INDIKATOR KESESUAIAN LAHAN KOMODITI NANAS LOKAL (Ananas comosus) KABUPATEN MAJENE

Indonesia boasts a high biodiversity, intricately linked to the various ecosystems within its territories. In Majene Regency, West Sulawesi Province, for instance, there is a unique commodity in the form of pineapple, locally known as 'pondang'. One of the efforts to preserve this unique pineapple commodity is to understand the characteristics of the cultivation land that has sustained it over time. This research aimed to characterize the land in the cultivation areas of Majene's local pineapple as fundamental information for farmers to comprehend the plant growth ecosystem and manage the land optimally. The research utilized purposive random sampling based on the cultivation locations of Majene's local pineapple. Observations revealed that the cultivation land conditions for Majene's local pineapple had an average temperature ranging from 25.65 to 29.75 ºC, rainfall between 1,488.05 and 2,820.50 mm, with humidity ranging from 63.38 to 89.00%. Additionally, soil fertility conditions in the research locations indicated high nutrient retention, as shown by slightly acidic to neutral soil pH values and high Cation Exchange Capacity (CEC), although some available nutrients indicated very low to low soil fertility levels, such as potassium. Soil management significantly influenced nutrient availability, soil salinity, and alkalinity in the research locations.

Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.

Pengaruh Pemberian Biochar Terhadap Perubahan Sifat Kimia Tanah Vertisol dan Pertumbuhan Kacang Hijau (Vigna radiata L.)

Vertisols are soils that have a high cation exchange capacity but tend to have a low organic matter content. Meanwhile, nutrients availability in vertisol tends to be low because these elements are bound by clay particles, so the nutrient availability is limited for plantsThe aim of this research is to investigate the influence of rice husk biochar and corn cob biochar application on the changes in chemical properties of Vertisol soil and the vegetative growth of mung bean (Vigna radiata L.). The study was conducted using a Randomized Complete Block Design (RCBD) with an experimental approach. There were 8 treatments repeated 6 times, resulting in a total of 48 experimental units. The rice husk biochar (P) treatments included the control without rice husk biochar (BSP0), rice husk biochar at a rate of 60 g/kg soil (150 tons/ha) + 2.5 kg soil (BSP1), rice husk biochar at a rate of 30 g/kg soil (75 tons/ha) + 2.5 kg soil (BSP2), and rice husk biochar at a rate of 15 g/kg soil (37.5 tons/ha) + 2.5 kg soil (BSP3). The corn cob biochar (J) treatments included the control without corn cob biochar (BTJ0), corn cob biochar at a rate of 60 g/kg soil (150 tons/ha) + 2.5 kg soil (BTJ1), corn cob biochar at a rate of 30 g/kg soil (75 tons/ha) + 2.5 kg soil (BTJ2), and corn cob biochar at a rate of 15 g/kg soil (37.5 tons/ha) + 2.5 kg soil (BTJ3). The research data were analyzed using Analysis of Variance (ANOVA) at a significance level of 5%. Significant differences between treatments were further analyzed using the Duncan's New Multiple Range Test (BNJ) at a significance level of 5%. The soil analysis was carried out at the Soil Physics and Soil Chemistry Laboratories, Faculty of Agriculture, Universitas Mataram. The results of the research showed that biochar application influenced the chemical properties of the soil (pH, Cation Exchange Capacity, Organic-C) and the growth of mung bean plants in Lombok's Vertisol soil. Biochar did not have a significant effect on the height of mung bean plants at 7 and 14 days after planting (DAP), but it had a significant effect at 21, 28, and 35 DAP. However, the application of biochar did not significantly affect the number of leaves and dry weight of mung bean plants.

(Invited) Exploiting Organic Materials for Next Generation Batteries

Energy storage plays, undoubtedly, a fundamental role in the process of total decarbonization of the global economy that is expected to take place in the coming decades. The energy transition to a renewable and sustainable generation will be the solution to reduce greenhouse gas emissions and thus achieve the European Commission´s goal of becoming the world´s first decarbonized economy. Our mission is therefore aligned with this goal by improving the industry competitiveness and sustainable development, from a benchmark position in energy research, generating disruptive knowledge in materials and high-tech solutions. Within the electrochemical storage area, and in particular organic hybrid materials group, we work from the synthesis and design of organic molecules and polymeric materials to the understanding of their properties and interfaces with the ultimate goal of developing next generation battery systems.In this talk, a general overview of our core research will be given with a special focus on the design of polymer electrolytes. In recent years we have explored various strategies to meet the requirements of electrolytes: high lithium cation conductivity and stability against high voltage and towards lithium metal (LiM). In this scenario we have synthesized new polymers and lithium salts. Inspired by poly(ethylene oxide), polymers containing ethylene oxide units will be presented, with decreased crystallinity to improve ionic conductivity.1 This improvement generally compromises the mechanical properties. In this respect, different strategies will be shown.2,3 However, it is difficult to design a polymer that meets all properties. In this scope, a bi-layer concept will be described and how salt migration can be addressed using a single-ion conducting polymer electrolyte (SLIC).4,5 Motivated by the bi-layer strategy, within SAFELiMOVE EU project a new solid-state-based technology have been proposed.6 The most relevant work carried out in the framework of the project will be presented.References I. Aldalur et al., J Power Sources, 347, 37–46 (2017).I. Aldalur et al., J Power Sources, 448, 227424 (2020)I. Aldalur, M. Martinez-Ibañez, M. Piszcz, H. Zhang, and M. Armand, Batter Supercaps, 1, 149–159 (2018)M. Arrese-Igor et al., ACS Energy Lett, 7, 1473–1480 (2022)M. Arrese-Igor et al., Energy Storage Mater, 45, 578–585 (2022)https://safelimove.eu/

The design of high-entropy metal sulfides promising high-performance gaseous elemental mercury removal

Regulating the surface coordination environment and improving the formation of active species represent the key factor in designing high-performance metal sulfide-based sorbents for gaseous Hg0 capture. This paper reported the Hg0 adsorption by high entropy metal sulfides for the first time, and clarified the mechanisms involved in the evolutions of active species as well as the Hg0 adsorption. The multiple metal components of the high entropy metal sulfides have great significance in improving the surface chemistry. The addition of Ce helps not only the formation of chemically homogeneous structure, but also the generation of high valence state metal cations and unsaturated sulfur species, thereby improving obviously the Hg0 removal ability. The synthesized CeNiCoMnCuSx has a high Hg0 adsorption capacity of 10.52 mg·g−1 at 80 %-breakthrough, and a Hg0 adsorption rate of 4.31 μg·g−1·min−1. The high valence state metal cations (Ni3+, Co3+, Mn4+, Cu2+ and Ce4+) and unsaturated Sx2− and S22− species can directly oxidize Hg0 and convert it into HgS. In comparison, the quaternary sulfide counterpart (NiCoMnCuSx) cannot form a main phase structure, and has obviously lower percentages of high valence state metal cations and unsaturated sulfur species. This work provides a new space for developing metal sulfides for Hg0 adsorption.

Additional of Organic Amendments in the Soil to Increase the Various Crop Yield: A Review

Agricultural production is threatened by the scarcity of current natural resources, an increasing total population, climatic change, and degraded soils. To feed the world's growing population, development strategies must be implemented that sustainably increase agricultural production while at the same time reducing the negative impacts of the activities. A number of amendments are currently being researched to improve the structure and fertility of soils. The properties of organic materials (biochar (BC), husk, and compost) were examined. The properties of BC have a large specific surface area, are highly porous, and have a high cation exchange capacity (CEC). These amendments could be used to slow down the continuous soil degradation and maintain soil productivity while facing global challenges. While the environmental effects have been extensively studied, the extent to which they can contribute to long-term intensification has yet to be determined. This review aims to contribute to the topic by providing a concise summary that combines both environmental evidence and agronomic considerations.

Induced Polarization Images the Plumbing System of Hydrothermal Vents in an Intracontinental Rift, Lake Abhé, Republic of Djibouti

AbstractRecent developments in induced polarization allow for the characterization of alteration halos within hydrothermal systems. We explore the possibility of using electrical conductivity and normalized chargeability tomograms in concert to image hydrothermal conduits thanks to their high cation exchange capacities associated with alteration. The hydrothermal plumbing system of the late‐stage rift area of Lake Abhé (Republic of Djibouti) is used to test the ability of induced polarization to reveal such plumbing system associated with the prominent hydrothermal chimneys serving as vents for the hydrothermal fluids. We show that induced polarization can be used to provide an alteration tomogram, which highlights the flow path toward 2 chimneys in the top 70 m below the surface of the sediments at Lake Abhé.

Comparison of The Antibacterial Activity of Bentonite and Amoksisilin Against Streptococcus Mutans Causes of Caries

Streptococcus mutans is a normal flora bacteria in the oral cavity. Streptococcus mutans colonizes the oral cavity during the eruption of the first teeth, which in turn causes the teeth to experience caries. Bentonite is a clay consisting of the mineral smectite, especially montmorillonite. Montmorillonite is a member of smectite with the chemical formula (Al2O3 4 SiO2 x H2O). The high cation exchange capacity and fine particle size can inhibit bacterial growth. This study aims to compare the antibacterial activity of bentonite and amoksisilin against Streptococcus mutans. Materials and research methods divide the bentonite solution into five groups with concentrations of 5%, 10%, 20%, 40%, and 100%, and one group of amoksisilin and one control group. The solution was tested for antibacterial activity by diffusion on blood agar against Streptococcus mutans. The results showed that all bentonite solution groups differed from the amoksisilin group (p 0.05). Meanwhile, the antibacterial activity of the bentonite solution group was no different from the negative control group (p 0.05). The conclusion from this study was that there was a difference in antibacterial activity between the bentonite and amoksisilin groups, where bentonite did not show inhibition of the growth of Streptococcus mutans bacteria

Basic Study on Applicability to Artificial Barriers for Radioactive Waste Disposal Facility for Various Zeolites

Artificial barriers are being considered for the burial disposal of low-level radioactive waste in Japan. The artificial barrier consists of i) a low permeable layer made of bentonite materials that suppresses migration of nuclides due to advection, and ii) a low diffusion layer that uses cementitious materials that suppresses migration of nuclides due to diffusion. In addition, as methods of disposing of radioactive waste generated by the accident at the Fukushima Daiichi Nuclear Power Station, controlled disposal and isolation-type disposal are being considered. We thought that it would be effective to add adsorption performance to the performance of suppressing migration of such radioactive substances. In this study, we designed and experimented on the adsorption performance of mortar mixed with various zeolites, which had never been examined. As evaluation methods, i) fluidity, ii) strength, iii) low diffusivity, and iv) distribution coefficient of cesium and iodine were obtained. Based on the results, we reexamined the composition and conducted experiments to examine the applicability to high-adsorption artificial barriers. As a result, it was confirmed that the mass transfer resistance tends to be low due to the zeolite being porous. It was also shown that the strength of mortar mixed with zeolite depends on the cement matrix. As a result of this research, the distribution coefficient of cesium in cementitious materials using zeolite with a high cation exchange capacity designed in this research is higher than that of cementitious materials for low-level radioactive waste disposal facilities currently in operation 1,500 times was obtained. On the other hand, we were able to discover the possibility of examining construction on a full-scale regarding fluidity and compressive strength. As a future task, it was found that it is necessary to investigate a more practical artificial barrier by increasing the strength and densification of the cement paste.

ON UPDATED CONTENT OF FOREIGN LANGUAGE EDUCATION FOR STUDENTS OF NON-LANGUAGE SPECIALTIES AT A UNIVERSITY

The author explores theoretical and practical issues aimed at fi nding innovative methods and strategies of education, the use of which will ensure not only an increase in the effectiveness of teaching a foreign language, but also the formation of professional identity among students at an early stage (1st–2nd year of study). In response to the need for fundamentally new approaches to defi ning the goals, objectives and principles of higher education, attempts are being made to revise approaches to the selection of professionally oriented content of the discipline “Foreign Language”. In the research, the author relies on the concepts of professional discourse and psychotherapeutic discourse as a source of situations of professional interaction for the formation of foreign language communicative competence among students – future clinical psychologists. The article also provides examples of communicative technologies: self-presentation, argumentation and active listening. The didactic potential of the discipline “Foreign Language” in the formation of high professional qualifi cations and competence of future specialists is considered. In the course of the study, an updated program of the discipline “Foreign Language” is being developed for the specialty 37.05.01 “Clinical Psychology” based on an analysis of existing curriculums, educational and methodological materials available in electronic library systems, professional standards that served as the basis for the Federal State Educational Standard of Higher Education in this specialty, as well as available scientifi c and methodological developments in teaching professionally oriented foreign languages, on the basis of which typical situations of professional communication of future clinical psychologists are identifi ed, criteria for selecting the content of foreign language training and recommendations for methodological support of the discipline are proposed. The author concludes that the formation of universal communicative competence should occur in conditions of immersion of students in professional discourse due to the careful selection of linguistic and sociocultural material of a professional orientation, as well as a set of situational tasks that involve the use of modern communicative technologies to solve problems of a professional orientation.

Construction of metal-organic framework/cellulose nanofibers-based hybrid membranes and their ion transport property for efficient osmotic energy conversion

The development of advanced nanofluidic membranes with better ion selectivity, efficient energy conversion and high output power density remains challenging. Herein, we prepared nanofluidic hybrid membranes based on TEMPO oxidized cellulose nanofibers (T-CNF) and manganese-based metal organic framework (MOF) using a simple in situ synthesis method. Incorporated T-CNF endows the MOF/T-CNF hybrid membrane with a high cation selectivity up to 0.93. Nanoporous MOF in three-dimensional interconnected nanochannels provides massive ion transport pathways. High transmembrane ion flux and low ion permeation energy barrier are correlated with a superior energy conversion efficiency (36 %) in MOF/T-CNF hybrid membrane. When operating under 50-fold salinity gradient by mixing simulated seawater and river water, the MOF/T-CNF hybrid membrane achieves a maximum power density value of 1.87 W m−2. About 5-fold increase in output power density was achieved compared to pure T-CNF membrane. The integration of natural nanofibers with high charge density and nanoporous MOF materials is demonstrated an effective and novel strategy for the enhancement of output power density of nanofluidic membranes, showing the great potential of MOF/T-CNF hybrid membranes as efficient nanofluidic osmotic energy generators.

High dietary cation and anion difference formulation increased heat dissipation in non-lactating goats fed at high ambient temperature.

In our previous study, we observed that a high dietary cation and anion difference (DCAD) of 40 mEq/kg dry matter (DM) in the diets of lactating dairy goats increased heat dissipation. In the present study, we believe that the level of DCAD fed to non-lactating and non-pregnant goats was twice as high as that fed to lactating goats in our previous study. This increase could have resulted in a greater water balance due to increased intake of water and unchanged urinary excretion. Therefore, this study aimed to determine the behavioral and heat dissipation effects of a dietary shift from low to high DCAD levels in dairy goats under tropical conditions. Seven non-lactating and non-pregnant crossbred goats were used in this study. All animals were initially fed a low DCAD (15 mEq/100 g DM) diet from days 0-6 and then switched to a high DCAD (89 mEq/100 g DM) diet from day 7 (high DCAD-7) to day 18 (high DCAD-18). The results revealed that a high DCAD increased DM intake from days 13-18 (p < 0.05). The larger daily meal size associated with the high DCAD-18 group was due to increased daytime meal sizes, not nighttime when compared to the low DCAD group. Dietary cation and anion difference supplementation did not affect daily water intake; however, drinking patterns differed between the low DCAD group and the high DCAD-7 group from 07:00 to 09:00 and during nighttime. Similarly, daily urine volume was unaffected by DCAD supplementation, but urinary patterns differed between the low DCAD and high DCAD-18 groups. The daily water balance remained unchanged across all treatments, yet, a higher morning water balance was observed in the high DCAD group. The high DCAD diet led to an increase in respiration rate and rectal temperature compared to the low DCAD diet. The observed eating, drinking, and urinary patterns collectively suggested that high DCAD supplementation mitigates the effects of heat stress in non-lactating goats fed at high ambient temperatures.