To address the control challenges of an aerial manipulator arm (AMA) mounted on a drone under conditions of model inaccuracy and strong disturbances, this paper proposes a hierarchical control architecture. In the upper-level control, Bézier curves are first used to generate smooth and continuous desired trajectory points, and the theory of singular trajectory lines along with a Radial Basis Function Neural Network (RBFNN) is introduced to construct a highly accurate multi-configuration inverse kinematic solver. This solver not only effectively avoids singular solutions but also enhances its precision online through data-driven methods, ensuring the accurate calculation of joint angles. The lower-level control focuses on optimizing the dynamic model of the manipulator. Using a Model Predictive Control (MPC) strategy, the dynamic behavior of the manipulator is predicted, and a rolling optimization process is executed to solve for the optimal control sequence. To enhance system robustness, an RBFNN is specifically introduced to compensate for external disturbances, ensuring that the manipulator maintains stable performance in dynamic environments and computes the optimal control commands. Physical prototype testing results show that this control strategy achieves a root mean square (RMS) error of 0.035, demonstrating the adaptability and disturbance rejection capabilities of the proposed method.