Hf Isotopic Compositions Research Articles

Late Cretaceous bimodal volcanic rocks in Shuanghu induced by lithospheric delamination beneath the Southern Qiangtang, Tibet

The southern Qiangtang (SQT) in central Tibet is characterized by sporadic Late Cretaceous magmatic rocks whose petrogenesis and tectonic implications remain unclear. Here, new zircon UPb ages and Hf isotope compositions, together with whole-rock element and isotope data have been collected for the Duoma volcanic rocks from the SQT, central Tibet. Zircon UPb dating indicates that the Duoma volcanic rocks crystallized at ca. 98 Ma. The basalts of the Duoma volcanic rocks have low SiO2 (51.49–53.36 wt%), high total alkalis (4.65–6.25 wt%), and display OIB-like isotopic signatures (87Sr/86Sr)i = 0.7051 to 0.7058, εNd(t) = +0.04 to +1.10), overall similar to intra-plate alkali basalts. Moreover, basalts exhibit slight depletion of high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti), but enrichment of light rare earth (LaN/YbN = 6.7–7.6) with no negative Eu anomalies (Eu/Eu* = 0.91–0.99). These geochemical features, together with their high La/Nb (1.56–1.70) and Zr/Hf (44.70–45.87) but low La/Ba (0.08–0.09) and Ca/Al (0.43–0.65) ratios, suggest that the Duoma basalts originated from partial melting of garnet clinopyroxenite that was metasomatized by depleted mantle-derived melts. The coexisting rhyolites have high SiO2 (69.78–69.92 wt%) and exhibit significant enrichment in large-ion lithophile elements (LILEs) and depletion in HFSEs (Nb, Ta, and Ti). Furthermore, the Duoma rhyolites are characterized by the decoupled Nd (εNd(t) values ranging from −4.4 to −11.1) and Hf (ɛHf(t) values ranging from −0.7 to +2.7) compositions, that character indicates that they were probably derived from the partial melting of the lower continental crust. The compositional bimodality and heterogeneous source of the Late Cretaceous volcanism indicate that they were formed in an extension setting, presumably triggered by lithospheric delamination beneath the SQT.

Building and reworking of Archean continental crust in the nucleus of the Yangtze Craton: Constraint from 3.4 Ga and 2.94 Ga granitoid gneisses in the Southern Kongling Complex

The TTG gneisses, a dominant lithological assemblage within Archean cratonic provinces, provide a window into the early evolution of the continental crust. The Kongling complex in South China preserves voluminous Archean granitoids, recording the early formation and evolution history of the Yangtze Craton. We present results of a comprehensive study involving field investigation, petrographic characterization, zircon U–Pb geochronology and Lu-Hf isotope tracing, and whole-rock geochemistry for the Archean granitoid gneisses from the Southern Kongling Complex. Igneous zircons from two granitic gneisses yielded weighted mean 207Pb/206Pb ages of 3399 ± 15 Ma (MSWD = 0.99, n = 24) and 3389 ± 12 Ma (MSWD = 1.02, n = 20). Zircons from the 3.4 Ga granitic gneiss also record a ca.3.0 Ga anatexis event which is contemporaneous with the widespread granitoid gneisses in the Kongling Complex. Geochemical and zircon Hf isotope data (εHf(t) values of − 3.41 to + 0.77 and two-stage Hf model ages of 3.65–3.80 Ga) for the granitic gneisses support a derivation from pre-existing Eoarchean (TDM2 = 3.73 Ga) crust. LA-ICP-MS zircon U-Pb dating yielded emplacement ages of 2948 ± 17 Ma for a migmatized trondhjemitic gneiss, and 2928 ± 14 Ma for a quartz monzonite gneiss. These two gneisses have similar zircon Hf model ages (TDM2 = 3.45 Ga) and both were emplaced during a major phase of mafic magma diapiric process that significantly reworked the old crust. The occurrences of 2.94 Ga trondhjemite and associated mafic blocks suggest intra-crustal differentiation by partial melting of low-K mafic rocks. We suggest that intra-crustal remelting and differentiation played a key role in the formation, evolution, and maturation of the micro-continents in Kongling during the Paleo- to Meso-Archean. The whole-rock geochemical and zircon Hf isotopic compositions of the different generations of granitoid gneisses from the Southern Kongling Complex are similar to those of the coeval gneisses (3.45 Ga and 2.95 Ga) from the northern part of the Kongling Complex, indicating a common tectono-magmatic history shared by both segments tracing back to as early as 3.4 Ga. The Archean granitoid gneisses from the Kongling Complex record remelting and differentiation of Eo- to Paleo-Archean crusts during the Paleo- to Meso-Archean, implying that Eoarchean crust is likely to have been preserved within the Kongling complex.

Zircon Hf isotopic compositions of the basement gneiss in Bayan Obo: Constraints on crustal evolution of the Yinshan Block in the North China Craton

Bayan Obo, located in the north margin of the Yinshan Block, North China Craton (NCC), contains the Archean to Paleoproterozoic basement rocks which may shed light on the early crustal evolution of the NCC. In this paper, to reveal the formation and modification of the basements, we report Hf isotope of zircons from the biotite plagiogneisses in Bayan Obo. Combined with the published U–Pb ages and Hf isotope compositions of the zircons from the Bayan Obo basement rocks, a comprehensive review was employed to provide new insights into the formation and modification of the basement in this area. The oldest formation age of the basement rocks was found to be approximately 2.6 Ga, with positive εHf(t) values indicating the contribution from the depleted mantle to the rocks. The age of ∼2.0 Ga marks the major formation period of the basement rocks. The varied εHf(t) values (−17.2 to +8.9) of the magmatic zircons suggest a mixture origin between the depleted mantle and crustal rocks for the gneiss. The basement went through extensive metamorphism during 1.95–1.9 Ga. In addition, zircon U–Pb–Hf isotope data of the Precambrian units in Guyang and Wuchuan, which are adjacent to Bayan Obo, were compiled for comparison. The comprehensive review on the data of the concordant magmatic zircons indicates the existence of 3.5 Ga crustal fragments in the Yinshan Block. The melting of the depleted mantle and the addition of juvenile materials into the crust at 2.6–2.9 Ga and 2.45–2.55 Ga were confirmed by the high positive εHf(t) values of the magmatic and inherited zircons. An increase in remelting of the crust at 2.0 Ga is deduced from the extremely unradiogenic Hf isotope of the magmatic zircons.

Petrology and geochemistry of Late Triassic rapakivi-type granites in the Dupangling area, South China: Role of fluid-rock interaction in the origin of rapakivi texture

Rapakivi-type granites not only document magmatic processes but also archive subsolidus interactions between granitic rock and fluid, and thereby provide crucial information about fluid infiltration in the Earth's crust. However, the key process to generate rapakivi texture is still debated. Here, we report comprehensive mineralogical, geochemical and Hf isotopic compositions of the Dupangling rapakivi granites (210.4–214.9 Ma) in the South China Block to investigate the effect of fluid-rock interaction on the origin of rapakivi feldspar. Dupangling rapakivi granites have high SiO2 (72.63–78.21 wt%) and alkali contents (Na2O + K2O = 6.14–9.06 wt%) with high K2O/Na2O ratios (1.37–2.64), characteristic of weakly peraluminous (A/CNK = 1.04–1.10) high-K calc-alkaline granites. Samples have weakly fractionated REE patterns with negative Eu anomalies (δEu = 0.05–0.38). They have negative whole-rock εNd(t) (−8.45 to −7.91), variable zircon εHf(t) (−9.7 to −1.0) and two-stage Hf isotope model ages (1.32–1.84 Ga), due to their derivation from a major early Mesoproterozoic crustal source with a subordinate late Paleoproterozoic component. Rapakivi feldspars in Dupangling granites are composed of an alkali-feldspar core and a plagioclase mantle. Fractures, pores and secondary inclusions (biotite, sericite, epidote and hematite) are closely associated with the mantles and oligoclase patches within alkali-feldspar cores. These pervasive microtextural features and variations of Be, Rb, Ba, Sr and LREE within rapakivi feldspars are interpreted to have formed through subsolidus fluid-induced dissolution-reprecipitation replacement processes. This study highlights that fluid-rock interaction plays an important role in generating rapakivi texture.

Tracing the Early Crustal Evolution of the North China Craton: New Constraints from the Geochronology and Hf Isotopes of Fuchsite Quartzite in the Lulong Area, Eastern Hebei Province

Understanding the composition, formation and evolution of the oldest continental crust is crucial for comprehending the mechanism and timing of crustal growth and differentiation on early Earth. However, the preservation of the ancient continental crust is limited due to extensive reworking by later tectonothermal events. In the Lulong area of eastern Hebei, abundant ca. 3.8–3.4 Ga detrital zircons of the fuchsite quartzite have been previously identified. Nonetheless, the provenance and Hf isotopic compositions of the fuchsite quartzite remain unclear. In this study, we present new detrital zircon ages and Hf isotopic for the fuchsite quartzite in the Lulong area to establish the timing of deposition, the provenance and the regional stratigraphic relationship. Zircon U-Pb dating indicates that the fuchsite quartzite was deposited between 3.3–3.1 Ga and most grains were sourced from the 3.8 Ga TTG gneisses and Paleoarchean magmas. Field investigations and regional correlations reveal that the fuchsite quartzite from the Lulong area is equivalent to that of the Caozhuang area. Zircon Hf isotopic data from eastern Hebei Province (Lulong and Caozhuang areas) and Anshan and Xinyang areas indicate that the oldest crustal growth event of North China Craton occurred in the Hadean.

Early Paleozoic subduction imprints of the Proto-Tethys Ocean: Evidence from the Appinite–Diorite–Granodiorite complex in East Kunlun, Northern Tibet

The East Kunlun Orogenic Belt (EKOB), on the northern margin of the Tibetan Plateau, forms a part of the western segment of the orogenic system in Central China. The Paleozoic tectonic evolution of the EKOB, along the western margin of Gondwana, is closely related to Paleozoic subduction and closure of the Proto-Tethys and is key to the palinspastic reconstruction of the Central Asia and Tethys domains. Numerous studies have been conducted on the Early Paleozoic granitoids in the EKOB. However, a convincing magmatic proxy to indicate the timing of oceanic subduction during the Early Paleozoic is yet to be well constrained, partially because the arc geochemical signature of the calc-alkaline granitoids is not a reliable indicator of oceanic subduction. Herein, we present new zircon U–Pb ages, whole-rock major and trace element analyses, and Nd–Pb and zircon Hf isotopic data for Early Ordovician appinite (mafic), diorite (intermediate), and granodiorite (felsic) intrusive rocks in the Dundegou (DDG) area of the EKOB, northern Tibet. The zircon U–Pb ages suggest this complex was emplaced at approximately 477–472 Ma. Abundant 557–510 Ma zircon xenocrysts and/or inherited zircons were found in the granodiorite and appinites, suggesting two earlier magmatic episodes during the late Ediacaran–Cambrian. Appinites and diorites are characterized by depletion in high field strength elements, with negative initial εNd(t) values (appinites: −6.5 to −9.4; diorites: −8.2 to −9.1) and negative zircon εHf(t) values (appinites: −2.5 to −10.3; diorites: −1.0 to −9.1). These features suggest that appinites and diorites were most likely derived from the partial melting of enriched mantle wedge peridotites with the addition of sediment-derived melts from the sedimentary veneer of the subducting slab, along with variable degrees of fractional crystallization and a limited extent of crustal contamination. The granodioritic magma was contributed by (a) the ancient mafic lower crust-derived magma, (b) the derivative felsic magma from a dioritic parent, and (c) a minor mantle-derived magma component, resulted in the formation of granodiorites with highly unradiogenic initial Nd and Hf isotopic compositions (εNd(t) values of −8.5 and εHf(t) values from −0.6 to −7.3). Our study suggests that the subcontinental lithospheric mantle beneath the EKOB is likely heterogeneous in terms of its isotopic composition. The DDG complex is the oldest appinite-bearing complex found so far in the EKOB and a good indicator of proto-Tethys oceanic subduction.

Strongly Peraluminous Highly Fractionated I-Type Granite from Bangong–Nujiang Metallogenic Belt, Tibet: Implications for Continental Evolution and Evaluation of Economic Potentiality

The research on highly fractionated granite has significant implications for both the evolution and compositional maturation of the continental crust and metallogenic exploration. As a means of further understanding crustal evolution and promoting ore exploration in the Bangong–Nujiang metallogenic belt (BNMB), we present the petrography, zircon LA–ICP–MS U–Pb age, and Hf isotopic data, along with the whole-rock geochemical and Sr–Nd isotopic composition on Kese highly fractionated granite in the Baingoin area within the BNMB, central Tibet. The results show that Kese granite possesses a zircon U–Pb age of 127.8 ± 1.7 Ma and a relative enrichment in zircon Hf isotopic composition (−12.8~+0.3) with a two-stage Hf model age of 1.2~2.0 Ga. This granite belongs to the high-K calc-alkaline series, characterized by a strongly peraluminous feature, and is enriched in large-ion lithophile elements (LILEs) and Nd isotopes (−7.86~−7.74). The granite was likely to have been derived from the mixed melts derived from 40%~45% juvenile basaltic lower crust, 15%~20% ancient lower, and 40% middle–upper, following intense fractional crystallization processes involving amphibole, biotite, plagioclase, and some accessory minerals during the magma’s evolution. We infer that Kese highly fractionated granite can be formed from the continental collision of the Lhasa–Qiangtang terranes initiated before 128 Ma. The reworking of pre-existing juvenile and ancient crustal materials drove the composition of the northern Lhasa terrane to that of a mature continental crust. Moreover, the distinctive geochemical features have shown that the high degree of differentiation led to intense magmatic–hydrothermal interaction during the formation of Kese granite. A comparison of the geochemical characteristics of mineralized and barren granites suggests that the highly fractionated granites in Baingoin from the BNMB have a high economic potential and are suitable for preliminary exploration of Sn–W-(U) deposits.

Fe–Mg Isotopes Trace the Mechanism of Crustal Recycling and Arc Magmatic Processes in the Neo‐Tethys Subduction Zone

AbstractThere has been intense debate on the mechanism of crustal recycling in subduction zones, and Fe–Mg isotopes may provide new constraints on this issue. This study reports Fe–Mg isotope data for mafic plutonic rocks from the eastern and central Gangdese arc, along with their associated trench sediments in southern Tibet. The δ26Mg values of the eastern Gangdese arc rocks show negative correlations with (87Sr/86Sr)i and (206Pb/204Pb)i values, but positive correlations with εNd(t) and εHf(t) values. Conversely, the δ56Fe values of the eastern Gangdese arc rocks show positive correlations with (87Sr/86Sr)i and (206Pb/204Pb)i values, but negative correlations with εNd(t) and εHf(t) values. The Mg and Fe isotopic compositions of the central Gangdese arc rocks are comparable with those of the eastern ones, but they do not correlate with Sr–Pb–Nd–Hf isotopic compositions. Notably, the Fe–Mg isotopic compositions of most arc rocks fall between those of local trench sediments and the mantle wedge. Combined qualitative analyses and quantitative simulations suggest that: (a) the Fe–Mg isotope variations observed in the eastern Gangdese arc rocks highlight the important role of source mixing between sediment‐derived melts and peridotite, whereas (b) the Fe–Mg isotope variations observed in the central Gangdese arc rocks reflect the superposition of carbonated serpentinite‐derived Mg‐rich fluids‐peridotite source mixing and source melting. The strong correlations between Fe–Mg isotope ratios and traditional geochemical tracers provide further evidence for the recycling of crustal materials in subduction zones via various types of slab‐derived fluids and melts.

Sources and petrogenesis of Late Triassic granitoids in the Yajiang gneiss dome group (eastern Songpan-Ganze orogenic belt) with tectonic implications

Numerous Mesozoic granitoid plutons with a substantial variety of petrologic and geochemical signatures intrude the Triassic metasedimentary rocks of the Songpan-Ganze accretionary-orogenic wedge in the eastern Tibetan Plateau. These granitoid rocks generally exhibit sharp contact with the Triassic sedimentary rocks. To better understand the genesis and emplacement of magmas associated with tectonic accretion along convergent plate boundaries, we present new LA-ICP-MS zircon U-Pb geochronology, major and trace elements, and Sr–Nd–Pb–Hf isotopic compositions for intermediate-to-felsic plutons in the Yajiang gneiss dome group (YGDG), including the Changzheng pluton, the Jiajika (Majingzi) pluton, the Rongxuka pluton, the Xiya pluton, the Xinduqiao pluton, and the Waduo diorite dikes in the eastern margin of the Songpan-Ganze orogenic belt (SGOB). By their typical petrological and geochemical characteristics, these plutons are classified as I-type granodiorite-diorite (Rongxuka, Xiya, Xinduqiao plutons, Waduo dikes) or S-type granite (Changzheng and Jiajika plutons). I-type granodiorite-diorites exhibit a high Mg# (average 49), medium-K cala-alkiline signature and are enriched in large-ion lithophile elements (e.g., Rb, Th, and U) but depleted in high field strength elements (e.g., Nb, Ta, and Ti), and with lower initial 87Sr/86Sr values (0.70622 to 0.70863) but a relatively high and concentrated εHf(t) (−27 to −1.9) and εNd(t) (−4.02 to −7.51); while S-type granites exhibit a high silica, high-K cala-alkiline signature with strong negative Eu anomalies (Eu/Eu* = 0.17–0.64), and possess high initial 87Sr/86Sr values but low εHf(t) (−40.1 to −0.9) and εNd(t) (−8.72 to −12.14) signatures, forming through partial melting of metasedimentary rocks from an ancient crust source. LA–ICP–MS zircon U-Pb dating indicates that they were emplacement between 207.2 ± 1.4 and 223.6 ± 2.2 Ma. Both types of granitoid rock were formed by the crustal partial melting followed by extensive fractional crystallization under high-temperature (700–850 °C), low-pressure (<15 kb) conditions. In combination with previous studies, our data provide evidence for an affinity between the eastern Songpan-Ganze andthe Yangtze craton basements, and suggest that the granitoid plutons formed in a syn-collisional to post-collisional setting at ca. 207–223 Ma.

Tracing Oligocene−Miocene source-to-sink systems in the deep Levant Basin: A sandstone provenance study

The Levant Basin in the Eastern Mediterranean contains an ∼3-km-thick, predominantly siliciclastic section of Oligocene−Miocene age, which hosts large hydrocarbon reservoirs (“Tamar Sands Play”). Here, we present a provenance study of Oligocene−Miocene sandstones based on detrital zircon U-Pb-Hf and heavy mineral assemblages. Samples were retrieved from four boreholes across the Levant Basin: Myra-1, Dolphin-1, Leviathan-1, and Karish North-1. Our investigations revealed that the sediments are dominated by Neoproterozoic and older Precambrian zircons with variable Hf isotopic composition, indicating that they were mainly reworked from Paleozoic−Mesozoic sandstones of African-Arabian provenance, with minor derivation from the Neoproterozoic basement of the Arabian-Nubian Shield. Variations in the proportions of pre−900 Ma zircons were encountered in various levels of the siliciclastic section. These zircons were markedly enriched (44%−57%) in the Rupelian and Aquitanian−Burdigalian intervals, accompanied by abundant detrital apatite peloids in the heavy mineral fraction, and relatively sparse (21%−38%) in the Chattian−Aquitanian and Langhian−Tortonian intervals, alongside scarce Mesozoic−Cenozoic zircons. These findings allow us to associate the deep-basin detrital record with two sedimentary transport systems that reached the Levant Basin from both NE Africa and Arabia simultaneously until the late Miocene, when sediment transport from Arabia ceased. While Rupelian and Aquitanian−Burdigalian sediments, including the main section of the “Tamar Sands,” were derived mainly from Arabian sources via the Levant continental margin, Chattian−Aquitanian and Langhian−Tortonian sediments were primarily sourced from NE Africa via the Nile Delta. Detrital contribution from the Eurasian side of the Eastern Mediterranean was not identified, suggesting that sand originating in the Arabia-Eurasia collision belt did not reach the Levant Basin.

Development of a back-arc basin from initial rifting to seafloor spreading: Constraints from Paleozoic basic rocks in the North Qinling accretionary orogen, central China

The progression from initial back-arc rifting to back-arc opening in ancient orogenic collages is important for reconstructing subduction histories, constraining tectonic switching, and understanding crustal growth and evolution. However, it is difficult to constrain this transition in ancient arcs. The Qinling-Dabie orogenic belt is one of the most important orogenic belts in eastern Asia, yet the history of Paleozoic accretionary processes in this belt remains equivocal, owing to a poor understanding of back-arc opening processes in the Erlangping unit. In this study, we present whole-rock geochemical analyses of mafic dikes in the Erlangping unit, along with U-Pb ages and Hf-O isotope compositions of zircon from these dikes. Zircon secondary ion mass spectrometry (SIMS) dating of these mafic dikes yielded U-Pb ages of 453 ± 3 Ma. The mafic dikes are calc-alkaline and are characterized by high K2O contents (1.16−3.16 wt%). They have enriched ([La/Yb]N = 4.3−14.9) light rare earth elements (REEs) and relatively flat heavy REE ([Dy/Yb]N = 0.9−1.5) patterns, and they exhibit enrichment in large ion lithophile elements (LILEs) but depletion in high field strength elements (HFSEs), resembling arc-like magmatism. These mafic dikes are characterized by relatively enriched initial 87Sr/86Sr (0.7049−0.7059), chondritic to slightly radiogenic εNd(t) (−0.36 to 1.33), and radiogenic whole-rock and zircon εHf(t) (+7.2−7.6 and +7.5−7.8, respectively). The zircons have δ18O values (5.0‰ ± 0.1‰) similar to those of normal mantle zircon. Accordingly, we interpret that the mafic dikes were derived from an enriched lithospheric mantle source metasomatized by subducted Proto-Tethys (Shangdan) ocean material. In contrast, previously reported ca. 440 Ma gabbros from the Erlangping unit are tholeiitic and have lower incompatible trace-element concentrations with less enrichment in LILEs and less depletion in HFSEs than the mafic dikes presented here. Whole-rock Nd and zircon Hf isotopic compositions suggest that these Silurian gabbros were derived from partial melting of a more depleted mantle with the involvement of asthenosphere, and they have a close geochemical affinity with back-arc basin basalts. In addition, trace-element ratios and geochemical modeling suggest higher melting pressures for the mafic dikes than the gabbros. The geochemical differences show systematic variations from island-arc basalt into back-arc basin basalt types, which is consistent with the magma source evolution of the Mariana Trough. Thus, we interpret that the ca. 454 Ma mafic dikes were emplaced when the infant arc split, and they record initial back-arc rifting in the Erlangping unit, whereas the Silurian gabbros subsequently formed during the opening of the back-arc basin. Our study provides a paradigm for deciphering the evolution of back-arc basins through the study of spatiotemporal geological and geochemical variations of mafic intrusions in ancient accretionary orogens.

Origins of magmatism in the Okinawa Trough: Fe–Sr–Nd–Pb–Hf isotopic constraints

ABSTRACT The Okinawa Trough is an incipient back-arc basin formed by the subduction of the Philippine Sea Plate beneath the Eurasian Plate and is a natural laboratory for studying basin evolution, magmatism, and crust-mantle interactions during the early stages of back-arc spreading. Back-arc spreading and recent magmatism are occurring mainly in the Middle Okinawa Trough (MOT) and Southern Okinawa Trough (SOT). In order to investigate the magmatism in the Okinawa Trough, volcanic rock samples from the MOT and SOT were analysed for Fe – Sr – Nd – Pb – Hf isotopic compositions. The Fe isotopic compositions of basaltic andesite samples from the SOT are similar to or lower than MORBs. The fluid/melt derived from the subducted slab, especially the fluid dehydrated from slab serpentinites and sediment-derived melts, entered the overlying depleted mantle wedge and participated in magma generation, which resulted in the low δ56Fe values of the SOT basaltic magmas. The δ56Fe values of volcanic rocks from the MOT increase with increasing SiO2 contents, suggesting a gradual enrichment of heavy Fe isotopes during the evolution of the magma as it ascended to the surface. While the Sr – Nd – Pb – Hf isotopic compositions do not vary significantly, suggesting that the different samples are the products of different degrees of crystal fractionation of comagma. The fractional crystallization of olivine, pyroxene, and ilmenite minerals, which enrich in light Fe isotopes, resulted in the gradual increase in Fe isotopic values of magma during its evolution. The dacites and rhyolites from the southernmost Okinawa Trough have the similar δ56Fe values with the basaltic andesite and the basalt from the SOT and MOT, accompanied by significantly lower Nd and Hf isotope ratios relative to basalts, reflecting that the contamination of crustal materials would not change the magma in Fe isotope compositions evidently. Compared with the MOT, the volcanic rocks from the SOT was more affected by subduction components on their underlying mantle, and those from the southernmost experienced more contamination by crustal materials in the evolving magma.

An amphibolitic source for “adakitic” I-type plutons in continental collision zones

Rocks with “adakitic” affinities are widespread in continental collision zones, recording important information about crustal thickening. Residual garnet during partial melting of the lower crust is traditionally considered to be responsible for heavy rare earth element and Y depletion, which is a key characteristic feature of these rocks. However, magmatic garnet is rarely observed in such adakitic igneous rocks and associated protolithic eclogite is also rarely reported. Instead, amphibole is a proposed abundant phase in lower arc crust. Whilst both garnet- and amphibole-rich assemblages can act as potential sources for intracrustal intermediate-silicic melts, their distinctive fractionation of fSm/Nd and fLu/Hf should, with time, lead to different Nd-Hf isotopic compositions in high Sr/Y rocks. Here we report whole-rock radiogenic Sr-Nd-Hf and stable Fe isotope compositions of well-characterized Oligocene to Miocene (33-14 Ma), post-collisional high-K adakitic intrusions from the Gangdese belt, South Tibet. The plutons have a low alumina saturation index and depleted Dy/Yb, pointing to negligible amounts of sediment contribution. They are characterized by variable initial 87Sr/86Sr ratios (0.7048 to 0.7078), mostly negative εNd (−4.9 to +0.3), positive εHf values (+1.5 to +8.3), and variable but heavy δ57Fe values ranging from +0.04 ± 0.08‰ to +0.35 ± 0.08‰. Modeling of Fe isotopes and fractionation factors of fSm/Nd and fLu/Hf indicate an amphibolite source. A Nd-Hf isotope correlation that is quasi-parallel to the mantle array can be best explained by the evolution of amphibolitic lower crust with a residence time of ca. 400 Myrs. Although these adakitic rocks have depleted, mantle-like Hf isotope compositions, they are part of an existing, older crustal foundation and thus represent a process of crustal reworking, instead of crustal growth. Therefore, proportions of mantle-derived materials that contributed to the Phanerozoic crustal growth based on Hf-in-zircon signatures alone may be overestimated. Combined mineral and whole-rock radiogenic and stable isotopes are required to address this issue in the future.

Late Mesozoic magmatism and gold metallogeny of the Jiaodong Peninsula, China: A response to the destruction of the North China Craton

The late Mesozoic destruction of the eastern North China Craton (NCC) resulted from intense crust-mantle interaction, culminating in the formation of world-class gold deposits in the Jiaodong Peninsula at ca. 120 Ma. We present zircon U-Pb geochronological data, Hf isotopic compositions, whole-rock major and trace element, and Sr-Nd-Pb isotopic compositions for two suites of granitoids: one (the Linglong suite) that hosts significant mineralization and the other (the Weideshan suite) that is largely unmineralized. The Linglong suite was emplaced in the Late Jurassic at 160 ± 3 Ma to 155 ± 3 Ma, whereas the Weideshan suite was emplaced in the Early Cretaceous at 121 ± 2 Ma to 118 ± 1 Ma, coeval with gold mineralization. Geochemical data indicate the Linglong suite was derived from the melting of thickened lower crust of the NCC, mixed with material from the Yangtze Craton (YC) and intervening Su-Lu Orogenic Belt, whereas the Weideshan suite was formed from the partial melting of lower continental crust, with the addition of enriched lithospheric mantle components. The Late Jurassic magmatism was associated with crustal growth resulting from the continental collision between the NCC and YC and subsequent subduction of the Paleo-Pacific Oceanic Plate (PPOP). In contrast, Early Cretaceous magmatism was triggered by rapid lithospheric thinning and asthenospheric upwelling resulting from slab roll-back and stagnation of the PPOP beneath the NCC. Lithospheric delamination induced the widespread development of secondary structures associated with the major Tan-Lu Fault, providing favorable loci for the accumulation of auriferous fluids.

Characteristics of early Paleozoic granite-pegmatite and associated lithium-beryllium mineralization in the Tugeman area, Altun orogenic system, northwestern China

The Altun Orogenic Belt (AOB) is located on the northern margin of the Tibetan Plateau. We report the petrography, zircon U-Pb ages, Hf isotopic compositions, and whole-rock geochemistry of the Tugeman pegmatitic and granitic rocks from the AOB to constrain their petrogenesis and tectonic setting. Zircon U-Pb dating of the pegmatitic and granitic rocks yielded ages of 500–440 Ma, which we interpret as the emplacement ages of the granites and formation age of pegmatite. The granites are weakly peraluminous to peraluminous (A/CNK = 1.01–1.26), and they have high SiO2 (63.9–74.2 wt%) and Al2O3 (13.7–17.6 wt%) and low CaO (0.72–3.80 wt%) and P2O5 (0.06–0.44 wt%) contents. They show marked depletion in HREEs, enrichment in LREEs, and pronounced negative Eu anomalies, and they are enriched in Th, U, K, Pb, Nd, and Sm and depleted in Ba, Nb, Ce, Sr, P, and Ti. Zircon εHf(t) values vary from − 12.0 to + 3.3, with two-stage Hf model ages of 2.2–1.2 Ga, implying that the granites were derived mainly from ancient crust with a minor contribution from juvenile crust. Weakly peraluminous pegmatitic rocks have geochemistry characters of SiO2 (74.4–79.9 wt%) and Al2O3 (12.3–14.9 wt%) and low CaO (0.08–0.69 wt%) and P2O5 (0.05–0.33 wt%), depletion in HREEs, enrichment in LREEs, depletion in Ba, La, Ce and Ti, enriched in U, K, Pb and P. Granitic pegmatite can be formed at different stages of crystallization differentiation of granitic magma, but the pegmatite associated with highly differentiated granites is favorable to the Li and/or Be mineralization, while the pegmatite associated with low differentiated granites (such as biotite granites) is unfavorable to the Li and/or Be mineralization. Based on our findings, we propose that the Tugeman granitic magmas originated from partial melting of crustal metagreywacke and metabasalt. Furthermore, we suggest that the early Paleozoic magmatism in the Central Altun Block (CAB) can be categorized into three groups, which correspond to different tectonic events. These events include the northward subduction of the Central Altun Ocean (CAO) beneath the CAB around 520 Ma, the closure of CAO at 490–480 Ma, and post-collisional extension at 480–440 Ma induced by slab breakoff and delamination of the subducted CAO.

Petrogenesis of the Triassic Dongjiangkou pluton in the South Qinling orogenic belt, Central China: Insufficient magma mixing of mafic and felsic magmas

Magma mixing or mingling between mafic and felsic magmas is a common phenomenon in granitoid magmatism, and chemical and mechanical interactions between the magmas are frequently observed in granitic rocks. The Dongjiangkou pluton is an example of magma mixing among the numerous early Mesozoic granitoid plutons that are exposed in eastern South Qinling. This pluton is predominantly composed of granodiorite and contains abundant mafic/intermediate microgranular enclaves (MMEs) and is sporadically intruded by mafic dykes. Both the granodiorite and MMEs were crystallized at 224–214 Ma and have inherited zircons of similar age ranges. The granodioritic rocks had metaluminous to weak peraluminous features and adakitic signatures and belong to the high-K calc-alkaline series, whereas the MMEs and dioritic dykes had low SiO2 contents and metaluminous features and belong to the high-K calc-alkaline to shoshonite series. All of the rocks had high Mg# values and similar geochemical characteristics regarding trace elements and Sr isotopes, but they had diverse whole-rock Nd-Pb and zircon Hf isotopic compositions. The Dongjiangkou granodiorite was produced by partial melting of old basement rocks and Paleozoic juvenile crust beneath South Qinling triggered by asthenospheric upwelling. Magma(s) of the Dongjiangkou MMEs may have been derived from deep mantle and injected into and mixed with the magma(s) of the granodiorite, but chemical and isotopic homogenization was not achieved during the magma mixing process. Clastic rocks may have played a major role in the formation of crust-derived magma(s), causing strong Nd-Hf isotopic decoupling of several granitoid plutons in South Qinling.

Age of provenance for the Palaeoproterozoic Kemen Group, Udokan Complex: Newly recognised Palaeoproterozoic crust-forming event in the western Aldan Shield, Siberian Craton

In this study, new geological, geochronological, and Hf isotopic data are presented for the metaterrigenous deposits of the Kemen Group of the Udokan Complex in the Chara-Olekma terrane of the Aldan Shield, Siberian Craton. Their age of deposition and possible provenances are discussed, along with crust-forming events in the Aldan Shield. The Palaeoproterozoic carbonate-terrigenous deposits of the Udokan Complex in the Kodar-Udokan basin are the hypostratotype of the Lower Proterozoic deposits of the Eastern Siberia and the Far East, and host one of the largest and oldest sediment-hosted copper deposits. Concordia ages of detrital zircons demonstrate age peaks of ca. 2.02, 2.15, 2.38, 2.54, 2.73, 2.82, 2.93, 2.96, 3.00, 3.04 and 3.14 Ga on the probability plot. The morphology, internal texture, and Hf isotopic composition of the Meso- and Neoarchean detrital zircons indicate reworked Paleo- to Mesoarchean crustal sources in provenance areas. No rocks with the ages of ca. 2.02 Ga have been previously recognised in the Chara-Olekma terrane. Characteristics of the ca. 2.02 detrital zircons indicate their primary magmatic origin and proximal sedimentary transport. Hf isotopic data imply that the Palaeoproterozoic rocks in provenance area originated mainly from juvenile sources in a subduction-related setting. The Palaeoproterozoic island arc or an active continental margin probably existed within the western Aldan Shield or its framing and were later completely eroded or partially overlain by younger sediments. Erosion of the Palaeoproterozoic orogen led to deposition of the Chinei and Kemen groups of the Udokan Complex over a short time interval of ca. 1.90–1.88 Ga. Detrital zircons from the Kemen Group deposits reveal for previously unrecognised and lost from geological record Palaeoproterozoic crust-forming event on the western Aldan Shield. Available data show that significant part of the Siberian Craton was formed during ca. 2.07–1.98 Ga crust-forming events that indicate the discrete episodic nature of the continental crust formation and must be considered in models of its growth. The differences in isotope structure and geological history of the Siberia and the Laurentia are in agreement with palaeogeographic reconstructions suggesting that Siberia and Laurentia were not joined together in the Columbia/Nuna supercontinent.

A database of detrital zircon U–Pb ages and Hf isotopic compositions from the Tarim, West Kunlun, Pamir, Tajik and Tianshuihai terranes

AbstractWith the development of detrital zircon U–Pb ages and Hf isotope analysis as conventional sedimentological research methods, a large number of studies have been conducted in the Tarim, West Kunlun, Tajik, Pamir and Tianshuihai regions and abundant data have been accumulated. Summarizing these data to characterize sedimentary units and source regions is more important than local studies of specific geological epochs; therefore, we compiled a database of detrital zircon U–Pb ages and Hf isotope analyses from the Tarim, West Kunlun, Pamir, Tajik and Tianshuihai terranes. The database contains data from 90 papers, including 35,281 individual U–Pb ages and 4,181 Hf isotope analyses. The database records the literature source, petrologic sample information, regional geological information, geographic coordinates and analytical parameters for each data point in as much detail as possible to allow readers to review, process, analyse and use the data. The database relies on the Deep‐time Digital Earth (DDE) platform and uses an open database update system to enable sharing and collaborative building. We encourage other researchers to contribute relevant published data to facilitate wider use.

Geochronology and Geochemistry of Early Cretaceous A‐type Granites in Central–Eastern Inner Mongolia, China: Implications for Late Mesozoic Tectonic Evolution of the Southern Great Xing'an Range

AbstractThe southern Great Xing'an Range is the most critical Sn‐polymetallic metallogenic belt in northeast China. However, the tectonic setting of the Early Cretaceous magmatic‐metallogenic “flare‐up” event remains uncertain. This paper presents an integrated study on the occurrence, petrology, zircon U‐Pb ages, whole‐rock geochemistry, and in situ zircon Hf isotopes for Wenduerchagan granites of Xi Ujimqin Banner, central‐eastern Inner Mongolia. These granites consist primarily of granite porphyry (with ages of 137 ± 1 Ma and 138 ± 1 Ma) and (porphyritic) alkali feldspar granite (with an age of 141 ± 2 Ma), corresponding to the early Early Cretaceous. They are A‐type granites characterized by high silicon, alkali, and TFeO/MgO contents while being depleted of Ba, Nb, Ta, Sr, P, and Ti. They show right‐dipping trend rare‐earth element distribution characteristics with negative Eu anomalies (Eu/Eu* = 0.01–0.20) and weak heavy rare‐earth element fractionation ((Gd/Yb)N = 0.77–2.30). They demonstrate homogeneous zircon Hf isotopic compositions (positive εHf(t) values from +5.3 to +7.1 and young two‐stage Hf model ages of 851–742 Ma) and high zircon saturation temperatures (av. 810°C). These geochemical characteristics indicate that Wenduerchagan granites originated from the partial melting of juvenile crust under high‐temperature and low‐pressure conditions. Wenduerchagan granites most likely formed in a post‐collisional compression‐extension transition regime caused by the closure of the Mongol–Okhotsk Ocean, when combined with regional geology. Such a transition regime can probably be attributed to the upwelling of the asthenospheric mantle caused by the break‐off of a subducted Mongol–Okhotsk oceanic slab. Upwelling asthenospheric mantle provided sufficient energy and favorable tectonic conditions for magmatism and mineralization of the Early Cretaceous.

U-Pb-Hf isotope compositions of detrital zircons from Tongtian River sediments of northern-central Tibetan Plateau: Implications for the closure of the Jinshajiang Ocean

The closure time of the Jinshajiang Ocean (a branch ocean of the Paleo-Tethys) has been widely debated due to the complex structure and strong deformation of the northern-central Tibetan Plateau. In this paper, the U-Pb-Hf isotope compositions of detrital zircons from Tongtian River sand sediments from the northern-central Tibetan Plateau were analyzed via laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The UPb ages of the detrital zircons from Tongtian River sand sediments were distributed in six major groups: 2685–2346 Ma, 2035–1676 Ma, 1220–580 Ma, 544–407 Ma, 297–157 Ma, and 46–20 Ma. The εHf(t) values (range from −30 to +19) of the detrital zircons varied within a wide range from negative to positive, indicating that the zircons were sourced from diverse host magmas. The 46–20 Ma zircons and their Hf isotope compositions reveal that the far-field effect of the Cenozoic India-Eurasia plate collision triggered reworking of the Neoproterozoic basement of the North Qiangtang terrane. The U-Pb-Hf isotope compositions of these detrital zircons indicate that the Tongtian River sand sediments are composed of a mixture of materials from the Bayan Har-Songpan Ganzi terrane and the North Qiangtang terrane, with a contribution ratio of 3:7. The UPb ages and Hf isotope compositions of the zircons from the Tongtian River sediments and regional igneous rocks suggest that the εHf(t) values of the Permian zircons are predominantly positive while those of the Triassic, especially the Late Triassic, are negative. This marked shift most likely indicates that the closure of the Jinshajiang Ocean occurred by at least the Late Triassic.