High Absorption Research Articles

Rapid Method for Simultaneous Determination of γ-Oryzanol Compounds in Rice (Oryza sativa) Grains using UV-Vis Spectroscopy and Chemometrics

Rice (Oryza sativa) contains γ-oryzanol, which consists of 4 main compounds: Cycloartenol ferulate, 2,4-methylenecycloartanyl ferulate, campesterol ferulate, and β-sitosterol ferulate, that contribute to the health benefits of rice. This research aimed to develop a rapid method to determine the 4 major γ-oryzanol compounds in 45 varieties covering pigmented (black and red) and non-pigmented (white) rice grain. The method was developed by integrating UV-Vis spectroscopy with chemometrics, specifically principal component analysis (PCA) and partial least square (PLS) regression. Sampling was performed across the Indonesian archipelago collecting 180 samples, which comprises 60 samples for each type of rice in form of rice husk, bran, whole grain, and polished rice. The results of PCA on the spectroscopic data successfully identified distinction for the 3 types of rice attributable by different type and levels of chemical compound in the grain. White rice exhibited a characteristic absorption at 325 nm while in pigmented (red and black) rice showed a maximum absorbance at 280 nm, indicating the presence of different composition of chemical compounds. A reliable model to predict the 4 major γ-oryzanol compounds was established with R2 calibration, R2 cross-validation, and R2 prediction higher than 0.9 was obtained using the spectroscopic data in the range from 200 to 400 nm. However, the PLS modeling was unsuccessful for red and black rice samples most likely due to the interfering high absorption of red colored compounds. Compared to the existing techniques for analyzing individual compounds of the γ-oryzanol by high-performance liquid chromatography, the newly developed approach using UV-Vis spectroscopy combined with chemometrics is more practical, faster, and cost-efficient and mainly, solvent and residues free. HIGHLIGHTS A rapid method was developed to determine 4 major γ-oryzanol compounds in rice. This method integrates UV-Vis spectroscopy with PCA and PLS regression chemometrics. PCA successfully identified the distinction among white, red, and black rice types. Reliable PLS models were established for white rice with R2 values above 0.9. The developed approach is more practical, faster, and residue-free than HPLC. GRAPHICAL ABSTRACT

Ionically assembled hemostatic powders with rapid self-gelation, strong acid resistance, and on-demand removability for upper gastrointestinal bleeding.

Upper gastrointestinal bleeding (UGIB) is bleeding in the upper part of the gastrointestinal tract with an acidic and dynamic environment that limits the application of conventional hemostatic materials. This study focuses on the development of N-[(2-hydroxy-3-trimethylammonium) propyl] chitosan chloride/phytic acid (HTCC/PA, HP) powders with fast hemostatic capability and strong acid resistance, for potential applications in managing UGIB. Upon contact with liquids within 5 seconds, HP powders rapidly transform into hydrogels, forming ionic networks through electrostatic interactions. The ionic crosslinking process facilitates the HP powders with high blood absorption (3.4 times of self-weight), sufficient tissue adhesion (5.2 and 6.1 kPa on porcine skin and stomach, respectively), and hemostasis (within 15 seconds for in vitro clotting). Interestingly, the PA imparts the HP powders with strong acid resistance (69.8% mass remaining after 10 days of incubation at pH 1) and on-demand removable sealing while HTCC contributes to fast hemostasis and good wet adhesion. Moreover, the HP powders show good biocompatibility and promote wound healing. Therefore, these characteristics highlight the promising clinical potential of HP powders for effectively managing UGIB.

Time-Dependent Resistance of Sol–Gel HfO2 Films to In Situ High-Temperature Laser Damage

Laser damage in films under long-term high-temperature conditions is a significant concern for advancing laser applications. This study focused on HfO2 films prepared using the sol–gel method with HfCl4 as a precursor. It examined the effects of temperature on various properties of the films, including their optical properties, microstructure, surface morphology, absorption, and laser-induced damage threshold (LIDT). The prepared film demonstrated desirable characteristics at the high temperature of 423 K, such as high transmittance, low absorption, and high LIDT. As the duration of its high-temperature exposure increased, the LIDT of the films gradually decreased. An intriguing finding was that the film’s LIDT exhibited an exponential decay pattern with prolonged heating time. This observation could be attributed to the power-law increase in defects on both the internal and surface areas of the film as the duration of high-temperature exposure lengthened. Moreover, even after a 15-day heating period at 423 K, the film maintained an LIDT of 12.9 J/cm2, indicating its potential applicability in practical high-temperature environments. This study provided a general pattern and a universal formula for understanding the laser damage of sol–gel films at high temperatures over time. Furthermore, it opened possibilities for future developments of laser films suitable for extreme environments.

Investigation on CO2 capture performance of low-viscosity diamine non-aqueous absorbents with N-methyldiethanolamine regulation

In recent years, non-aqueous absorbents have attracted increasing attention due to their ability of significantly reducing sensible and latent heats in regeneration processes compared to conventional organic amine aqueous solution. But high viscosity of non-aqueous absorbents after CO2 absorption saturation became an obstacle to their industrial application. Here, a novel low-viscosity diamine non-aqueous absorbent for high-efficiency CO2 capture was proposed, in which N-methyldiethanolamine (MDEA) with steric hindrance effect was introduced as a regulator and dimethyl sulfoxide (DMSO) as a cosolvent. The effects of MDEA on CO2 capture performance of various non-aqueous absorbents and its regulation mechanism on CO2 absorbent viscosity were investigated systematically. Experimental results showed that when 25 wt% 2-(2-aminoethylamino)ethanol (AEEA) was screened as main CO2 absorption component, AEEA/MDEA/DMSO non-aqueous absorbent exhibited a high CO2 absorption capacity of 2.55 mol/kg and a fast CO2 absorption rate. Based on further mass fraction optimisation, it was found that the lowest viscosity of non-aqueous absorbents after CO2 absorption was 13.12 mPa s and the highest CO2 regeneration reached 93.5 % with AEEA and MDEA were 17.5 wt% and 12.5 wt%, respectively. 13C NMR tests showed that two characteristic peaks of carboxylated carbon appeared in CO2 products, which indicated that both amino groups on AEEA molecule were involved in CO2 absorption reaction. DFT calculations indicated that hydrogen bonding strength between MDEA and CO2 products was relatively lower than that of AEEA and CO2 products, which favored reducing absorbent saturation viscosity significantly. Thermodynamic analysis revealed that total regeneration energy consumption for 17.5 wt% AEEA/12.5 wt% MDEA/70 wt% DMSO non-aqueous absorbent was 1.72 GJ/t CO2, which was 53 % lower than that of MEA aqueous solution.

Enhancing the Sensitivity and Spatial Imaging Resolution of a Hybrid X-Ray Imaging Screen via Energy Transfer at the ZnS (Ag) and a Thermally Activated Delayed Fluorescence Interface.

Novel scintillation materials have played an indispensable role in the recent remarkable progress witnessed for X-ray imaging technology. Herein, a high-performance X-ray scintillation screen was developed based on a highly efficient hybrid system combining inorganic ZnS (Ag) with thermally activated delayed fluorescence (TADF) scintillator materials via an interfacial energy transfer (EnT) mechanism. ZnS (Ag) has a high X-ray absorption capacity and functions as the initial layer for efficiently converting high-energy X-ray photons into low-energy visible light (acting as a sensitizer) while also serving as an energy donor. The TADF component, on the contrary, is an energy acceptor and forms an active scintillating layer. By harnessing TADF chromophores that can efficiently capture both singlet and triplet excitons, our composite material offers a remarkable spatial imaging resolution of 24 line pairs per millimeter, surpassing those of the majority of existing organic and inorganic scintillators. Further, our interfacial energy transfer strategy effectively amplifies the radioluminescence intensity of the TADF scintillator by a factor of 75, offering an outstanding light yield of 38,000 photons/MeV. This advancement represents a remarkable breakthrough in organic X-ray scintillation technology and is a notable achievement within the X-ray imaging field, paving the way for novel applications in medical imaging and security inspection.

Robust Ultrablack Coating for Omnidirectional Broadband Light Absorption

AbstractDeveloping robust ultrahigh light absorption coatings has been a significant challenge, limited by the absorption‐adhesion tradeoff. Herein, a robust carbon‐based coating with omnidirectional broadband high absorption is designed and fabricated using a one‐step spray method. A novel rapidly cross‐linking resin is utilized as the binder to enhance adhesion. Beyond leveraging the intrinsic optical properties of carbon absorbents, the construction of a micro‐nano multi‐scale trapping structure is crucial for achieving high absorption efficiency in the coating. Innovatively, an inorganic matting agent is introduced to further diminish reflection by scattering incident light. The resulting ultrablack coating demonstrates good adhesion and an exceptionally high integral light absorption of 99.34% within the wavelength range of 1500–1800 nm, marking the highest reported value for binder‐incorporated spray coatings to date. This robust coating also exhibits outstanding thermal stability and resistance to vacuum thermal cycling and vibration. Furthermore, the application of the ultrablack coating via spraying is scalable and can be readily adapted to the surfaces or interiors of complex structural components made from diverse materials. The coating shows remarkable potential for solar energy harvesting and target stealth. This study presents a simple and efficient approach for developing robust ultrablack coatings suitable for widespread practical applications.

Carbazole-Based Dual-Band Electrochromic Polymers: The Effect of Linkage Sites on Electrochromic Performance.

Dual-band electrochromic (EC) materials are expected to be utilized as building materials for energy saving, but their cycle stability is still an obstacle. Here, two D-A conjugated polymers, PDPPCz36 and PDPPCz27, based on diketopyrrolopyrrole and carbazole linked with different sites, are synthesized. Both of them exhibit dual-band EC behaviors with a dark blue color in the neutral state and high absorption in the near-infrared (NIR) region when oxidized. However, PDPPCz36 exhibits better cycle stability and a shorter response time than PDPPCz27. In the visible (VIS) region, the PDPPCz36 film exhibits an initial light modulation range (ΔT) of 43.0% and that of the PDPPCz27 film is 41.3%. After 100 cycles of redox, the ΔT of the PDPPCz36 film declines by 32%, while that of PDPPCz27 attenuates by more than 50%. A similar tendency is evident in the NIR region. Moreover, PDPPCz36 shows subsecond colored switch times both in the VIS (0.4 s) and NIR (0.7 s) regions, while those of PDPPCz27 are 2.1 and 1.6 s, respectively. Further research suggests that 3,6-linked carbazoles in PDPPCz36 simultaneously inhibit the side reaction and film aggregation, which leads to better redox stability and shorter response time in both EC tests and devices.

Silk fibroin-based bioelectronic devices for high-sensitivity, stable, and prolonged in vivo recording

Silk fibroin, recognized for its biocompatibility and modifiable properties, has significant potential in bioelectronics. Traditional silk bioelectronic devices, however, face rapid functional losses in aqueous or in vivo environments due to high water absorption of silk fibroin, which leads to expansion, structural damage, and conductive failure. In this study, we developed a novel approach by creating oriented crystallization (OC) silk fibroin through physical modification of the silk protein. This advancement enabled the fabrication of electronic interfaces for chronic biopotential recording. A pre-stretching treatment of the silk membrane allowed for tunable molecular orientation and crystallization, markedly enhancing its aqueous stability, biocompatibility, and electronic shielding capabilities. The OC devices demonstrated robust performance in sensitive detection and motion tracking of cutaneous electrical signals, long-term (over seven days) electromyographic signal acquisition in live mice with high signal-to-noise ratio (SNR >20), and accurate detection of high-frequency oscillations (HFO) in epileptic models (200–500 Hz). This work not only improves the structural and functional integrity of silk fibroin but also extends its application in durable bioelectronics and interfaces suited for long-term physiological environments.

Synthesis and assessment of the Mo/MoO3/CZTS/Ag diode fabricated by one-pot hydrothermal route: impact of temperature

A facile one-step hydrothermal method was utilized to prepare Cu2ZnSnS4 film employing EDTA as a complexing agent. An effective Molybdenum oxide layer was also formed in the same approach for forming the Cu2ZnSnS4 film. The influence of preparation temperature on structural, morphology, and optical characteristics was studied. The formation of crystalline kesterite phase Cu2ZnSnS4 films with preferred orientation along the (112) plane was confirmed by X-ray diffraction and Raman spectroscopy, and it was also demonstrated that structure property changes with preparation temperatures: kesterite phase Cu2ZnSnS4 is formed at lower preparation temperatures and kesterite phase Cu2ZnSnS4 and Cu2S are formed with increasing preparation temperature. Also, Raman analysis confirmed the formation of a Molybdenum oxide layer on the Mo substrate. Field emission scanning electron microscopy revealed that surface morphology changes from leaves of trees to flake-flowers. According to UV-visible analysis, Cu2ZnSnS4 films exhibited high and wide absorbance spectra in the visible and infrared regions and a band gap between (1.67-1.9) eV. Photoluminescence analysis revealed emission peaks at (1.569, 1.55, and 1.56) eV for samples prepared at (160, 200, and 230)0C, respectively, which is very close to the band's gap of Cu2ZnSnS4. Finally, the electrical study of Mo/MoO3/CZTS/Ag junctions was performed by using current-voltage (I-V) measurement.

Investigation on indium concentration in two-terminal tandem indium gallium nitride solar cells by SCAPS-1D

Indium gallium nitride (InGaN) thin-film solar cell is a promising photovoltaic (PV) device. InGaN’s bandgap is tunable from 0.7 to 3.4 eV and it exhibits a high absorption coefficient exceeding 105 cm−1. Besides, InGaN solar cells can be used in tandem configuration, to effectively absorb the solar spectrum. Previous works found that increased indium (In) concentration leads to inverse relationship between open-circuit voltage (Voc) and power conversion efficiency (PCE) of the solar cell. This leads to deleterious device performance. This study aims to assess the performance of two-terminal InGaN tandem solar cells using SCAPS-1D simulation software. The findings revealed maximum short-circuit current density (Jsc) of 26.19 mA cm−2, open-circuit voltage (Voc) of 2.13 V, fill factor (FF) of 89.68%, and PCE of 30.17% from the tandem device. The results indicate that higher In concentration enhances light absorption and the overall PCE, with tandem cells outperforming single-junction cells. This study makes a valuable contribution to the advancement of high-efficiency solar technology based on InGaN.

Bending response and energy absorption of sandwich beams with combined reinforced auxetic honeycomb core

This study introduces a reinforced star-shaped auxetic honeycomb (RSSAH) sandwich beam, enhanced with hollow thin-walled tubes to improve bending resistance and energy absorption performance. The bending performance of the RSSAH is systematically investigated through quasi-static three-point bending tests and finite element numerical simulations. The findings suggest that when subjected to mid-span stress, the RSSAH displays both localized indentation and overall bending deformation, accompanied by notable negative Poisson’s ratio (NPR) impact under bending loads. Parametric studies are undertaken by numerical simulations to investigate the impact of compression position, auxetic angle, and face sheet thickness on the bending mode of the auxetic honeycomb sandwich beam. The analysis shows that the RSSAH can exhibit excellent bending performance and, at one of the compression positions, displays double-plateau stress characteristics. It is also found that altering key geometric parameters, such as the auxetic angle and panel thickness ratio, can greatly improve the bending capabilities of the RSSAH, achieving stable plastic deformation and high energy absorption. Finally, compared to star-triangle honeycomb (STH) sandwich beam, traditional reentrant honeycomb (RH) sandwich beam and star-shaped auxetic honeycomb (SSAH) sandwich beam, the RSSAH demonstrates superior bending performance and energy absorption capacity. This study offers insights and references for the development of innovative reinforced auxetic honeycomb sandwich beams.

JADES – the Rosetta stone of JWST-discovered AGN: deciphering the intriguing nature of early AGN

ABSTRACT JWST has discovered a large population of active galactic nuclei (AGN) at high redshift, which are weak in the X-rays. Here we present the NIRSpec spectrum of the most extreme of these objects, GN-28074, an AGN at $z=2.26$ with prominent hydrogen and He i broad lines, and with the highest limit on the bolometric to X-ray luminosity ratio among all spectroscopically confirmed AGN in GOODS. This source is also characterized by a mid-IR excess, likely associated with the AGN torus’ hot dust. The high bolometric luminosity and moderate redshift of this AGN allow us to explore its properties more in depth relative to other JWST-discovered AGN. The NIRSpec spectrum reveals prominent, slightly blueshifted absorption of H$\alpha$, H$\beta$, and He i $\lambda$10830. The Balmer absorption lines require gas with densities of $n_{\rm H}\gt 10^8~{\rm cm}^{-3}$, consistent with clouds in the broad-line region (BLR). This finding suggests that part of the X-ray weakness is due to high (Compton-thick) X-ray absorption by clouds in the BLR, or in its outer regions. GN-28074 is also extremely radio-weak. The radio weakness can also be explained in terms of absorption, as the inferred density of the BLR clouds makes them attenuate the radio emission through free–free absorption. Alternatively, the nuclear magnetic field may be underdeveloped, resulting both in intrinsically weak radio emission and lack of hot corona, hence intrinsic X-ray weakness. Finally, we show that recently proposed scenarios, invoking hyper-dense outflows or Raman scattering to explain the broad H$\alpha$, are ruled out.

Elucidating the Supramolecular Interaction of Positively Supercharged Fluorescent Protein with Anionic Phthalocyanines.

Developing bioinspired materials to convert sunlight into electricity efficiently is paramount for sustainable energy production. Fluorescent proteins are promising candidates as photoactive materials due to their high fluorescence quantum yield and absorption extinction coefficients in aqueous media. However, developing artificial bioinspired photosynthetic systems requires a detailed understanding of molecular interactions and energy transfer mechanisms in the required operating conditions. Here, the supramolecular self-assembly and photophysical properties of fluorescent proteins complexed with organic dyes are investigated in aqueous media. Supercharged mGreenLantern protein, mutated to have a charge of +22, is complexed together with anionic zinc phthalocyanines having 4 or 16 carboxylate groups. The structural characterization reveals a strong electrostatic interaction between the moieties, accompanied by partial conformational distortion of the protein structure, yet without compromising the mGreenLantern chromophore integrity as suggested by the lack of emission features related to the neutral form of the chromophore. The self-assembled biohybrid shows a total quenching of protein fluorescence, in favor of an energy transfer process from the protein to the phthalocyanine, as demonstrated by fluorescence lifetime and ultrafast transient absorption measurements. These results provide insight into the rich photophysics of fluorescent protein-dye complexes, anticipating their applicability as water-based photoactive materials.

Dimension-Dependent Nonlinear Optical Properties of Stanene Nanosheets.

Stanene (Sn)-based materials, with a graphene-like hexagonal structure, are now attracting considerable interest for potential applications in photoelectricity. However, the nonlinear optical properties of stanene remain largely unexplored. In this work, we prepared different sizes of stanene by liquid phase exfoliation and differential centrifugation methods, including two-dimensional (2D) Sn nanosheets (NSs) and zero-dimensional (0D) Sn nanodots (NDs). Z-scan measurements reveal that 2D Sn NSs exhibited high saturable absorption behavior, while the 0D Sn NDs led to reverse saturable absorption. Femtosecond ultrafast transient absorption spectra revealed that the reverse saturable absorption of Sn NDs is derived from a stronger excited state absorption and faster exciton relaxation dynamics. This research expands the potential applications of stanene in laser shielding and other ultrafast photonics technologies.

An adaptive assisted method based on MOPSO for THz MMA effective designing

Abstract To address the high time cost and low efficiency of traditional terahertz metamaterial absorber design, an adaptive method based on multi-objective particle swarm optimization was proposed. First, we presented a symmetric absorber of a four-split-ring resonator with a cross-shaped top layer. The structural parameters were optimized by the particle swarm optimization and multi-objective particle swarm optimization algorithms. The simulation results indicated that the multi-objective particle swarm optimization rapidly obtained geometric parameters that balance the high absorptivity and high quality factors. This method quickly identified a symmetric structure with absorptivity greater than 99% and quality factor of 377.45 at 1.584 THz. Additionally, the asymmetric structure achieved near-perfect absorption at 1.585 THz with a Q value of 281.32. By studying the electric field distribution and the surface current distribution, the physical mechanism of the absorber designed has been explained. This adaptive assisted method based on multi-objective particle swarm optimization can efficiently design metamaterial absorbers and offer an artificial intelligence strategy for terahertz functional device design.

Unveiling the recently synthesis noncentrosymmetric layered ASb3X2O12 (A = K, Rb, Cs, Tl; X = Se, Te) via first principles calculations

This study explores the structural, optical, and thermoelectric properties of non-centrosymmetric layered selenite and tellurite compounds KSb3Se2O12, RbSb3Se2O12, CsSb3Se2O12, TlSb3Se2O12, KSb3Te2O12, RbSb3Te2O12, CsSb3Te2O12, TlSb3Te2O12 to assess their potential for sustainable and renewable energy technologies. The selenite and tellurite compounds feature distinct non-centrosymmetric layered crystal structures, which are key to their unique optical and electronic properties. The materials display a layered structure without a center of symmetry, characterized by distinct atomic arrangements, and their band gaps vary depending on the constituent elements. For selenites, band gaps range from 2.97 eV to 3.19 eV, while for tellurites, they range from 2.75 eV to 3.02 eV, indicate their suitability for indirect semiconducting applications. The investigated materials exhibit high absorbance in the ultraviolet region, suggesting they are promising for solar cell applications. The energy loss function peaks at 14 eV, indicating minimal optical loss in the infrared and visible spectra. The static dielectric constants ε1(0) were calculated, showing variations based on the elemental composition. The response of ε2(ω) demonstrates strong interactions in the ultraviolet region, corresponding to electronic transitions from the valence to the conduction bands. Thermoelectric properties, evaluated with the BoltzTrap code using transport theory. The Seebeck coefficient of p-type semiconductors typically increases with temperature, but TlSb3Se2O12 shows an even greater increase, suggesting enhanced thermoelectric properties. Both selenites and tellurites have rising electrical conductivities, with ASb3Se2O12 peaking at 800 K. The Power Factor improves with temperature, reaching a peak for TlSb3Se2O12. These compounds exhibit favorable electrical conductivity and power factor, suggesting potential applications in thermoelectric systems. The figure of merit (ZT) values spanning from 0.90 to 1.51, with a maximum ZT value of 1.41 at 800 K, TlSb3Se2O12 shows great potential for high-temperature thermoelectric applications. These findings advance the understanding of non-centrosymmetric oxide materials and provide valuable insights for developing advanced materials for energy technologies.

Optimization of cubic SrZrO3 perovskite oxides under varying stress conditions for high-performance optoelectronic devices: a DFT study

PurposeThe study highlights our findings, including the confirmation of phase stability through XRD analysis, the characterization of optical properties revealing high absorption and conductivity and the analysis of mechanical stability through elastic constants. Additionally, we present detailed results on the band gap, EELS analysis and the suitability of SrZrO3 perovskite oxides for next-generation optoelectronic devices.Design/methodology/approachCubic SrZrO3 perovskite oxides were designed within the framework of density functional theory (DFT) via the CASTEP code under varying stress conditions (0–100 GPa), aiming to explore the key properties for diverse applications. The phase stability was confirmed by XRD analysis. From 0 to 40 GPa, there is an increase in the band gap from 3.330 to 3.615 eV, while it narrows from 3.493 to 3.155 eV beyond 60 GPa. The optical characteristics revealed high absorption, superior conductivity and a lower loss function. Significantly, the elastic constants (C11, C12 and C44) satisfy the Born-stability criterion, ensuring the mechanical stability of the compound. Additionally, the Poisson’s ratio, Pugh ratio (B/G), Frantsevich ratio, Cauchy pressure (PC) and anisotropy factor ensured both ductile and anisotropic characteristics. Higher values of Young’s modulus and shear modulus signify a superior ability to withstand longitudinal stresses. In the EELS analysis, distinctive energy-loss peaks resulting from absorption and emission correlated with diverse electronic transitions and energy levels associated with Sr, Zr and O atoms are used to probe the precise exploration of the electronic and optical characteristics of materials with a high degree of accuracy. Based on these findings, the designed SrZrO3 perovskite oxides are particularly suitable for applications in various optoelectronic devices.FindingsCASTEP codes were utilized to design the cubic SrZrO3 perovskite under varying stress conditions ranging from 0 to 100 GPa. The phase stability was confirmed through XRD analysis. A distinctive trend in the band gap was observed: an increase from 3.330 eV to 3.615 eV as the stress increased from 0 to 40 GPa and a decrease from 3.493 to 3.155 above 60 GPa. A higher absorption and conductivity and a lower loss function were found for the optical properties. The mechanical stability was ensured by elastic constants (C11, C12, and C44) satisfying the Born-stability criteria. Additionally, the Poisson’s ratio, Pugh’s ratio (B/G), Frantsevich ratio, Cauchy pressure (PC) and anisotropy factor were used to verify the ductility and anisotropy of the materials. Higher values of Young’s modulus and shear modulus indicate a superior ability to withstand longitudinal stresses. EELS analysis revealed distinctive energy-loss peaks associated with Sr, Zr and O atoms, enabling precise exploration of the electronic and optical characteristics with a high degree of accuracy. As expected, the designed SrZrO3 perovskite oxides exhibit favorable properties, making them particularly suitable for next-generation optoelectronic devices.Originality/valueIn this study, we utilized DFT within the CASTEP code framework to investigate the properties of cubic SrZrO3 perovskite oxides under varying stress conditions ranging from 0 to 100 GPa. Our research aimed to explore the key properties of SrZrO3 for diverse applications, particularly in optoelectronic devices.

Impact of Cost Structure on Indonesia Food Industry Value Added

The food industry is a consistently growing sector, even in challenging economic conditions, driven by population growth and increased demand. Recognizing its importance, the Indonesian government has identified the food and beverage industry as a key sector in its Industry 4.0 roadmap. However, challenges such as reliance on imported raw materials and high labor absorption rates persist. This study analyzes the impact of cost structure on the value-added in Indonesia's food industry from 2017 to 2021, using data from Indonesia Statistics on large and medium industries. The Panel Data Regression results reveal that raw material costs and fixed capital costs positively and significantly affect value-added. These findings suggest that effective cost management, innovation, and the use of advanced technology are crucial for optimizing value-added in this sector.

Mechanical, electrical, and piezoresistive properties of modified conductive recycled fine aggregate smart mortar

The application of recycled fine aggregates (RFA) in smart conductive mortar is of great significance for conserving natural resources and protecting the environment. However, the high water absorption and microstructural defects of RFA limit its widespread use in smart conductive mortar. This study employs an agar gel impregnation treatment containing graphite particles to improve the properties of RFA. The resulting modified conductive recycled fine aggregate (M-RFA) exhibited a 2.8 % reduction in water absorption. The workability, mechanical properties, electrical properties, and self-sensing capabilities of the modified recycled fine aggregate mortar (M-RFAM) were studied. It was found that the workability and mechanical properties of the smart conductive mortar prepared with M-RFA were slightly reduced but remained within acceptable ranges (28-day compressive strength greater than 33 MPa). At the same time, it achieved low resistivity and high strain-sensing sensitivity, with the highest strain-sensing sensitivity being 61.9 (30 times higher than ordinary strain gauges). The influence of loading rate and moisture content on the self-sensing ability of conductive mortar was also investigated, revealing a positive correlation between moisture content and stress-sensing ability. Furthermore, the study found that factors such as AC frequency, curing age, moisture content, and temperature significantly affect resistivity. These factors should be considered in practical applications and further research.

Dual-Mode cellulose acetate@Al2O3/MWCNTs Janus fabric with radiative cooling and solar heating for personal thermal management

Personal thermal management (PTM) textiles with heating and cooling functionalities are highly appealing due to their potential to offer personalized comfort while also contributing to decrease energy consumption. However, most PTM fabrics are static and unable to meet the human body’s thermal comfort needs during seasonal and ambient temperature fluctuations. Herein, this work presents a dual-mode Janus Metafabric to provide radiation cooling and solar heating. The cooling side of Metafabric (cellulose acetate@Al2O3 porous coating) offers high solar reflectance (92.12 %), infrared emissivity (83.22 %), and net cooling power of 55.85 W·m−2. The heating side (multi-walled carbon nanotubes) exhibits a high solar absorption rate (88.4 %). Compared with raw fabric, it can achieve an additional cooling of 4.58 °C and heating of 38.02 °C. In addition, Metafabric also have excellent ultraviolet resistance, wear resistance, and washing properties, making it suitable for practical wearing. By flipping the Janus fabric, it is easy to switch between the cooling and heating modes to adapt to dynamic ambient temperature changes, which have great potential for maintaining human thermal comfort and alleviating the energy crisis.