Hf Isotopic Signatures Research Articles

U–Pb age and Hf isotopic composition of detrital zircons from the modern river of the South Tianshan orogenic belt and their implications for Palaeozoic tectonic and crustal evolution

The U–Pb and Lu–Hf isotopic research of detrital zircons was carried out in southern modern rivers of the South Tianshan (STS) orogenic belt to understand the accretionary processes and crustal evolution in this region. Detrital zircons from river sands yield two dominant age populations at 460–390 Ma and 310–260 Ma with several Precambrian age groups. Such age patterns imply that the significant magmatic events occurred during the Palaeozoic in the STS. Comparative studies on U–Pb age of the detrital zircons from northern and southern river sands in the STS belt provide constraints on the tectonic evolution of the STS belt and its surrounding blocks. Abundant 500–460 Ma detrital zircons in northern river sands probably reflect a bidirectional subduction of the Palaeozoic Central Tianshan Ocean under the Yili Block and the Central Tianshan Block. The 460–390 Ma zircon population in both northern and southern river sands likely implies a bidirectional subduction of the South Tianshan Ocean. A lack of the 380–320 Ma zircon grains in the southern river sands may indicates the northward subduction of the South Tianshan Ocean. A final collision between the Tarim Craton and the south‐western Central Asian Orogenic Belt possibly took place in the Late Carboniferous; the 310–260 Ma zircon population in both northern and southern river sands suggests syn‐ and post‐collisional magmatism. Based on the Hf isotopic signatures in the detrital zircon and magmatic zircons, we propose new constraints on the Palaeozoic crustal evolution of the STS. The continent formation in the STS belt was characterised by reworking of the ancient crust in a compressional environment during the Ordovician (ca. 460–440 Ma). Abundant significant juvenile materials progressively added to the crust through time in an extensional tectonic regime since Late Ordovician to Devonian (ca. 440–390 Ma). The crustal formation is mainly dominated by reworking of the Precambrian basement rocks with limited contribution of juvenile components input into magma formation during Late Carboniferous to Early Permian (ca. 310–260 Ma).

Combined Zircon, Molybdenite, and Cassiterite Geochronology and Cassiterite Geochemistry of the Kuntabin Tin-Tungsten Deposit in Myanmar

AbstractThe Kuntabin Sn-W deposit, located in southern Myanmar, is characterized by abundant greisen-type and quartz vein-type cassiterite and wolframite mineralization. We have conducted multiple geochronological methods and isotope and trace element analyses to reveal the age and evolution of the Kuntabin magmatichydrothermal system.Zircon U-Pb dating of the two-mica granite yielded a weighted mean 206Pb/238U age of 90.1 ± 0.7 Ma. Cassiterite U-Pb dating provided a lower intercept age of 88.1 ± 1.9 Ma in the Tera-Wasserburg U-Pb concordia diagram. Molybdenite Re-Os dating returned a weighted mean model age of 87.7 ± 0.5 Ma and an isochron age of 88.7 ± 2.7 Ma. These ages indicate a genetic relationship between granite and Sn-W mineralization in the Kuntabin deposit and record the earliest magmatism and Sn-W mineralization in the Sibumasu and Tengchong terranes related to subduction of the Neo-Tethys oceanic slab. Three generations of cassiterite have been identified with distinctive cathodoluminescence textures and trace element patterns, indicating the episodic input of ore-forming fluids and distinctive changes in the physical-chemical conditions of the Kuntabin magmatichydrothermal system. Sudden changes of fluid pressure, temperature, pH, etc., may have facilitated the deposition of Sn and W. Rhenium contents of molybdenite from the Kuntabin deposit and many other Sn-W deposits in Myanmar are characteristically low compared to porphyry Cu-Mo-(Au) deposits worldwide. In combination with zircon Hf isotope signatures, we infer that granites associated with Sn-W deposits in Myanmar were predominantly derived by melting of ancient continental crust and contain minimal mantle contribution.Subduction of the Neo-Tethys oceanic slab from west of the West Burma terrane reached beneath the Sibumasu terrane and led to magmatism and Sn-W mineralization at ~90 Ma when the Kuntabin deposit was formed. The Paleoproterozoic Sibumasu crust was activated during the subduction-related magmatism to form predominantly crust derived melts. After a high degree of fractional crystallization and fluid exsolution, physical-chemical changes of the hydrothermal fluid resulted in Sn and W precipitation to form the Kuntabin Sn-W deposit.

Switching from advancing to retreating subduction in the Neoproterozoic Tarim Craton, NW China: Implications for Rodinia breakup

Geodynamic drivers for the supercontinent cycle are generally attributed to either top-down (subduction-related) or bottom-up (mantle-related) processes. Compiled geochemical data and U–Pb ages and Hf isotopic signatures for magmatic and detrital zircons from the Tarim Craton reveal a distinct change in subduction style during the Neoproterozoic. The subduction cycle is recorded in increasing and decreasing intensity of subduction-related magmatic rocks and time-equivalent sedimentary successions, and converse trends of εHf(t) values and corresponding changes in crustal incubation time. These trends are consistent with a switch from advancing to retreating subduction. The switch likely occurred at ca. 760 Ma when zircon εHf(t) values increase and crustal incubation times decrease following a transitional shift between 800 ​Ma and 760 ​Ma. A switch at this time is consistent with Rodinia breakup and may have resulted in the late Neoproterozoic Tarim rift basin. The long-lived (ca. 500 Ma) subduction recorded in the Tarim Craton suggests the predominance of a top-down process for Rodinia breakup on this part of its margin.

Late Neoarchean granites in the Qixingtai region, western Shandong: Further evidence for the recycling of early Neoarchean juvenile crust in the North China Craton

The Neoarchean basement rocks of the Qixingtai region in the northwest of western Shandong, eastern North China Craton are divided into western and eastern domains, separated by a ductile shear zone. The western domain is mainly composed of early Neoarchean tonalitic and supracrustal rocks, and the eastern domain is composed of late Neoarchean crustally‐derived granite with diverse early Neoarchean enclaves up to several kilometres long of supracrustal and gneissic TTG‐diorite rocks. This study reports an integrated field, whole‐rock geochemistry and zircon U–Pb‐Hf study on the granites and their enclaves in the eastern domain. The supracrustal enclaves are mainly composed of meta‐basaltic and meta‐ultramafic rocks and are the same in lithological association and formation time as the 2,750–2,700 Ma Liuhang “Formation” in the western area. The TTG‐diorite enclaves can be divided into early and late groups. Magmatic zircons from early TTG‐diorite samples have U–Pb ages of 2,731 ± 17 to 2,748 ± 13 Ma and εHf(t) values of +2.7 to +9.5, whereas trondhjemite samples of the late group have U–Pb zircon ages of 2,588 ± 18 to 2,606 ± 12 Ma and εHf(t) values of +0.6 to +6.5. The Hf isotopic signatures on magmatic zircon from the >2,700 Ma diorite‐tonalites indicate that they are predominantly juvenile crustal additions, probably with minor involvement of older crust in their genesis, as given by tDM (Hf) ages ranging back to 2.92 Ga. The eastern granites range from monzogranite to syenogranite in composition and commonly have negative Eu anomalies, indicating residual plagioclase in the source region. Magmatic zircons from two granite samples have U–Pb ages of 2,516 ± 24 and 2,527 ± 18 Ma and εHf(t) values of +1.0 to +7.0. A fine‐grained syenogranite dyke contains inherited early Neoarchean zircons with εHf(t) values of +1.6 to +7.4. The isotopic signatures of the late Neoarchean granites that dominate the eastern domain show that they were derived from partial melting recycling of older continental crust recognized in the region – early Neoarchean rocks formed as a result of juvenile crustal additions. This is a common signature for late Archean crustal evolution throughout much of the North China Craton, and is the hallmark of some other Archean terranes, such as the Dharwar Craton of south India. The geodynamic explanations for the formation globally of vast amounts of crustally‐derived late Neoarchean granite are discussed.

Slab-controlled elemental–isotopic enrichments during subduction initiation magmatism and variations in forearc chemostratigraphy

Supra-subduction zone (SSZ) ophiolites formed in forearc settings and the Izu–Bonin–Mariana (IBM) in-situ forearc show conversions from normal mid-ocean ridge basalt (MORB) to boninitic affinities, which are widely interpreted as rules for the evolving chemical geodynamics of subduction initiation magmatism (SIM). Nevertheless, forearc sequence generated by subduction initiation need not always include boninitic rocks. Here we reconstruct a forearc chemostratigraphy without boninitic affinity based on the Central Palawan and Amnay (CPA) ophiolites of the west Philippines to show diversity in melt evolution of SIM. Zircon U–Pb dating on the MORB-type Amnay gabbros reveal a 10 m.y. of seafloor spreading from 33 to 23 Ma. These ages together with the progressively enriched zircon in-situ oxygen isotopes (δ18O= 1.62–10.1‰) and whole rock elemental and Nd–Hf isotopic signatures ([La/Yb]N= 0.19–3.45; Nb/Yb= 0.07–5.24; εNd= 2.1–10.2; εHf= 11.2–24.1) indicate that the depleted MORB mantle (DMM)-type source of the Amnay ophiolite was getting enriched by fluxing of aqueous slab fluid in the early stage followed by addition of adakitic and Nb-enriched slab melts in the later stage. This distinct mantle evolution together with higher εHf at a given εNd of the Amnay mafic samples than the contemporaneous South China Sea (SCS) oceanic samples do not support previous interpretation that the Amnay ophiolite was a fragment of the SCS. However, the 33–23 Ma Amnay ophiolite can be the younger part of the 34 Ma forearc-type Central Palawan ophiolite, and both (i.e. the CPA ophiolites) represent on-land fragments of the NW Sulu Sea. We propose that the 34–23 Ma CPA ophiolites and the NW Sulu Sea constitute forearc basin of the late Oligocene–middle Miocene island arc–backarc basin duo of the Cagayan Ridge and SE Sulu Sea, associated with subduction of the Cretaceous to Eocene Proto-SCS since 34 Ma. The CPA ophiolites lack boninite but show geochemical progression from normal to enriched MORB affinities, whose melt evolution differs from that of the IBM SIM. We attribute the differences in SIM and variations in forearc chemostratigraphy to the subduction of a younger slab with thick terrigenous sediment cover of the Proto-SCS versus an older slab with thin pelagic sediment cover of the Pacific Plate.

Sandstone provenance analysis in Longyan supports the existence of a Late Paleozoic continental arc in South China

Because of the limited magmatic and metamorphic record, the Late Paleozoic tectonic setting in South China remains controversial. This paper presents sedimentologic data and provenance analysis of Upper Paleozoic sandstones in Longyan, which are rich in quartz (73–90%) and poor in lithic fragments (2–12%) and feldspar (3–25%). Devonian sandstones contain mostly metamorphic lithic fragments (e.g., quartzite), whereas Carboniferous-Permian sandstones contain mostly felsic volcanic and subvolcanic lithic fragments indicating provenance from felsic volcanic rocks. Detrital zircon U-Pb age spectra of Devonian-Carboniferous sandstones display modes at ~440 Ma and 420–380 Ma, with subordinate Mesoproterozoic age components, pointing at the Nanling terrane and the western-middle part of the Wuyi terrane as most likely ultimate sediment sources. Permian sandstones inherited the age components mentioned above, but also include peaks at ~290 Ma and ~1850 Ma. The ~290 Ma component corresponds to the age of Late Paleozoic magmatism in southeastern China and southwest Japan. Numerous detrital zircons aged at 350–250 Ma also occur in Permo-Triassic strata exposed across South China and southwest Japan. Based on regional data and on the ages and Hf isotope signatures of detrital zircon, we infer that a Late Paleozoic continental arc existed in the coastal area of southeastern China and contributed detritus to the adjacent sedimentary basins. The Permo-Triassic igneous rocks locally exposed in the area may represent the remnant of that continental arc. Arc growth may have been responsible for the westward retreat of a broad Upper Paleozoic carbonate platform.

Rifting of the Kaapvaal Craton during the early Paleoproterozoic: Evidence from magmatism in the western Transvaal subbasin (South Africa)

The Neoarchean to Paleoproterozoic (ca. 2.65–2.06 Ga) Transvaal Supergroup of the Kaapvaal Craton is dominated by clastic and chemical sedimentary rocks, with few strata-bound igneous units. Two ca. 2.2 Ga igneous units in its upper part (Pretoria Group), the Machadodorp Member of the Silverton Formation and the Mashishing dyke swarm, have so far only been recognized in the eastern part of the Transvaal subbasin. As these units are near-contemporaneous with an early Paleoproterozoic geochemical excursion to higher Th/Nb ratios compared to both older and younger igneous units, they probably mark a change in the geodynamic evolution of the craton. In the present contribution, we provide new data on the igneous units within the Silverton Formation (one lava and 5 sills) from a borehole (BB11) in the south-western part of the Transvaal subbasin. Two of these igneous units are particularly interesting because they show strong geochemical similarities to the Machadodorp Member and Mashishing dyke swarm, which are thus more spatially extensive than previously thought. In combination with existing data, our results further show that the Machadodorp Member corresponds to two separate, possibly not co-magmatic, igneous events, as documented by low- and high-Th basalts. The low-Th lavas show flat mantle-normalized REE and multi-element patterns, along with depleted Nd and Hf isotopic signatures, which are unusual among Precambrian magmatic rocks in the craton. This signature can be explained by partial melting of a depleted spinel peridotite incorporated into the subcratonic lithospheric mantle (SCLM) by a prior subduction event. A failed rifting event can have triggered melting of such a shallow source in a cratonic context. Even though comparable in age, the high-Th ca. 2.2 Ga Mashishing dyke swarm comes from a very different source, likely a part of the SCLM that had experienced subduction-related fluid metasomatism around the Archean – Proterozoic transition. About 150 million years later, the Bushveld Complex possibly exploited the same rifting structures during its intrusion.

Removal of continental lithosphere beneath the Canary archipelago revealed from a U[sbnd]Pb Age and Hf/O isotope study of modern sand detrital zircons

We present new geochemical, UPb age, HfO isotope compositions for more than 400 detrital zircons collected from modern sands located throughout western Fuerteventura, Canary Islands as a proxy for the timing and origin of its plutonic history. This approach provides a new perspective and more complete time-integrated record of the islands geologic evolution. Fuerteventura UPb detrital zircon age spectra document that magmatism was initiated at ~35 Ma, was most prolific during the main shield-building stage (30–15 Ma), youngs southward, corroborates the existence of a low magma fluxing period (15–6 Ma), and provides new evidence for the existence that Pliocene and younger (at least as young as 0.24 ± 0.02 Ma) plutons with a variety of magma compositions accompanied post-shield volcanism until recent times. Most Fuerteventura detrital zircons have sub-mantle SIMS oxygen isotope compositions (δ18O < 5.0‰), and overlap compositions reported previously for gabbro/basalt xenoliths entrained in nearby Gran Canaria lavas, interpreted to be fragments of high-temperature seawater-altered Layer 3 oceanic crust.The detrital zircon Hf isotope compositions (εHfi: +15.0 to −0.2) display a much larger variation than recorded in previous studies of volcanic rocks from the Canary or Cape Verde islands. This extreme isotopic variation demonstrates that Fuerteventura detrital zircons provide a more sensitive record of the involvement of multiple sources in magma genesis. The high-εHf (>+12) zircons document the involvement of a depleted reservoir that is isotopically most similar to Middle Atlas SCLM. The low-εHf zircons, specifically those <+1, document the involvement of a reservoir that is more enriched than HIMU and overlaps the composition of NW African lower crust. These extreme εHf compositions indicate the presence of NW African lithosphere beneath Fuerteventura during the shield-building stage of island growth. The absence of a highly depleted Hf isotopic signature in young detrital zircons is interpreted to document the removal of SCLM during a magmatic shutdown initiated at ~15 Ma. Lithosphere erosion could be linked to a pulsed edge-driven convection cell responsible for SCLM delamination along a NE-trending corridor in NW Africa. The detrital zircon Hf and O isotope compositions indicate that both oceanic and continental lithosphere have existed beneath the island. This lithosphere is heterogeneous, consisting of high-T seawater altered oceanic crust, continental lower crust, and subcontinental mantle lithosphere; consistent with formation above a complex lithospheric transition zone created during Triassic-Jurassic rifting and opening of the Central Atlantic Ocean. Importantly, this detrital zircon study demonstrates that a more complete time-integrated record of a long-lived ocean island's geological history is preserved in modern sand samples, in part because a significant portion of Fuerteventura has been removed by erosion.

Hidden Eoarchean crust in the southwestern Central Asian Orogenic Belt

U-Pb and Hf-isotope analyses of zircon xenocrysts from drilling-sampled Carboniferous volcanic rocks suggest the presence of unexposed Eoarchean crust beneath the Junggar Basin (NW China), southwestern Central Asian Orogenic Belt (CAOB). The oldest zircon population with U-Pb ages of 3.8 Ga shows chondritic εHf(t) of −0.7 to +0.7, and Hf model ages of 3900–3952 Ma (TDM) and 3973–4062 Ma (Tcrust). Three slightly younger populations at 3.7, 3.62 and 3.45 Ga have εHf(t) of −5.7 to +2.4, TDM of 3.6–3.9 Ga and Tcrust of 3.7–4.1 Ga. The youngest xenocrysts yield U-Pb ages of 2.55 Ga with εHf(t) values of +3.7 to +8.0. Crustal mineral inclusions and the trace-element compositions of all these zircons show that they probably crystallized from granitic magmas. The observation of deeply hidden Archean crust significantly older than the exposed Phanerozoic upper crust suggests that the juvenile origin in CAOB may be overestimated, and the study of crustal growth rates through time for young orogens will require revision. By comparing the Hf isotopic signatures of ancient zircons (>3.4 Ga) worldwide, we infer that there may have been a great change in early crustal evolution at the Hadean–Archean transition (~3.9 Ga), possibly linked to the Late Heavy Bombardment (LHB).

A SIMS U-Pb (zircon) and Re-Os (molybdenite) isotope study of the early Paleozoic Macquarie Arc, southeastern Australia: Implications for the tectono-magmatic evolution of the paleo-Pacific Gondwana margin

New SIMS U-Pb (zircon) data for intrusive rocks of the Macquarie Arc and adjacent granitic batholiths of the Lachlan Orogen (southeastern Australia) provide insight into the magmatic and tectonic evolution of the paleo-Pacific Gondwana margin in the early Paleozoic. These data are augmented by Re-Os dates on molybdenite from four Cu-Au mineralised porphyry systems to place minimum age constraints on igneous crystallization. The simplicity of the zircon age distributions, and absence of older inheritance, stands in contrast to previous geochronological studies. The earliest magmatism within the Macquarie Arc is registered by a ca. 503 Ma gabbro from the Monza igneous complex, whereas a monzodiorite from the same drillhole records the youngest (ca. 432 Ma). Igneous activity in the Macquarie Arc thus overlapped deformation and magmatism in the craton-proximal Delamerian Orogen to the west, and the emplacement of the Lachlan granitic batholiths at 435–430 Ma; the thermal pulse associated with the latter may have triggered the formation of richly mineralised Silurian porphyries in the Macquarie Arc. The juvenile Hf isotope signature of the Monza Gabbro, together with the lack of zircon inheritance and the radiogenic Hf-Nd isotope systematics of Ordovician Macquarie Arc rocks, is consistent with early development of the arc, or a precursor magmatic belt, in an oceanic setting remote from continental influences, and with the arc being built on primitive Cambrian mafic crust. Outboard arc magmatism in the Cambrian may have initiated in response to convergent Delamerian orogenesis adjacent the Gondwana margin. Overlapping radiogenic isotope-time trends are consistent with the evolution of the Macquarie Arc and the Gondwana continental margin being linked from the Cambrian to the Silurian. These data provide further evidence for the growth of continental crust along the southeastern Australian segment of this margin being related to the dynamics of an extensional accretionary orogenic system.

Geochronology, geochemistry and petrogenesis of the Dengfuxian lamprophyres: Implications for the early Cretaceous tectonic evolution of the South China Block

The middle–late Mesozoic tectonic evolution of the South China Block is not well constrained due to limited studies of synchronous mafic rocks in this area. The Dengfuxian area is located at the central to northern parts of the Nanling Range in the South China Block with many lamprophyre dikes seen cross-cutting the late Jurassic granites. This contribution is the first to report the whole-rock geochemistry, zircon U–Pb age and Sr–Nd–Hf isotope signature of these lamprophyres; provide a geochronological and petrogenetic studies that sheds new light on regional geodynamic evolution. The Dengfuxian lamprophyre dikes have variable contents of major oxides like SiO2 (58.45–65.19 %), Al2O3 (12.18–15.73 %), Fe2O3T (6.31–6.93 %), MgO (2.48–4.14 %), CaO (4.21–5.19 %), Na2O (1.08–3.02 %), K2O (2.78–4.00 %), TiO2 (0.59–1.00 %), MnO (0.15–0.33 %) and P2O5 (0.28–1.22 %). Identified as high-K calc-alkaline rock series, the lamprophyres are enriched in large ion lithophile elements (e.g., Rb, U, K and Pb) but depleted in Ba, Sr and high field strength elements (e.g., Nb, Ta, Zr and Hf). The HREEs are relative depleted compared to LREEs, with weak Ce anomalies (Ce/Ce* = 0.99–1.06) but marked negative Eu anomalies (Eu/Eu* = 0.61–0.79). A total of 30 magmatic zircon grains from the studied lamprophyre yields weighted mean U–Pb ages of 141–143 Ma, suggestive of an early Cretaceous emplacement. The Negative εNd(t) (–4.3 to –6.0) and εHf(t) (–4.1 to –10.9) values, old Nd depleted mantle model ages (TDM = 1231–1628 Ma) and Hf single stage model ages (TDM = 998–1243 Ma), with high initial 87Sr/86Sr (0.71057–0.71322) indicate that the parent magma was sourced from a subduction-modified enriched mantle. Together with integrated major and trace elements studies, it can be inferred that the parent magma of the Dengfuxian lamprophyres originated from low degree (1–3 %) partial melting of an enriched mantle source (garnet peridotite) that was altered by subduction sediments in a progressive intra-plate extension environment. The magma experienced significant fractional crystallization of olivine, clinopyroxene, plagioclase, Fe-Ti oxides and apatite with little crustal contamination. A two-stage geodynamic model is presented to constrain the tectonic evolution of the South China Block during the early Cretaceous.

Sediment provenance of pre- and post-collisional Cretaceous–Paleogene strata from the frontal Himalaya of northwest India

Whereas the timing for India–Asia collision remains debated, contrasting collisional models provide testable predictions in terms of sediment source contributions during the accumulation of Paleocene to middle Eocene deposits now exposed in the frontal Himalayan system. Within the Lesser Himalaya and frontal thrust system of northwest India, discontinuous exposures of the Cretaceous Singtali Formation and upper Paleocene–middle Eocene Subathu Formation yield a record of these early collisional stages. To test competing collisional models, we analyze the provenance of these deposits with new detrital zircon U-Pb and Hf isotopic data which can distinguish among Indian plate, Asian plate, Kohistan-Ladahk arc, and various Himalayan sources. Detrital zircon age distributions for the Singtali Formation are dominated by Paleoproterozoic zircons with a distinct Cretaceous age component, whereas age data from the Subathu Formation record (1) a marked increase in the relative abundance of Cambrian–Neoproterozoic grains, (2) a decrease in the proportion of Paleoproterozoic grains, and (3) distinct Permian and Late Cretaceous–Paleocene age components. All Cretaceous grains from the Singtali Formation yielded crustal Hf isotopic signatures, indicating a distinctive pre-collisional source of Cretaceous grains of Indian affinity. Zircon Hf isotopic signatures from <320 Ma grains in the Subathu Formation show a significant lower to middle Eocene increase in source diversity, including juvenile grains most likely originating from the Asian plate and Kohistan-Ladakh arc. This requires inception of India-Asia collision by ∼44–50 Ma—the depositional age of the uppermost Subathu Formation. This major provenance shift is similar to that observed for pre- and post-collisional Tethyan Himalayan strata in the north, which is suggestive of a single contiguous basin linking the Lesser Himalaya by ∼44–50 Ma and contests the notion that the Lesser and Tethyan Himalaya were separated by a “Greater India Basin” during the Eocene. When coupled with the well documented Paleocene–early Eocene provenance record of the Tethyan Himalaya, these new data provide support for a collisional model in which Asian detritus reached the northernmost edge of India by ∼59 Ma with terminal closure of both the Shyok and Indus-Yarlung suture zones by ∼54 Ma.

What is underneath the juvenile Ordovician Macquarie Arc (eastern Australia)? A question resolved using Silurian intrusions to sample the lower crust

The Ordovician intra-oceanic Macquarie Arc of eastern Australia collided with the eastern Gondwanan margin at ~440 Ma. However, the deep crustal architecture resulting from this assembly is poorly known. This is addressed here by a zircon U-Pb-Hf study of the post-assembly Silurian Browns Creek Intrusive Complex and Davies Creek Granite dykes that intrude into the arc, and not adjacent Gondwanan sedimentary sequences. Zircon UPb dating integrated with CL imagery indicate two igneous phases at 430–437 Ma and 420–426 Ma and a zircon recrystallisation phase at 395–396 Ma attributed to a late thermal event. The magmatic zircon initial ɛHf values vary from −5.1 to +4.7. This signature indicates the source of these granitic rocks is strongly influenced by typical pre-Silurian Gondwanan material. Granitic rock and zircon compositions demonstrate that at the likely temperature of the Silurian granitic magma, especially the Davies Creek Granite dykes, inherited source zircons were mostly dissolved, explaining the absence of pre-Ordovician xenocrysts within the zircon population. The unradiogenic Hf isotopic signatures preserved in the Silurian magmatic zircons demonstrate the contribution of Gondwanan crustal material to the magma source region. These results support the interpretation of the Macquarie Arc as an intra-Panthalassa ocean allochthon, emplaced and resting over the edge of Gondwanan crystalline basement, possibly including the continent-derived sedimentary rocks of the Adaminaby Group.

The combined Zr and Hf isotope inventory of bulk rock and sequentially leached chondrite samples

The stepwise acid digestion of primitive chondritic meteorites allows the identification of nucleosynthetic isotope anomalies that are otherwise hidden on the bulk rock scale. Here, we present for the first time combined isotope data for acid leachates, residues, and bulk rock aliquots of several primitive chondrites for the geo- and cosmochemically similar elements Zr and Hf. Our analyses reveal significant Zr and Hf isotope anomalies that (i) are complementary between acid leachates and residues and (ii) well-correlated with each other. The observed Zr and Hf anomalies strongly suggest variable contributions of common s-process carrier phases to the different leachates and residues. Ratios of r- (and p-process) Zr and Hf isotopes appear to be uniform in leachates and residues. In contrast to the well-correlated anomalies found in our leaching experiments, nucleosynthetic Zr and Hf isotope signatures seem to be decoupled on the bulk rock scale. This contrast may result from the heterogeneous distribution of neutron-rich Zr material devoid Hf, or alternatively be caused by the presence of anomalous CAI material which overprinted s-process deficits that were initially correlated.In contrast to a previous study, we find no direct evidence for the presence of a third isotopically distinct nucleosynthetic Zr component.

Zircon U-Pb-Hf isotopes and geochemistry of Jurassic igneous rocks from the southern Zhangguangcai Range, NE China: constraints on magmatism, petrogenesis and tectonic implications

ABSTRACT In this study, we present new zircon U-Pb and Hf isotope data and geochemical analyses for Jurassic igneous rocks from the southern Zhangguangcai Range, NE China. In the context of our new U/Pb data together with other published data (n = 165), we recognize three major magmatic pulses in the eastern Songnen Block during the Jurassic: earliest Jurassic (200–195 Ma), late Early Jurassic (183–175 Ma) and early Late Jurassic (ca. 163 Ma). According to the petrological classification scheme, rocks are divided into two categories of andesite and I-type granitoids. Generally, Early Jurassic monzogranites have more evolved compositions with SiO2, Al2O3, and K2O+Na2O concentrations of 67–74 wt.%, 13.28–17.04 wt.% and 7.25–9.31 wt.%, respectively than Late Jurassic granodiorite. Early Jurassic andesite has SiO2, Al2O3, Na2O+K2O contents of 54.64–56 wt.%, 17.27–17.44 wt.% and 3.47–4.06 wt.%, respectively with low Mg# values of 0.18–0.26. In addition, all samples show enrichment in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depletion in high strength field elements (HSFEs, such as Nb, Ta, P and Ti) and low Sr/Y and (La/Yb)N ratios, all of which are characteristic of arc-type magmatic signatures. In view of the Hf isotope signatures, these rocks show high initial 176Hf/177Hf ratios (0.282711–0.283069) corresponding to positive εHf(t) values (+0.39 to +13.66) and Neoproterozoic two-stage model ages (1154–550 Ma). In summary, the geochemical results suggest that the primary magmas of Jurassic granitoids were derived from variable degrees of partial melting of juvenile lower crust, whereas Early Jurassic andesite was derived from the partial melting of mantle wedge peridotite metasomatized by hydrous melts from subducting sediments and/or oceanic crust. The Jurassic arc-type magmatism in the eastern Songnen Block indicates that the Mudanjiang oceanic plate was still subducting in the Jurassic.

Geochemistry and geochronology of zircons from granite-hosted gold mineralization in the Jiaodong Peninsula, North China: Implications for ore genesis

Large-scale quart-vein and structurally-controlled gold mineralization is intensely developed in the Jiaodong Peninsula, North China Craton and is typified by the Linglong and Jiaojia deposits, respectively. In this work, zircons from typical gold-bearing ores of the Sanshandao Northern Sea (SNS), Jiuqu (JQ) and Canzhuang (CZ) gold deposits were compared in terms of texture, U–Pb age, trace element content and Hf isotopic signatures in order to discern whether zircon from ore samples can be used as an indicator of ore genesis and grade. Most studied zircons are magmatic in origin with a hydrothermal overprint (i.e., zircons with core-rim assemblages, fractured-dissolution textures and hydrothermal activity-related fluid/mineral inclusions). Three zircon age clusters were differentiated: ~120 Ma, ~150 Ma and >2000 Ma. The ~120 Ma zircons show evidence of hydrothermal alteration (dark in cathodoluminescent images with hydrothermal rim textures) and are characterized by high LREE, P, Ti and εHf(t) (−21 to −15) and young TDMC (2100–2500 Ma). This suggests an interaction between the mantle and crust at the magma source, and that a P/Ti-rich, Al-poor, high temperature, high fO2, wet late-stage residual granitic melt and intense hydrothermal alteration played an important role in the formation of gold mineralization. The ~150 Ma zircons have high Y, Nb, Ta and U contents, low εHf(t) (−26 to −20) and old TDMC (2300–3000 Ma) ages, and HREE-enriched patterns with pronounced Ce and Eu anomalies. These features indicate a reduced, cool and Al-rich magma which did not favor gold mineralization, even though it was highly evolved. This also implies that the degree of magma differentiation is not the key factor that led to gold mineralization in the Jiaodong gold province. The >2000 Ma zircons are primarily limited to gold ores with high Pb contents, HREE-enriched patterns and variable Ce and Eu anomalies, indicating that they were inherited from the Paleoproterozoic (2000–2200 Ma) basement. In addition, the SNS high-grade ores yielded zircon with the greatest U-Pb age range (mainly 110–180 Ma) and the most pronounced hydrothermal overprinting, indicating that large-scale mineralization resulted from multi-stage granitic intrusion, with intense fluid dissolution and metasomatism. This research highlights that correlations between zircon age populations, Hf isotope signatures, internal structures and trace element patterns can provide insights into ore genesis and fluid evolution in gold mineralization systems.

Petrogenesis and mantle source characteristics of the late Cenozoic Baekdusan (Changbaishan) basalts, North China Craton

Late Cenozoic intraplate basaltic rocks in northeastern China have been interpreted as being derived from a mantle source composed of DMM and EM1 components. To constrain the origin of the enriched mantle component, we have now determined the geochemical compositions of basaltic rocks from the active Baekdusan volcano on the border of China and North Korea. The samples show LREE-enriched patterns, with positive Eu and negative Ce anomalies. On a trace element distribution diagram, they show typical oceanic island basalt (OIB)-like LILE enrichments without significant Nb or Ta depletions. However, compared with OIB, they show enrichments in Ba, Rb, K, Pb, Sr, and P. The Nb/U ratios are generally within the range of OIB, but the Ce/Pb ratios are lower than those of OIB. Olivine phenocrysts are characterized by low Ca and high Ni contents. The radiogenic isotopic characteristics (87Sr/86Sr = 0.70449 to 0.70554; εNd = −2.0 to +1.8; εHf = −1.7 to +6.1; 206Pb/204Pb = 17.26 to 18.12) suggest derivation from an EM1-like source together with an Indian MORB-like depleted mantle. The Mg isotopic compositions (δ26Mg = −0.39 ± 0.17‰) are generally lower than the average upper mantle, indicating carbonates in the source. The 87Sr/86Sr ratios decrease with decreasing δ26Mg values whereas the 143Nd/144Nd and (Nb/La)N ratios increase. These observations suggest the mantle source of the Baekdusan basalts contained at least two components that resided in the mantle transition zone (MTZ): (1) recycled subducted ancient (∼2.2–1.6 Ga) terrigenous silicate sediments, possessing EM1-like Sr–Nd–Pb–Hf isotopic signatures and relatively high values of δ26Mg; and (2) carbonated eclogites with relatively MORB-like radiogenic isotopic compositions and low values of δ26Mg. These components might have acted as metasomatizing agents in refertilizing the asthenosphere, eventually influencing the composition of the MTZ-derived plume that produced the Baekdusan volcanism.

Nd-Hf Isotopic Decoupling of the Silurian—Devonian Granitoids in the Chinese Altai: A Consequence of Crustal Recycling of the Ordovician Accretionary Wedge?

Voluminous Silurian-Devonian granitoids intruded a greywacke-dominated Ordovician accretionary wedge in the Chinese Altai. These granitoids are characterized by significant Nd-Hf isotopic decoupling, the underlying mechanism of which, so far, has been poorly understood. This issue is addressed in this study by the integration of our new and regional published geological and geochemical data. Geological studies indicated a close spatial relationship between the regional anatexis of the Ordovician wedge and the formation of the granitoids, which is characterized by a gradual textural evolution from the partial molten Ordovician wedge sedimentary rocks (the Habahe Group) to the granitoid bodies. Compositionally, these granitoids and the Ordovician Habahe Group rocks displayed close geochemical similarities, in the form of arc-like trace elemental signatures as well as comparable Nd isotopic characteristics. Combined with regional available data, we suggest that the Silurian-Devonian granitoids originated from the immature and chemically primitive Habahe Group rocks. Since Nd and Hf isotopic data for the Habahe Group rocks show significant Nd-Hf isotopic decoupling, we propose that the Silurian-Devonian granitoids inherited the Nd and Hf isotopic signatures from their sources, i.e., the Habahe Group rocks. In other words, the Nd-Hf decoupling in the Habahe Group rocks is the primary causative factor leading to the prevailing Nd-Hf isotopic decoupling of the Silurian-Devonian granitoids in the Chinese Altai.

Implication of Mesoproterozoic (∼1.4 Ga) magmatism within microcontinents along the southern Central Asian Orogenic Belt

The southern Central Asian Orogenic Belt contains numerous microcontinents including the Kazakhstan-Yili block, Central Tianshan Arc and Junggar block in the west, the Erguna, Xing'an, Songliao and Jiamusi-Khanka blocks in the east, bridging by the Tuva-Mongolia block, Beishan Orogenic Belt and Alax block in the central region. New geochemical and geochronological data from the microcontinental blocks within the southern Beishan Orogenic Belt provide new insight into the Precambrian crustal evolution of this region. Five granitoids from the Jiujing region yielded igneous zircon 206Pb/238U ages of 1450–1401 Ma, and zircon xenocrysts from late Paleozoic plutons in the Jiujing, Qiaowan, and Shibandun regions have 206Pb/238U ages that also cluster at ∼1.4 Ga. Those data suggest that crust of this age is widespread beneath the southern Beishan Orogenic Belt. The ∼1.4 Ga zircons display depleted Hf isotopic signatures (εHf(t) = 2.0–11.1) and show relatively young two-stage Hf model ages (1.9–1.4 Ga), indicating rapid reworking of juvenile mantle-derived materials. Integrating these results with similar geochronological data from the Kyrgyz North Tianshan, Yili block, Central Tianshan Arc, northern Alxa block and Xilinhot block, we propose that the CAOB incorporates an extensive assemblage of Mesoproterozoic (1450–1360 Ma) magmatism that can be traced over ca. 3000-km long a west-east trending belt. These Mesoproterozoic granitoids display distinct geochemical signatures (e.g., Ga/Al*10,000 ranging from 1.46 to 3.88 and Zr + Nb + Ce + Y varying largely from 101 to 1066 ppm) and show a temporal progression from orogenic to anorogenic over a relatively short period. This suggests a tectonic setting that likely evolved from compressional to extensional environments during 1450–1360 Ma, perhaps resulting from slab roll back. We suggest that the 1450–1360 Ma magmatism along the southern CAOB corresponds with a transition from a compressional to extensional environment on the margin of the Nuna supercontinent.

Origin and tectonic implications of Early Cretaceous high- and low-Mg series rocks and mafic enclaves in the Bomi–Chayu Fold Belt, SE Tibet

Early Cretaceous granitoids are widespread on the Tibetan Plateau and record the tectonic evolution of several Tethyan oceans. We describe Early Cretaceous high-Mg (Mg# > 50) and low-Mg (Mg# < 50) granitoids, minor diorites, and mafic enclaves from the Bomi–Chayu Fold Belt, SE Tibet. Zircon U-Pb dating reveals two episodes of granitoid emplacement at ~122 and ~117 Ma. High-Mg series rocks have higher Mg# and compatible element concentrations (e.g., Cr and Ni) than low-Mg series samples. Their Mg# and compatible element abundances are also elevated relative to an experimental melt generated under the conditions of a thickened lower crustal. Enriched whole-rock Nd and zircon Hf isotopic signatures, coupled with low Y (<18 ppm) and Yb (<1.9 ppm) concentrations in some samples, indicate that the high-Mg series was derived from thickened lower crust and underwent minor mixing with cumulate pyroxenite in the lower crust. In contrast, low-Mg series rocks record a purely crustal origin, although differences are noted between Na-rich (subgroup 1) and K-rich (subgroup 2) compositions. Mafic enclaves hosted in the granitoids yield identical formation ages and isotopic compositions to their host rocks, suggesting a common origin. The spatial–temporal distribution of Early Cretaceous granitoids in the Bomi–Chayu Fold Belt indicates that magmatism occurred in an analogous tectonic regime to that of similar rocks in the Tengchong Terrane. The Bomi–Chayu granitoids are therefore distinct from those in the northern and central Lhasa subterranes and are related to the evolution of the Myitkyina Tethys Ocean in eastern Myanmar.