Hg Concentrations In Sediments Research Articles

Comprehensive analysis of mercury pollution in the surface riverine sediments in the Haihe Basin, China

The Haihe Basin extends over 318,000km2 or 3.3% of the total area of China, has a population of over 120 million, and is one of China's most polluted river basins. We investigated the pollution and risks from mercury (Hg) in surface riverine sediments of this basin and found that total Hg concentrations in surface sediments ranged from 0.001 to 1.05mg/kg and averaged 0.054mg/kg. Using the modified European Community Bureau of Reference standard method, we found that the exchangeable/acid-soluble, reducible, oxidizable, and residual fractions of Hg accounted for 9.86, 6.54, 11.0, and 72.6% of total Hg, respectively. The riverine sediments in the Da Qing He watershed had the highest anthropogenic enrichment of Hg (enrichment factor >1.5). There was a high potential ecological risk from Hg in the riverine sediments in the upper reaches of the Bei San He and Da Qing He watersheds, the middle reaches of the Luan He and Hei Long Gang watersheds, and the lower reaches of the Zi Ya He watershed. Comparison with risk assessment code showed that the riverine sediments in the Da Qing He, Luan He, and Tu-Hai Ma-Xia He watersheds represented a medium risk, with 16.6, 11.9, and 11.8% of Hg in the exchangeable/acid-soluble fraction, respectively.

Mercury, n-alkane and unresolved complex mixture hydrocarbon pollution in surface sediment across the rural–urban–estuarine continuum of the River Clyde, Scotland, UK

ABSTRACTSurface sediments (n=85) from a 160-km river-estuarine transect of the Clyde, UK, were analysed for total mercury (Hg), saturated hydrocarbons and unresolved complex mixtures (UCMs) of hydrocarbons. Results show that sediment-Hg concentration ranges from 0.01 to 1.38mgkg–1 (mean 0.20mgkg–1) and a spatial trend in Hg-content low–high–low–high, from freshwater source, to Glasgow, to estuary, is evident. In summary, sediment-Hg content is low in the upper Clyde (mean of 0.05Hg mgkg–1), whereas sediments from the Clyde in urbanised Glasgow have higher Hg concentrations (0.04 to 1.26mgkg–1; mean 0.45mgkg–1), and the inner estuary sediments contain less Hg (mean 0.06mgkg–1). The highest mean sediment Hg (0.65mgkg–1) found in the outer estuary is attributed to historical anthropogenic activities. A significant positive Spearman correlation between Hg and total organic carbon is observed throughout the river estuary (0.86; P<0.001). Comparison with Marine Scotland guidelines suggests that no sites exceed the 1.5mgkg–1 criterion (Action Level 2); 22 fall between 0.25 and 1.5mgkg–1 dry wt. (Action Level 1) and 63 are of no immediate concern (<0.25mgkg–1 dry wt.). Saturated (n-alkane) hydrocarbons in the upper Clyde are of natural terrestrial origin. By contrast, the urbanised Glasgow reaches and outer estuary are characterised by pronounced and potentially toxic UCM concentrations in sediments (380–914mg/kg and 103–247mgkg–1, respectively), suggesting anthropogenic inputs such as biodegraded crude oil, sewage discharge and/or urban run-off.

Estimates of recovery of the Penobscot River and estuarine system from mercury contamination in the 1960's

Mercury (Hg) was discharged in the late 1960s into the Penobscot River by a chlor-alkali production facility, HoltraChem. Using total Hg concentration profiles from 56 stations (58 sediment cores) in the Penobscot River (PBR), Mendall Marsh (MM), Orland River (OR) and Penobscot Estuary (ES), and sediment accumulation rates derived using detailed profiles of total Hg concentrations and radionuclide activities (137Cs, 239,240Pu, 210Pb), recovery from system-wide Hg pollution was assessed. Total Hg concentration profiles showed sharp maxima at depths attributed in time to a 1967 release date, and were divided into two sections: the first 21years (1967–1988; rapid recovery), and the recent 21years (1988–2009; slower recovery). The recent 21years of Hg input were used to estimate ‘apparent’ recovery rates, yielding exponentially decreasing total Hg concentrations. Apparent recovery half-times (T1/2=ln2/α) were calculated from an exponential fit of Hg(t)=Hg(t=21)∗exp(−α∗t)+Hg(∞) to total Hg concentration profiles over the past 21years (assuming Hg(∞) of 0, 100, or 400ngg−1). Mean T1/2 values were, at PBR 31years (16 of 24 cores), at MM 22years (9 of 11 cores), at ES 20 to 120years (mean of 78years; 12 of 18 cores), and at OR 69years (3 of 5 cores). In 18 out of 57 cores, concentrations either increased towards the surface or remained the same, indicating slower or incomplete ‘communication’ with the larger system. The Penobscot River and Estuary system has recovered substantially since 1967, and top 1cm sediment Hg concentrations (Hg(0)) from areas in rapid communication with the larger system are converging to 600–700ngg−1 (1967 maxima of 70,000+ngg−1). However, to recover from Hg(0) of 700ngg−1 to a Hg(∞) of <100ngg−1 would require 3 or more half-times.

A survey of metal concentrations in marine sediment cores in the vicinity of an old mercury-mining area in Karaburun, Aegean Sea.

The aim of this study was to assess the historical trends of metal concentrations in coastal sediments in the vicinity of an inactive mining area, find background values and contamination levels of metals around the Karaburun peninsula, and then search for other sources of mercury in marine sediment cores using multivariate statistical analysis and report the potential ecological risks from that metal contamination. Surface sediment samples were taken from seven stations. Water depths were less than 20m (coastal area) at stations KB07 and KB08. The depths at stations KB01, KB02, and KB03 were between 20 and 40m, and stations KB05 and KB06 were more than 40m (open area). In surface sediments at depths between 20 and 40m, Mo, Cu, Pb, Zn, Ni, Co, Fe, Cd, Ti, Zr, Sn, As, Y, and Hg levels revealed higher contamination factors (Cf) compared to those of the coastal and open areas. Also, sediment samples were taken for historical records at stations KB01 and KB02 for 2012. Metal concentrations of Cu, Zn, Ni, Co, As, Sb, Cr, Ba, Ti, Al, and Hg in the sediment core samples were significantly higher during the Holocene (~5700 BC to 2000 B.C.) and Medieval Warm periods (~1000 A.D. to 1400 A.D.) and tended to decrease towards the Little Ice Age (2200 B.C. to the birth of Jesus Christ). Background concentration of Hg in sediment was found as 1.67μg/g around the Karaburun peninsula. Average EF values higher than 20 were identified for As, Hg, Sb, and Ca. Ni and Hg levels were found above the PEL values. It was determined that the accumulation effect of Hg coming from the mafic rocks due to erosion in the marine environment was higher than that of Hg coming from the mine. The factor analyses showed an association between Hg, Ni, and Co. This reveals the importance of the contribution of mafic rocks reaching the marine environment by wave erosion. According to the factor analyses, high concentrations of Pb, Zn, Cd, As, Sb, Ba, Ti, and Zr were detected in the lithogenic sources.

Effect of Sediments on Bioaccumulation of Mercury in Fish Body in the Water-Level-Fluctuating Zone of the Three Gorges Reservoir Area

Mercury (Hg) in the aquatic environment is easy to accumulate in fish. In order to study the effect of the sediments on Hg accumulation in fish in the water-level-fluctuation zone of the Three Gorges Reservoir, we conducted a 90-days simulated flooding experiment by using the sediments with different concentrations of Hg. Our study showed that the concentrations of the total mercury (THg) and methyl mercury (MeHg) in the overlying water increased after flooding, and the concentrations in the muscle of fish kept increasing in the period of experiment, the concentrations in the viscera and head increased in the earlier period but seemingly decreased in the later period. The bioaccumulated Hg content in the fresh was higher than that in the viscera and head, between which there was no significant difference. Compared with the control group (no sediment), the presence of sediments obviously increased the content of Hg bioaccumulated in fish, and the bioaccumulated Hg level increased with the Hg concentrations in sediment. The THg and MeHg in different fish parts presented a similar variation trend with the BCF ranging 1.93×105-8.89×105 for MeHg and 1.3×103-12.8×103 for inorganic mercury, indicating that MeHg was more prone to accumulate in fish. The MeHg in fish was significantly related with THg, and accumulated MeHg occupied about 80.1% (muscle), 79.3% (visceral) and 66.7% (head) of increased THg. After the reflooding of the sediment in the water-level-fluctuating zone, net methylation could occur with MeHg as the product, and then MeHg would diffuse to overlay water, further increasing the Hg bioaccumulation in fish. Therefore, the potential pollution risk of Hg in the water-level-fluctuationg zone with large area of the Three Gorges Reservoir cannot be ignored.

Historical Characteristics of Contamination and Risk of Heavy Metals in Weishan Lake, China.

Combined with the dating analysis of 210Pb and 137Cs, the historical concentration and risk of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn in the core sediment of Weishan Lake were determined. Pollution concentrations, enrichment factor, geo-accumulation index, and ecological risk index of these metals and C/N ratio indicate that the natural inputs prevailed till early 1900s. From late 1970s onwards, the risk posed by these metals was significantly increased. Cu and Hg might cause adverse biological effects. The increase of soil erosion and wastewater discharge in the watershed promoted input and accumulation of these metals in the lake. The coal and petroleum industry in the catchment led the more accumulation of Hg, Cd and Cu in the lake.

Petroleum oil and mercury pollution from shipwrecks in Norwegian coastal waters

Worldwide there are tens of thousands of sunken shipwrecks lying on the coastal seabed. These potentially polluting wrecks (PPW) are estimated to hold 3–25milliont of oil. Other hazardous cargo in PPW includes ordnance, chemicals and radioactive waste. Here, we present and discuss studies on mercury (Hg) and oil pollution in coastal marine sediment caused by two of the >2100 documented PPW in Norwegian marine waters. The German World War II (WWII) submarine (U-864) lies at about 150m below the sea surface, near the Norwegian North Sea island of Fedje. The submarine is estimated to have been carrying 67t of elemental Hg, some of which has leaked on to surrounding sediment. The total Hg concentration in bottom surface sediment within a 200m radius of the wreckage decreases from 100g/kgd.w. at the wreckage hotspot to about 1mg/kgd.w. at 100m from the hotspot. The second wreck is a German WWII cargo ship (Nordvard), that lies at a depth of ca. 30m near the Norwegian harbor of Moss. Oil leakage from Nordvard has contaminated the bottom coastal sediment with polycyclic aromatic hydrocarbons (PAH). The findings from this study provide useful insight to coastal administration authorities involved in assessing and remediating wreck-borne pollution from any of the tens of thousands of sunken shipwrecks.

Role of Organic Carbon Sources and Sulfate in Controlling Net Methylmercury Production in Riverbank Sediments of the South River, VA (USA)

ABSTRACTMercury (Hg) transport and methylmercury (MeHg) production in riverbank sediments are complex processes influenced by site-specific physical and biogeochemical conditions. The South River watershed in VA, USA, contains elevated concentrations of Hg in riverbank and floodplain sediments, which has the potential to methylate. The role of specific organic carbon sources in promoting methylation reactions in natural sediments under dynamic flow conditions is not well understood. Four saturated column experiments were conducted, including a control column, which received South River water as an influent solution, and three columns that received South River water amended with: acetate (5.8 mM); lactate (5.7 mM); and lactate (5.7 mM) with SO42− (10.1 mM). The amendments were selected to promote growth of different microorganisms to gain an understanding of the microbial processes, controlling rates of methylation. The column receiving lactate and SO42− had the highest MeHg concentrations in the effluent and in the pore water near the effluent at 1.8 and 4.9 μg L−1, respectively. At the cessation of the column experiments, the lactate–sulfate column sediments contained the highest populations of enumerable sulfur-reducing bacteria and the highest solid-phase MeHg at 530 ± 100 ng g−1 dry wt. from the interval closest to the influent. The results suggest that the form and availability of electron donors and acceptors are primary factors controlling rates of methylation in the South River sediment.

Long-term scenarios of mercury budgeting and exports for a Mediterranean hot spot (Marano-Grado Lagoon, Adriatic Sea)

The Marano-Grado Lagoon (MGL) is extensively contaminated by mercury (Hg) from local sources and long-term (500 years) tidally delivered inputs from the Idrija Hg mine (Slovenia) through Isonzo River suspended loads.A multibox WASP-7 (Water Analysis Simulation Program) model was used to simulate the long-term dynamics of the mercury cycle in the MGL.Scenario simulations were used to compute changes in the system over 100 years. Present and future Hg concentrations in water, sediment, and Hg budgets were compared, including evasion and MeHg inputs to the Mediterranean Sea, based on climate changes and mercury capping in tributary rivers.Using the Ref baseline scenario, the model computes a general decrease in HgT of 13% in the water column and of 80% in sediment and a strong MeHg increase in sediment (+73%). The net sea export of HgT decreases by 57% to up to 48 kg/y while MeHg increases by 10% to up to 0.63 kg/y.The lagoon sediment recovery time of HgT up to a target level of 0.3 mg/kg is computed over 570 years for surface sediments (1750 for subsurface sediments). When removing Hg from boundaries, the same target value for surface sediments is reached within 110 years.

Mercury and Methylmercury Dynamics in Sediments on a Protected Area of Tagus Estuary (Portugal)

The Tagus Estuary is one of the most Hg-contaminated estuaries in SW Europe. Sediment cores were sampled at two low Hg-contaminated sites inside the natural park, Alcochete (ALC) and Vale Frades (VF), and analyzed for mercury and methylmercury. Concentrations of Hg and MeHg in sediments were below 1 μg g−1 and 4.4 ng g−1, respectively. While in summer organic matter and/or excess SO4 2− promotes Hg methylation, in winter, Hg availability is the sole driver for methylation. Diffusive fluxes in the sediment/water interface show a sink of Hg species in the ALC site (ca. 170 mg year−1 of Hg and 60 mg year−1 of MeHg), while in the VF area, a sink of MeHg (ca. 1900 mg year−1) as well as a source of Hg (ca. 2000 mg year−1) is observed. The morphology and hydrodynamic regime of the Tagus Estuary seem to influence Hg dynamics even in areas with low levels of Hg contamination.

Is mercury from small-scale gold mining prevalent in the southeastern Peruvian Amazon?

There is an ongoing debate on the fate of mercury (Hg) in areas affected by artisanal and small-scale gold mining (ASGM). Over the last 30 years, ASGM has released 69 tons of Hg into the southeastern Peruvian Amazon. To investigate the role of suspended matter and hydrological factors on the fate of ASGM-Hg, we analysed riverbank sediments and suspended matter along the partially ASGM-affected Malinowski-Tambopata river system and examined Hg accumulation in fish. In addition, local impacts of atmospheric Hg emissions on aquatic systems were assessed by analysing a sediment core from an oxbow lake. Hg concentrations in riverbank sediments are lower (20–53 ng g−1) than in suspended matter (∼400–4000 ng g−1) due to differences in particle size. Elevated Hg concentrations in suspended matter from ASGM-affected river sections (∼1400 vs. ∼30–120 ng L−1 in unaffected sections) are mainly driven by the increased amount of suspended matter rather than increased Hg concentrations in the suspended matter. The oxbow lake sediment record shows low Hg concentrations (64–86 ng g−1) without evidence of any ASGM-related increase in atmospheric Hg input. Hg flux variations are mostly an effect of variations in sediment accumulation rates. Moreover, only 5% of the analysed fish (only piscivores) exceed WHO recommendations for human consumption (500 ng g−1). Our findings show that ASGM-affected river sections in the Malinowski-Tambopata system do not exhibit increased Hg accumulation, indicating that the released Hg is either retained at the spill site or transported to areas farther away from the ASGM areas. We suspect that the fate of ASGM-Hg in such tropical rivers is mainly linked to transport associated with the suspended matter, especially during high water situations. We assume that our findings are typical for ASGM-affected areas in tropical regions and could explain why aquatic systems in such ASGM regions often show comparatively modest enrichment in Hg levels.

Geochemistry and mercury contamination in receiving environments of artisanal mining wastes and identified concerns for food safety

Artisanal small-scale gold mining (ASGM) using mercury (Hg) amalgamation has been occurring on Buru Island, Indonesia since early 2012, and has caused rapid accumulation of high Hg concentrations in river, estuary and marine sediments. In this study, sediment samples were collected from several sites downstream of the Mount Botak ASGM site, as well as in the vicinity of the more recently established site at Gogrea where no sampling had previously been completed. All sediment samples had total Hg (THg) concentrations exceeding Indonesian sediment quality guidelines and were up to 82 times this limit at one estuary site. The geochemistry of sediments in receiving environments indicates the potential for Hg-methylation to form highly bioavailable Hg species. To assess the current contamination threat from consumption of local seafood, samples of fish, molluscs and crustaceans were collected from the Namlea fish market and analysed for THg concentrations. The majority of edible tissue samples had elevated THg concentrations, which raises concerns for food safety. This study shows that river, estuary and marine ecosystems downstream of ASGM operations on Buru Island are exposed to dangerously high Hg concentrations, which are impacting aquatic food chains, and fisheries resources. Considering the high dietary dependence on marine protein in the associated community and across the Mollucas Province, and the short time period since ASGM operations commenced in this region, the results warrant urgent further investigation, risk mitigation, and community education.

BIOMONITORING DAMPAK EKOLOGIS MERKURI DI DAERAH ALIRAN SUNGAI TORAUT KABUPATEN BOLAANG MONGONDOW

ABSTRACT Traditional gold mining in Toraut Watershed Bolaang Mongondow District was used Merkuri Amalgamation that produced tailing. Tailing are discharged to river and environment sorounding that can enter Toraut River and flows to the down stream Mongondow river (beach Inobonto). This study aims: 1) To determine Hg concentrations in River Toraut up stream, middle stream and down stream; 2) To determine Hg concentrations in sediment of the River Toraut up stream, middle stream and down stream; 3) To determine Hg concentrations in aquatic plantsof the River Toraut up stream, middle stream and down stream. Location research in River Toraut up stream, middle stream and down stream. Data collected by observation and laboratory analysis Merkuri concentration in River Toraut, sediment, and aquatic plant. Method data analysis are descriptif, Graphic Method and to compare with standart Goverment PP. No.82/2001 Class II. The analysis showed that the concentration of Merkuri in River Toraut up stream, in the middle stream and down stream is&lt;0.00005 mg/l. The concentration of Merkuri in sediments River Toraut up stream, the middle stream and down stream ranged &lt; 0.05-1.45 mg/kg dry. The concentration of Merkuri in tissue plant aquatic location up stream of the River Toraut, the middle stream and down stream range &lt; 0.001-0.013 mg /kg wet.Keywords : biomonitoring, ecological impacts merkuri, Toraut Watershed

Pollution characteristics of mercury (Hg) in surface sediments of major basins, China

To investigate the pollution status and potential pollution risk of mercury (Hg) in China, surface sediment samples were collected from eight hundred and eighty-one sites, including ten major basins (Songhua River Basin (SRB), Liao River Basin (LRB), Hai River Basin (HRB), Yellow River Basin (YRB), Huai River Basin (HuRB), Yangtze River Basin (YtRB), Pearl River Basin (PRB), Southeastern River Basin (SeRB), Southwestern River Basin (SwRB) and Northwestern River Basin (NwRB)). Results showed that Hg concentrations in sediments of ten basins in China ranged from 0.001 to 8.800mg/kg, with average±S.D. value of 0.274±0.675mg/kg, which was obviously higher than Chinese soil background value (0.038mg/kg) and Chinese sediment background value (0.040mg/kg). The mean Hg concentration of ten basins decreased in the order of HRB>YtRB>SRB>PRB>HuRB>SwRB>YRB>SeRB>LRB>NwRB. Moreover, it was found that the Hg concentrations in the sediments of LRB, YtRB, PRB, SeRB and SwRB were partly driven by their total organic carbon (TOC) contents, while the effect of pH on the distribution of Hg was not obvious. The Hg concentration data were also compared with those got in other periods (1994–2015) to obtain the general variation tendency of Hg level. It was recorded that Hg concentrations in HRB have remained on high levels for a long history, while Hg contamination situation in YRB after 2004 has potentially turned to be better. The results of pollution assessment by sediment quality assessment guidelines (SQGs), contamination factor (CF), geoaccumulation index (Igeo) and potential ecological risk (Ei) suggested that YRB and HRB were the most seriously polluted river basins among the ten basins. It is urgent of constructing SQGs in China to scientifically evaluate the Hg pollution in the future.

Fluvial geomorphology and aquatic‐to‐terrestrial Hg export are weakly coupled in small urban streams of Columbus, Ohio

AbstractAlthough mercury (Hg) contamination is common in stream ecosystems, mechanisms governing bioavailability and bioaccumulation in fluvial systems remain poorly resolved as compared to lentic systems. In particular, streams in urbanized catchments are subject to fluvial geomorphic alterations that may contribute to Hg distribution, bioaccumulation, and export across the aquatic‐to‐terrestrial boundary. In 12 streams of urban Columbus, Ohio, we investigated the influence of fluvial geomorphic characteristics related to channel geometry, streamflow, and sediment size and distribution on (1) Hg concentrations in sediment and body burdens in benthic larval and adult emergent aquatic insects and (2) aquatic‐to‐terrestrial contaminant transfer to common riparian spiders of the families Pisauridae and Tetragnathidae via changes in aquatic insect Hg body burdens as well as in aquatic insect density and community composition. Hydrogeomorphic characteristics were weakly related to Hg body burdens in emergent insects (channel geometry) and tetragnathid spiders (streamflow), but not to Hg concentrations in sediment or benthic insects. Streamflow characteristics were also related to emergent insect density, while wider channels were associated with benthic insect community shifts toward smaller‐bodied and more tolerant taxa (e.g., Chironomidae). Thus, our results provide initial evidence that fluvial geomorphology may influence aquatic‐to‐terrestrial contaminant Hg transfer through the collective effects on emergent insect body burdens as well as on aquatic insect community composition and abundance.

Mercury dilution by autochthonous organic matter in a fertilized mangrove wetland

A dated sediment core from a highly-fertilized mangrove wetland located in Cubatão (SE Brazil) presented a negative correlation between mercury (Hg) and organic carbon contents. This is an unusual result for a metal with well-known affinity to organic matter. A dilution of Hg concentrations by autochthonous organic matter explained this observation, as revealed by carbon stable isotopes signatures (δ13C). Mercury dilution by the predominant mangrove-derived organic matter counterbalanced the positive influences of algal-derived organic matter and clay contents on Hg levels, suggesting that deleterious effects of Hg may be attenuated. Considering the current paradigm on the positive effect of organic matter on Hg concentrations in coastal sediments and the expected increase in mangrove organic matter burial due to natural and anthropogenic stimulations of primary production, predictions on the influences of organic matter on Hg accumulation in mangrove wetlands deserve caution.

Mercury profiles in sediment from the marginal high of Arabian Sea: an indicator of increasing anthropogenic Hg input.

Total Hg distributions and its speciation were determined in two sediment cores collected from the western continental marginal high ofIndia. Total Hg content in the sediment was found to gradually increase (by approximately two times) towards the surface in both the cores. It was found that Hg was preferentially bound to sulfide under anoxic condition. However, redox-mediated reactions in the upper part of the core influenced the total Hg content in the sediment cores. This study suggests that probable increase in authigenic and allogenic Hg deposition attributed to the increasing Hg concentration in the surface sediment in the study area.

Persistent Hg contamination and occurrence of Hg-methylating transcript (hgcA) downstream of a chlor-alkali plant in the Olt River (Romania).

Chlor-alkali plants using mercury(Hg) cell technology are acute point sources of Hg pollution in the aquatic environment. While there have been recent efforts to reduce the use of Hg cells, some of the emitted Hg can be transformed to neurotoxic methylmercury (MeHg). Here, we aimed (i) to study the dispersion of Hg in four reservoirs located downstream of a chlor-alkali plant along the Olt River (Romania) and (ii) to track the activity of bacterial functional genes involved in Hg methylation. Total Hg (THg) concentrations in water and sediments decreased successively from the initial reservoir to downstream reservoirs. Suspended fine size particles and seston appeared to be responsible for the transport of THg into downstream reservoirs, while macrophytes reflected the local bioavailability of Hg. The concentration and proportion of MeHg were correlated with THg, but were not correlated with bacterial activity in sediments, while the abundance of hgcA transcript correlated with organic matter and Cl(-) concentration, indicating the importance of Hg bioavailability in sediments for Hg methylation. Our data clearly highlights the importance of considering Hg contamination as a legacy pollutant since there is a high risk of continued Hg accumulation in food webs long after Hg-cell phase out.

Heavy metal spatial variation, bioaccumulation, and risk assessment of Zostera japonica habitat in the Yellow River Estuary, China

Globally, seagrass habitats are decreasing due to both natural and environmental contaminations by human activities, including heavy metal pollution. To expand the global seagrass detection network, this study reports the spatial distributions of Zostera japonica seagrass habitats in the Yellow River Estuary, China. In addition, heavy metal concentrations of Z. japonica tissue, sediment, and surface seawater were analyzed to determine the bioaccumulation and consequent ecological risk to Z. japonica habitats due to the effects of heavy metals. It was found that concentrations of heavy metals were 1.00–2.03 times higher in seagrass-rooted sediment than in adjacent non-seagrass sediment, except for Mn (with a factor of 0.99). Pb and Hg concentrations in sediments exceeded background values more than the other heavy metals, by factors of 1.74 and 1.24, respectively. Metal concentrations in the surrounding seawater were 2.60–4.63 times higher at seagrass sites than at non-seagrass sites, except for Hg (factor of 0.97). Metal concentrations were much higher in seagrass tissues than in the sediment (e.g., bioconcentration factor of Cd is 30.95). Pb concentrations in water may cause the greatest adverse reactions among aquatic organisms, while As, Cr, Hg, Mn and Cu in sediments may occasionally cause negative ecological effects. Z. japonica showed higher bioaccumulation of Cd and Pb in the above-ground tissues. Among other recent studies of seagrasses from other parts of the world, Cd concentrations are similar to the results of the present study, but Pb concentration in present study is higher than in other studies. In conclusion, Pb and As in the surrounding environment present potential risks to the seagrass habitats of the Yellow River Estuary, China.

Microelement composition of bottom sediments in Mekong River delta, Republic of Vietnam

Mean concentrations of Zn, Cu, Pb, Cd, As, and Hg in water and bottom sediments of Mekong Delta (Socialist Republic of Vietnam) over low-water period of 2013 were evaluated. The space distribution of the chemical composition of bottom sediments shows a tendency toward an increase in the concentrations of the examined microelements toward the sea coastline. The mechanism of those changes was considered and attributed to a release of low-solubility compounds from water and with sorption of microelements on alluvium and sediment particles at the mixing of river and sea water. The value of surface water pH was suggested as an indicator of current and forecasted variations of the concentrations of some microelements in bottom sediments.