Hf Isotopic Analyses Research Articles

Carboniferous–Early Permian volcano-sedimentary units from the northern margin of the North China Craton recorded subduction initiation in the Paleo-Asian Ocean

The precise timing of subduction initiation of the Paleo-Asian Ocean (PAO) in the northern margin of the North China Craton (NCC) remains controversial. In this study, we have conducted zircon UPb dating, whole-rock major and trace elements, and zircon Hf isotope analyses on metadacites and metamorphic greywackes from the Changde volcano-sedimentary rocks, feldspar quartz sandstones and argillaceous siltstones from the Luquantun Formation and the Sidao sedimentary rocks in central-eastern Jilin Province (NE China), to constrain the initial closure of the PAO. We obtained Early Carboniferous zircon UPb ages (345 ± 2 Ma and 351 ± 7 Ma) from the Changde volcano-sedimentary rocks. The metadacites are characterized by the enrichment in light rare earth elements and large ion lithophile elements, depletion in heavy rare earth elements and high field strength elements, and rare earth element ratios similar to those of the continental crust, indicating that these rocks originated from crustal melting. The metadacites exhibit affinity with the peraluminous A-type granite, with high zircon εHf(t) values (+3.46 − +12.21) and TDM2 of 1132–571 Ma, suggesting that they formed in a post-collisional extensional setting. Detrital zircon UPb ages from the Luquantun Formation and Sidao sedimentary rocks constrain their maximum depositional ages to the Late Carboniferous (319 ± 5 Ma) and Early Permian (284 ± 4 Ma), respectively. Most detrital zircons have age peaks at 1800 Ma with negative zircon εHf(t) values, and 2500 Ma with positive zircon εHf(t) values, suggesting that the Carboniferous–Early Permian sediments from these two formations were mainly sourced from the NCC. Moreover, the chemical index of alteration, index of compositional variability, and plagioclase index of alteration values suggest that the sediments of the Changde volcano-sedimentary rocks originated from a mafic igneous source with a low degree of weathering and a sedimentary recycling history, while the samples from the Luquantun Formation and Sidao sedimentary rocks were sourced from an intermediate-felsic igneous rock with a moderate to intense degree of weathering and mainly influenced by source composition. The crystallization age curves and summary plots of detrital zircons indicate that the Early Carboniferous metamorphic greywackes from the Changde Formation were mainly deposited in a passive margin, while the Carboniferous–Early Permian sediments of the Luquantun Formation and Sidao sedimentary rocks were mainly deposited in an active margin. We suggest that the tectonic transition from passive to active margin occurred at ∼333 Ma, marking subduction initiation in the PAO close to the northern margin of the NCC.

The Cretaceous suturing process of the eastern Bangong–Nujiang Ocean, Basu area

The Bangong–Nujiang Ocean played an important role in the formation of the Tibetan Plateau prior to the Cenozoic India–Eurasia collision. However, there are still uncertainties about the subduction polarity and timing of the Lhasa–Qiangtang collision. We conducted sandstone petrologic and detrital zircon U–Pb–Hf isotopic analyses on the Cretaceous Wada mélange, trench-fill strata and Duoni Formation in the Basu area in the eastern Bangong–Nujiang Suture Zone. The Wada mélange (∼114 Ma) exhibits block-within-matrix features and a detrital zircon U-Pb age spectrum characterized by multiple peaks at 114–180 Ma, 200–300 Ma, and 1800–2000 Ma. The trench-fill strata consist of coherent chert, sandstone, and mudstone, with a detrital zircon age spectrum dominated by a single peak at ∼120 Ma. The εHf(t) values of the 110–300 Ma detrital zircon grains in the Wada mélange and trench-fill strata range from −20 to +10 and are consistent with those of the South Qiangtang Terrane. The εHf(t) values of the ∼120 Ma detrital zircons are all negative, and these grains were likely derived from a remnant Cretaceous arc in the South Qiangtang Terrane to the north. These data suggest that the accretionary wedge was derived from the South Qiangtang Terrane during the northward subduction of the Bangong–Nujiang Ocean. The Duoni Formation (∼113 Ma) represents peripheral foreland basin deposits with the Lhasa Terrane as the basement. Provenance analysis indicates that these deposits received clastic material mainly from the South Qiangtang Terrane and to a lesser degree from the North Lhasa Terrane. Our results suggest that the Lhasa–Qiangtang collision occurred in the Early Cretaceous (∼113 Ma) in the eastern segment of the Bangong–Nujiang Suture Zone.

Origin and Geological Implications of Monzogranites and Rhyolitic Porphyries in the Wunugetu Porphyry Copper–Molybdenum Deposit, Northeast China: Evidence from Zircon U-Pb-Hf Isotopes and Whole-Rock Geochemistry

The Wunugetu deposit, a large-scale porphyry copper–molybdenum deposit, is located in the southern Erguna block. Its ore bodies are primarily found within monzogranites, granite porphyries, and biotite monzogranites. Additionally, the deposit contains late-stage intrusive dykes of rhyolitic porphyries. This study examined the deposit’s monzogranites and rhyolitic porphyries using lithogeochemistry, zircon U-Pb dating, and Hf isotopic analysis. The main findings include: (1) Zircon U-Pb dating showed that the monzogranites formed around 209.0 ± 1.0 Ma, whereas the rhyolitic porphyries in the northern portion formed around 170.49 ± 0.81 Ma, suggesting magmatic activity in the deposit spanned from the Late Triassic to the Middle Jurassic. (2) The monzogranites exhibited high silicon content (73.16–80.47 wt.%) and relatively low aluminum content (10.98–14.37 wt.%). They are enriched in alkalis (content: 3.42–10.10 wt.%) and deficient in magnesium and sodium, with aluminum saturation indices (A/CNK) ranging from 1.1 to 2.9. In addition, the monzogranites are enriched in large-ion lithophile elements (LILEs) such as Rb, K, and Ba and deficient in high-field-strength elements (HFSEs) like Nb, P, and Ti. (3) The monzogranites have low Zr + Nb + Ce + Y contents of (151.3–298.6 ppm) × 10−6 and 10,000 × Ga/Al ratios varying between 1.20 and 2.33, suggesting that they are characteristic of I-type granites. (4) Positive zircon εHf(t) values ranging from +0.3 to +7.6 in both rhyolitic porphyry and monzogranite samples, increasing with younger emplacement ages, imply that the deposit’s rocks originated from magmatic mixing between mantle-derived mafic magmas and remelts of the juvenile crust. Considering these results and the regional geological evolution, this study proposes that the Wunugetu deposit was formed in an active continental margin setting and was influenced by the Late Triassic–Middle Jurassic southeastward subduction of the Mongol-Okhotsk Ocean.

New geochemical and geochronological insights on forearc magmatism across the Sanak-Baranof belt, southern Alaska: A tale of two belts

Abstract The Sanak-Baranof belt includes a series of near-trench plutons that intrude the outboard Chugach–Prince William terrane over ~2200 km along the southern Alaskan margin. We present new petrological, geochronological, and geochemical data for comagmatic microgranitoid enclaves and granitoid rocks from the Crawfish Inlet (ca. 53–47 Ma) and Krestof Island (ca. 52 Ma) plutons on Baranof and Krestof Islands, as well as the Mount Stamy (ca. 51 Ma) and Mount Draper (ca. 54–53 Ma) plutons and associated mafic rocks that intrude the Boundary block at Nunatak Fiord near Yakutat, Alaska, USA. These data suggest that intrusion of the Sanak-Baranof belt plutons is actually a tale of two distinct belts: a western belt with crystallization ages that young systematically from west to east (63–56 Ma) and an eastern belt with crystallization ages ranging from 55 to 47 Ma, but with no clear age progression along the margin. Hf isotope analyses of magmatic zircon from the western Sanak-Baranof belt become increasingly evolved toward the east with εHft = 9.3 ± 0.7 on Sanak Island versus εHft = 5.1 ± 0.5 for the Hive Island pluton in Resurrection Bay. The Hf isotope ratios of eastern Sanak-Baranof belt rocks also vary systematically with age but in reverse, with more evolved ratios in the oldest plutons (εHft = +4.7 ± 0.7) and more primitive ratios in the youngest plutons (εHft = +13.7 ± 0.7). We propose that these findings indicate distinct modes of origin and emplacement histories for the western and eastern segments of the Sanak-Baranof belt, and that the petrogenesis of eastern Sanak-Baranof belt plutons (emplaced subsequent to 57–55 Ma) was associated with an increasing mantle component supplied to the youngest eastern Sanak-Baranof belt magmas. These plutons reveal important information about offshore plate geometries and a dynamic period of plate reorganization ca. 57–55 Ma, but a clearer picture of the tectonic setting that facilitated these Sanak-Baranof belt intrusions cannot be resolved until the magnitude and significance of lateral translation of the Chugach–Prince William terrane are better understood.

Petrogenesis of Neoarchean granitic gneisses from the Daqishan area of the Dabie orogen and implications for the early crustal evolution of the Northern Yangtze Craton

ABSTRACT The Yangtze Craton is one of the crucial cratons constitued the eastern Asia continent. It is characterized by Archaean to Paleoproterozoic basement rocks, making it an excellent area to study the Precambrian geologic and tectonic regime. Recently, abundant Archaean rocks have been reported from the Dabie Orogen, which providing important information to understanding the early evolution of the Northern Yangtze Craton. In this contribution, we present petrological, whole-rock geochemical, and zircon U – Pb – Hf isotopic analyses on newly discovered Neoarchean granite in the Dabie Orogen. We identified 2744 ± 10 Ma and 2715 ± 11 Ma (~2.74 Ga) Na-rich granitic gneisses, 2691 ± 6 Ma and 2696 ± 8 Ma (~2.69 Ga) A2-type granitic gneisses, and 2664 ± 8 Ma, 2664 ± 6 Ma, 2672 ± 7 Ma, 2642 ± 10 Ma (~2.66 Ga) A1-type granitic/syenite gneisses from the Daqishan area of the Dabie Orogen. Geochemical and zircon Hf isotope data indicate that the ~ 2.74 Ga Na-rich granitic gneisses were partial melting products of thickened mafic crust with limited depleted mantle input, while the 2.69 Ga and 2.66 Ga A-type granitic gneisses represent felsic magmatism in a post-collisional to an extensional tectonic setting. Based on our research, we categorized the Northern Yangtze Craton into the Kongling domain and Dabie domain by comparing with the distribution of the zircon U-Pb magmatic ages and metamorphic events. We suggest that the initial unified basement of the northern proto-Yangtze Craton formed during the Nuna supercontinent cycle at ~ 2.0 Ga.

Research on characteristics and geological genesis of large-scale deep-seated landslide in tuff formation

In engineering practice, engineers generally treated tuff as a lumpy material with a poorly defined laminated structure and a rock group that was not susceptible to slide failure. Most studies of tuff landslides had focused on small clastic landslides in shallow strata with weathering boundaries and lithologic interfaces as slip surfaces. This paper takes a large-scale, deep-seated tuff landslide on the southeast coast of China as the research project. We used borehole TV imaging and exploration tunnels to confirm the material composition and structural characteristics of the tuff stratum and used exploration tunnels to expose the slip soil directly. Microscopic identification, mineralogical composition analysis, zircon U-Pb isotope dating, and Hf isotope analysis of slip soils collected from the exploration tunnels elucidated the geologic background and genesis of the large-scale deep-seated landslides in the tuff stratum. It was found that the formation of a tuff stratum in the landslide area was caused by multi-volcanic orogeny and multi-phase tectonics. The timing of the melting of the original magma from these volcanic events also differs. During these intervals between eruptions, deposition occurred, and this sedimentary material formed the slip soil.

A uniform basement: Implications for the tectonics of Beishan Orogenic Belt in the southern Central Asian Orogenic Belt

The orogen is a significant window for studying the history and architecture of Earth; its architecture involves many significant issues. Currently, research on the architecture of orogenic belts mainly focuses on the process of orogeny, and few studies focus on the tectonics before the orogeny, which somewhat constrains orogen evolution. The nature of the basement(s) of microcontinents in the Beishan Orogenic Belt (BOB) in the middle Central Asian Orogenic Belt (CAOB) has been debated for a long time, which causes confusion about the tectonics of the BOB. This study conducted field surveys, geochronology, geochemistry, and Hf isotope analysis on the major microcontinents of BOB. The age information of ca. 1.4 Ga and the Paleoproterozoic-Archean with small scale were found in the northern BOB. The northern BOB (NBOB) and southern BOB (SBOB) (separated by the Hongliuhe-Niujuanzi-Xichangjing ophiolitic mélange belt) have experienced similar magmatic thermal events at ca. 1.4 Ga and ca. 0.9 Ga, which are revealed by the analogical tectonic setting, formation ages, and Hf isotopic features. The Precambrian basements of the NBOB and SBOB are analogous in terms of rock assemblages, detrital zircon ages, magmatic rock ages, εHf(t) of Precambrian rocks, and Hf crustal model ages TDMC of Paleozoic igneous rocks, which imply that they shared similar history and provenance and might originate from a uniform basement. The basement has no close tectonic affinity to the adjacent cratons or blocks, except the Baltica Craton and Laurentia Craton. And it might have been involved in the amalgamation of the Columbia Supercontinent and be situated on the periphery of the Rodinia Supercontinent, and then fragmented when the Rodinia Supercontinent rifted apart.

Petrogenesis of high heat producing granites and their contribution to geothermal resource in the Huangshadong geothermal field, South China

The Huangshadong geothermal field (HGF), situated in the contact zone between Mesozoic granites and NE-striking dominant faults in South China, has great geothermal potential. Petrogenesis of reservoir rock plays an important role in understandings its genetic mechanism and assessing geothermal potential. However, due to the lack of rock sample at depth collected from the geothermal reservoir, the petrogenesis of granites in the geothermal reservoirs of the HGF, remains an enigma. This study elucidated the petrogenetic characteristics of these granites sampled directly from geothermal reservoir at the depth of ∼3,000 km and their geothermal implications through zircon U-Pb dating, geochemical analysis, and Hf isotopic analysis. The zircon U-Pb ages indicate that the magmatism evolution of HGF contains three eras, namely, Cretaceous (135 ± 4 to 143.6 ± 2.8 Ma), Jurassic (152.7 ± 2.7 to 176.7 ± 1.8 Ma), and Permian granites (251 ± 9.1 to 251 ± 5 Ma) from the youngest to oldest. The reservoir granites were emplaced during the latest stage of Cretaceous intrusion, as indicated by the zircon U-Pb ages (135 ± 4 Ma and 135.3 ± 2.4 Ma) of rock samples from the deep part of well HR-1. These Cretaceous rocks are highly fractionated I-type granites, featuring high SiO2, K2O, and Na2O contents, high Rb/Sr ratios, low Zr/Hf, Nb/Ta, and Th/U ratios, and A/CNK values of 1.05–1.13. Compared to other Cretaceous granites outcropping on the margin of the HGF, these granites have undergone the strongest fractional differentiation. The Cretaceous granites in the HGF are high-heat-producing rocks (>5 μW/m3), with an average heat production rate of 6.63 μW/m3. Notably, the Cretaceous reservoir granites (as reservoir rocks) serve as an important heat source for the formation of geothermal resources in the HGF. In addition, the zircon Hf isotopic composition indicates that the reservoir Cretaceous granites originated from Meso-to Paleo-Proterozoic lower crustal materials (TDM2: 1,385 to 1907 Ma).

New Insights on the Early Proto-Tethys Subduction History: Evidence from Ages and Petrogenesis of Volcanic Rocks in the Bulunkuole Complex, West Kunlun Orogen

Abstract The Proto-Tethys Ocean has played a significant role in the geological history of Earth. However, ongoing debates persist regarding the timing and polarity of its early subduction. Volcanic rocks associated with iron deposits in the Bulunkuole Complex, West Kunlun Orogen, offer insights into both the complex’s formation age and Proto-Tethys evolution. This study presents newly obtained zircon U–Pb age data (~536 Ma) along with comprehensive whole-rock major and trace element and Sr–Nd–Hf isotope analyses of these volcanic rocks. Our dataset implies that the Bulunkuole Complex partly formed in the early Paleozoic rather than entirely in the Paleoproterozoic, as previously suggested. Geochemically, the volcanic rocks exhibit enrichments in large ion lithophile elements and light rare earth elements, along with depletions in high-field strength elements. They also display elevated initial 87Sr/86Sr values (0.71093, 0.72025) and negative εNd(t) values (−5.13, −6.18), classifying them as continental arc volcanic rocks. These geochemical fingerprints, complemented by zircon εHf(t) values (−12.7 to −1.6), indicate that the parental magmas of the volcanic rocks were produced by partial melting of the lithospheric mantle wedge, which had been metasomatized by subducted sediment-derived melts. The available data, in conjunction with previously published findings, strongly suggest that the Proto-Tethys Ocean subducted southward prior to approximately 536 Ma due to the assembly of Gondwana. Subsequent slab rollback may have resulted in a crustal thinning of 9–25 km during 536–514 Ma. Further shifts in subduction dynamics led to the transition from high-angle subduction to either normal or low-angle subduction, facilitating the formation of a thicker crust ranging from 39 to 70 km between 514 and 448 Ma. This study, therefore, provides valuable insights into the early evolution of the Proto-Tethys Ocean and contributes significantly to our understanding of the tectonic history of the West Kunlun Orogen.

Late Cretaceous high Sr/Y rocks and local crustal thickening in the eastern Gangdese batholith, southern Tibet

The voluminous Late Cretaceous calc-alkaline magmatic rocks in the Gangdese batholith provide an important record on the mechanisms of the thickening and growth of the continental crust in a continental arc environment. Here, we report data from zircon UPb geochronology and geochemical (whole-rock element and SrNd isotopes and zircon Hf isotope) analyses for the granodiorite and granite from Langxian to Lilong in the eastern Gangdese batholith. These data show that 1) the intermediate-felsic rocks formed at 82–70 Ma and are Na-rich peraluminous rocks. 2) The granodiorite commonly developed magmatic epidote with allanite-rich cores. 3) They are characterized by high Sr/Y and (La/Yb)N ratios, exhibiting an adakitic affinity. 4) Most of the samples have positive εHf(t) (+5.2 − +12.4) and bulk εNd(t) (+1.9 − +2.8) values, indicating that they were derived from partial melting of juvenile crust. 5) The crustal thickness in the eastern part of the Gangdese batholith locally thickened to ∼67 km. The data presented in this paper demonstrates that the Late cretaceous granodiorite and granite were generated by partial melting of the juvenile thickened lower crust (∼67 km) with deep seated emplacement, and then they experienced rapid exhumation. The magmatic flare-up (90–75 Ma) and ocean ridge subduction in the eastern Gangdese batholith are responsible for the magma inflation and local crustal thickening.

Petrogenesis of 2.7–2.65 Ga TTGs in the Wutai Complex: Constraints on the Neoarchean crustal evolution of the North China Craton

The Wutai complex, located on the boundary between the Eastern and Western Blocks of the North China Craton (NCC), offers valuable insight into early crustal growth and evolution of the NCC. In this study, a suite of 2.7–2.65 Ga TTG gneisses has been identified in the Wutai complex. Zircon grains from eight samples indicate that their protoliths were emplaced between 2706 Ma and 2640 Ma. The trondhjemites have low K2O/Na2O, high La/Yb and Sr/Y ratios, and positive Eu anomalies. The observed trend of decreasing Dy/Yb and Dy/Dy* ratios with increasing La/Yb ratios support for an amphibole-dominated fractional crystallization process during the TTG formation. Zircon Hf and oxygen isotope analyses (εHf(t) = 3.5–7.0, TDM = 2.86–2.71 Ga; δ18O = 5.5–6.3 ‰) indicate that the parental magma may originate from juvenile crustal sources altered by surface water at low temperature. When combined with the previous studies of volcanic rocks and TTGs formed around 2.5 Ga, it becomes evident that the Wutai complex experienced significant crustal growth during the period from 2.7 to 2.5 Ga. The identification of 2.7–2.65 Ga magmatic activity as well as the older detrital/xenocryst zircons up to 3.6 Ga, provide increasing evidence that the Wutai complex has a much longer and nearly continuous geological history. Combined with geological evidence, zircon data compilations and the Re-depletion model age distribution of the mantle xenoliths of the NCC, it can be inferred that the period from 2.6 to 2.5 Ga was likely the most significant for the crustal generation within the NCC's geological history.

Zircon U-Pb-Hf Isotopes and Whole-Rock Geochemistry of the “Kulumudi Formation” from the Laofengkou Area (West Junggar): Implications of the Construction of a Juvenile Arc in the Junggar–Balkhash Ocean

The properties of ancient magmatic arcs are crucial for understanding the tectonic evolution of the Central Asian Orogenic Belt. The Middle Devonian Kulumudi Formation in the Laofengkou area of West Junggar lacks accurate chronological data constraints, which hampers the knowledge of the nature of the Late Paleozoic magmatic arcs in the West Junggar and circum-Balkhash areas. In this contribution, samples of pyroclastic rocks and sedimentary rocks were collected from the volcano–sedimentary strata of the Kulumudi Formation. Petrography, zircon U-Pb-Hf isotopic analysis and whole-rock geochemistry were carried out to constrain the age and the tectonic setting of the Kulumudi Formation. The zircon U-Pb age of the lithic crystal tuff from the Kulumudi Formation on the northeast side of the Alemale Mountains was 386 ± 2 Ma, accurately indicating that this rock unit formed during the Middle Devonian. However, the fine sandstone near the Huojierte Mongolian Township, originally assigned as the “Kulumudi Formation”, yielded a maximum depositional age of 341 ± 3 Ma. Combined with the stratigraphic contact, this rock unit was redefined to belong to the Lower Carboniferous Jiangbasitao Formation. According to the whole-rock geochemistry study, the lithic crystal tuff of the Kulumudi Formation was characterized as medium potassium–calc–alkaline series rock, which is relatively enriched in light rare earth elements and large ion lithophile elements (i.e., Rb, Ba, K) and depleted in high-field-strength elements (i.e., Nb, Ta, Ti), showing similar geochemical characteristics to the volcanic arc rocks. By contrast, the fine sandstone from the Jiangbasitao Formation had Al2O3/SiO2 (0.25–0.29) and K2O/Na2O (1.29–1.72) ratios close to those derived from the continental arc and active continental margin and was characterized as part of the continental arc field in the La-Th-Sc and Th-Sc-Zr/10 tectonic discrimination diagrams. Zircon Hf isotope analysis showed that the εHf(t) values of the Kulumudi Formation were +5.6–+12.8, and those of the Jiangbasitao Formation were +11.43–+15.48, both of which show highly positive juvenile characteristics. The above data indicate that the Kulumudi Formation and Jiangbasitao Formation both formed in a juvenile arc setting with ocean–continent subduction. Combined with the previous work, it was concluded that the southward subduction of the ocean basin represented by the Darbut–Karamay ophiolitic mélanges beneath the newly accreted arc crustal segments produced a juvenile arc with positive Hf isotope characteristics.

Chronological and Mineralogical Records of the Langqi Pluton, Fuzhou: Constraints on the Magma Mixing Process

The mafic microgranular enclaves (MMEs) from Mesozoic intermediate-acid magmatic rocks, widely developed along the Fujian coast, are considered to be the results of large-scale crust–mantle interaction by magma mixing. This paper is based on zircon U-Pb chronology, along with zircon Hf isotope and mineral analyses for the host granite and MMEs from Langqi Island, in order to investigate the magma mixing mechanism of the Langqi pluton in Fuzhou, Southeast China. The results indicate that the MMEs were emplaced during the late Early Cretaceous (98.9 ± 2.2 Ma), identical to the age of the granite (100.1 ± 1.1 Ma) within the error range. The zircon εHf(t) values for the granite and MMEs are in the ranges of −2.1~0.0 and −1.7~+1.1. The zircon Hf isotope data indicate that both the granite and MMEs were predominantly derived from the ancient crustal basement of Cathaysia, with a partial mantle-derived contribution. The An values of plagioclase phenocrysts with oscillatory zoning patterns in the MMEs show oscillatory changes from the core to the rim, indicating multiple mixing events between the two magmas with different compositions. Amphiboles in the MMEs show characteristics of crust–mantle contamination, and the Ti migrated from the mafic magma with high concentration to the felsic magma with low concentration during the magma mixing process. Biotites in the host rock and MMEs belong to primary biotite, and they have relatively high MgO contents (ave. 12.78 wt.%) and relatively low FeOT/(MgO + FeOT) ratios (ave. 0.56), showing characteristics of crust–mantle contamination. The crust–mantle magma interaction in a crystal, mushy state played a significant role in controlling the formation and evolution of the Langqi pluton. The magmatism was predominantly sourced from mixing between the mantle-derived mafic magma and the crust-derived felsic magma during the subduction of the Paleo-Pacific Plate, resulting in the formation of the Langqi doleritic veins, granites, and MMEs.

Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block, NW China and their geological significance: Constraints from drill cores geochronology and geochemistry studies

As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive εHf(t) values (–0.04 to +11.35) with TDM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon εHf(t) values (–1.93 to + 6.58) with TDM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A1-type granite formed in a continental rift setting.Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica.

Methodologies for 176Lu-176Hf Analysis of Zircon Grains from the Moon and Beyond.

Zircons are found in extraterrestrial rocks from the Moon, Mars, and some differentiated meteorite parent-bodies. These zircons are rare, often of small size, and have been affected by neutron capture induced by cosmic ray exposure. The application of the 176Lu-176Hf decay system to zircons from planetary bodies such as the Moon can help establish the chronology of large-scale differentiation processes such as the crystallization of the lunar magma ocean. Here, we present methods to measure the isotopic composition of Hf of extraterrestrial zircons dated using ID-TIMS U-Pb after chemical abrasion. We introduce a 2-stage elution scheme to separate Hf from Zr while preserving the unused Zr fraction for future isotopic analysis. The effect of neutron capture is also re-examined using the latest thermal neutron capture cross sections and epithermal resonance integrals. Our tests show that the precision of Hf isotopic analyses is close to what is theoretically attainable. We have tested this method to a limited set of zircon grains from lunar rocks returned by the Apollo missions (lunar soil 14163, fragmental polymict breccia 72275, and clast-rich breccia 14321). The model ages align with previously reported values, but further work is needed to assess the chronology of lunar magma ocean crystallization as only a handful of small zircons (5 zircons from 3 samples) were analyzed, and the precision of the analyses can be improved by measuring more and larger lunar zircon grains.

Nature of the Two Episodes of Paleoproterozoic Magmatism (2495 Ma and 2190 Ma) in the Trans-North China Orogen, North China, with Implications for the Tectonic Evolution

Abstract Understanding the temporal and spatial evolution of the North China Craton (NCC) basement, formed by amalgamation, is a crucial issue in global geosciences. The Huozhou complex is situated at the core of the Trans-North China Orogen (TNCO) in the NCC and comprises a considerable number of Palaeoproterozoic granitic gneisses, providing valuable insights into the tectonic evolution of the TNCO. In this study, comprehensive field geological surveys, petrology, chronology, geochemistry, and Hf isotope analysis were conducted to investigate the genesis and tectonic context of the Xingtangsi and Zhengnangou granitic gneisses and elucidate the TNCO’s tectonic evolution. The Xingtangsi granite gneiss yielded a magmatic zircon age of 2495±34 Ma, implying its Palaeo-proterozoic or Archean origin, as previously suggested. Its protolith was I-type peraluminous granite, primarily generated through the partial melting of pre-existing continental crust materials with a small quantity of mantle-derived magma. The Zhengnangou granitic gneiss’s protolith was A-type granite, and its magmatic zircon age was 2,190 ±11 Ma, indicating its Palaeoproterozoic origin rather than Archean. TDM1(Ma) for the Zhengnangou granitic gneiss ranged from 2,424 to 2,498 Ma, TDM2(Ma) varied from 2563 to 2684 Ma, and the εHf(t) value ranged from 1.3 to 3.3. These results suggest that it was primarily derived from newly formed crustal materials without any mantle-derived addition. Integrating our data with the literature, the ∼2.5 Ga magmatic activity in the Huozhou area may have formed in the tectonic setting of the continental arc, and ∼2.2 Ga A-type granite may have formed in a post-collisional extensional environment.

Formation of boehmite through desilication of volcanic-ash-altered kaolinite and its retention for gallium: Contribution to enrichment of aluminum and gallium in coal

Multiple parting bands within Permo–Carboniferous coal that are generally enriched in critical metals in the northern North China have been confirmed to be altered from volcanic ash (tonsteins). The tonsteins and adjacent coal in some areas contain boehmite with varying contents. Whether or not the boehmite has a relationship with the volcanic-ash-altered kaolinite remains poorly understood. Herein, petrographical, mineralogical, whole-rock geochemical, and in-situ elemental analyses, combined with U–Pb–Hf isotopic analysis of zircon, were performed for the boehmite-bearing/rich partings and coal collected from the eastern edge of the Datong and Jungar coalfields. Except for the boehmite, well-ordered kaolinite is predominant in the parting samples, where the columnar/tabular and vermicular kaolinite are commonly present. Additionally, the zircons separated from the representative parting and coal samples are mostly igneous origin with only one age population of ca. 300 Ma, almost same with the depositional age of the coal, suggesting that the kaolinite in the inorganic constitutes of the investigated coal seams were mainly altered from volcanic ash. Numerous fine-grained boehmite exhibit textural features of replacement for columnar/tabular and vermicular kaolinite along the cleavage cracks in the parting samples, suggesting that such boehmite were formed from desilication of volcanic-ash-altered kaolinite. The tonsteins and coal along the eastern edge of the coalfields were uplifted and influenced by fault activities due to Indosinian and Yanshan orogeny, which were probably experienced intensive leaching by silica-undersaturated percolating water and groundwater, resulting in desilication of volcanic-ash-altered kaolinite and precipitation of residual Al as boehmite. The Ga, preserved in the alumina octahedral sheets of volcanic-ash-altered kaolinite, were retained by boehmite due to its very similar geochemical behavior with Al. The formation of boehmite and its retention for Ga made a contribution to the genesis of high–Al–Ga coal in the northern North China.

Petrogenesis and tectonic implication of the Triassic syenitic complexes in the eastern Qinling orogen, central China

Alkaline igneous rocks usually provide significant information on the mantle-derived components, magmatic processes and crust–mantle interaction due to their deep source. The Songxian syenite, located in the Xiong'er terrane of the Qinling Orogen, is one of the most typical alkaline intrusions in the Early Mesozoic. Geochemical, geochronological and in situ Sr–Nd–Hf isotopic analyses were conducted on the alkali-feldspar syenite and aegirine-augite syenite samples collected from the Songxian syenite, in order to reveal the magma sources, petrogenesis and possible geodynamic implications. All the rock samples are enriched in alkali (Na2O + K2O = 11.74 to 15.14 wt%), light rare earth elements and large ion lithophile elements, and depleted in high field strength elements. Zircon LA–ICP–MS U–Pb dating of medium- and fine-grained alkali-feldspar syenites yield emplacement ages of 235.5 ± 0.9 Ma and 232.7 ± 3.3 Ma, respectively. In addition, the aegirine-augite syenite generally developed as dyke or vein cutting through the two types of alkali-feldspar syenite in the field, indicating multiple pulses of magmatism. In-situ Sr-Nd isotopic analyses on magmatic apatite yielded (87Sr/86Sr)i ratios from 0.707959 to 0.710414 and εNd(t) from −19.3 to −13.9 for alkali-feldspar syenite, while the analyses for aegirine-augite syenite yielded (87Sr/86Sr)i ratios from 0.717948 to 0.721470 and εNd(t) from −25.5 to −24.5. The difference suggests that the Songxian syenite may be generated from multi-stage magmatic episodes. The first magmatic incident mainly originated from the partial melting of the enriched lithospheric mantle, mixed with the lower crust-derived melts. The second mixing magma might involve more proportion of Archean to Paleoproterozoic crust-derived materials. During the Early Mesozoic, the Mian-Lue oceanic slab subducted northward to the asthenosphere mantle and induced asthenosphere upwelling. Under the tectonic setting, the mixture of enriched mantle- and crust-derived melts occurred to form the Songxian syenite.

Archean to Paleoproterozoic magmatic and metamorphic evolution of the Lofoten – Vesterålen area in northern Norway through zircon U-Pb and Hf isotopic analysis

Neoarchean (2.8–2.5 Ga) and Paleoproterozoic (2.5–1.6 Ga) crust preserves a record of major crustal growth events, the oldest supercontinent assemblies, and the likely transition to modern plate tectonics. The Lofoten–Vesterålen area in Norway underwent a multistage tectono-magmatic history from the Neoarchean to the Paleoproterozoic. In this region three main components are distinguished: 1) a granulite facies zone (GFZ); 2) an amphibolite facies zone (AFZ); and 3) an anorthosite-mangerite-charnockite-granite (AMCG) suite. New zircon U-Pb and Lu-Hf isotope data are used to investigate the evolution of this 2.7–2.6 and 1.9–1.8 Ga crust and evaluate how the developments fit in the global context of Earth’s crustal evolution. In-situ LASS–MC-ICPMS analyses were conducted on zircons to simultaneously determine U-Pb ages and Hf isotope compositions. Solution Hf isotope compositions were additionally obtained on zircons previously dated by ID-TIMS. In general, there is a good agreement between solution and in-situ data. Samples from the GFZ and AFZ both yield Neoarchean (2.7–2.6 Ga) and Paleoproterozoic (1.9–1.8 Ga) populations. Neoarchean populations have εHf(i) of +0.9 to −0.3; Paleoproterozoic populations have εHf(i) around −16 and −7 at ∼1.80 and ∼1.87 Ga, respectively. The AMCG suite was emplaced in two magmatic pulses: the early one at 1.87–1.86 Ga characterized by εHf(∼1.87 Ga) ∼ −7, and the main pulse at 1.80–1.79 Ga has εHf(∼1.80 Ga) between −4.0 and −15.0. Metamorphic overprinting recorded within the GFZ and the AMCG at ∼1.80 Ga is absent in the AFZ, supporting the hypothesis of a tectonic boundary between these domains. The Hf isotope compositions suggest that Paleoproterozoic magmatism was sourced from a combination of juvenile material and incorporated ancient crust, probably in variable proportions, as suggested by the variation in the isotope composition of the AMCG suite. Broadly chondritic Hf isotope compositions in Neoarchean rocks indicate the absence of significantly older crust as a source component. Main crustal growth events recorded in the Lofoten–Vesterålen area coincide with global age peaks and zircon Hf isotope record. The AMCG suite was emplaced during the Columbia supercontinent assembly. Neoarchean and Paleoproterozoic crust in the Lofoten–Vesterålen area exemplifies the elevated preservation potential in collisional tectonic settings.

Zircon xenocryst geochronology and implications for the Lhasa terrane evolution: Insights from Cenozoic volcanic rocks (Coqen, Tibet)

The Cenozoic volcanic rocks of Coqen are located in the western central Lhasa subterrane, where knowledge of the regional lithospheric architecture and related magmatic processes is still lacking. To address this issue, we used in situ U–Pb dating, Lu–Hf isotopic and mineral inclusion analysis in zircon xenocrysts among trachyandesite. These zircons from volcanic samples yielded wide U–Pb ages from 18 Ma to 2424 Ma, showing three significant age peaks at ∼246 Ma, 193 Ma, and the most intense one at 128 Ma, which represent three major magmatic processes that developed in the area. The earliest zircon dates suggest the age of volcanic eruption in the Coqen area was not earlier than 18 Ma. zircon xenocrysts trace elements data point to the central Lhasa subterrane continental crust origin. We provide evidence for evolutive magmatism of the Lhasa terrane by calculating ΔFMQ, and show that the oxygen fugacity goes from reduced to oxidized (Cambrian to Miocene). The very low εHf(t) indicate a long-term magmatic event sequence, with the Zenong Group having the most vigorous magmatic activity. The old U–Pb ages and TDMC confirmed that an ancient basement of the Precambrian exist in the middle Lhasa terrane. Our work also restores the tectonic and crustal thickness evolutionary process of Coqen area even entire Lhasa terrane. In the back of a series of thickening and thinning processes, the Tibetan crust drastically thickened at ∼54 Ma, and gradually created what is now believed to be the thickest crust in the world.